NA
This industrial Safety Data Sheet provides health and safety information for occupational use only.
Company
:
Colgate
-
Palmolive Co
Telephone
Emergency telephone
Medical Emergency
Signal word
: Danger
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name
Product code : 200000022795
: B02930530004
Manufacturer or supplier's details
number
(24HR):
Recommended use of the chemical and restrictions on use
Recommended use
: PALMOLIVE ECO AUTO DISHWASHING GEL LEMON
SPLASH
300 Park Avenue
New York, NY 10022
: US: Consumer Affairs - 1-800-468-6502
: For emergencies involving spill, leak, fire, exposure or acci-
dent call CHEMTREC (24hr) at (800) 424-9300 or
(703) 527-3887.
For MEDICAL EMERGENCIES involving this product call:
(888) 489-3861
: A formulated dishwashing liquid
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Physical state
Colour
GHS Classification
Skin corrosion
Serious eye damage
GHS Label element
Hazard pictograms
Hazard statements : H314 Causes severe skin burns and eye damage.
liquid
white
: Category 1
: Category 1
:
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This industrial Safety Data Sheet provides health and safety information for occupational use only.
Prevention
:
IARC
No component of this product present at levels greater than or
ACGIH
OSHA
NTP
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
H318 Causes serious eye damage.
Precautionary statements
Potential Health Effects
Inhalation
Skin
Eyes
Ingestion
Aggravated Medical Condi-
tion
Carcinogenicity:
:
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P310 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Imme-
diately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/ physician.
P363 Wash contaminated clothing before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
: Overexposure may cause respiratory tract irritation.
: May cause skin irritation upon prolonged contact.
: Causes eye irritation on direct contact.
: Harmful if swallowed.
: None known.
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
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Chemical Name
CAS-No. Concentration
(%) SODIUM CARBONATE
497-19-8 >= 5 - < 10
Hazardous combustion pro
d-
No hazardous combustion products are known
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
SODIUM SILICATE 1344-09-8 >= 1 - < 5
SODIUM HYPOCHLORITE 7681-52-9 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
If inhaled
In case of skin contact
In case of eye contact
If swallowed
Most important symptoms
and effects, both acute and
delayed
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car-
ucts
Special protective equipment
for firefighters
: Remove victim to fresh air. Get medical attention, if symp-
toms persist.
: Flush skin with large amounts of water. If irritation develops
and persists, get medical attention.
: Flush eyes with water at least 15 minutes. Get medical atten-
tion if eye irritation develops or persists.
: Drink 8 ounces of clear water. Get medical attention.
: Causes serious eye damage.
Causes severe burns.
bon dioxide.
:
: Self-contained breathing apparatus and full protective clothing
should be worn when fighting chemical fires.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Methods and materials for
containment and cleaning up
: Use personal protection recommended in Section 8 of the
SDS.
: Cover with inert, absorbent material and remove to disposal
container. Spill area may be slippery. Flush with plenty of wa-
ter.
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Components
CAS-No. Value type
Control param
e-
Basis
Engineering measures
:
Respiratory protection
: No personal respiratory protective equipment normally r
e-
Hygiene measures
In an
industrial work environment, avoid eye and prolonged
Density
1.16 g/cm3
Incompatible materials
Strong oxidizing agents
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
SECTION 7. HANDLING AND STORAGE
Conditions for safe storage : Store at controlled room temperature at 20-25°C (68-77°F).
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
(Form of
exposure)
SODIUM HYPOCHLORITE 7681-52-9 STEL 2 mg/m3 US WEEL
In an industrial work environment, no special precautions or
control measures are required.
Personal protective equipment
quired.
Protective measures
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Colour
pH
Flash point
: In an industrial work environment, if a splash is likely, chemi-
cal goggles may be needed. Prolonged skin contact may
require protective gloves. For consumer use, no unusual
precautions are necessary.
:
skin contact.
: liquid
: white
: 12.5
: > 100 °C
:
ters / Permissible
concentration
SECTION 10. STABILITY AND REACTIVITY
Possibility of hazardous reactions
Hazardous decomposition
products
: Hazardous polymerisation does not occur.
:
: None known.
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This industrial Safety Data Sheet provides health and safety information for occupational use only.
Acute oral toxicity
Acute toxicity estimate
: > 5,000 mg/kg
Acute dermal toxicity
Acute toxicity estimate
: > 5,000 mg/kg
Acute inhalation toxicity
Remarks
:
No data available
Acute inhalation toxicity
LC50
(Rabbit
):
> 10.5 mg/l
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Not classified based on available information.
Product:
:
Acute inhalation toxicity
Components:
SODIUM CARBONATE:
Acute oral toxicity
Acute inhalation toxicity
Acute dermal toxicity
SODIUM SILICATE:
Acute oral toxicity
Acute dermal toxicity
SODIUM HYPOCHLORITE:
Acute oral toxicity
Acute dermal toxicity
Skin corrosion/irritation
Causes severe burns.
Method: Calculation method
: Acute toxicity estimate : > 40 mg/l
Exposure time: 4 h
Test atmosphere: vapour
Method: Calculation method
:
Method: Calculation method
: LD50 (Rat): 2,800 mg/kg
: LC50 (Rabbit): 2.3 mg/l
Exposure time: 2 h
Test atmosphere: No information available.
Method: No information available.
: LD50 (Rabbit): > 2,000 mg/kg
Method: No information available.
