OFF 629374 User Manual

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Product name

:

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT
II

Recommended use

:

Insect Repellent

Manufacturer, importer,
supplier

:

S.C. Johnson & Son, Inc.
1525 Howe Street
Racine WI 53403-2236

Telephone

:

[phone]

Emergency telephone
number

:

24 Hour Medical Emergency Phone: [phone]

24 Hour International Emergency Phone: [phone]
24 Hour Transport Emergency Phone: [phone]

Hazard classification

Hazard category

Hazards identification

Aerosol

Category 1

Extremely flammable aerosol.

Eye irritation

Category 2A

Causes serious eye irritation.

Gases under pressure

Liquefied gas

Contains gas under pressure;
may explode if heated.

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

1. PRODUCT AND COMPANY IDENTIFICATION

Product information

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Globally Harmonized System (GHS) Classification

Labelling
Hazard symbols

Flame
Gas cylinder
Exclamation mark

Signal word
Danger

Hazard statements

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.

Precautionary statements

1/14

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Other hazards

:

None identified

Chemical Name

CAS-No.

Weight percent

Ethyl alcohol

64-17-5

30.00 - 60.00

N,N-Diethyl-m-toluamide

134-62-3

30.00 - 60.00

Butane

106-97-8

1.00 - 5.00

Propane

74-98-6

1.00 - 5.00

Isobutane

75-28-5

1.00 - 5.00

Eye contact

:

IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/ attention.

Skin contact

:

If you suspect a reaction to this product, discontinue use and
remove contaminated clothing.

Inhalation

:

No special requirements.

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
If eye irritation persists: Get medical advice/ attention.
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Protect from sunlight. Store in a well-ventilated place.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Do not pierce or burn, even after use.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Wash hands thoroughly after handling.

3. COMPOSITION/INFORMATION ON INGREDIENTS

The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Ingestion

:

No special requirements

Suitable extinguishing
media

:

Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.

Specific hazards during
firefighting

:

Aerosol Product - Containers may rocket or explode in heat of
fire. Do not allow run-off from fire fighting to enter drains or
water courses.

Further information

:

Fight fire from maximum distance or protected area. Cool and
use caution when approaching or handling fire-exposed
containers. Wear full protective clothing and positive pressure
self-contained breathing apparatus. In case of fire and/or
explosion do not breathe fumes.

NFPA Classification

:

NFPA Level 2 Aerosol

Personal precautions

:

Remove all sources of ignition.
Wear personal protective equipment.
Wash thoroughly after handling.

Environmental
precautions

:

Do not flush into surface water or sanitary sewer system.
Use appropriate containment to avoid environmental
contamination.
Outside of normal use, avoid release to the environment.

Methods and materials
for containment and
cleaning up

:

If damage occurs to aerosol can:
Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

5. FIREFIGHTING MEASURES

6. ACCIDENTAL RELEASE MEASURES

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Precautions for safe
handling

:

Avoid contact with eyes and lips.
For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Pressurized container.
Do not pierce or burn, even after use.
Wash thoroughly after handling.

Advice on protection
against fire and explosion

:

Keep away from sources of ignition - No smoking.
Do not spray on an open flame or other ignition source.

Requirements for storage
areas and containers

:

Protect from sunlight. Do not expose to temperatures
exceeding 50 °C/ 122 °F.
Keep away from food, drink and animal feedingstuffs.
Keep in a dry, cool and well-ventilated place.

Other data

:

Stable under recommended storage conditions.

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

7. HANDLING AND STORAGE

Handling

Storage

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Components

CAS-No.

mg/m3

ppm

Non-

standard

units

Basis

Ethyl alcohol

64-17-5

1,900 mg/m3

1,000 ppm

-

OSHA TWA

Ethyl alcohol

64-17-5

-

1,000 ppm

- ACGIH

STEL

Butane

106-97-8

-

1,000 ppm

- ACGIH

STEL

Propane

74-98-6

-

1,000 ppm

- ACGIH

TWA

Propane

74-98-6

1,800 mg/m3

1,000 ppm

-

OSHA TWA

Isobutane

75-28-5

-

1,000 ppm

- ACGIH

STEL

Respiratory protection

:

Do not spray in enclosed areas.

