Page 1
Cleaner.
SAFETY DATA SHEET
Product name
Distributed by
Product use
1. Product and company identification
:
:
:
D0041252 v7.0
:
SDS #
Formulation #:
:
#0041250_12
Professional MOP & GLO® Multi-Surface Floor Cleaner - Fresh Citrus Scent
:
Website:
http://www.rbnainfo.com
Emergency telephone
number (Medical)
Emergency telephone
number (Transport)
:
1-800-338-6167
1-800-424-9300 (U.S. & Canada) CHEMTREC
Outside U.S. and Canada (North America), call Chemtrec:703-527-3887
:
This SDS is designed for workplace employees, emergency personnel and for other conditions and situations
where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of
USDOL Occupational Safety and Health Administration.
This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid
language is provided on the product label in accordance with the applicable government regulations, and shown
in Section 15 of this SDS.
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
Reckitt Benckiser LLC.
Morris Corporate Center IV
399 Interpace Parkway (P.O. Box 225)
Parsippany, New Jersey 07054-0225
+1 973 404 2600
Reckitt Benckiser (Canada) Inc.
1680 Tech Avenue, Unit #2
Mississauga, Ontario L4W 5S9
CANADA
Telephone: +1 905 283 7000
2. Hazards identification
Classification of the
substance or mixture
Not classified
:
Signal word
:
No signal word.
Hazard pictograms
:
GHS label elements
Not applicable.
1/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Professional MOP & GLO® Multi-Surface Floor Cleaner - Fresh Citrus Scent
Page 2
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
2. Hazards identification
Hazard statements
:
No known significant effects or critical hazards.
Supplemental label
elements
:
None known.
Hazards not otherwise
classified
:
None known.
General
Prevention
:
Not applicable.
Response
:
Not applicable.
Storage
:
Not applicable.
Disposal
:
Not applicable.
:
Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Precautionary statements
3. Composition/information on ingredients
Mixture
:
Substance/mixture
Poly(oxy-1,2-ethanediyl), α-tridecyl-ω-hydroxy-
1 - 2.5
24938-91-8
Diethylene glycol monoethyl ether
0.1 - 1
111-90-0
Ingredient name
CAS number
%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
4. First aid measures
Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur.
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
May cause eye irritation upon direct contact with eyes.
:
Eye contact
Over-exposure signs/symptoms
Inhalation
No specific data.
:
Eye contact
:
No specific data.
Potential acute health effects
2/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Page 3
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
Skin contact
Ingestion
No specific data.
No specific data.
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:::
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
3/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Page 4
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill
:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill
:
7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
:
Protective measures
Put on appropriate personal protective equipment (see Section 8).
:
Precautions for safe handling
Diethylene glycol monoethyl ether
AIHA WEEL (United States, 10/2011).
TWA: 25 ppm 8 hours.
8. Exposure controls/personal protection
Ingredient name
Exposure limits
Hand protection
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with sideshields.
Eye/face protection
:
:
Environmental exposure
controls
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:
Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures
:
Control
Individual protection measures
Occupational exposure limits
Skin protection
4/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Page 5
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection
:
Body protection
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid. [Liquid.]
Not available.
1.009 to 1.011
Not available.
Not available.
Not available.
Citrus
Odor
pH
Tan.
Color
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.3°C (>199.9°F)
Not available.
8 to 9 [Conc. (% w/w): 100%]
Not available.
Odor threshold
Partition coefficient: noctanol/water
:::
:
:
:
:
:
:
:
:
:
::Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive
(flammable) limits
:
Not available.
Decomposition temperature
:
Not available.
Viscosity
Dynamic (room temperature): 3 to 10 mPa·s (3 to 10 cP)
:
Flow time (ISO 2431)
:
Not available.
Aerosol product
Heat of combustion
:
0.000000001 kJ/g
10. Stability and reactivity
Conditions to avoid
No specific data.
The product is stable.
Chemical stability
No specific data.
:
:
Incompatible materials
:
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
5/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Page 6
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
10. Stability and reactivity
Hazardous decomposition
products
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
:
11. Toxicological information
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
Irritation/Corrosion
Poly(oxy-1,2-ethanediyl), αtridecyl-ω-hydroxy-
Skin - Mild irritant
Rabbit
-
672 hours 2
Grams
-
Diethylene glycol monoethyl
ether
Eyes - Mild irritant
Rabbit
-
125
milligrams
-
Eyes - Moderate irritant
Rabbit
-
500
milligrams
-
Skin - Mild irritant
Rabbit
-
24 hours 500
milligrams
-
Product/ingredient name
Result
Score
Exposure
Observation
Species
Information on toxicological effects
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Sensitization
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Information on the likely
routes of exposure
Inhalation
:
No known significant effects or critical hazards.
Skin contact
:
No known significant effects or critical hazards.
