Oatey 3466s, 3456s, 3446s, 3436s, 3424 DATA SHEET

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SAFETY DATA SHEET

1. Identification

Product identifier

Other means of identification

Synonyms

Recommended use

Recommended restrictions

Manufacturer/Importer/Supplier/Distributor information

Company Name

Address

Hot Blue Medium Bodied PVC Cement

3466s, 3456s, 3446s, 3436s, 3424

Joining PVC Pipes

None known.

Oatey Co.

4700 West 160th St.

Cleveland, OH 44135

Telephone

E-mail

Transport Emergency

Emergency First Aid

Contact person

2. Hazard(s) identification

Physical hazards

Health hazards

OSHA defined hazards

Label elements

Signal word

Hazard statement

Precautionary statement

Prevention

Response

216-267-7100

info@oatey.com

Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)

1-877-740-5015

MSDS Coordinator

Category 2Flammable liquids

Category 4Acute toxicity, oral

Category 2Skin corrosion/irritation

Category 2ASerious eye damage/eye irritation

Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure

Category 3 narcotic effectsSpecific target organ toxicity, single exposure

Category 1Aspiration hazard

Not classified.

Danger

Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist/vapors. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/eye protection/face protection.

If swallowed: Immediately call a poison center/doctor. Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. In case of fire: Use alcohol-resistant foam, carbon dioxide, dry powder or water fog for extinction.

Hot Blue Medium Bodied PVC Cement SDS US

949225 Version #: 01 Revision date: - Issue date: 28-May-2019

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Storage

Disposal

Hazard(s) not otherwise classified (HNOC)

Supplemental information

Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Dispose of contents/container in accordance with local/regional/national/international regulations.

Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen.

None.

3. Composition/information on ingredients

Mixtures

Composition comments

All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures

Inhalation

Skin contact

Eye contact

Ingestion

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed

General information

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell.

Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.

Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain.

Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed.

Take off all contaminated clothing immediately. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse.

CAS number %Chemical name

109-99-9 45 - 50Tetrahydrofuran

9002-86-2 15 - 20Polyvinyl chloride

108-94-1 10 - 15Cyclohexanone

78-93-3 10 - 15Methyl ethyl ketone

67-64-1 5 - 10Acetone

112945-52-5 1 - 5Fumed Silica

< 1

5. Fire-fighting measures

Suitable extinguishing media

Unsuitable extinguishing media

Specific hazards arising from the chemical

Special protective equipment and precautions for firefighters

Fire fighting equipment/instructions

Specific methods

General fire hazards

Hot Blue Medium Bodied PVC Cement SDS US

949225 Version #: 01 Revision date: - Issue date: 28-May-2019

Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).

Do not use water jet as an extinguisher, as this will spread the fire.

Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed.

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk.

Use standard firefighting procedures and consider the hazards of other involved materials.

Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age.

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6. Accidental release measures

U.S. - OSHA

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Personal precautions, protective equipment and emergency procedures

Methods and materials for containment and cleaning up

Environmental precautions

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist/vapors. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures against static discharge. Use only non-sparking tools. This product is miscible in water.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use water spray to reduce vapors or divert vapor cloud drift. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material. Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoid breathing mist/vapors. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.

Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits

TWA 0.8 mg/m3 Unspecified.Fumed Silica (CAS

112945-52-5)

STEL 5 ppmPolyvinyl chloride (CAS

9002-86-2)

TWA 1 ppm

PEL 2400 mg/m3Acetone (CAS 67-64-1)

PEL 200 mg/m3Cyclohexanone (CAS

108-94-1)

PEL 590 mg/m3Methyl ethyl ketone (CAS

78-93-3)

PEL 590 mg/m3Tetrahydrofuran (CAS

109-99-9)

ValueComponents Type

20 mppcf Unspecified.

ValueComponents Type

1000 ppm

50 ppm

200 ppm

Form

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US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueComponents Type

US. OSHA Table Z-3 (29 CFR 1910.1000)

US. ACGIH Threshold Limit Values

U.S. - NIOSH

US. NIOSH: Pocket Guide to Chemical Hazards

200 ppm

112945-52-5)

9002-86-2)

108-94-1)

78-93-3)

9002-86-2)

109-99-9)

ValueComponents Type

TWA 0.8 mg/m3Fumed Silica (CAS

20 mppcf

TWA 5 mg/m3 Respirable fraction.Polyvinyl chloride (CAS

15 mg/m3 Total dust.

50 mppcf Total dust.

15 mppcf Respirable fraction.