Hand protection

:

No special requirements.

Eye protection

:

Safety glasses with side-shields

Skin and body protection

:

No special requirements.

Hygiene measures

:

Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.

Form

:

aerosol

Color

:

clear

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

Personal protective equipment

9. PHYSICAL AND CHEMICAL PROPERTIES

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Odor

:

characteristic

Odour Threshold

:

No data available

pH

:

Not applicable

Melting point/freezing point

:

Not applicable

Initial boiling point and
boiling range

:

No data available

Flash point

:

< -7 °C
< 19.4 °F
Method: Tag Closed Cup (TCC)
Propellant

Evaporation rate

:

No data available

Flammability (solid, gas)

:

Sustains combustion

Upper/lower flammability or
explosive limits

:

No data available
Vapour pressure

:

No data available

Vapour density

:

No data available
Relative density

:

0.84 g/cm3 at 21 °C

Solubility(ies)

:

slightly soluble

Partition coefficient: n­octanol/water

:

No data available

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

6/14

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Auto-ignition temperature

:

No data available

Decomposition temperature

:

No data available
Viscosity, dynamic

:

Viscosity, kinematic

:

No data available

Oxidizing properties

:

No data available

Volatile Organic
Compounds
Total VOC (wt. %)*

:

65 % - additional exemptions may apply
*as defined by US Federal and State Consumer Product
Regulations

Other information

:

None identified

:

No data available

Possibility of hazardous
reactions

:

Stable under recommended storage conditions.

Conditions to avoid

:

Heat, flames and sparks.

Incompatible materials

:

Strong oxidizing agents

Hazardous decomposition
products

:

Thermal decomposition can lead to release of irritating gases
and vapours.

Emergency Overview

:

Danger

Acute oral toxicity

:

LD50

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

2,329 mg/kg

Acute inhalation toxicity

:

GHS LC50 (dust and mist)
estimated
> 2.25 mg/l

Acute dermal toxicity

:

LD50
estimated
> 5,000 mg/kg

GHS Properties

Classification

Routes of entry

Acute toxicity

No classification proposed

-

Skin corrosion/irritation

No classification proposed

-

Eye irritation

Category 2A -

Skin sensitisation

No classification proposed

-

Respiratory
sensitisation

No classification proposed

-

Germ cell mutagenicity

No classification proposed

-

Carcinogenicity

No classification proposed

-

Reproductive toxicity

No classification proposed

-

Specific target organ
toxicity - single
exposure

No classification proposed

-

Specific target organ
toxicity - repeated
exposure

No classification proposed

-

Aspiration hazard

No classification proposed

-

Aggravated Medical
Condition

:

Do not apply to cuts or irritated skin.

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

12. ECOLOGICAL INFORMATION

Product : The product itself has not been tested.

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Ethyl alcohol

flow­through
test LC50

Pimephales promelas
(fathead minnow)

14,200
mg/l

96 h
N,N-Diethyl-m-toluamide

static test
LC50

Oncorhynchus mykiss
(rainbow trout)

71.25 mg/l

96 h
Butane

No data
available

Propane

LC50

Fish

27.98 mg/l

96 h

Isobutane

LC50

Fish

27.98 mg/l

96 h

Ethyl alcohol

static test
EC50

Daphnia magna (Water
flea)

2 mg/l

48 h

Components

End point

Species

Value

Exposure
time

Components

End point

Species

Value

Exposure
time

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

Toxicity

The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.