: LD50 (Rat): 1,153 mg/kg
:
: LD50 (Rabbit): 4,640 mg/kg
Method: No information available.
: LD50 (Rat): 8,800 mg/kg
Method: OECD Test Guideline 401
:
Exposure time: 4 h
Test atmosphere: vapour
Method: OECD Test Guideline 403
: LD50 (Rabbit): > 20,000 mg/kg
Method: OECD Test Guideline 402
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This industrial Safety Data Sheet provides health and safety information for occupational use only.
Remarks
:
No data available
Result
:
Irritation to eyes, reversing within 21 days
Exposure routes
:
Inhalation
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
Components:
SODIUM CARBONATE:
SODIUM SILICATE:
Remarks: No data available
SODIUM HYPOCHLORITE:
Result: Corrosive after 3 minutes to 1 hour of exposure
Serious eye damage/eye irritation
Causes serious eye damage.
Components:
SODIUM CARBONATE:
SODIUM SILICATE:
Remarks: No data available
SODIUM HYPOCHLORITE:
Result: Irreversible effects on the eye
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Components:
SODIUM CARBONATE:
Exposure routes: Inhalation
Remarks: No data available
Exposure routes: Dermal
Remarks: No data available
SODIUM SILICATE:
Remarks: No data available
Exposure routes: Dermal
Remarks: No data available
SODIUM HYPOCHLORITE:
Exposure routes: Inhalation
Result: Does not cause respiratory sensitisation.
Exposure routes: Dermal
Result: Does not cause skin sensitisation.
Germ cell mutagenicity
Not classified based on available information.
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This industrial Safety Data Sheet provides health and safety information for occupational use only.
DOT :
TDG : Not regulated.
IATA
:
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Further information
Product:
Remarks: This product has not been tested as a whole. However, this formula was reviewed by
expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is
determined to be safe for its intended use. This review has taken into consideration available
safety-related information including information on individual ingredients, similar formulas and
potential ingredient interactions. This review is a component of the hazard determination used to
prepare the statements in Section 3 of the SDS.
SECTION 12. ECOLOGICAL INFORMATION
The product has not been tested as a whole for environmental toxicity. However, environmental
information on the ingredients in this product have been reviewed by the Environmental, Health and
Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This
evaluation is based on available information on individual ingredients, interactions of ingredients,
and similar ingredients. Biodegradability claims are supported by data on ingredients (i.e., surfactants
are biodegradable) or testing conducted on the final product (i.e., This product is biodegradable).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Any disposal practice must be in compliance with local, state
and federal laws and regulations (contact local or state envi-
ronment agency for specific rules). Do not dump in sewers,
any body of water or on the ground.
SECTION 14. TRANSPORT INFORMATION
Not regulated.
Not regulated.
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This industrial Safety Data Sheet provides health and safety information for occupational use only.
IMDG
:
OSHA Hazards
SARA 311/312
Hazards
SARA 302
SARA 313
Benzene
71-43-2
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
Not regulated.
International Regulation
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
SECTION 15. REGULATORY INFORMATION
: Harmful by ingestion., Severe skin irritant, Severe eye irritant
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
SODIUM HYPOCHLORITE 7681-52-9 100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
: Acute Health Hazard
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A:
SODIUM
HYPOCHLORITE
SODIUM HYDROXIDE 1310-73-2
ZINC CHLORIDE 7646-85-7
: No chemicals in this material are subject to the reporting re-
quirements of SARA Title III, Section 302.
: This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
7681-52-9
Calculated product RQ
(lbs)
The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table
117.3:
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ZINC CHLORIDE
7646
-85-7
Benzene
71-43-2
Benzene
71-43-2
SODIUM SILICATE
1344
-09-8
ZINC CHLORIDE
7646
-85-7
SODIUM CARBONATE
497-19-8
SODIUM HYPOCHLORITE
7681
-52-9
California Prop 65
:
TSCA
: All ingredients in this product are listed on the TSCA Inventory
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
SODIUM
HYPOCHLORITE
SODIUM HYDROXIDE 1310-73-2
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
Massachusetts Right To Know
Pennsylvania Right To Know
SODIUM HYPOCHLORITE 7681-52-9
WATER Water
SODIUM CARBONATE 497-19-8
SODIUM HYPOCHLORITE 7681-52-9
SODIUM HYDROXIDE 1310-73-2
SODIUM SULFATE 7757-82-6
7681-52-9
New Jersey Right To Know
The components of this product are reported in the following inventories:
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
WATER Water
SODIUM SILICATE 1344-09-8
SODIUM POLYACRYLATE 9003-04-7
This product does not contain any chemicals known to State
of California to cause cancer, birth defects, or any other reproductive harm.
or are not required to be listed on the TSCA Inventory.
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NFPA:
HMIS III:
1 0
1 0 3
PALMOLIVE ECO AUTO DISHWASHING GEL LEMON SPLASH
Version 1.0 SDS Number: 660000000234 Revision Date: 05/12/2015
SECTION 16. OTHER INFORMATION
Further information
HEALTH
FLAMMABILITY
PHYSICAL HAZARD
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
2
Special hazard.
Flammability
Instability
Health
Disclaimer: The information on this sheet is limited to the material identified and is believed by
the Colgate-Palmolive Company to be correct based on its knowledge and information as of
the date noted. Colgate makes no representation, guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss resulting from the use of the material.
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