NA
This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
Company
Telephone
Emergency telephone
: For emergencies involving spill, leak, fire, exposure or acc
i-
Medical Emergency
Recommended use
: A formulated multi
-
purpose cleaner
Eye irritation
: Category 2A
Signal word
:
Warning
MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
product. For information regarding consumer applications of this product, refer to the product label.
Version 1.0 SDS Number: 660000000228 Revision Date: 05/19/2015
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name
Product code : 200000028236
: B02906500003
Manufacturer or supplier's details
number
(24HR):
Recommended use of the chemical and restrictions on use
: MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
: Colgate-Palmolive Co
300 Park Avenue
New York, NY 10022
: US: Consumer Affairs - 1-800-468-6502
dent call CHEMTREC (24hr) at (800) 424-9300 or
(703) 527-3887.
For MEDICAL EMERGENCIES involving this product call:
(888) 489-3861
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance
Colour
GHS Classification
Skin irritation
Skin sensitisation
GHS Label element
Hazard pictograms
liquid
amber
: Category 2
: Category 1
:
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NA
This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
Hazard statements
: H315
Causes skin irritation.
Prevention
:
Inhalation
: No adverse effects due to inhalation are expected.
Aggravated Medical Cond
i-
: None known.
IARC
ACGIH
OSHA
NTP
MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
product. For information regarding consumer applications of this product, refer to the product label.
Version 1.0 SDS Number: 660000000228 Revision Date: 05/19/2015
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
Precautionary statements
Potential Health Effects
:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
Disposal:
P501 Dispose of contents/ container to an approved waste disposal plant.
Skin
Eyes
Ingestion
tion
Carcinogenicity:
: May cause skin irritation upon prolonged contact.
: Causes eye irritation on direct contact.
: May be harmful if swallowed in large quantities.
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
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NA
This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
by NTP.
In case of skin contact
Flush skin with large amounts of water. If irritation develops
Most important symptoms
Causes skin irritation.
Suitable extinguishing media
Use water spray, alcohol
-
resistant foam, dry chemical or ca
r-
Methods and materials for
Cover with inert, absorbent material and remove to disposal
MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
product. For information regarding consumer applications of this product, refer to the product label.
Version 1.0 SDS Number: 660000000228 Revision Date: 05/19/2015
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Chemical Name CAS-No. Concentration (%)
SODIUM HYDROXIDE 1310-73-2 >= 1 - < 5
CITRONELLA (CYMBOPOGON NARDUS) OIL 8000-29-1 >= 0.1 - < 1
SECTION 4. FIRST AID MEASURES
If inhaled
In case of eye contact
If swallowed
and effects, both acute and
delayed
SECTION 5. FIREFIGHTING MEASURES
Hazardous combustion products
Special protective equipment
for firefighters
: Remove victim to fresh air. Get medical attention, if symp-
toms persist.
:
and persists, get medical attention.
: Flush eyes with water at least 15 minutes. Get medical atten-
tion if eye irritation develops or persists.
: Drink 8 ounces of clear water. Get medical attention.
:
May cause an allergic skin reaction.
Causes serious eye irritation.
:
bon dioxide.
: No hazardous combustion products are known
: Self-contained breathing apparatus and full protective clothing
should be worn when fighting chemical fires.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
containment and cleaning up
: Use personal protection recommended in Section 8 of the
SDS.
:
container. Spill area may be slippery. Flush with plenty of water.
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NA
This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
Conditions for safe storage
Store at controlled room temperature at 20
-
25°
C (68
-
77°F).
Engineering measures
:
In an industrial work environment, no special precautions or
Density
1.0 g/cm3
MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
product. For information regarding consumer applications of this product, refer to the product label.
Version 1.0 SDS Number: 660000000228 Revision Date: 05/19/2015
SECTION 7. HANDLING AND STORAGE
:
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type
SODIUM HYDROXIDE 1310-73-2 C 2 mg/m3 ACGIH
C 2 mg/m3 NIOSH REL
TWA 2 mg/m3 OSHA Z-1
C 2 mg/m3 OSHA P0
(Form of
exposure)
Control parameters / Permissible
concentration
Basis
control measures are required.
Personal protective equipment
Respiratory protection
Protective measures
Hygiene measures
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Colour
pH
Flash point
: No personal respiratory protective equipment normally re-
quired.
: In an industrial work environment, if a splash is likely, chemi-
cal goggles may be needed. Prolonged skin contact may
require protective gloves. For consumer use, no unusual
precautions are necessary.
: In an industrial work environment, avoid eye and prolonged
skin contact.
: liquid
: amber
: 11.0
: > 200 °F
:
SECTION 10. STABILITY AND REACTIVITY
Possibility of hazardous reactions
: Hazardous polymerisation does not occur.
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NA
This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
Incompatible materials
Strong oxidizing agents
Acute oral toxicity
LD50
(Rat
):
> 5,000 mg/kg
Remarks
:
No data available
Result
:
Risk of serious damage to eyes.
MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
product. For information regarding consumer applications of this product, refer to the product label.