ValueComponents Type

STEL 500 ppmAcetone (CAS 67-64-1)

TWA 250 ppm

STEL 50 ppmCyclohexanone (CAS

TWA 20 ppm

STEL 300 ppmMethyl ethyl ketone (CAS

TWA 200 ppm

TWA 3 mg/m3 Respirable particles.Polyvinyl chloride (CAS

STEL 100 ppmTetrahydrofuran (CAS

TWA 50 ppm

Form

112945-52-5)

108-94-1)

112945-52-5)

78-93-3)

109-99-9)

ValueComponents Type

REL 6 mg/m3 Unspecified.Fumed Silica (CAS

ValueComponents Type

TWA 590 mg/m3Acetone (CAS 67-64-1)

250 ppm

TWA 100 mg/m3Cyclohexanone (CAS

25 ppm

TWA 6 mg/m3Fumed Silica (CAS

STEL 885 mg/m3Methyl ethyl ketone (CAS

300 ppm

TWA 590 mg/m3

200 ppm

STEL 735 mg/m3Tetrahydrofuran (CAS

250 ppm

TWA 590 mg/m3

Form

Hot Blue Medium Bodied PVC Cement SDS US

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US. NIOSH: Pocket Guide to Chemical Hazards

Biological limit values

ACGIH Biological Exposure Indices

with hydrolysis

ValueComponents Type

200 ppm

ValueComponents Determinant Specimen Sampling Time

Acetone (CAS 67-64-1)

Cyclohexanone (CAS 108-94-1)

25 mg/l Acetone Urine

80 mg/l 1,2-Cyclohexan

ediol,

with

hydrolysis

8 mg/l Cyclohexanol,

Methyl ethyl ketone (CAS

2 mg/l MEK Urine

78-93-3)

Tetrahydrofuran (CAS

2 mg/l TetrahydrofuranUrine

109-99-9) * - For sampling details, please see the source document.

Exposure guidelines

US - California OELs: Skin designation

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.

US - Minnesota Haz Subs: Skin designation applies

Cyclohexanone (CAS 108-94-1) Skin designation applies.

US - Tennessee OELs: Skin designation

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.

US ACGIH Threshold Limit Values: Skin designation

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Tetrahydrofuran (CAS 109-99-9) Can be absorbed through the skin.

US. NIOSH: Pocket Guide to Chemical Hazards

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.

Appropriate engineering controls

Explosion-proof general and local exhaust ventilation. Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station and safety shower.

Individual protection measures, such as personal protective equipment

Eye/face protection

Wear safety glasses with side shields (or goggles). Face shield is recommended.

Urine

Skin protection

Hand protection

Wear appropriate chemical resistant gloves. Other suitable gloves can be recommended by the glove supplier.

Skin protection

Other

Respiratory protection

Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.

If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn.

Thermal hazards

General hygiene considerations

Wear appropriate thermal protective clothing, when necessary.

When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state

Form

Color

Odor

Odor threshold

Hot Blue Medium Bodied PVC Cement SDS US

949225 Version #: 01 Revision date: - Issue date: 28-May-2019

Liquid.

Translucent liquid.

Blue.

Solvent.

Not available.

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Skin contact

Eye contact

redness and pain.

Acute toxicity

Melting point/freezing point

Initial boiling point and boiling range

Flash point

Evaporation rate

Flammability (solid, gas)

Upper/lower flammability or explosive limits

Flammability limit - lower (%)

Flammability limit - upper (%)

Explosive limit - lower (%)

Explosive limit - upper (%)

Vapor pressure

Vapor density

Relative density

Solubility(ies)

Solubility (water)

Partition coefficient (n-octanol/water)

Auto-ignition temperature

Decomposition temperature

Viscosity

Other information

Explosive properties

Oxidizing properties

VOC

Not available.

150.8 °F (66 °C)

-4.0 °F (-20.0 °C)

5.5 - 8

Not applicable.

1.8

11.8

Not available.

145 mm Hg @ 20 C

2.5

0.94 +/- 0.02

Negligible

Not available.

800 - 2200 cP

Not explosive.

Not oxidizing.

< 510 g/l SCAQMD 1168/M316A

10. Stability and reactivity

Reactivity

Chemical stability

Possibility of hazardous reactions

Conditions to avoid

Incompatible materials

Hazardous decomposition products

The product is stable and non-reactive under normal conditions of use, storage and transport.

Material is stable under normal conditions.

No dangerous reaction known under conditions of normal use.

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Acids. Strong oxidizing agents. Amines. Ammonia. Caustics. Isocyanates.

Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.

11. Toxicological information

Information on likely routes of exposure

Inhalation

Ingestion

Symptoms related to the physical, chemical and toxicological characteristics

Information on toxicological effects

May cause drowsiness and dizziness. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Prolonged inhalation may be harmful.

Causes skin irritation.

Causes serious eye irritation.

Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.

Harmful if swallowed. May be fatal if swallowed and enters airways.

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Acetone (CAS 67-64-1)

Respiratory sensitization

Acute

Dermal

LD50 Rabbit > 15700 mg/kg, 24 Hours

Inhalation

Vapor

LC50 Rat

Oral

LD50 Rat 5800 mg/kg

Cyclohexanone (CAS 108-94-1)

Acute

Inhalation

Vapor

LC50 Rat

Oral

LD50 Rat 2650 mg/kg

Methyl ethyl ketone (CAS 78-93-3)

Acute

Dermal

LD50 Rat 6400 mg/kg

Inhalation

Vapor

LC50 Rat

Oral

LD50 Rat 2600 mg/kg

Tetrahydrofuran (CAS 109-99-9)

Acute

Inhalation

LC50 Rat 53.9 mg/l, 4 Hours

Oral

LD50 Rat 1650 mg/kg

Test ResultsComponents Species

76 mg/l, 4 Hours

> 6.2 mg/l, 4 Hours

1890 mg/kg

1620 mg/kg

34.5 mg/l, 4 Hours

Skin corrosion/irritation

Serious eye damage/eye irritation

Respiratory or skin sensitization

Skin sensitization

Germ cell mutagenicity

Carcinogenicity

Hot Blue Medium Bodied PVC Cement SDS US

949225 Version #: 01 Revision date: - Issue date: 28-May-2019

Causes skin irritation.

