Misty AMRA32916 User Manual

Page 1
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
Mat erial name
:
A00329 MS T SI-DRY S ILICONE 16net 11 Mat erial number
:
000000000001033585
Company
:
Zep Inc .
Address
:
1310 Seaboard Indus trial B lvd. , NW At l anta, GA 30318 Telephone
:
404-352-1680
Em ergency telephone numbers
For SDS Information
:
Complianc e Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transporta tion Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded. In t he Di stric t of Columbia 202 -483-7616
Recommended use
:
Lubricant Appearance
Aeros ol cont aining a l iquefied gas
Colour
colourless
Odour
hydrocarbon-like
Flammable aerosols
:
Category 1
Gases under pressure
:
Liquefied gas
Skin irritation
:
Category 2
Eye irritation
:
Category 2A
Spec i fic target organ t oxici ty ­si ngle expos ure
:
Category 3 (Central nervous system)
Hazard pic tograms
:
Signal word
:
Danger
Hazard statements
:
H222 Extremely flammable aerosol. H280
Contai ns gas under pressure; m ay expl ode if heated.
H315
Causes skin irritat ion.
H319
Caus es serious eye irrit ation.
H336
May c ause drows iness or diz zines s.
SECTI ON 1. PRODUCT AND COMPANY IDENTIFICATION
Manufa cturer or supplier's detail s
Recommended use of the chemical and restrict ions on us e
SECTI ON 2. HAZARDS IDENTIFI CATION
Emergency Overview
GHS Cl a ssifi ca tion
GHS label elements
1 / 12
Page 2
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
Precautionary stat ements
:
Prevention: P210
Keep away from heat/s parks /open flames /hot surfac es. No sm oking. P211 Do not spray on an open flame or ot her ignit ion sourc e. P251
Pres suriz ed cont ainer: Do not pi erce or burn, even aft er use. P261
A void breathing dust/ fume/ gas/ mist/ vapours/ spray.
P26
4 W ash ski n thoroughly aft er handling.
P271
Us e onl y outdoors or i n a wel l-vent i lated area.
P280 W ear prot ective gl oves/ eye prot ecti on/ face protec tion.
Re sponse
:
P302 + P352 IF ON S KIN: W ash with plenty of s oap and water. P304 + P340 + P312
IF INHALED: Remove person to fresh air and keep c omfortable for breathi ng. Call a POISON CENTER/doc tor i f you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for s everal minutes. Rem ove contac t lenses, i f present and easy to do. Con
tinue rinsing.
P332 + P313
If ski n i rritation oc c urs: Get medic al advice/ attention. P337 + P313
If eye irrit ation pers is ts: Get medic al advi ce/ attention. P362 Take off c ontami nated clot hing and wash before reuse.
Stora ge
:
P403 + P233
S tore i n a well-ven
tilated place. Keep container ti ght l y cl os ed. P405
St ore l ock ed up.
P410 + P412
P rotect from sunli ght. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal
:
Dispose of c ont ents/ container in ac cordance wi t h l ocal regulation.
Subs tanc e / Mi xt ure
:
Mixture
Chemic al name
CAS-No.
Concentration
[%]
acetone
67-64-1
>= 30 - < 50
Distillates (petroleum), light distillate hydrotreating proc ess , low-boiling
68410-97-9
>= 20 - < 30 butane
106-97-8
>= 20 - < 30
propane
74-98-6
>= 5 - < 10
General advice
:
Move out of dangerous area. Show this safety data sheet to t he doctor i n attendanc e. Do not leave the vict i m unatt ended.
If inhaled
:
Consult a physi cian after signific ant ex posure. If unconsc ious place i n rec overy pos iti on and s eek medic al
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Haza rdous compone nts
The ex act percentages of disc losed s ubst ances are wi thheld as trade sec rets.
SECTION 4 . FI RST AI D MEAS URES
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Page 3
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
advice.
In cas e of s kin c ontac t
:
If skin irritation persists, call a physician. W ash off im mediat ely wi th plent y of water for at least 15 minutes. If on clothes , rem ove c lothes .
In cas e of ey e c ontac t
:
Remove contact lenses. Flush eyes wi t h water at l east 15 mi nutes. Get m edi cal att ention i f ey e i rritation devel ops or persists . Keep ey e wi de open whil e rinsi ng.
If s wal lowe d
:
Keep res piratory t ract cl ear. DO NOT induc e vom iting unles s direct ed to do so by a phys ic ian or poi son c ontrol c enter.
Suit able ex tingui shing m edia
:
Alc ohol-res ist ant foam Carbon dioxide (CO2) Dry c hem i cal
Unsuit able extinguishing media
:
High volum e wat er jet
Spec i fic hazards during firefighting
:
Do not allow run-off from fire fight ing to enter drains or water courses.
