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SAFETY DATA SHEET
Physical hazards
Flammable liquids
Category 2
Health hazards
Acute toxicity, oral
Category 4
Skin corrosion/irritation
Category 2
Serious eye damage/eye irritation
Category 2A
Specific target organ toxicity, single exposure
Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure
Category 3 narcotic effects
Aspiration hazard
Category 1
OSHA defined hazards
Not Classified
Label elements
Signal word
Danger
Hazard statement
Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
May cause drowsiness or dizziness.
Precautionary statement
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a wellventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
Response
If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
1. Identification
Product identifier Oatey Clear Cleaner
Other means of identification
Product code 1400E
Synonyms Part Numbers: 30766, 30779, 30782, 30795, 30805, 32216, 32217, 32218, 32219
Recommended use Cleaning PVC, CPVC or ABS pipe and fittings
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company Name Oatey Inc.
Address 4700 West 160th Street
Cleveland, OH 44135
Telephone 216-267-7100
E-mail info@oatey.com
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator
2. Hazard(s) identification
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Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor
if you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical
advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash before reuse. In case of fire: Use appropriate media to extinguish.
Storage
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal
Dispose of contents/container in accordance with local/regional/national/international
regulations.
Hazard(s) not otherwise
classified (HNOC)
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
May form explosive peroxides.
3. Composition/information on ingredients
Chemical name
CAS number
%
Acetone
67-64-1
75-95
Cyclohexanone
108-94-1
1-5
Methy ethyl ketone
78-93-3
0-5
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.
Skin contact
Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Aspiration may cause
pulmonary edema and pneumonitis.
Most important
symptoms/effects, acute and
delayed
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe
eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Skin irritation. May cause redness and pain.
Indication of immediate medical
attention and special treatment
Needed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with
water immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
General information
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
Suitable extinguishing media
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a
source of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire-fighting
equipment/instructions
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can
do so without risk.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards
Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form
explosive organic peroxide when exposed to air or light or with age.
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out
of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate
area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist
Mixtures
*Designates that a specific chemical identity and or percentage of composition has been withheld as a trade secret.
4. First-aid measures
5. Fire-fighting measures
6. Accidental release measures
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or vapor. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Ventilate closed spaces before entering them. Local authorities should be
advised if significant spillages cannot be contained. For personal protection, see section 8 of the
SDS.
Methods and materials for
containment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep
combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in
water.
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet
to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up
the product and place into a container for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to
containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface
thoroughly to remove residual contamination.
Never return spills to original container for reuse. For waste disposal, see sect. 13 of the SDS.
Environmental precautions
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,
sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof
general and local exhaust ventilation. Take precautionary measures against static discharges.
All equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or
smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.
Observe good industrial hygiene practices.
Conditions for safe storage,
including any incompatibilities
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).
Occupational exposure limits
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Components
Type
Value FORM
Acetone (CAS 67-64-1)
PEL
2400 mg/m3
1000 ppm
Cyclohexanone (CAS 108-94-1)
PEL
200 mg/m3
50 ppm
Methyl ethyl ketone (CAS 78-93-3)
PEL
590 mg/m3
200 pp,
US. ACGIH Threshold Limit Values
Components
Type
Value FORM
Acetone (CAS 67-64-1)
STEL
TWA
750 ppm
500 ppm
Cyclohexanone (CAS 108-94-1)
STEL
50 ppm
Methyl ethyl ketone (CAS 78-93-3)
STEL
TWA
300 ppm
200 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
Value
8. Exposure controls/personal protection
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Acetone (CAS 67-64-1)
TWA
590 mg/m3
250 ppm
Cyclohexanone (CAS 108-94-1)
TWA
100 mg/m3
25 ppm
Methyl ethyl ketone (CAS 78-93-3)
STEL
TWA
885 mg/m3
300 ppm
590 mg/m3
200 ppm
Biological limit values
ACGIH Biological Exposure Indices
Components
Value
Determinant
Specimen
Sampling Time
Acetone (CAS 67-64-1)
50 mg/l
Acetone
Urine
*
Cyclohexanone (CAS 108-94-1)
80 mg/l
8 mg/l
1,2-Cyclohexanediol, with
hydrolysis
Cyclohexanol, with
hydrolysis
Urine
*
Methyl ethyl ketone (CAS 78-93-3)
2 mg/l
MEK
Urine
*
*- For sampling details, see the source document.
Exposure guidelines
US - California OELs: Skin designation
Cyclohexanone (CAS 108-94-1)
Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Cyclohexanone (CAS 108-94-1)
Skin designation applies.
US - Tennessee OELs: Skin designation
Cyclohexanone (CAS 108-94-1)
Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1)
Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1)
Can be absorbed through the skin.
Appropriate engineering
controls
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Skin protection
Hand
Wear appropriate chemical resistant gloves.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn..
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Liquid
Form
Liquid
Color
Clear
Odor
Solvent
Odor threshold
Not available.
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pH
Not Applicable
Melting point/freezing point
Not available.