Causes serious eye irritation.

Not a respiratory sensitizer.

This product is not expected to cause skin sensitization.

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Risk of cancer cannot be excluded with prolonged exposure. In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. This product contains polyvinyl chloride (PVC) that is not a fabricated product, and is therefore, defined and regulated as a toxic and hazardous substance under 29 C.F.R. §

1910.1017 due to the presumed presence of residual vinyl chloride monomer. The concentrations of residual vinyl chloride calculated to be contained in this product are well below the threshold for classification in accordance with 29 C.F.R. § 1910.1200.

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IARC Monographs. Overall Evaluation of Carcinogenicity

Aspiration hazard

Acute

Partition coefficient n-octanol / water (log Kow)

Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. Fumed Silica (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans. Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans. Tetrahydrofuran (CAS 109-99-9) 2B Possibly carcinogenic to humans.

NTP Report on Carcinogens

Not listed.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)

Polyvinyl chloride (CAS 9002-86-2) Cancer

Reproductive toxicity

Specific target organ toxicity -

This product is not expected to cause reproductive or developmental effects.

May cause respiratory irritation. May cause drowsiness and dizziness.

single exposure

Specific target organ toxicity -

Not classified.

repeated exposure

May be fatal if swallowed and enters airways.

Chronic effects

Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.

12. Ecological information

Ecotoxicity

Components Test ResultsSpecies

Acetone (CAS 67-64-1)

Aquatic

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Chronic

Cyclohexanone (CAS 108-94-1)

Aquatic

Methyl ethyl ketone (CAS 78-93-3)

Aquatic

Tetrahydrofuran (CAS 109-99-9)

Aquatic

Chronic

Persistence and degradability

Bioaccumulative potential

LC50Crustacea 8800 mg/l, 48 HoursDaphnia pulex

LC50Fish 7163 mg/l, 96 HoursPimephales promelas

NOECCrustacea > 79 mg/l, 21 daysDaphnia magna

LC50Fish 527 mg/l, 96 HoursPimephales promelas

EC50Crustacea 5091 mg/l, 48 HoursDaphnia magna

LC50Fish 3220 mg/l, 96 HoursPimephales promelas

LC50Crustacea 5930 mg/l, 24 HoursDaphnia magna

LC50Fish 2160 mg/l, 96 HoursPimephales promelas

NOECAlgae 3700 mg/l, 8 daysScenedesmus quadricauda

No data is available on the degradability of this product.

Acetone (CAS 67-64-1) -0.24 Cyclohexanone (CAS 108-94-1) 0.81 Methyl ethyl ketone (CAS 78-93-3) 0.29 Tetrahydrofuran (CAS 109-99-9) 0.46

Mobility in soil

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No data available.

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Other adverse effects

13. Disposal considerations

Disposal instructions

Local disposal regulations

Hazardous waste code

Waste from residues / unused products

Contaminated packaging

14. Transport information

DOT

UN number UN proper shipping name Transport hazard class(es)

Class Subsidiary risk

Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk

IATA

UN number UN proper shipping name Transport hazard class(es)

Class

Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user

IMDG

UN number UN proper shipping name Transport hazard class(es)

Class

Subsidiary risk Packing group Environmental hazards

Marine pollutant EmS Special precautions for user

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

The product contains volatile organic compounds which have a photochemical ozone creation potential.

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations.

Dispose in accordance with all applicable regulations.

The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

UN1133 Adhesives

3 II Read safety instructions, SDS and emergency procedures before handling. 149, B52, IB2, T4, TP1, TP8 150 173 242

UN1133 Adhesives

II No. 3L Read safety instructions, SDS and emergency procedures before handling.

UN1133 ADHESIVES

No. F-E, S-D Read safety instructions, SDS and emergency procedures before handling. Not established.

15. Regulatory information

US federal regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

Hot Blue Medium Bodied PVC Cement SDS US

949225 Version #: 01 Revision date: - Issue date: 28-May-2019

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

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CERCLA Hazardous Substance List (40 CFR 302.4)

Acetone (CAS 67-64-1) Listed. Cyclohexanone (CAS 108-94-1) Listed. Methyl ethyl ketone (CAS 78-93-3) Listed. Tetrahydrofuran (CAS 109-99-9) Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)

Polyvinyl chloride (CAS 9002-86-2) Cancer

Central nervous system Liver Blood Flammability

Toxic Substances Control Act (TSCA)

All components of the mixture on the TSCA 8(b) inventory are designated “active”.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous

Yes

chemical

Classified hazard