Recommended use of the chemical and restrictions on use
Recommended use : Storage Protection
Revision Date:
11/4/2020
SDS Number:
MGSP1
McKees Rocks, PA 15136
Date of last issue: Date of first issue: 11/12/14
Restrictions on use : None known.
SECTION 2. HAZARDS IDENTIFICATION
The hazards reflected on this SDS are based upon industrial quantities (40-50 pounds) of diphenyl.
The risks posed by consumer quantities of 1.8 ounces or less are significantly lower.
GHS classification in accordance with 29 CFR 1910.1200
Skin irritation: Category 2
Eye irritation: Category 2A
Specific target organ
systemic toxicity - single
exposure
GHS label elements
Hazard pictograms:
Signal Word: Warning
: Category 3 (Respiratory system)
Hazard Statements: H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312 IF INHALED: Remove person t o fresh air
and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
P305 + P351 +
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Date of last issue: Date of first issue: 11/12/14
P338 IF IN EYES: Rinse cautiously with water
Disposal:
P501 Dispose of contents/ con
posal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture: Substance
Components
Chemical name CAS-No.Concentration (% w/w)
Biphenyl; diphenyl 92-52-490-100%
SECTION 4. FIRST AID MEASURES
If inhaled: Remove person to fresh air and keep comfortable for
breathing.
If breathing is difficult, give oxygen.
Consult a physician if necessary.
In case of skin contact: Wash off immediately with soap and plenty of water while
removing all contaminated clothes and shoes.
If skin irritation occurs: Get medical advice/ attention.
In case of eye contact: In case of contact, immediately flush eyes with plenty of water
If swallowed : Rinse mouth.
Most important symptoms
and effects, both acute and
delayed
Notes to physician: Treat symptomatically.
SECTION 5. FIRE-FIGHTING MEASURES
ision Date:
Rev
11/4/2020
SDS Number:
MGSP1
Wash contaminated clothing before reuse.
for at least 15 minutes.
Get medical attention if symptoms occur.
Never give anything by mouth to an unconscious person.
Get medical advice/ attention.
If swallowed, DO NOT induce vomiting unless directed to do
so by medical personnel.
: Causes skin irritation
Causes serious eye irritation.
May cause respiratory irritation.
The molten product can cause serious burns.
Date of last issue: Date of first issue: 11/12/14
.
Suitable extinguishing media : Water spray
Carbon dioxide (CO2)
Dry chemical
Foam
Unsuitable extinguishing
media
Hazardous combustion products
Further information : Use a water spray to cool fully closed containers.
Special protective equipment
or fire-fighters
f
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
: Do not use a solid water stream as it may scatter and spread
fire.
: Hazardous decomposition products due to incomplete
combustion
Carbon oxides
Do not allow run-off from fire fighting to enter drains or water
courses.
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.
: Ventilate the area.
Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
Avoid contact with skin and eyes.
Wash skin thoroughly after handling.
Wear appropriate personal protective equipment.
Local authorities should be advised if significant spillages
cannot be contained.
Environmental precautions : Clear up spills immediately and dispose of waste safely.
Methods and materials for
containment and cleaning up
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : Do not breathe vapors or spray mist.
Revision Date:
11/4/2020
SDS Number:
MGSP1
Collect spillage.
: Sweep up and shovel into suitable containers for disposal.
Handle product only in closed system or provide appropriate
exhaust ventilation at machinery.
In case of insufficient ventilation, wear suitable respiratory
equipment.
Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
Wear appropriate personal protective equipment.
Avoid contact with skin, eyes and clothing.
Wash thoroughly after handling.
Wash contaminated clothing before reuse.
Drain o
or maintenance.
Handle in accordance with good industrial hygiene and safety
practice.
r remove substance from equipment prior to break -in
Date of last issue: Date of first issue: 11/12/14
Minimize dust generation and accumulation.
Conditions for safe storage : Store locked up.
Keep container tightly closed in a dry and well-ventilated
place.
Keep in a cool place away from oxidizing agents.
Materials to avoid : Keep container tightly closed.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Biphenyl; diphenyl 92-52-4 TWA 0.2 ppm ACGIH
TWA 0.2 ppm
TWA 0.2 ppm
TWA 0.2 ppm
Engineering measures : Good general ventilation (typically 10 air changes per hour)
should be used. Ventilation rates should be matched to
conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain
airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne
Respiratory protection : Use a properly fitted, particulate filter respirator complying
Eye protection:Wear safety glasses with side shields (or goggles).
Revision Date:
11/4/2020
Hand protection
Remarks : Wear suitable gloves. When handling hot material, use heat
SDS Number:
MGSP1
levels to an acceptable level.
with an approved standard if a risk assessment indicates this
is necessary.
Respirator selection, use, and maintenance must be in
accordance with regulatory requirements, if applicable.
If engineering controls do not maintain airborne
concentrations below recommended exposure limits (where
applicable) or to an acceptable level (in c
exposure limits have not been established), an approved
respirator must be worn.
resistant gloves.
Date of last issue: Date of first issue: 11/12/14
ountries where
Skin and body protection: Wear suitable protective clothing.
Protective measures: Ensure that eye flushing systems and safety showers are
located close to the working place.
SECTION 9. PHYSICAL AND CHEMICAL
Appearance : Tablets, or solid bar
Color : white
Odor : aromatic
Odor Threshold : not determined
pH : not determined
Melting point/range : 156 °F / 69 °C
Boiling point/boiling range: 491 °F / 255 °C
Flash point : 235 °F / 113 °C
PROPERTIES
(1,013 hPa)
(1,013 hPa)
Method: Cleveland open cup
Evaporation rate
Flammability (solid, gas) : May form combustible dust concentrations in air during proc e-
: not determined
5 / 14
Loading...
+ 9 hidden pages
You need points to download manuals.
1 point = 1 manual.
You can buy points or you can get point for every manual you upload.