OFF 611090 User Manual

Page 1
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
Product name
:
OFF!® DEEP WOODS® SPORTSMEN INSECT REPELLENT I
Recommended use
:
Insect Repellent
Manufacturer, importer, supplier
:
S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236
Telephone
:
+18005585252
Emergency telephone number
:
24 Hour Medical Emergency Phone: (866)231-5406
24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300
Hazard classification
Hazard category
Hazards identification
Eye irritation
Category 2B
Causes eye irritation.
Other hazards
:
None identified
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Globally Harmonized System (GHS) Classification
Labelling Hazard statements
Causes eye irritation.
Precautionary statements
If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Wash hands thoroughly after handling.
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Page 2
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
Chemical Name
CAS-No.
Weight percent
N,N-Diethyl-m-toluamide
134-62-3
60.00 - 100.00
Eye contact
:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention.
Skin contact
:
If you suspect a reaction to this product, discontinue use and remove contaminated clothing.
Inhalation
:
No special requirements.
Ingestion
:
No special requirements
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during firefighting
:
Container may melt and leak in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses.
Further information
:
Fight fire from maximum distance or protected area. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.
3. COMPOSITION/INFORMATION ON INGREDIENTS
The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
5. FIREFIGHTING MEASURES
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Page 3
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
Personal precautions
:
Wear personal protective equipment. Wash thoroughly after handling.
Environmental precautions
:
Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment.
Methods and materials for containment and cleaning up
:
Dike large spills. Clean residue from spill site.
Precautions for safe handling
:
Avoid contact with eyes and lips. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Wash thoroughly after handling.
Advice on protection against fire and explosion
:
Normal measures for preventive fire protection.
Requirements for storage areas and containers
:
Keep container closed when not in use. Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place. Respiratory protection
:
Do not spray in enclosed areas.
6. ACCIDENTAL RELEASE MEASURES
7. HANDLING AND STORAGE
Handling
Storage
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above.
Personal protective equipment
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Page 4
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
Hand protection
:
No special requirements.
Eye protection
:
No special requirements.
Skin and body protection
:
No special requirements.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.
Form
:
liquid
Color
:
yellow
Odor
:
mild
Odour Threshold
:
pH
:
Not applicable
Melting point/freezing point
:
Initial boiling point and boiling range
:
545 °F
Flash point
:
> 148.8 °C > 299.84 °F Method: Tag Closed Cup (TCC)
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Upper/lower flammability or explosive limits
:
No data available
Vapour pressure
:
No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
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Page 5
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
Vapour density
:
No data available
Relative density
:
1 g/cm3
Solubility(ies)
:
negligible
Partition coefficient: n­octanol/water
:
No data available
Auto-ignition temperature
:
No data available
Decomposition temperature
:
No data available
Viscosity, dynamic
:
No data available
Viscosity, kinematic
:
No data available
Oxidizing properties
:
No data available
Volatile Organic Compounds Total VOC (wt. %)*
:
0 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
Other information
:
None identified
:
No data available
Possibility of hazardous reactions
:
Stable under recommended storage conditions.
Conditions to avoid
:
Direct sources of heat. Incompatible materials
:
None known.
10. STABILITY AND REACTIVITY
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Page 6
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
Hazardous decomposition products
:
Thermal decomposition can lead to release of irritating gases and vapours.
Emergency Overview
:
Warning
Acute oral toxicity
:
LD50 2,420 mg/kg
Acute inhalation toxicity
:
GHS LC50 (dust and mist)
5.95 mg/l
Acute dermal toxicity
:
LD50 4,223 mg/kg
GHS Properties
Classification
Routes of entry
Acute toxicity
No classification proposed
-
Skin corrosion/irritation
No classification proposed
-
Eye irritation
Category 2B -
Skin sensitisation
No classification proposed
-
Respiratory sensitisation
No classification proposed
-
Germ cell mutagenicity
No classification proposed
-
Carcinogenicity
No classification proposed
-
Reproductive toxicity
No classification proposed
-
Specific target organ toxicity - single exposure
No classification proposed
-
Specific target organ toxicity - repeated exposure
No classification proposed
- Aspiration hazard
No classification proposed
-
11. TOXICOLOGICAL INFORMATION
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Page 7
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
Aggravated Medical Condition
:
Do not apply to cuts or irritated skin.
N,N-Diethyl-m-toluamide
static test LC50
Oncorhynchus mykiss (rainbow trout)
71.25 mg/l
96 h N,N-Diethyl-m-toluamide
No data available
N,N-Diethyl-m-toluamide
No data available
Component
Biodegradation
Exposure time
Summary
N,N-Diethyl-m-toluamide
No data available
Component
Bioconcentration
Partition Coefficient n-
Components
End point
Species
Value
Exposure time
Components
End point
Species
Value
Exposure time
Components
End point
Species
Value
Exposure time
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested. Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions.
Toxicity to fish
Toxicity to aquatic invertebrates
Toxicity to aquatic plants
Persistence and degradability
Bioaccumulative potential
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Page 8
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
factor (BCF)
Octanol/water (log)
N,N-Diethyl-m-toluamide
No data available
No data available
Component
End point
Value
N,N-Diethyl-m-toluamide
No data available
Component
Results
N,N-Diethyl-m-toluamide
Not fulfilling PBT and vPvB criteria
Other adverse effects
:
None known.
PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist.
Mobility
PBT and vPvB assessment
13. DISPOSAL CONSIDERATIONS
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
Land transport
Not classified as dangerous in the meaning of transport regulations.
Sea transport
Not classified as dangerous in the meaning of transport regulations.
Air transport
Not classified as dangerous in the meaning of transport regulations.
15. REGULATORY INFORMATION
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Page 9
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
Notification status
:
All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Notification status
:
All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
California Prop. 65
:
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Registration # / Agency
4822-276/EPA
Health
2
Flammability
1
Reactivity
0
FIFRA Labeling
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
WARNING: Causes substantial but temporary eye injury. Harmful if swallowed. Use of this product may cause skin reactions in rare cases.
16. OTHER INFORMATION
HMIS Ratings
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Page 10
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/23/2015
SDS Number 350000003959
Health
2
Fire
1
Reactivity
0
Special
-
Prepared by
SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
NFPA Ratings
This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
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