OFF 616304 User Manual

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

1. PRODUCT AND COMPANY IDENTIFICATION
Product information

Product name
Recommended use

Manufacturer, importer,
supplier

Telephone
Emergency telephone
number

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Globally Harmonized System (GHS) Classification
Hazard classification Hazard category Hazards identification

Aerosol Category 1 Extremely flammable aerosol.
Eye irritation Category 2A Causes serious eye irritation.
Gases under pressure Liquefied gas Contains gas under pressure;

Labelling
Hazard symbols

Flame
Gas cylinder
Exclamation mark

Signal word
Danger

Hazard statements

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.

: OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

: Insect Repellent

: S.C. Johnson & Son, Inc.

1525 Howe Street
Racine WI 53403-2236

: [phone]
: 24 Hour Medical Emergency Phone: [phone]

24 Hour International Emergency Phone: [phone]
24 Hour Transport Emergency Phone: [phone]

may explode if heated.

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

Precautionary statements

If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
If eye irritation persists: Get medical advice/ attention.
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Protect from sunlight. Store in a well-ventilated place.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Do not spray on an open flame or other ignition source.
Do not pierce or burn, even after use.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Wash hands thoroughly after handling.

Other hazards

: None identified

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. Weight percent
N,N-Diethyl-m-toluamide 134-62-3 10.00 - 30.00
Ethyl alcohol 64-17-5 10.00 - 30.00
Butane 106-97-8 10.00 - 30.00
Corn starch 9005-25-8 10.00 - 30.00
Propane 74-98-6 5.00 - 10.00
Isobutane 75-28-5 5.00 - 10.00
Isopropyl Myristate 110-27-0 1.00 - 5.00
Magnesium carbonate 546-93-0 1.00 - 5.00

The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES
Eye contact

: IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/ attention.

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

Skin contact

Inhalation
Ingestion

5. FIREFIGHTING MEASURES

: If you suspect a reaction to this product, discontinue use and

remove contaminated clothing.
: No special requirements.
: No special requirements

Suitable extinguishing
media

Specific hazards during
firefighting

Further information

NFPA Classification

6. ACCIDENTAL RELEASE MEASURES
Personal precautions

Environmental
precautions

Methods and materials
for containment and
cleaning up

: Use water spray, alcohol-resistant foam, dry chemical or

carbon dioxide.

: Aerosol Product - Contain ers may rocket or explode in heat of

fire. Do not allow run-off from fire fighting to enter drains or
water courses.

: Fight fire from maximum distance or protected area. Cool and

use caution when approaching or handling fire-exposed
containers. Wear full protective clothing and positive pressure
self-contained breathing apparatus. In case of fire and/or
explosion do not breathe fumes.

: NFPA Level 2 Aerosol

: Remove all sources of ignition.

Wear personal protective equipment.
Wash thoroughly after handling.

: Do not flush into surface water or sanitary sewer system.

Use appropriate containment to avoid environmental
contamination.
Outside of normal use, avoid release to the environment.

: If damage occurs to aerosol can:

Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.

7. HANDLING AND STORAGE
Handling

Precautions for safe
handling

Advice on protection
against fire and explosion

Storage
Requirements for storage

areas and containers

: Avoid contact with eyes and lips.

For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Pressurized container.
Do not pierce or burn, even after use.
Wash thoroughly after handling.

: Keep away from sources o f ignition - No smoking.

Do not spray on an open flame or other ignition source.

: Protect from sunlight. Do not expose to temperatures

exceeding 50 °C/ 122 °F.
Keep away from food, drink and animal feedingstuffs.
Keep in a dry, cool and well-ventilated place.

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits

Components CAS-No. mg/m3

Ethyl alcohol 64-17-5 1,900 mg/m3 1,000 ppm
Ethyl alcohol 64-17-5 - 1,000 ppm

Butane 106-97-8 - 1,000 ppm

Corn starch 9005-25-8 5 mg/m3
Corn starch 9005-25-8 15 mg/m3
Corn starch 9005-25-8 10 mg/m3

Propane 74-98-6 1,800 mg/m3 1,000 ppm
Propane 74-98-6 - -

Isobutane 75-28-5 - 1,000 ppm

Magnesium
carbonate
Magnesium
carbonate

Personal protective equipment

546-93-0 15 mg/m3 ­546-93-0 5 mg/m3 -

ppm

-

-

-

Non-

standard

units

-

-

-

-

-

-

-

-

-

-

-

Basis

OSHA TWA

ACGIH

STEL

ACGIH

STEL
OSHA TWA
OSHA TWA

ACGIH

TWA

OSHA TWA

ACGIH

TWA

ACGIH

STEL
OSHA TWA
OSHA TWA

Respiratory protection
Hand protection
Eye protection

: Do not spray in enclosed areas.
: No special requirements.

