Myron L 6PFCE User Manual

ULTRAMETER
Operation
Manual
MODELS 6PFCE & 4P
20 Sep. 2013
Reference Junction under Glass pH Bulb
These Measurement keys will:
• Turn instrument on
• Measure parameter
• Exit any function
(Built-in
Electrodes)
Preprogrammed variable conductivity/ TDS ratios
Parameters
Wrist/neck strap slot
(user supplied)
pH/ORP Sensor Protective Cap
This key for:
• Calibration
• Memory Clear
• Solution Selection
• Confirmation
Up key/Memory Store
Down key/Memory Recall
Conductivity Cell
USER mode
for programming special temperature compensation factor and conductivity/TDS ratio
Displayed here:
• Temperature
readout
• USER temperature
compensation or conductivity/TDS ratio
• Memory Storage/
Recall
• pH Calibration
ORP
Electrode
pH Glass
Electrode
pH/ORP Sensor
(Replaceable)
For detailed explanations see Table of Contents
Temperature Sensor
MODEL 6PFCE
Shown with bluDock™ option installed
Time & Date displayed here
TEST Value
i
ii
I. INTRODUCTION
Thank you for selecting the feature-packed Ultrameter II™, one of the Myron L Company’s latest in an increasing line of instruments utilizing advanced microprocessor-based circuitry and SMT manufacturing processes. This circuitry makes the instrument extremely accurate, reliable and very easy to use.
Model 6PIIFCE includes Myron L Company’s exclusive Free Chlorine Equivalent (FCE) feature for making ORP-based free chlorine measurements. Both Ultrameter IIs now also feature optional wireless data transfer. Other features include a clock with time and date, memory of up to 100 locations with time and date stamp, the ability of the user to adjust the timeout “Auto oFF”, and enhanced performance.
See Features and Specications on pages 2 & 3.
The most exciting new feature is data logging with the ability to download the memory or stored test data wirelessly with its corresponding time, date and unit name. This feature allows the user to create spreadsheets and graphs with ease and quickly and accurately manipulate data more effectively. The optional bluDock™ and accompanying U2CI software is compatible with most computers using either Microsoft Windows XP, Vista, or 7™ or Macintosh OSX™. The data may be imported into a variety of spreadsheet formats like Microsoft Excel CSV™. Please Note: Although the Myron L Company has performed extensive testing, we cannot guarantee compatibility of all applications and formats. We suggest testing your application and format for compatibility before relying on it.
Bluetooth®
For your convenience, a brief set of instructions is provided on the bottom side of your Ultrameter II. A waterproof pocket-sized card with abbreviated instructions is also included with the instrument.
Special note ... Conductivity, resistivity, and TDS require mathematical correction to 25°C values (ref. Temperature Compensation, pg. 39). On the left of the Ultrameter II’s liquid crystal display is shown an indicator of the salt solution characteristic used to model temperature compensation of conductivity and its TDS conversion. The indicator may be KCl, NaCl, 442™ or User. Selection affects the temperature correction of conductivity, and the calculation of TDS from compensated conductivity (ref. Conductivity Conversion to Total Dissolved Solids (TDS), pg. 41). The selection can affect the reported conductivity of hot or cold solutions, and will change the reported TDS of a solution. Generally, using KCl for conductivity, NaCl
for resistivity, and 442 (Natural Water characteristic) for TDS will reect
present industry practice for standardization. This is how your instrument, as shipped from the factory, is set to operate. For use in sea water desalination for example, both the conductivity and TDS may easily be changed to NaCl.
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II. FEATURES and SPECIFICATIONS
A. Features
• ORP-based FCE free chlorine measurement, displayed as ppm
concentration (6PFCE)
• Superior resolution 4 digit LCD displays full 9999 µS/ppm
• Cond/TDS accuracy of ±1% of READING in a handheld instrument
±0.1% at calibration point
• All electrodes are internal for maximum protection
• Improved 4 electrode sensor technology
• Waterproof to 1 meter/3 feet
• Autoranging conductivity/TDS/resistivity
• Prompts for easy pH calibration (6PFCE)
• Factory calibrations stored in microprocessor
• 3 conductivity/TDS solution conversions preprogrammed into
microprocessor
• User mode feature allows: Programming your own cond/TDS conversion factor
Programming your own temperature compensation factor Disabling temperature compensation
• Real Time Clock with Time and Date
• Data Logging with TIME and DATE in memory
• Memory stores 100 readings
• User adjustable timeout “Auto oFF”
Bluetooth®
wireless download capability with optional bluDock™
B. General Specications Display 4 Digit LCD
Dimensions (LxWxH) 196 x 68 x 64 mm/
7.7 x 2.7 x 2.5 in.
