Nyco NL147 User Manual

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SAFETY DATA SHEET
Issue Date 18-Jan-2017 Revision Date 18-Jan-2017 Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier Product Name
Other means of identification Product Code Synonyms
Details of the supplier of the safety data sheet Company Name
Emergency telephone number Emergency Telephone
Dyn-A-Max Mop On Wax & Finish Remover
Nyco Products Company 5332 Dansher Road Countryside, IL 60525 (708) 579-8100 nycoproducts.com
Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION
Classification OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Category 5 Acute toxicity - Dermal Category 5 Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1
Label elements
Emergency Overview
Danger
Hazard statements
May be harmful if swallowed May be harmful in contact with skin Causes severe skin burns and eye damage
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Appearance Clear Physical state Liquid Odor Solvent Precautionary Statements - Prevention
Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response
Immediately call a POISON CENTER or doctor/physician Specific Treatment (See Section 4 on the SDS) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician IF SWALLOWED: Rinse mouth. DO NOT induce vomiting Drink plenty of water Immediately call a POISON CENTER or doctor/physician
Precautionary Statements - Storage
Store locked up
Precautionary Statements - Disposal
Disposal should be in accordance with applicable regional, national and local laws and regulations
Hazards not otherwise classified (HNOC) Other Information
Unknown Acute Toxicity 0.03798% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight-% Trade Secret
2-butoxyethanol 111-76-2 10-30 *
Monoethanolamine 141-43-5 7-13 *
Potassium Hydroxide 1310-58-3 1-5 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures General advice Skin Contact
Eye contact
Immediate medical attention is required. Immediate medical attention is required. Wash off immediately with soap and plenty of
water while removing all contaminated clothes and shoes. Immediate medical attention is required. Rinse immediately with plenty of water, also under
the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area.
Inhalation
Ingestion
Self-protection of the first aider
Remove to fresh air. Call a physician or poison control center immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person. Remove from exposure, lie down. Clean mouth with water and drink afterwards plenty of water. Call a physician or poison control center immediately.
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
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Most important symptoms and effects, both acute and delayed Symptoms
Indication of any immediate medical attention and special treatment needed Note to physicians
Any additional important symptoms and effects are described in Section 11: Toxicology Information.
Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
Specific hazards arising from the chemical
The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating and toxic gases and vapors. In the event of fire and/or explosion do not breathe fumes.
Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Caution: Use of water spray when fighting fire may be inefficient.
None. None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Personal precautions
Environmental precautions Environmental precautions
Methods and material for containment and cleaning up Methods for containment Methods for cleaning up
Evacuate personnel to safe areas. Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Keep people away from and upwind of spill/leak.
Do not allow into any sewer, on the ground or into any body of water. Should not be released into the environment. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Take
up mechanically, placing in appropriate containers for disposal. Clean contaminated surface thoroughly. Prevent product from entering drains. Dam up. After cleaning, flush away traces with water.
7. HANDLING AND STORAGE
Precautions for safe handling Advice on safe handling
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation, especially in confined areas. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems.
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Conditions for safe storage, including any incompatibilities Storage Conditions
Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled containers.
Incompatible materials
Incompatible with strong acids and bases. Incompatible with oxidizing agents.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
2-butoxyethanol
111-76-2
Monoethanolamine
141-43-5
Potassium Hydroxide
1310-58-3
Diethanolamine
111-42-2
Sodium Hydroxide
1310-73-2
NIOSH IDLH Immediately Dangerous to Life or Health
.
TWA: 20 ppm TWA: 50 ppm
STEL: 6 ppm
TWA: 3 ppm
Ceiling: 2 mg/m
TWA: 1 mg/m3 inhalable fraction
and vapor
S*
Ceiling: 2 mg/m
TWA: 240 mg/m
3
(vacated) TWA: 25 ppm
(vacated) TWA: 120 mg/m
3
IDLH: 700 ppm
TWA: 5 ppm
TWA: 24 mg/m
3
(vacated) S*
S*
TWA: 3 ppm
TWA: 6 mg/m
(vacated) TWA: 3 ppm
(vacated) TWA: 8 mg/m
(vacated) STEL: 6 ppm
3
(vacated) STEL: 15 mg/m (vacated) Ceiling: 2 mg/m
(vacated) TWA: 3 ppm
(vacated) TWA: 15 mg/m
3
TWA: 2 mg/m
(vacated) Ceiling: 2 mg/m
3
3
3 3
3
3
3
IDLH: 30 ppm
TWA: 3 ppm
TWA: 8 mg/m
STEL: 6 ppm
STEL: 15 mg/m Ceiling: 2 mg/m
TWA: 3 ppm
TWA: 15 mg/m IDLH: 10 mg/m
Ceiling: 2 mg/m
3
3
3
3
3
3
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
Appropriate engineering controls Engineering Controls
Showers, Eyewash stations & Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Skin and body protection
Tight sealing safety goggles. Face protection shield. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact.