Initial boiling point and boiling
range
151 °F (66.11 °C)
Flash point
0.0 – 4.0 °F (-18 to -15°C)
Evaporation rate
5.5 – 8
Upper/lower flammability or explosive limits
Flammability limit – lower (%)
2.0
Flammability limit – upper (%)
13.0
Explosive limit - lower (%)
Not Available
Explosive limit - upper (%)
Not Available
Vapor pressure
145 mmHg @ 20 C
Vapor density
2.5
Relative density
0.82 +/- 0.02
Solubility(ies)
Solubility (water)
Negligible
Partition coefficient
(n-octanol/water)
Not Available
Auto-ignition temperature
Not Available
Decomposition temperature
>150°C (>302°F)
Viscosity
Not Available
Other information
Bulk Density
6.8 lb/gal
VOC (Weight %)
20g/L SCAQMD 1168/M24
10. Stability and reactivity
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
reaction
No dangerous reaction known under conditions of normal use.
Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials
Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.
Hazardous decomposition
products
No hazardous decomposition products are known.
Information on likely routes of exposure
Inhalation
May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation
to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Prolonged inhalation may be harmful.
Skin contact
Causes skin irritation.
Eye contact
Causes serious eye irritation.
Ingestion
May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed.
Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a
serious chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe
eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of
overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Information on likely routes of exposure
Acute Toxicity
Components
Species
Results
Acetone (CAS 67-64-1)
Acute
Dermal
LD50
Inhalation
LC50
Oral
LD50
Rabbit
Rat
Rat
20 ml/kg
50 mg/l, 8 hours
58000 mg/kg
11. Toxicological information
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Cyclohexanone (108-94-1)
Acute
Dermal
LD50
Inhalation
LC50
Oral
LD50
Rabbit
Rat
Rat
948 mg/kg
8000 ppm, 4 hours
1540 mg/kg
*Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye
irritation
Causes serious eye irritation.
Respiratory or skin sensitization
Respiratory sensitization
Not available.
Skin sensitization
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
IARC Mongraphs. Overall Evaluation of Carcingenicity
Cyclohexanone (CAS 108-94-1)
Polyvinyl chloride (CAS 9002-86-2)
Silica, amorphous, fumed (CAS 112945-52-5)
3 Not classifiable as to carcinogenicity to humans.
3 Not classifiable as to carcinogenicity to humans.
3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Polyvinyl chloride (CAS 9002-86-2)
Cancer
Reproductive toxicity
This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity
Single exposure
Repeated exposure
Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.
Not Classified.
Aspiration Hazard
May be fatal if swallowed and enters airways.
Chronic effects
Prolonged inhalation may be harmful.
Further information
None noted.
12. Ecological information
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging
effect on the environment.
Components
Species
Results
Acetone (CAS 67-64-1)
Aquatic
Fish – LC 50
Fathead minnow (Pimephales promelas)
>100 mg/l, 96 hours
Cyclohexanone (108-94-1)
Aquatic
Fish – LC 50
Fathead minnow (Pimephales promelas)
481-578 mg/l, 96 hours
Persistence and degradability
No data is available on the degradability of this product..
Bio accumulative potential
No data is available.
Partition coefficient n-octanol / water (log Kow)
Acetone (CAS 67-64-1)
-0.24
Cyclohexanone (CAS 108-94-1)
0.81
Methyl ethyl ketone (CAS 78-93-3)
0.29
Mobility in soil
Not available
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone
creation potential, endocrine disruption, global warming potential) are expected from
this component.
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain
13. Disposal considerations
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into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or
used container. Dispose of contents/container in accordance with local, regional, national or
international regulations.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container
is emptied.
14. Transportation information
DOT
UN number
UN1993
UN Proper Shipping Name
Flammable liquids, n.o.s. (Acetone RQ = 5128 LBS)
Transport Hazard class(es)
Class
Subsidiary risk
Label(s)
3
3
Packing group
II
Special precautions for
user
Read safety instructions, SDS and emergency procedures before handling.
Special provisions
IB2, T7, TP1, TP8, TP28
Packaging exceptions
150
Packaging non bulk
202
Packaging bulk
242
IATA
UN number
UN1993
UN Proper Shipping Name
Flammable liquid, n.o.s. (Acetone, Cyclohexanone)
Transport hazard class(es)
Class
Subsidiary risk
3
-
Packing group
II
Environmental hazards
No.
ERG Code
3H
Special precautions for
user
Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number
UN1993
UN Proper Shipping Name
Flammable liquid, n.o.s. (Acetone, Cyclohexanone)
Transport hazard class(es)
Class
Subsidiary risk
3
-
Packing group
II
Environmental hazards
Marine polluntant
No.
EmS
F-E, S-E
Special precautions for
user
Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to. Not available.
Annex II of MARPOL 73/78 and
the IBC Code
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15. Regulatory information
U.S. Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not Regulated
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1) LISTED
Cyclohexanone (CAS 108-94-1) LISTED
Methyl ethyl ketone (CAS 78-93-3) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard – No
SARA 302 Extremely hazardous substance
Not Listed
SARA 311/312 Hazardous chemical
No
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
Not regulated.
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1) 35 %WV
Methyl ethyl ketone (CAS 78-93-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
US state regulations
US. Massachusetts RTK - Substance List
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Methyl ethyl ketone (CAS 78-93-3)
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Methyl ethyl ketone (CAS 78-93-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Methyl ethyl ketone (CAS 78-93-3)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
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California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to
Country(s) or region
Inventory name
On inventory (yes/no)*
Canada
Domestic Substances List (DSL)
Yes
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
No
Issue Date
05-27-2015
Revision Date
-
Version #
01
HMIS Rating
Health: 2
Flammability: 3
Physical Hazards: 0
NFPA ratings
2
Disclaimer
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
contain any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the
governing country(s).
16. Other information, including date of preparation or last revision
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