: Safety glasses with side-shields

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

Skin and body protection
Hygiene measures

9. PHYSICAL AND CHEMICAL PROPERTIES
Form
Form
Color
Odor

Odour Threshold

pH

Melting point/freezing point
Initial boiling point and

boiling range
Flash point

Evaporation rate

Flammability (solid, gas)

Upper/lower flammability or
explosive limits

: No special requirements.
: Handle in accordance with good industrial hygiene and safety

practice. Wash thoroughly after handling.

: aerosol
: Compressed gas
: white
: pleasant

: No data available

: 10.3

(as aqueous solution)

: No data available
: No data available

: < -7 °C

< 19.4 °F
Propellant

: No data available

: Sustains combustion

: No data available

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

Vapour pressure

Vapour density

Relative density
Solubility(ies)

Partition coefficient: n­octanol/water

Auto-ignition temperature

Decomposition temperature

Viscosity, dynamic

Viscosity, kinematic

Oxidizing properties
Volatile Organic

Compounds
Total VOC (wt. %)*

Other information

: No data available

: No data available

: 0.82 g/cm3
: dispersible

: No data available

: No data available

: Test not applicable for this product type

: No data available

: No data available

: No data available
: 52.6 % - additional exemptions may apply

*as defined by US Federal and State Consumer Product
Regulations

: None identified :

10. STABILITY AND REACTIVITY

Possibility of hazardous

: If accidental mixing occurs and toxic gas is formed, exit area

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

reactions

Conditions to avoid

Incompatible materials

Hazardous decomposition
products

11. TOXICOLOGICAL INFORMATION

immediately. Do not return until well ventilated.

: Heat, flames and sparks.

: Strong oxidizing agents

Do not mix with bleach or any other household cleaners.
Strong bases

: Thermal decomposition can lead to release of irritating gases

and vapours.

Emergency Overview
Acute oral toxicity

Acute inhalation toxicity
Acute dermal toxicity

: Danger
:

:
:

GHS Properties Classification Routes of entry

Acute toxicity No classification proposed
Skin corrosion/irritation No classification proposed
Eye irritation Category 2A
Skin sensitisation No classification proposed
Respiratory

sensitisation
Germ cell mutagenicity No classification proposed

Carcinogenicity No classification proposed
Reproductive toxicity No classification proposed
Specific target organ No classification proposed -

No classification proposed

-

-

-

-

-

-

-

-

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

toxicity - single
exposure

Specific target organ
toxicity - repeated
exposure

Aspiration hazard No classification proposed

Aggravated Medical
Condition

12. ECOLOGICAL INFORMATION

No classification proposed

: Do not apply to cuts or irritated skin.

-

-

Product : The product itself has not been tested.
Toxicity

The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.

Toxicity to fish

Components End point Species Value Exposure

time

N,N-Diethyl-m-toluamide static test

LC50

Oncorhynchus mykiss
(rainbow trout)

Ethyl alcohol LC50 Fish 11,200

Butane LC50

QSAR

Fish 27.98 mg/l

Corn starch static test

LC50
Measured
No
informatio
n

Fish 5,000 mg/l

71.25 mg/l

mg/l

96 h

96 h

96 h

96 h

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

available.

Propane LC50 Fish 27.98 mg/l

Isobutane LC50

QSAR

Fish 27.98 mg/l

Isopropyl Myristate

LC50

Danio rerio (zebra fish) 8,400 mg/l

Magnesium carbonate static test

LC50

Pimephales promelas
(fathead minnow)

Toxicity to aquatic invertebrates

2,800 mg/l

96 h

96 h

96 h

96 h

Components End point Species Value Exposure

N,N-Diethyl-m-toluamide LC50

semi-

static test
NOEC
Measured
OECD
Guideline
211
(Daphnia
magna
Reproduct
ion Test)

Ethyl alcohol static test

LC50

Daphnia magna (Water
flea)

Daphnia magna 3.7 mg/l 21 d

Ceriodaphnia dubia

10/16

75 mg/l

time

51 h

48 h

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

NOEC Daphnia magna 9.6 mg/l 9 d

5,012 mg/l

Butane No data

available

Corn starch No data

Propane LC50

available

Isobutane LC50

QSAR

Daphnid

Daphnid

Isopropyl Myristate EC50 Daphnia magna (Water

flea)

Magnesium carbonate No data

Toxicity to aquatic plants

available

14.22 mg/l

48 h

16.33 mg/l

48 h

100 mg/l 48 h

Components End point Species Value Exposure

N,N-Diethyl-m-toluamide NOEC Pseudokirchneriella

subcapitata (green algae)

Ethyl alcohol Static

EC50

Chlorella vulgaris (Fresh
water algae)

