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SAFETY DATA SHEET
Issue Date 07-Mar-2018 Revision Date 07-Mar-2018 Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Synonyms
Details of the supplier of the safety data sheet
Company Name
Emergency telephone number
Emergency Telephone
Green Kleen Multi-Purpose Cleaner Degreaser
NL950
None
Nyco Products Company
5332 Dansher Road
Countryside, IL 60525
(708) 579-8100
nycoproducts.com
Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Not classified
Acute toxicity - Dermal Not classified
Skin corrosion/irritation Category 3
Label elements
Emergency Overview
Warning
Hazard statements
Causes mild skin irritation
Appearance Clear Physical state Liquid Odor Sassafras
Precautionary Statements - Prevention
Use only in a well-ventilated area
Wear protective gloves/protective clothing/eye protection/face protection
Do not breathe dust/fume/gas/mist/vapors/spray
Do not eat, drink or smoke when using this product
Wash face, hands and any exposed skin thoroughly after handling
Precautionary Statements - Response
_____________________________________________________________________________________________
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Specific Treatment (See Section 4 on the SDS)
If skin irritation occurs: Get medical advice/attention
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Drink plenty of water
Immediately call a POISON CENTER or doctor/physician
Precautionary Statements - Disposal
Disposal should be in accordance with applicable regional, national and local laws and regulations
Hazards not otherwise classified (HNOC)
Other Information
• Harmful to aquatic life with long lasting effects
• Harmful to aquatic life
Unknown Acute Toxicity 0.02% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight-% Trade Secret
Surfactant Blend Proprietary 1-5 *
1-Butoxy-2-Propanol 5131-66-8 1-5 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures
Skin Contact
Eye contact
Inhalation
Ingestion
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Wash off immediately with plenty of water. Wash skin with soap and water.
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician.
Remove to fresh air.
Clean mouth with water and drink afterwards plenty of water.
Any additional important symptoms and effects are described in Section 11: Toxicology
Information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
Specific hazards arising from the chemical
No Information available.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Caution: Use of water spray when fighting fire may be inefficient.
None.
None.
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NL950 Green Kleen Multi-Purpose Cleaner Degreaser Revision Date 07-Mar-2018
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Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Ensure adequate ventilation, especially in confined areas.
Environmental precautions
Environmental precautions
See Section 12 for additional ecological information.
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevent further leakage or spillage if safe to do so.
Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Incompatible materials
Keep containers tightly closed in a dry, cool and well-ventilated place.
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
2-(2-methoxypropoxy)propano
34590-94-8
Sodium Hydroxide
1310-73-2
.
STEL: 150 ppm
TWA: 100 ppm
S*
Ceiling: 2 mg/m
TWA: 600 mg/m
(vacated) TWA: 100 ppm
(vacated) TWA: 600 mg/m
(vacated) STEL: 150 ppm
(vacated) STEL: 900 mg/m
3
(vacated) Ceiling: 2 mg/m
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate engineering controls
Engineering Controls
Showers, Eyewash stations & Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
Wear safety glasses with side shields (or goggles).
Wear protective gloves and protective clothing.
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
TWA: 100 ppm
(vacated) S*
S*
TWA: 2 mg/m
3
3
3
3
3
IDLH: 600 ppm
TWA: 100 ppm
TWA: 600 mg/m
STEL: 150 ppm
STEL: 900 mg/m
IDLH: 10 mg/m
Ceiling: 2 mg/m
3
3
3
3
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required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
General Hygiene
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Color
Odor
Odor threshold
Property Values Remarks • Method
pH
Specific Gravity
Viscosity
Melting point/freezing point
Flash point
Boiling point / boiling range
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Water solubility
Partition coefficient
Autoignition temperature
Decomposition temperature
Liquid
Clear
Green
Sassafras
No Information available
9.0 - 10.5
1.01
<25 cP @ 25°C
No Information available
None
100 °C / 212 ° F Degrees
No Information available
No data available
No Information available
No Information available
No Information available
No Information available
Complete
No Information available
No Information available
No Information available
Other Information
Density Lbs/Gal
VOC Content (%)
8.41
3.5
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Extremes of temperature and direct sunlight.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
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Product Information
Inhalation
Eye contact
Skin Contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Surfactant Blend > 2000 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) 1-Butoxy-2-Propanol
5131-66-8
Avoid breathing vapors or mists. May cause irritation of respiratory tract.