Toxicity to fish

Toxicity to aquatic invertebrates

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

NOEC

Daphnia magna

9.6 mg/l

9 d

N,N-Diethyl-m-toluamide

No data
available

Butane

No data
available

Propane

LC50

Daphnid

14.22 mg/l

48 h

Isobutane

LC50

Daphnid

16.33 mg/l

48 h

Ethyl alcohol

Static
EC50

Chlorella vulgaris (Fresh
water algae)

275 mg/l

72 h
N,N-Diethyl-m-toluamide

No data
available

Butane

No data
available

Propane

No data
available

Isobutane

EC50

Green algea

8.57 mg/l

96 h

Component

Biodegradation

Exposure
time

Summary

Ethyl alcohol

97 %

28 d

Readily biodegradable
N,N-Diethyl-m-toluamide

No data available

Butane

100 %

385.5 h

Readily biodegradable

Components

End point

Species

Value

Exposure
time

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

Toxicity to aquatic plants

Persistence and degradability

10/14

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Propane

70 %

< 10 d

Readily biodegradable

Isobutane

70 %

< 10 d

Readily biodegradable

Component

Bioconcentration

factor (BCF)

Partition Coefficient n-

Octanol/water (log)

Ethyl alcohol

3.2 estimated

-0.35 Measured

N,N-Diethyl-m-toluamide

No data available

No data available

Butane

No data available

2.89

Propane

No data available

2.36

Isobutane

1.57 - 1.97

2.8

Component

End point

Value

Ethyl alcohol

No data available

N,N-Diethyl-m-toluamide

No data available

Butane

No data available

Propane

No data available

Isobutane

No data available

Component

Results

Ethyl alcohol

Not fulfilling PBT and vPvB criteria

N,N-Diethyl-m-toluamide

Not fulfilling PBT and vPvB criteria

Butane

Not fulfilling PBT and vPvB criteria

Propane

Not fulfilling PBT and vPvB criteria

Isobutane

Not fulfilling PBT and vPvB criteria

Other adverse effects

:

None known.

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

Bioaccumulative potential

Mobility

PBT and vPvB assessment

11/14

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

PESTICIDAL WASTE:
For disposal information, please read and follow Disposal
instructions on the pesticide label.
Consumer may discard empty container in trash, or recycle
where facilities exist.

Land transport

Sea transport

Air transport

UN number

1950

1950

1950

UN proper
shipping name

AEROSOLS,
Flammable, 2.1

AEROSOLS,
Flammable, 2.1

AEROSOLS,
Flammable, 2.1

Transport hazard
class(es)

2.1 2 2.1

Packing group

- - -

Environmental
hazards

-

- -

Special
precautions for
user

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

Limited quantities
derogation may be
applicable to this
product, please
check transport
documents.

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

15. REGULATORY INFORMATION

FIFRA Labeling

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to
certain labeling requirements under federal pesticide law. These requirements differ from the
classification criteria and hazard information required for safety data sheets, and for workplace labels of
non-pesticide chemicals.
Following is the hazard information as required on the pesticide label:

12/14

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Notification status

:

All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

Notification status

:

All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental
Protection Act (CEPA).

California Prop. 65

:

This product is not subject to the reporting requirements under
California's Proposition 65.

Registration # / Agency

4822-397/US/EPA

Health

2

Flammability

4

Reactivity

0

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

WARNING:
Causes substantial but temporary eye injury.
Harmful if swallowed.
Use of this product may cause skin reactions in rare cases.
Flammable.
Contents under pressure.
Exposure to temperatures above 120° F may cause bursting.

16. OTHER INFORMATION

HMIS Ratings

13/14

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 1.1

Print Date 03/04/2015

Revision Date 02/23/2015

SDS Number 350000004808
GEN_SOF Number 16144

Health

2

Fire

4

Reactivity

0

Special

-

Prepared by

SC Johnson Global Safety Assessment &
Regulatory Affairs (GSARA)

OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT II

NFPA Ratings

This information is being provided in accordance with the Occupational Safety and Health Administration
(OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where
product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information

This document has been prepared using data from sources considered to be technically reliable. It does
not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.
Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available
information when using product for any particular use and to comply with all Federal, State, Provincial
and Local laws and regulations.

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