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0.521 mg/l 96 h

275 mg/l 72 h

time

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

Butane EC50

QSAR

Corn starch No data

available

Propane No data

available

Isobutane EC50

QSAR

Isopropyl Myristate EC50

Magnesium carbonate static test

EC50
Read­across
(Analogy)

Persistence and degradability

Component Biodegradation Exposure

N,N-Diethyl-m-toluamide 83.8 % 28 d Readily biodegradable
Ethyl alcohol 97 % 28 d Readily biodegradable
Butane 100 % 385.5 h Readily biodegradable
Corn starch No data available Readily biodegradable
Propane 70 % < 10 d Readily biodegradable
Isobutane 70 % < 10 d Readily biodegradable
Isopropyl Myristate 91.4 % 28 d
Magnesium carbonate No data available

Bioaccumulative potential

Component Bioconcentration Partition Coefficient n-

Green algae

Green algae

Desmodesmus
subspicatus

Desmodesmus
subspicatus (green algae)

time

7.71 mg/l 96 h

8.57 mg/l 96 h

> 100
mg/l

> 100
mg/l

Summary

Readily biodegradable

72 h

72 h

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

factor (BCF) Octanol/water (log)

N,N-Diethyl-m-toluamide 21.9 estimated 2.4
Ethyl alcohol 3.2 estimated -0.35 Measured
Butane No data available 2.89
Corn starch No data available No data available

Propane No data available 2.36
Isobutane 1.57 - 1.97 2.8
Isopropyl Myristate 1,220.1 7.71
Magnesium carbonate 0.89 QSAR -2.12 QSAR

Mobility

Component End point Value

N,N-Diethyl-m-toluamide Koc
Ethyl alcohol No data available

Butane No data available
Corn starch No data available
Propane No data available
Isobutane No data available
Isopropyl Myristate log Koc 4.08
Magnesium carbonate No data available

PBT and vPvB assessment

Component Results

N,N-Diethyl-m-toluamide Not fulfilling PBT and vPvB criteria
Ethyl alcohol Not fulfilling PBT and vPvB criteria
Butane Not fulfilling PBT and vPvB criteria
Corn starch Not fulfilling PBT and vPvB criteria
Propane Not fulfilling PBT and vPvB criteria
Isobutane Not fulfilling PBT and vPvB criteria
Isopropyl Myristate Not fulfilling PBT and vPvB criteria

43.3

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

Magnesium carbonate Not fulfilling PBT and vPvB criteria

Other adverse effects :

13. DISPOSAL CONSIDERATIONS

No data available

PESTICIDAL WASTE:

For disposal information, please read and follow Disposal
instructions on the pesticide label.
Consumer may discard empty container in trash, or recycle
where facilities exist.

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

UN number

UN proper

shipping name
Transport hazard
class(es)
Packing group

Environmental
hazards

Special

precautions for

user

15. REGULATORY INFORMATION

Land transport Sea transport Air transport

1950 1950 1950
AEROSOLS,
Flammable

2.1 2 2.1

-

- - -

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

AEROSOLS,
Flammable

-

Limited quantities
derogation may be
applicable to this
product, please
check transport
documents.

AEROSOLS,
Flammable

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

-

FIFRA Labeling

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to
certain labeling requirements under federal pesticide law. These requirements differ from th e
classification criteria and hazard information required for safety data sheets, and for workplace labels of
non-pesticide chemicals.

Following is the hazard information as required on the pesticide label:
WARNING:

Causes substantial but temporary eye injury.
Harmful if swallowed.
Use of this product may cause skin reactions in rare cases.
Extremely flammable
Contents under pressure.
Exposure to temperatures above 120° F may cause bursting.

Notification status

Notification status

California Prop. 65

: All ingredients of this product are listed or are excluded from

listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

: All ingredients of this product comply with the New S ubstances

Notification requirements under the Canadian Environmental
Protection Act (CEPA).

: This product is not subject to the reporting requirements under

California's Proposition 65.

Registration # / Agency

4822-572/US/EPA
30598/PMRA

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VIII (DRY)

Version 2.0 Print Date 09/08/2016
Revision Date 07/12/2016 SDS Number 350000015104

16. OTHER INFORMATION

HMIS Ratings

Health
Flammability

2
4

Reactivity

NFPA Ratings

Health
Fire
Reactivity
Special

This information is being provided in accordance with the Occupational Safety and Health Administration
(OSHA) regulation (29 CFR 1910.1200). The information supplied is de signed for workplaces where
product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information

This document has been prepared using data from sources considered to be technically reliable. It does
not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.
Actual conditions of use are beyond the seller's control. User is responsible to evaluate all avai lable
information when using product for any particular use and to comply with all Federal, State, Provincial
and Local laws and regulations.

0

2
4
0

-

Prepared by SC Johnson Global Safety Assessment &

Regulatory Affairs (GSARA)

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