Weight 352 g/12.4 oz.
Case Material VALOX*
Cond/Res/TDS Cell Material VALOX* Cond/TDS Electrodes (4) 316 Stainless Steel Cond/Res/TDS Cell Capacity 5 ml/0.2 oz.
pH/ORP Sensor Well Capacity 1,2 ml/0.04 oz. (6PFCE)
Power 9V Alkaline Battery
Battery Life >100 Hours/5000 Readings Operating/Storage Temperature 0-55°C/32-132°F Protection Ratings IP67/NEMA 6 (waterproof to 1 meter/3 feet)
EMI/EMC Ratings EN61326-1: 2006 + Annex A: 2008
(hand-held devices)
(Conformité Européenne)
CISPR 11: 2003 IEC 61000-4-2: 2001 and, IEC 61000-4-3: 2002
* ™ SABIC Innovative Plastics IP BV
Additional information is available on our website:
www.myronl.com
MADE IN USA
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C. Specication Chart
If either ORP or pH is outside the specied limits, the instrument will display “-Or-”.
D. Warranty/Service The Myron L Ultrameter II, excluding the pH/ORP sensor (6PFCE), has a Two (2) Year Limited Warranty. The pH/ORP sensor (6PFCE) has a
Six (6) Month Limited Warranty for materials and workmanship. If an instrument fails to operate properly, see Troubleshooting Chart, pg. 36.
The battery and pH/ORP sensor are user-replaceable. For other service,
return the instrument prepaid to the Myron L Company.
MYRON L COMPANY
2450 Impala Drive
Carlsbad, CA 92010-7226 USA
+1-760-438-2021 E-Mail: info@myronl.com techquestions@myronl.com
www.myronl.com
If, in the opinion of the factory, failure was due to materials or workmanship, repair or replacement will be made without charge. A reasonable service charge will be made for diagnosis or repairs due to normal wear, abuse or tampering. This warranty is limited to the repair or replacement of the Ultrameter II only. The Myron L Company assumes no other responsibility or liability.
E. Ultrameter II Models
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TABLE OF CONTENTS
Instrument Illustration .......................................i
I. INTRODUCTION ................................... 1
II. FEATURES and SPECIFICATIONS .................... 2
A. Features ................................2
B. General Specications .....................2
C. Specication Chart ........................3
D. Warranty/Service..........................3
E. Ultrameter II Models ....................... 3
III. RULES of OPERATION..............................7
A. Operation ...............................7
B. Characteristics of the Keys ..................7
C. Operation of the Keys ......................7
1. Measurement Keys in General.........7
2. COND, RES and TDS Keys ........... 7
3. pH and ORP/Fr Chl Keys (6PFCE) ...... 8
4. CAL/MCLR Key ....................8
5. UP or DOWN Keys..................9
IV. AFTER USING THE ULTRAMETER II .................. 9
A. Maintenance of the Conductivity Cell ..........9
B. Maintenance of the pH/ORP Sensor (6PFCE)....9
V. SPECIFIC RECOMMENDED MEASURING
PROCEDURES .............................9
A. Measuring Conductivity &
Total Dissolved Solids (TDS)............. 9
B. Measuring Resistivity .....................10
C. Measuring pH (6PFCE) ....................10
D. Measuring ORP (6PFCE)................... 10
1. ORP/FCE Mode Selection............. 11
2. Measuring ORP .................... 11
E. Measuring Free Chlorine Using FCE..........12
1. Prepare for FCE Measurement ......... 12
2. FC
E
Flow Method ................... 12
3. FCE Immersion Method............... 13
4. FCE Best Practices .................. 14
VI. SOLUTION SELECTION............................14
A. Why Solution Selection is Available ..........14
B. The 4 Solution Types .....................14
C. Calibration of Each Solution Type ............14
D. Procedure to Select a Solution ..............14
E. Application of User Solution Type ............15
1. User Programmable Temperature
Compensation (Tempco) ........15
2. Disabling Temperature Compensation ... 15
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TABLE OF CONTENTS
3. User Programmable Conductivity to
TDS Ratio ....................16
VII. CALIBRATION .................................... 17
A. Calibration Intervals ......................17
B. Rules for Calibration of the Ultrameter II ...... 17