May cause eye irritation upon direct contact with eyes.
:
Eye contact
:
Not available.
Potential acute health effects
Diethylene glycol monoethyl
ether
LD50 Oral
Rat
7500 mg/kg
-
6/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Page 7
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
11. Toxicological information
Not available.
No known significant effects or critical hazards.
:
Ingestion
No known significant effects or critical hazards.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
No specific data.
:
::Eye contact
:
No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate
effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
12. Ecological information
Toxicity
Poly(oxy-1,2-ethanediyl), αtridecyl-ω-hydroxy-
Acute LC50 0.71 mg/l Marine water
Crustaceans - Americamysis
bahia
48 hours
Acute LC50 7500 µg/l Fresh water
Fish - Lepomis macrochirus
96 hours
Diethylene glycol monoethyl
ether
Acute LC50 3340000 µg/l Fresh water
Daphnia - Daphnia magna Neonate
48 hours
Acute LC50 6010000 µg/l Fresh water
Fish - Ictalurus punctatus
96 hours
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
7/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Page 8
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
12. Ecological information
LogP
ow
BCF
Potential
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Product/ingredient name
Diethylene glycol monoethyl
ether
-0.54
-
low
Soil/water partition
coefficient (KOC)
:
Not available.
Mobility in soil
Not available.
13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
:
Disposal methods
14. Transport information
Not available.
-
DOT Classification
TDG Classification
Not available.
Not applicable.
-
Not
Regulated
Not applicable.
-
IMDG Class
Not applicable.
Not available.
-
Not applicable.
Not
Regulated
IATA-DGR Class
Not available.
Regulatory
information
UN number
Proper shipping
name
Classes
PG*
Label
Additional
information
-
Not
Regulated
-
-
Not
Regulated
-
Mexico
Classification
Not
Regulated
Not applicable.
Not available.
-
-
8/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Page 9
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
14. Transport information
PG* : Packing group
Special precautions for user
Transport within user’s premises:
always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307
: zinc oxide
Clean Water Act (CWA) 311
: ammonia; sodium hydroxide; potassium hydroxide
:
TSCA 8(a) PAIR
: 2-(4-tert-butylbenzyl)propionaldehyde
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
United States inventory (TSCA 8b)
: All components are listed or exempted.
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Listed
Clean Air Act Section 602
Class I Substances
:
Not listed
Clean Air Act Section 602
Class II Substances
:
Not listed
DEA List I Chemicals
(Precursor Chemicals)
:
Not listed
DEA List II Chemicals
(Essential Chemicals)
:
Not listed
SARA 313
Product name
CAS number
%
2-(2-ethoxyethoxy)ethanol
111-90-0
1
2-(2-ethoxyethoxy)ethanol
111-90-0
1
Form R - Reporting
requirements
Supplier notification
SARA 302/304
SARA 304 RQ
:
Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification
:
Not applicable.
Poly(oxy-1,2-ethanediyl), α-tridecyl-ωhydroxy-
1 - 2.5
No.
No.
No.
Yes.
No.
Diethylene glycol monoethyl ether
0.1 - 1
Yes.
No.
No.
Yes.
No.
Name
%
Fire
hazard
Sudden
release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
9/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Page 10
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
15. Regulatory information
No signal word.
No specific hazard.
Keep out of reach of children.
Do not mix bleach based cleaning products with ammonia.
Signal word
:
Hazard statements
:
Precautionary measures
:
Label elements
None of the components are listed.
Massachusetts
:
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
New York
:
None of the components are listed.
New Jersey
:
The following components are listed: GLYCOL ETHERS
Pennsylvania
:
The following components are listed: GLYCOL ETHERS
State regulations
None of the components are listed.
WHMIS (Canada)
Class D-2B: Material causing other toxic effects (Toxic).
:
Canada
Canadian NPRI
:
Canada inventory
:
All components are listed or exempted.
CEPA Toxic substances
:
None of the components are listed.
Canadian lists
16. Other information
Hazardous Material
Information System (U.S.A.)
0
0
0
000
National Fire Protection
Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
:
:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the complete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.
Personal protection
A
10/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
Page 11
D0041252 v7.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
16. Other information
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue
Date of previous issue
Version
:
:
:
Indicates information that has changed from previously issued version.
18/05/2017
09/10/2014.
7
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA
49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 systems to classify chemicals does so at their own risk.
Prepared by
:
Reckitt Benckiser LLC.
Product Safety Department
1 Philips Parkway
Montvale, New Jersey 07646-1810 USA.
FAX: 201-476-7770
Revision comments
:
Addition of Canada address on section 1.
RB is a member of the CSPA Product Care Product Stewardship Program.
Key to abbreviations
:
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
11/11
18/05/2017
Date of issue
:
SDS #
FF0041250
(D0041252) NA
:
Code #
D0041252 v7.0
:
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