Version 1.0 SDS Number: 660000000228 Revision Date: 05/19/2015
:
Hazardous decomposition
products
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity
Components:
SODIUM HYDROXIDE:
Acute oral toxicity
Acute inhalation toxicity
Acute dermal toxicity
CITRONELLA (CYMBOPOGON NARDUS) OIL:
Acute inhalation toxicity
Acute dermal toxicity
Skin corrosion/irritation
Causes skin irritation.
Components:
SODIUM HYDROXIDE:
: None known.
: Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
: LD50 (Rabbit): 500 mg/kg
: Remarks: No data available
: Remarks: No data available
:
: Remarks: No data available
: LD50 (Rabbit): > 5,000 mg/kg
Method: No information available.
CITRONELLA (CYMBOPOGON NARDUS) OIL:
Result: Severe skin irritation
Serious eye damage/eye irritation
Causes serious eye irritation.
Components:
SODIUM HYDROXIDE:
Remarks: No data available
CITRONELLA (CYMBOPOGON NARDUS) OIL:
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NA
This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
Exposure routes
:
Dermal
Remarks
:
This product has not been t
ested as a whole. However, this formula was reviewed by
MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
product. For information regarding consumer applications of this product, refer to the product label.
Version 1.0 SDS Number: 660000000228 Revision Date: 05/19/2015
Respiratory or skin sensitisation
Skin sensitisation: May cause an allergic skin reaction.
Respiratory sensitisation: Not classified based on available information.
Components:
SODIUM HYDROXIDE:
Exposure routes: Inhalation
Remarks: No data available
Remarks: No data available
CITRONELLA (CYMBOPOGON NARDUS) OIL:
Exposure routes: Inhalation
Remarks: No data available
Exposure routes: Dermal
Result: May cause sensitisation by skin contact.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Further information
Product:
expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is
determined to be safe for its intended use. This review has taken into consideration available
safety-related information including information on individual ingredients, similar formulas and
potential ingredient interactions. This review is a component of the hazard determination used to
prepare the statements in Section 3 of the SDS.
SECTION 12. ECOLOGICAL INFORMATION
The product has not been tested as a whole for environmental toxicity. However, environmental
information on the ingredients in this product have been reviewed by the Environmental, Health and
Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This
evaluation is based on available information on individual ingredients, interactions of ingredients,
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NA
This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
DOT :
TDG :
IATA
:
IMDG
:
OSHA Hazards
: Toxic by ingestion
SARA 311/312
Hazards
MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
product. For information regarding consumer applications of this product, refer to the product label.
Version 1.0 SDS Number: 660000000228 Revision Date: 05/19/2015
and similar ingredients. Biodegradability claims are supported by data on ingredients (i.e., surfactants
are biodegradable) or testing conducted on the final product (i.e., This product is biodegradable).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Any disposal practice must be in compliance with local, state
and federal laws and regulations (contact local or state environment agency for specific rules). Do not dump in sewers,
any body of water or on the ground.
SECTION 14. TRANSPORT INFORMATION
Not regulated.
Not regulated.
Not regulated.
Not regulated.
International Regulation
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
SODIUM HYDROXIDE 1310-73-2 1000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
Calculated product RQ
(lbs)
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
: Acute Health Hazard
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NA
This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
SARA 302
: No chemicals in this material are subject to the reporting r
e-
SARA 313
SODIUM HYDROXIDE
1310
-73-2
Sodium tallate
61790
-45-2
California Prop 65
:
MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
product. For information regarding consumer applications of this product, refer to the product label.
Version 1.0 SDS Number: 660000000228 Revision Date: 05/19/2015
quirements of SARA Title III, Section 302.
: This material does not contain any chemical components with
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A:
SODIUM HYDROXIDE 1310-73-2
The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table
117.3:
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
Massachusetts Right To Know
Pennsylvania Right To Know
Sodium tallate 61790-45-2
New Jersey Right To Know
The components of this product are reported in the following inventories:
TSCA
Inventories
SODIUM HYDROXIDE 1310-73-2
TRISODIUM NITRILOTRIACETATE 5064-31-3
WATER Water
SODIUM HYDROXIDE 1310-73-2
WATER Water
SODIUM HYDROXIDE 1310-73-2
This product does not contain any chemicals known to State
of California to cause cancer, birth defects, or any other reproductive harm.
: All ingredients in this product are listed on the TSCA Inventory
or are not required to be listed on the TSCA Inventory.
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
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NA
This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
NFPA:
HMIS III:
1 0
PHYSICAL HAZARD
1 0 1
MURPHY OIL SOAP WOOD CLEANER LIQUID - ORIGINAL
product. For information regarding consumer applications of this product, refer to the product label.
Version 1.0 SDS Number: 660000000228 Revision Date: 05/19/2015
SECTION 16. OTHER INFORMATION
Further information
Flammability
1
Health
Disclaimer: The information on this sheet is limited to the material identified and is believed by
the Colgate-Palmolive Company to be correct based on its knowledge and information as of
the date noted. Colgate makes no representation, guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss resulting from the use of the material.
Special hazard.
Instability
HEALTH
FLAMMABILITY
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
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