1. Calibration Steps .................. 17
2. Calibration Limits ..................18
C. Calibration Procedures ....................18
1. Conductivity or TDS Calibration ....... 18
2. User Calibration Conductivity/TDS.....18
3. Resistivity Calibration ............... 19
4. Reloading Factory Calibration
(Cond or TDS) ................19
5. pH Calibration (6PFCE) .............19
6. ORP Calibration (6PFCE) ............21
7. Temperature Calibration ............. 21
VIII. CALIBRATION INTERVALS ......................... 22
A. Suggested Intervals ......................22
B. Calibration Tracking Records ............... 22
C. Conductivity, RES, TDS Practices............22
D. pH and ORP Practices (6PFCE) .............23
IX. MEMORY........................................23
A. Memory Storage ......................... 23
B. Memory Recall ..........................23
C. Clearing a Record/Memory Clear ............24
X. TIME and DATE................................... 24
A. Setting TIME ............................24
B. Setting DATE............................25
C. DATE FORMAT “US & International (Int)” ...... 26
XI. TEMPERATURE FORMAT “Centigrade & Fahrenheit” ..... 26
XII. TOTAL RETURN to FACTORY SETTINGS..............27
XIII. CELL CHECK .................................... 28
XIV. AUTO OFF ......................................28
XV. USER Mode CALIBRATION LINC™ FUNCTION .........29
A. Calibration of Ultrameter II for use in
User mode .......................... 29
B. Setting User mode Calibration “Linc” .........30
C. Canceling User mode Calibration “Linc” .......31
XVI. bluDock™ Wireless Data Transfer Instructions........... 32
A. Software Installation ...................... 32
B. Hardware Setup .........................32
C. Memory Stack Download ..................33
XVII. CARE and MAINTENANCE .........................34
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TABLE OF CONTENTS
A. Temperature Extremes .................... 34
B. Battery Replacement...................... 34
C. pH/ORP Sensor Replacement (6PFCE) ....... 34
D. Cleaning Sensors ........................ 34
XVIII. TROUBLESHOOTING CHART ....................... 36
XIX. ACCESSORIES...................................38
A. Conductivity/TDS Standard Solutions .........38
B. pH Buffer Solutions (6PFCE) ................ 38
C. pH Sensor Storage Solution (6PFCE) .........38
D. ORP Sensor Conditioner Solution (6PFCE)..... 38
E. Soft Protective Carry Cases ................ 39
F. Hard Protective Carry Cases ...............39
G. Replacement pH/ORP Sensor (6PFCE) ....... 39
H. bluDock™ Wireless Data Transfer
Accessory Package ................... 39
XX. TEMPERATURE COMPENSATION (Tempco)
of Aqueous Solutions ........................ 39
A. Standardized to 25°C ..................... 39
B. Tempco Variation.........................39
C. An Example of 2 different solution selections and
the resulting compensation ............. 40
D. A Chart of Comparative Error ............... 40
E. Other Solutions ..........................41
XXI. CONDUCTIVITY CONVERSION to
TOTAL DISSOLVED SOLIDS (TDS) ............41
A. How it’s Done ...........................42
B. Solution Characteristics ...................42
C. When does it make a lot of difference?........ 42
XXII. TEMPERATURE COMPENSATION (Tempco)
and TDS DERIVATION....................... 43
A. Conductivity Characteristics ................ 43
B. Finding the Tempco of an Unknown Solution ... 43
C. Finding the TDS Ratio of an Unknown Solution ....43
XXIII. pH and ORP (6PFCE) ...............................44
A. pH (6PFCE) .............................44
B. ORP/Oxidation-Reduction Potential/
REDOX (6PFCE) .....................46
C. Free Chlorine Equivalent ..................47
1. FCE as an Indicator of Sanitizing
Strength .....................47
2. FCE Units ........................ 47
XXIV. SOFTWARE VERSION ............................. 48
XXV. GLOSSARY......................................49
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III. RULES of OPERATION
A. Operation Using the instrument is simple:
Individual or multiple parameter readings may be obtained by lling individual sensors or entire cell cup area.