Respiratory protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
General Hygiene
When using do not eat, drink or smoke. Keep away from food, drink and animal feeding stuffs. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Avoid contact with skin, eyes or clothing. Take off all contaminated clothing and wash it before reuse. Wear suitable gloves and eye/face protection.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state
Liquid
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Appearance Color Odor Odor threshold
Clear Light Red Solvent No Information available
Property Values Remarks • Method
pH Specific Gravity Viscosity
Melting point/freezing point
Flash point Boiling point / boiling range Evaporation rate Flammability (solid, gas)
Flammability Limits in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Water solubility Partition coefficient Autoignition temperature Decomposition temperature
13.0 +
1.065 <25 cP @ 25°C No Information available
>200 °F <1
No data available
No Information available No Information available No Information available No Information available Complete No Information available No Information available No Information available
Other Information
Density Lbs/Gal VOC Content (%)
8.88 26
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Exposure to air or moisture over prolonged periods.
Incompatible materials
Incompatible with strong acids and bases. Incompatible with oxidizing agents.
Hazardous Decomposition Products
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Product Information
Inhalation
Avoid breathing vapors or mists. Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact Skin Contact
Avoid contact with eyes. Corrosive. Causes severe eye damage. Avoid contact with skin. Corrosive. Contact with skin may cause severe irritation and burns.
Prolonged contact with skin may result in the absorption of potentially harmful amounts leading to possible liver and kidney damage.
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Ingestion
May be harmful if swallowed. Ingestion causes acute irritation and burns to the mucous membranes of the mouth, trachea, esophagus and stomach. Ingestion may result in the absorption of potentially harmful amounts leading to possible liver and kidney damage.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
2-butoxyethanol 111-76-2 Monoethanolamine 141-43-5 Potassium Hydroxide 1310-58-3
= 470 mg/kg ( Rat ) = 99 mg/kg ( Rabbit ) = 450 ppm ( Rat ) 4 h
= 1720 mg/kg ( Rat ) = 1000 mg/kg ( Rabbit ) = 1 mL/kg
( Rabbit )
= 284 mg/kg ( Rat ) - -
-
Information on toxicological effects Symptoms
No Information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization
Germ cell mutagenicity Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
2-butoxyethanol 111-76-2
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 3 -Not classifiable as a human carcinogen
Reproductive toxicity STOT - single exposure STOT - repeated exposure
Chronic toxicity
No Information available. No Information available. The table below indicates whether each agency has listed any ingredient as a carcinogen.
A3 Group 3 - -
No Information available. No Information available. No Information available. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Avoid repeated exposure. Possible risk of irreversible effects. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects.
Target organ effects
Blood, Central nervous system, EYES, hematopoietic system, Kidney, Liver, Respiratory system, Skin.
Aspiration hazard
No Information available.
Numerical measures of toxicity - Product Information Unknown Acute Toxicity
0.03798% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) ATEmix (dermal) ATEmix (inhalation-dust/mist) ATEmix (inhalation-vapor)
2,233.00 4,240.00
5.80 3,000.00
12. ECOLOGICAL INFORMATION
Ecotoxicity
2.33798% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
2-butoxyethanol
111-76-2
Monoethanolamine
141-43-5
15: 72 h Desmodesmus subspicatus
- 1490: 96 h Lepomis macrochirus
mg/L EC50
mg/L LC50 static 2950: 96 h
Lepomis macrochirus mg/L LC50
227: 96 h Pimephales promelas mg/L LC50 flow-through 3684: 96 h Brachydanio rerio mg/L LC50 static
300 - 1000: 96 h Lepomis
macrochirus mg/L LC50 static 114 -
196: 96 h Oncorhynchus mykiss
1000: 48 h Daphnia magna mg/L EC50 1698 - 1940: 24 h Daphnia
magna mg/L EC50
65: 48 h Daphnia magna mg/L
EC50
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mg/L LC50 static 200: 96 h
Potassium Hydroxide