Hazardous combus tion products
:
Carbon dioxide (CO2) Carbon monoxide Smoke Silicon oxides
Spec i fic ext i ngui shing methods
:
Use ex tinguishing measures that are appropriat e to local ci rc um stances and the s urroundi ng environment.
Further information
:
Collec t contam inated fire ex tinguis hing water s eparately . This mus t not be discharged i nto drai ns. Fire res idues and c ontam inated fire ex tinguis hing wat er mus t be dis posed of in ac cordanc e with loc al regulations . For safety reasons in case of fire, cans sh
ould be stored separat ely i n c los ed cont ainment s. Use a water spray to cool full y clos ed containers.
Spec i al protect i ve equi pm ent for fi refi ght er s
:
Wear self-contained breathing apparatus for firefighting if necessary.
Pers onal precaut ions , protective equipment and emergency procedures
:
Use pers onal protec tive equipment . Ens ure adequate vent ilat ion. Remove all sourc es of ignit ion. Evacuate personnel to safe areas. Beware of vapours acc umulat ing t o form ex plosi ve concentrat i ons . V apours can accum ul ate i n l ow areas .
SECTI ON 5. FI REFIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
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Page 4
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
Environmental precautions
:
Prevent produc t from enteri ng drai ns. Prevent further leak age or spil lage if safe t o do s o. If the produc t c ontami nates ri vers and l akes or drains inform respective authorities.
Met hods and mat erials for cont ainment and cl eaning up
:
Soak up with inert abs orbent material (e. g. sand, silica gel, aci d bi nder, universal binder, sawdust ). Sweep up
or vac uum up spi llage and collec t in s uit able
container for dis posal.
Advice on safe handling
:
Do not breathe vapours or spray m ist . Avoid exposure
- obtain s pecial instruc tions before us e.
Avoid contact wi
th skin and ey es . For personal prot ect ion see sec tion 8. Smok ing, eat ing and drink ing shoul d be prohibi ted i n t he applic ati on area. Take precaut ionary meas ures agains t s tat ic di sc harges. Provide suffic ient ai r exc hange and/or exhaus t in work rooms. Open dr
um carefully as content m ay be under pressure. Dispos e of rinse water in accordanc e with l ocal and national regulations. Alway s replace c ap after us e.
Conditi ons for safe st orage
:
BE WA RE: A erosol i s pres suriz ed. Keep away from direc t sun exposure and temperatures over 50 °C. Do not open by force or throw int o fire even after use. Do not spray on flames or red
-hot objec ts. No sm oking. Containers which are opened must be carefully res ealed and kept upright to prevent leak age. Observe label precautions. Electrical installations / working materials must comply with the t echnological s afet y st andards. Keep in a dry, cool and well
-ventilated place.
Mat erials t o avoid
:
Oxi dizi ng agents
Components
CAS-No.
Value t ype (Form of exposure)
Control parameters Permissible concentration
Basis
acetone
67-64-1
TWA
500 ppm
ACGIH
STEL
750 ppm
ACGIH
TWA
250 ppm 590 mg/ m3
NIOSH RE L
TWA
1,000 ppm 2,400 m g/m3
OSHA Z-1
SECTI ON 7. HANDLI NG AND STORAGE
SECTI ON 8. EXP OSURE CONTROLS /PERSONAL PROTECTI ON
Components with workplace control parameters
/
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Page 5
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
TWA
750 ppm 1,800 m g/m3
OSHA P 0
STEL
1,000 ppm 2,400 m g/m3
OSHA P 0
Distillates (petroleum), light distillate hydrot reating process, low-boiling
68410-97-9
TWA
500 ppm 2,000 m g/m3
OSHA Z-1
TWA
400 ppm 1,600 m g/m3
OSHA P 0
butane
106-97-8
TWA
800 ppm 1,900 m g/m3
NIOSH RE L
TWA
800 ppm 1,900 m g/m3
OSHA P 0
propane
74-98-6
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm 1,800 m g/m3
NIOSH RE L
TWA
1,000 ppm 1,800 m g/m3
OSHA Z-1
TWA
1,000 ppm 1,800 m g/m3
OSHA P 0
Component
CAS-No.
Control
parameters
Biological specimen
Sampling
time
Permissible
concentration
Basis
2-PROPANONE
67-64-1
Acetone
Urine
End of
shift (As
soon as
possible
after
exposure
ceases)
50 mg/ l
ACGIH BEI
Respiratory protection
:
In t he case of vapour format i on use a respirator with an approved filter.
Remarks
:
The suitability for a specific workplace should be disc uss ed with the produc ers of the protect ive gloves.
