Page 1
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
1/12
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Product name
:
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No.
4822-612)
Recommended use
:
Insect Repellent
Manufacturer, importer,
supplier
:
S.C. Johnson & Son, Inc.
1525 Howe Street
Racine WI 53403-2236
Telephone
:
+18005585252
Emergency telephone
number
:
24 Hour Medical Emergency Phone: (866)231-5406
24 Hour International Emergency Phone: (703)527-3887
24 Hour Transport Emergency Phone: (800)424-9300
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Globally Harmonized System (GHS) Classification
Hazard classification
Hazard category
Hazards identification
Eye irritation
Category 2B
Causes eye irritation.
Flammable liquids
Category 4
Combustible liquid.
Labelling
Hazard statements
Combustible liquid.
Causes eye irritation.
Precautionary statements
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
If eye irritation persists: Get medical advice/ attention.
Page 2
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
2/12
Store in a well-ventilated place. Keep cool.
Dispose of contents/ container to an approved incineration plant.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Wash hands thoroughly after handling.
Other hazards
:
None identified
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS-No.
Weight percent
p-Menthane-3,8-Diol
42822-86-6
10.00 - 30.00
Ethyl alcohol
64-17-5
5.00 - 10.00
propane-1,3-diol
504-63-2
1.00 - 5.00
The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
Eye contact
:
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/ attention.
Skin contact
:
If you suspect a reaction to this product, discontinue use and
remove contaminated clothing.
Inhalation
:
No special requirements.
Ingestion
:
No special requirements
5. FIREFIGHTING MEASURES
Suitable extinguishing
media
:
Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Page 3
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
3/12
Specific hazards during
firefighting
:
Flammable liquid. Vapors are heavier than air and may travel
to a source of ignition and flash back. Liquid run-off to sewers
may create fire/explosion hazard. Container may melt and leak
in heat of fire. Do not allow run-off from fire fighting to enter
drains or water courses.
Further information
:
Fight fire from maximum distance or protected area. Cool and
use caution when approaching or handling fire-exposed
containers. For large quantities of flammable liquids, consider
containment to prevent the spread of fire. Wear full protective
clothing and positive pressure self-contained breathing
apparatus. In case of fire and/or explosion do not breathe
fumes.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
:
Remove all sources of ignition.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Wear personal protective equipment.
Wash thoroughly after handling.
Environmental
precautions
:
Do not flush into surface water or sanitary sewer system.
Use appropriate containment to avoid environmental
contamination.
Outside of normal use, avoid release to the environment.
Methods and materials
for containment and
cleaning up
:
Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.
7. HANDLING AND STORAGE
Handling
Precautions for safe
handling
:
Avoid contact with eyes and lips.
For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Wash thoroughly after handling.
Page 4
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
4/12
Advice on protection
against fire and explosion
:
Keep away from sources of ignition - No smoking.
Storage
Requirements for storage
areas and containers
:
Keep container closed when not in use.
Keep away from food, drink and animal feedingstuffs.
Store in a well-ventilated place. Keep cool.
Other data
:
Stable at normal ambient temperature and pressure.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Components
CAS-No.
mg/m3
ppm
Non-
standard
units
Basis
Ethyl alcohol
64-17-5
1,900 mg/m3
1,000 ppm
-
OSHA TWA
Ethyl alcohol
64-17-5
-
1,000 ppm
- ACGIH
STEL
Personal protective equipment
Respiratory protection
:
Do not spray in enclosed areas.
Hand protection
:
No special requirements.
Eye protection
:
Safety glasses with side-shields
Skin and body protection
:
No special requirements.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Page 5
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
5/12
Form
:
liquid
Color
:
milky
Odor
:
Alcohol Odor
Odour Threshold
:
Test not applicable for this product type
pH
:
7
at (24.7 C)
see user defined free text
Melting point/freezing point
:
Test not applicable for this product type
Initial boiling point and
boiling range
:
74.5 C
Flash point
:
> 74.5 °C
> 166.1 °F
Evaporation rate
:
Test not applicable for this product type
Flammability (solid, gas)
:
Does not sustain combustion.
Upper/lower flammability or
explosive limits
:
Test not applicable for this product type
Vapour pressure
:
Test not applicable for this product type
Vapour density
:
Test not applicable for this product type
Relative density
:
0.9837 g/ml at 20 C
Page 6
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
6/12
Solubility(ies)
:
dispersible
Partition coefficient: noctanol/water
:
Test not applicable for this product type
Auto-ignition temperature
:
does not ignite
Decomposition temperature
:
Test not applicable for this product type
Viscosity, dynamic
:
1,387 cps
at 20.0 C
see user defined free text
Viscosity, kinematic
:
Test not applicable for this product type
Oxidizing properties
:
Volatile Organic
Compounds
Total VOC (wt. %)*
:
10.1 % - additional exemptions may apply
*as defined by US Federal and State Consumer Product
Regulations
Other information
:
None identified
:
10. STABILITY AND REACTIVITY
Possibility of hazardous
reactions
:
Stable under recommended storage conditions.
Conditions to avoid
:
Heat, flames and sparks.