Rinse the conductivity cell or pH/ORP sensor (6PFCE) well with test solution 3 times and rell. Temperature and/or
measurement extremes will require additional rinses for maximum accuracy.
Press the desired measurement key to start measurement.
Pressing the key again restarts the 15 second “Auto oFF” timer.
Note the value displayed or press the MS key to store the
reading (ref. Memory Storage, pg. 23). It’s that simple!
B. Characteristics of the Keys
Though your Ultrameter II has a variety of sophisticated options, it is designed to provide quick, easy, accurate measurements by simply pressing one key.
All functions are performed one key at a time.
There is no “off” key. After 15 seconds of inactivity the
instrument turns itself off (60 seconds in CAL mode). User
adjustable up to 75 seconds (ref. Auto oFF, pg. 28).
Rarely is it necessary to press and
to Select a Solution, pg. 14; or Conductivity or TDS Calibration,
pg. 18).
C. Operation of the Keys (See Instrument Illustration, pg. i)
1. Measurement Keys in General Any of the 5 measurement keys in the upper part of the keypad turns on the instrument in the mode selected. The mode is shown at the bottom of the display, and the measurement units appear at the right. Pressing a measurement key does this even if you are in a calibration sequence and also serves to cancel a change (ref. Leaving Calibration, pg. 17).
hold
a key (as in Procedure
2. COND, RES and TDS Keys These 3 keys are used with solution in the Conductivity Cell. Precautions:
While lling cell cup ensure no air bubbles cling on the cell wall.
If the proper solution is not selected (KCl, NaCl, 442 or User),
refer to Why Solution Selection is Available, pg. 14 and Procedure to Select a Solution, pg. 14. a. COND Key Solution to be tested is introduced into the conductivity cell and a press
of displays conductivity with units on the right. On the left is
shown the solution type selected for conductivity.
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b. RES Key
ORP
Fr Chl
ORP
Fr Chl
A press of displays resistivity with units on the right. On the left
is shown solution type selected for resistivity (ref. Solution Selection, pg.
14). The range of display of resistivity is limited to between 10 kilohms
(KΩ) and 30 megohms (MΩ). A solution outside that range will only show
[- - - -] in the display. c. TDS Key A press of displays Total Dissolved Solids with units on the right.
This is a display of the concentration of material calculated from compensated conductivity using the characteristics of a known material. On the left is shown solution type selected for TDS (ref. Solution Selection, pg. 14).
3. pH and ORP/Fr Chl Keys (6PFCE) Measurements are made on solution held in the pH/ORP sensor well (ref. pH and ORP, pg. 44). The protective cap is removed and the sensor well is lled and rinsed with the sample enough times to completely
replace the storage solution.
After use, the pH/ORP sensor well must be relled with Myron L Storage
Solution, and the protective cap reinstalled securely (ref. Maintenance
of the pH/ORP Sensor, pg. 9 and Cleaning Sensors, 2. pH/ORP, pg. 34). a. pH Key (6PFCE)
A press of
b. ORP/Fr Chl Key (6PFCE)
displays pH readings. No units are displayed on the right.
In ORP mode, a press of
displays Oxidation-Reduction
Potential/REDOX reading in millivolts; “mV” is displayed.
When the FCE mode is activated, a press of
displays the Free
Chlorine Equivalent reading in “ppm” alternating with the FCE predictive ORP reading in “mV”.
4. CAL/MCLR Key
A press of allows you to enter the calibration mode while
measuring conductivity, TDS or pH. Once in CAL mode, a press of this
key accepts the new value. If no more calibration options follow, the instrument returns to measuring (ref. Leaving Calibration, pg. 17).
If
is held down for about 3 seconds when the ORP or FCE
functions are active, CAL mode is not entered. Instead either “OrP” or “Chl” will appear depending on which mode is active. Change modes by pressing the Up or Down buttons. Press any parameter key to exit ORP unit preference selection or let the unit time out. ORP unit preference will be saved.