Avoid contact with eyes. Direct contact may cause redness and irritation.
Avoid contact with skin. Prolonged or repeated contact may dry skin and cause irritation.
Do not taste or swallow. May cause gastro intestinal irritation.
= 5660 µL/kg ( Rat ) = 1900 mg/kg
( Rat )
= 3100 mg/kg ( Rabbit ) -
Information on toxicological effects
Symptoms
No Information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation
Sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Target organ effects
Aspiration hazard
MAY CAUSE SKIN IRRITATION.
No Information available.
No Information available.
No Information available.
No Information available.
No Information available.
No Information available.
Central nervous system, EYES, Respiratory system.
No Information available.
Numerical measures of toxicity - Product Information
Unknown Acute Toxicity
0.02% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
62,848.00
50,032.00
12. ECOLOGICAL INFORMATION
Ecotoxicity
1.77% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
Surfactant Blend - 1.2: 96 h Oncorhynchus mykiss
2-(2-methoxypropoxy)propano
34590-94-8
Tetrasodium EDTA
64-02-8
Trisodium nitrilotriacetate
5064-31-3
1.01: 72 h Desmodesmus
subspicatus mg/L EC50
560 - 1000: 96 h Chlorella vulgaris
- 10000: 96 h Pimephales promelas
59.8: 96 h Pimephales promelas
mg/L LC50 static 41: 96 h Lepomis
macrochirus mg/L LC50 static
mg/L EC50
93 - 170: 96 h Pimephales promelas
mg/L LC50 flow-through 252: 96 h
Lepomis macrochirus mg/L LC50
560 - 1000: 96 h Oryzias latipes
mg/L LC50 semi-static 72 - 133: 96
h Oncorhynchus mykiss mg/L LC50
static 560 - 1000: 96 h Poecilia
reticulata mg/L LC50 560 - 1000: 96
h Poecilia reticulata mg/L LC50
semi-static 470: 96 h Pimephales
promelas mg/L LC50 static 175 -
225: 96 h Lepomis macrochirus
mg/L LC50
mg/L LC50 static
5.3: 48 h Daphnia mg/L LC50
1919: 48 h Daphnia magna mg/L
LC50
610: 24 h Daphnia magna mg/L
EC50
560 - 1000: 48 h Daphnia magna
mg/L LC50
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mg/L LC50 static 560 - 1000: 96 h
Oryzias latipes mg/L LC50 114: 96
h Pimephales promelas mg/L LC50
Sodium Hydroxide
1310-73-2
Persistence and degradability
No Information available.
Bioaccumulation
Bioaccumulative potential.
- 45.4: 96 h Oncorhynchus mykiss
mg/L LC50 static
-
Other adverse effects
No Information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging
Do not reuse container.
This product contains one or more substances that are listed with the State of California as a hazardous waste.
14. TRANSPORT INFORMATION
The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please
refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment.
For additional information, please contact the distributor listed in section 1 of this SDS.
DOT
TDG
Not regulated
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
Complies
Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
2-(2-methoxypropoxy)propano - 34590-94-8 1.0
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
No
No
No
No
No
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This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product has been evaluated and does not require warning labeling under California Proposition 65.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
2-(2-methoxypropoxy)propano
34590-94-8
Trisodium nitrilotriacetate
5064-31-3
Sodium Hydroxide
1310-73-2
U.S. EPA Label Information
X X X
- X -
X X X
EPA Pesticide Registration Number
Not Applicable
16. OTHER INFORMATION
NFPA Health hazards 0 Flammability 0 Instability 0 Physical and Chemical
Properties -
HMIS Health hazards 0 Flammability 0 Physical hazards 0 Personal protection B
Issue Date
Revision Date
Revision Note
No Information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
07-Mar-2018
07-Mar-2018
End of Safety Data Sheet
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