Incompatible materials
:
Strong oxidizing agents
Do not mix with bleach or any other household cleaners.
Strong bases
Page 7
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
7/12
Hazardous decomposition
products
:
Thermal decomposition can lead to release of irritating gases
and vapours.
11. TOXICOLOGICAL INFORMATION
Emergency Overview
:
Warning
Acute oral toxicity
:
LD50 > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 > 10 mg/L
Acute dermal toxicity
:
LD50: > 5,000 mg/kg
GHS Properties
Classification
Routes of entry
Acute toxicity
No classification proposed
Oral
Acute toxicity
No classification proposed
Dermal
Acute toxicity
No classification proposed
Inhalation - Dust and Mist
Acute toxicity
No classification proposed
Inhalation - Vapour
Acute toxicity
No classification proposed
Inhalation - Gas
Skin corrosion/irritation
No classification proposed
-
Eye irritation
Category 2B -
Skin sensitisation
No classification proposed
-
Respiratory
sensitisation
No classification proposed
-
Germ cell mutagenicity
No classification proposed
-
Carcinogenicity
No classification proposed
-
Reproductive toxicity
No classification proposed
-
Page 8
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
8/12
Specific target organ
toxicity - single
exposure
No classification proposed
-
Specific target organ
toxicity - repeated
exposure
No classification proposed
-
Aspiration hazard
No classification proposed
-
Aggravated Medical
Condition
:
Do not apply to cuts or irritated skin.
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested.
Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.
Toxicity to fish
p-Menthane-3,8-Diol
semistatic test
LC50
Measured
OECD
Test
Guideline
203
Danio rerio (zebra fish)
62 mg/l
96 h
Ethyl alcohol
LC50
Fish
11,200
mg/l
96 h
propane-1,3-diol
Components
End point
Species
Value
Exposure
time
Page 9
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
9/12
Toxicity to aquatic invertebrates
p-Menthane-3,8-Diol
static test
EC50
Measured
OECD
Test
Guideline
202
Daphnia magna (Water
flea)
68 mg/l
48 h
Ethyl alcohol
static test
LC50
Ceriodaphnia dubia
5,012 mg/l
48 h
NOEC
Daphnia magna
9.6 mg/l
9 d
propane-1,3-diol
Toxicity to aquatic plants
p-Menthane-3,8-Diol
EC50
Measured
Desmodesmus
subspicatus (green algae)
52 mg/l
72 h
Ethyl alcohol
Static
EC50
Chlorella vulgaris (Fresh
water algae)
275 mg/l
72 h
Components
End point
Species
Value
Exposure
time
Components
End point
Species
Value
Exposure
time
Page 10
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
10/12
propane-1,3-diol
No data
available
Persistence and degradability
Component
Biodegradation
Exposure
time
Summary
p-Menthane-3,8-Diol
75 %
28 d
Readily biodegradable
Ethyl alcohol
97 %
28 d
Readily biodegradable
propane-1,3-diol
No data available
Bioaccumulative potential
Component
Bioconcentration
factor (BCF)
Partition Coefficient nOctanol/water (log)
p-Menthane-3,8-Diol
14.95 estimated
1.8 - 4.0
Ethyl alcohol
3.2 estimated
-0.35 Measured
propane-1,3-diol
No data available
No data available
Mobility
Component
End point
Value
p-Menthane-3,8-Diol
No data available
Ethyl alcohol
No data available
propane-1,3-diol
No data available
PBT and vPvB assessment
Component
Results
p-Menthane-3,8-Diol
Not fulfilling PBT and vPvB criteria
Ethyl alcohol
Not fulfilling PBT and vPvB criteria
Other adverse effects
:
None known.
Page 11
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
11/12
13. DISPOSAL CONSIDERATIONS
PESTICIDAL WASTE:
For disposal information, please read and follow Disposal
instructions on the pesticide label.
Consumer may discard empty container in trash, or recycle
where facilities exist.
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
Land transport
Not classified as dangerous in the meaning of transport regulations.
Sea transport
Not classified as dangerous in the meaning of transport regulations.
Air transport
Not classified as dangerous in the meaning of transport regulations.
15. REGULATORY INFORMATION
Notification status
:
All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.
California Prop. 65
:
This product is not subject to the reporting requirements under
California's Proposition 65.
Page 12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
OFF! BOTANICALS INSECT REPELLENT IV (EPA Reg. No. 4822-612)
Version 1.0
Print Date 01/12/2018
Revision Date 03/21/2017
SDS Number 350000032739
GEN_SOF Number 45293
12/12
16. OTHER INFORMATION
HMIS Ratings
Health
1
Flammability
2
Reactivity
0
NFPA Ratings
Health
1
Fire
2
Reactivity
0
Special
-
This information is being provided in accordance with the Occupational Safety and Health Administration
(OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where
product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
This document has been prepared using data from sources considered to be technically reliable. It does
not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.
Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available
information when using product for any particular use and to comply with all Federal, State, Provincial
and Local laws and regulations.
Prepared by
SC Johnson Global Safety Assessment &
Regulatory Affairs (GSARA)
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