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If is held down for about 3 seconds at any other time, CAL mode
but “SEL” appears to allow Solution Selection (ref. pg. 14) with the Up or is not entered, Down keys. As in calibration, the CAL key is now an “accept” key. While reviewing stored records, the MCLR side of the key is active to
allow clearing records (ref. Clearing a Record/Memory Clear, pg. 24).
5. UP or DOWN Keys
While measuring in any parameter, the or
the Memory Store and Memory Recall functions. While in CAL mode, the keys step or scroll the displayed value up or down. A single press steps the display and holding either key scrolls the value rapidly.
While in Memory Recall, the keys scroll the display up and down through the stack of records (ref. Memory Recall, pg. 23).
IV. AFTER USING THE ULTRAMETER II A. Maintenance of the Conductivity Cell Rinse out the cell cup with clean water. Do not scrub the cell. For oily
lms, squirt in a foaming non-abrasive cleaner and rinse (ref. Cleaning
Sensors, pg. 34). Even if a very active chemical discolors the electrodes, this does not affect the accuracy; leave it alone.
keys activate
B. Maintenance of the pH/ORP Sensor (6PFCE) The sensor well must be kept wet with a saline solution. Before replacing
the rubber cap, rinse and ll the sensor well with Myron L pH Sensor
Storage Solution. If unavailable, use an almost saturated KCl solution,
pH 4 buffer or a saturated solution of table salt and tap water (ref. pH and ORP Practices to Maintain Calibration, pg. 23). NEVER USE
DISTILLED WATER.
V. SPECIFIC RECOMMENDED MEASURING PROCEDURES If the proper solution is not selected (KCl, NaCl, 442 or User), see Solution Selection, pg. 14.
NOTE: After sampling high concentration solutions or temperature extremes, more rinsing may be required. When sampling low conductivity
solutions, be sure the pH cap is well seated so that no solution washes into the conductivity cell from around the pH cap.
A. Measuring Conductivity & Total Dissolved Solids (TDS)
1. Rinse cell cup 3 times with sample to be measured. (This conditions the temperature compensation network and prepares the cell.)
2. Rell cell cup with sample.
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3. Press or .
4. Take reading. A display of [- - - -] indicates an overrange condition.
B. Measuring Resistivity Resistivity is for low conductivity solutions. In a cell cup the value may drift from trace contaminants or absorption from atmospheric gasses, so
measuring a owing sample is recommended.
1. Ensure pH protective cap is secure to avoid contamination.
2. Hold instrument at 30° angle (cup sloping downward).
3. Let sample ow continuously into conductivity cell with no aeration.
4. Press
key; use best reading.
NOTE: If reading is lower than 10 kilohms display will be dashes: [ - - - - ]. Use Conductivity.
C. Measuring pH (6PFCE)
1. Remove protective cap by rotating while grasping and pulling up.
2. Rinse pH/ORP sensor well and conductivity cell cup 3 times with sample to be measured. Shake out each sample to remove any residual liquid.
3. Rell both sensor well and cell cup with sample.
4. Press
5. Note value displayed.
6. IMPORTANT: After use, ll pH/ORP sensor well with Myron L
pH Sensor Storage Solution and replace protective cap. If Myron L pH Sensor Storage Solution is unavailable, use a strong KCl solution, a pH 4 buffer, or a saturated solution of table salt and tap water (ref. Cleaning Sensors, 2. pH/ORP, pg.
34).
The Ultrameter II features the ability to measure the activity of oxidizing or reducing chemicals in solution as ORP mV. The instrument also includes an innovative Free Chlorine Equivalent (FCE) feature (Measuring Free Chlorine Using FCE, pg. 12) that uses ORP and pH to measure free available chlorine (FAC) concentration in ppm. ORP mV and ppm of free available chlorine (FAC) are the two most commonly used sanitizer units of measure in water quality management.
Do not allow pH/ORP sensor to dry out.
D. Measuring ORP
.
10
1. ORP / FCE Mode Selection
PPM
The Ultrameter II allows the user to choose between measuring oxidizing sanitizers using either ORP mV or as parts per million (ppm) of equivalent free chlorine. Use ORP to directly measure the oxidizing power of all sanitizers like ozone, bromine, peracetic acid or chlorine. Use FCE to measure the strength of oxidizing sanitizers as ppm of equivalent free chlorine. To select between ORP and Free Chlorine modes:
1. Press
.