1310-58-3
Tetrasodium EDTA
64-02-8
Sodium Sulfate
7757-82-6
Diethanolamine
111-42-2
Trisodium nitrilotriacetate
5064-31-3
Sodium Hydroxide
1310-73-2
- 80: 96 h Gambusia affinis mg/L
1.01: 72 h Desmodesmus subspicatus mg/L EC50
- 13500 - 14500: 96 h Pimephales
2.1 - 2.3: 96 h Pseudokirchneriella subcapitata mg/L EC50 7.8: 72 h Desmodesmus subspicatus mg/L
EC50
560 - 1000: 96 h Chlorella vulgaris
mg/L EC50
- 45.4: 96 h Oncorhynchus mykiss
Oncorhynchus mykiss mg/L LC50
41: 96 h Lepomis macrochirus mg/L
LC50 static 59.8: 96 h Pimephales
promelas mg/L LC50 3040 - 4380:
96 h Lepomis macrochirus mg/L
LC50 static 6800: 96 h Pimephales
promelas mg/L LC50 static 13500:
96 h Lepomis macrochirus mg/L
4460 - 4980: 96 h Pimephales
promelas mg/L LC50 flow-through
1200 - 1580: 96 h Pimephales
promelas mg/L LC50 static 600 -
1000: 96 h Lepomis macrochirus
93 - 170: 96 h Pimephales promelas mg/L LC50 flow-through 560 - 1000:
96 h Oryzias latipes mg/L LC50
semi-static 470: 96 h Pimephales
promelas mg/L LC50 static 560 -
1000: 96 h Poecilia reticulata mg/L
promelas mg/L LC50 252: 96 h
Lepomis macrochirus mg/L LC50 72
- 133: 96 h Oncorhynchus mykiss mg/L LC50 static 175 - 225: 96 h
Lepomis macrochirus mg/L LC50
static 560 - 1000: 96 h Poecilia
reticulata mg/L LC50 semi-static
560 - 1000: 96 h Oryzias latipes
flow-through
-
LC50 static
610: 24 h Daphnia magna mg/L
EC50
promelas mg/L LC50 static
2564: 48 h Daphnia magna mg/L
EC50 630: 96 h Daphnia magna
mg/L EC50
LC50
55: 48 h Daphnia magna mg/L
EC50
mg/L LC50 static
560 - 1000: 48 h Daphnia magna
mg/L LC50
LC50 114: 96 h Pimephales
mg/L LC50
-
mg/L LC50 static
Persistence and degradability
No Information available.
Bioaccumulation
Bioaccumulative potential.
Chemical Name Partition coefficient
Other adverse effects
2-butoxyethanol
111-76-2
Monoethanolamine
141-43-5
Potassium Hydroxide
1310-58-3
No Information available
0.81
-1.91
0.65
0.83
13. DISPOSAL CONSIDERATIONS
Waste treatment methods Disposal of wastes
Contaminated packaging
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Do not reuse container.
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Chemical Name California Hazardous Waste Status
Potassium Hydroxide
1310-58-3
Toxic
Corrosive
14. TRANSPORT INFORMATION
The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of this SDS.
DOT
UN/ID No. Proper shipping name Hazard Class Packing Group Special Provisions Description Emergency Response Guide Number
TDG
UN/ID No. Proper shipping name Hazard Class Packing Group Description
UN1760 Corrosive liquids, n.o.s. 8 II B2, IB2, T11, TP2, TP27 UN1760, Corrosive liquids, n.o.s (contains Potassium Hydroxide and Ethanolamine), 8, II 154
UN1760 Corrosive liquids, n.o.s. 8 II UN1760, Corrosive liquids, n.o.s. (contains Potassium Hydroxide and Ethanolamine), 8. II
15. REGULATORY INFORMATION
International Inventories
TSCA DSL/NDSL
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
2-butoxyethanol - 111-76-2 1.0
SARA 311/312 Hazard Categories
Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
Complies Complies
Yes Yes No No No
Chemical Name CWA - Reportable
Potassium Hydroxide
1310-58-3
Quantities
1000 lb - - X
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
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Potassium Hydroxide
1310-58-3
1000 lb - RQ 1000 lb final RQ
RQ 454 kg final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
Diethanolamine - 111-42-2 Carcinogen
WARNING: This product contains a chemical known to the state of California to cause cancer. WARNING: This product contains a chemical known in the State of California to cause birth defects or other reproduction harm.
Chemical Name(s):
Acetic acid, 2,2,-dichloro-
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
2-butoxyethanol
111-76-2
Monoethanolamine
141-43-5
Potassium Hydroxide
1310-58-3
Sodium Sulfate
7757-82-6
Diethanolamine
111-42-2
Sodium Hydroxide
1310-73-2
Trisodium nitrilotriacetate
5064-31-3
U.S. EPA Label Information
X X X X X X X X X
- X X X X X X X X
- X -
EPA Pesticide Registration Number
Not Applicable
16. OTHER INFORMATION
NFPA Health hazards 3 Flammability 1 Instability 0 Physical and Chemical
Properties Yes
HMIS Health hazards 3 Flammability 1 Physical hazards 0 Personal protection C Issue Date
Revision Date Revision Note
No Information available
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
18-Jan-2017 18-Jan-2017
End of Safety Data Sheet
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