2. Press and hold
for approximately 3 seconds.
The current preference for ORP units of measure is displayed. Factory setting for this preference is ORP mV.
3. Press the or
keys to toggle between mV (standard
ORP mode) and FCE ppm. The setting chosen is displayed.
4. Press any parameter key to exit ORP unit preference selection
or let the unit time out. ORP unit preference will be saved.
2. Measuring ORP
1. Ensure the 6PFCE is in ORP mode (ref. ORP Mode Selection,
pg. 10).
2. Remove protective cap by rotating while grasping and pulling up.
3. Rinse sensor well and cell cup 3 times with sample to be
measured. Shake out each sample to remove any residual liquid.
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4. Rell both sensor well and cell cup with sample.
5. Press .
6. Take reading.
7. Press MS to store reading in memory, if desired.
IMPORTANT: After use, ll pH/ORP sensor well with Myron L
pH Sensor Storage Solution and replace protective cap. If Myron L pH Sensor Storage Solution is unavailable, you can use a strong KCl solution, a pH 4 buffer, or a saturated solution of table salt and tap water (ref. Cleaning Sensors, 2. pH/ORP, pg. 34). Do not allow pH/ORP sensor to dry out.
E. Measuring Free Chlorine Using FC
E
The FCE function can be used to measure discrete samples, owing solution and bodies of water. Measurement technique is particular to the type of sample. For accurate results, use the FCE Flow Method described
in section 2 below to measure discrete or owing samples. Use the FCE
Immersion Method described in section 3 below in situations where the 6PFCE can be dipped to obtain a sample. Read through section 4. FCE Best Practices before you begin.
1. Prepare for FCE Measurement
1. For ease of measurement, set the instrument’s Auto oFF feature
to 75 sec (ref. Auto oFF, pg. 28).
2. Ensure the FCE mode has been activated (ref. ORP/FCE Mode Selection, pg. 10).
3. Remove protective cap from the pH/ORP sensor by rotating
while grasping and pulling up.
2. FCE Flow Method
1. Empty the pH/ORP sensor well of all storage solution.
2. Hold the 6PFCE at a 30º angle (cup sloping downward).
3. Thoroughly ush the sensor well and cell cup with a steady
stream of the solution you intend to measure by allowing the
solution to ow into and out of the sensor well and cell cup for at
least 10 seconds.
4. Let sample ow continuously into conductivity cell with no
aeration.
5. Allow both the sensor well and cell cup to remain lled with
sample.
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6. Press
predicted nal ORP value and a free chlorine equivalent
concentration in ppm. Both readings will change rapidly at rst.
7. Wait for the readings to stabilize. When the mV and ppm values are unchanging for 5 consecutive readings, the FCE reading has reached a stable level. This may take 1 to 2 minutes. NOTE: If the reading takes more than 1 minute to stabilize,
. The instrument will begin alternating between a
press the
from disturbing the measurement process. Annunciators will
alert you when either the pH or ORP of the nal FCE ppm value
are Out of Range (“-Or-”).
8. Press MS to store reading in memory if desired.
3. FCE Immersion Method
NOTE: Use this method for pools, spas and other large standing bodies of water.
1. Hold instrument beneath the surface of the water to avoid
surface effects on the water’s chemistry.
2. Swirl the instrument around for at least 10 seconds to thoroughly rinse the cell cup and sensor well.
3. Continue holding the instrument under the surface while taking the reading.
4. Press .
5. The instrument will begin alternating between a predicted nal
ORP value and a free chlorine equivalent concentration in ppm.
Both readings will change rapidly at rst.
after 1 minute to prevent Auto oFF feature
6. Wait for the readings to stabilize. When the mV and ppm values are unchanging for 5 consecutive readings, the FCE reading has reached a stable level. This may take 1 to 2 minutes. NOTE: If the reading takes longer than 1 minute to stabilize,
press after 1 minute to prevent Auto oFF feature from
disturbing the measurement process. Annunciators will alert
you when either the pH or ORP of the nal FCE ppm value are
Out of Range (“-Or-”).
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