Ey e protect i on
:
Ey e wash bottle wi t h pure water Tightly fitt ing safet y goggles Wear face-shield and protective suit for abnormal processing problems.
Sk i n and body prot ection
:
Impervious clothing Choose body prot ec tion according to the amount and concentrat i on of t he dangerous substanc e at the work place.
Hygiene measures
:
W hen usi ng do not eat or drink . W hen using do not smok e. W ash hands before break s and at t he end of work day.
Biologica l occupational exposure l i m i ts
Pe rsonal protective equi pm ent
Hand protection
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Page 6
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
Appearance
:
Aeros ol cont aining a l iquefied gas
Colour
:
colourless
Odour
:
hydrocarbon-like
Odour Threshold
:
No data availabl e
pH : Not appli cable
Melt ing point /freezi ng poi nt
:
No data availabl e
Boil ing point
:
No data availabl e
Flash point
:
No data availabl e
Evaporation rate
:
> 1
Flammabilit y (solid, gas)
:
Ex tremely flam m abl e aerosol .
Upper explos ion limit
:
No data availabl e
Lower explos ion limit
:
No data availabl e
Vapour pressure
:
No data availabl e
Relative vapour density
:
No data availabl e
Density
:
No data availabl e
Water solubility
:
partly sol ubl e
Part iti on coeffici ent: n ­octanol/water
:
No data availabl e
Auto-ignition temperature
:
not det erm i ned
Thermal decomposition
:
No data availabl e
Heat of com bust ion
:
39.79 k J/g
Reactivity
:
Stable
Chemic al stability
:
St able under normal c onditions .
Possibility o f hazar dous reactions
:
Vapours may form ex plosive mixture with air. No decom posit ion if st ored and applied as direc ted.
Conditions to avoid
:
Heat, flames and s parks . Ex tremes of t emperature and direc t s unlight .
Incompatible mat erials
:
Oxi dizi ng agents
Hazardous decompos ition
:
Carbon oxides
SECTI ON 9. PHYSICAL AND CHEMICAL PROPERTI ES
Solubility(ies)
SECTI ON 10. STABILITY AND REACTIVITY
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Page 7
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
products
IARC
Group 2B : Poss i bl y carci nogenic t o humans
Distillates (petroleum), light distillate hydrot reating proc ess , low-boiling
68410-97-9
OSHA
No com ponent of this product present at levels greater than or equal to 0. 1% i s identi fied as a carcinogen or potent i al carcinogen by OSHA.
NTP
No com ponent of this product present at levels greater than or equal to 0. 1% i s identi fied as a known or an tic i pat ed carc i nogen by NTP.
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg Method
: Calc ulat ion method
Acute oral toxicity
:
LD50 Rat: 5,800 mg/ k g
Acute inhalation toxic ity
:
LC50 Rat: 132 mg/l Exposure time
: 3 h
LC50 Rat: 50.1 mg/l
Acute derm al toxicity
:
LD50 G uinea pig: > 7,426 m g/k g
LD50 Rabbit: > 7,426 mg/kg
Acute inhalation toxic ity
:
LC50 Mouse: 1,237 mg/l Exposure time
: 2 h
LC50 Rat: 1,355 mg/l
Acute inhalation toxic ity
:
LC50 Mouse: 1,237 mg/l Exposure time
: 2 h
LC50 Rat: 658 mg/l
SECTI ON 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinoge nicity:
Acute toxicity
Product:
Components: acetone:
butane:
propane:
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Page 8
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
Exposure time: 4 h
LC50 Rat: 1,355 mg/l
Remark s: Irritating to skin.
Remark s : Ey e irri tat ion
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. , Concent rations subs tantially above the T LV value may caus e narc otic effects., Solvents may degrease the skin.
Skin corrosion/i rri ta ti on
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
No data availabl e
Germ ce ll mutagenicity
No data availabl e
Carcinoge nicity
No data availabl e
Reproductive toxi city
No data availabl e
acetone: Distilla tes (pe troleum), light distillate hydrotreating proce ss, low -boiling: butane: propane:
STOT - single exposure
No data availabl e
STOT - repeated exposure
No data availabl e
Aspirati on toxicity
No data availabl e
Further i n formation
Product:
SECTI ON 12. ECOLOGICAL INFORMATION Ecotoxicity
8 / 12
Page 9
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
Partit ion c oeffic ient: n­octanol/water
:
Remarks: N o data available
Partit ion c oeffic ient: n­octanol/water
:
Pow: 2.89
Regulation
40 CFR Protection of Environment; Part 82 Protection of St
ratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air A ct Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological in
formation
:
An environmental haz ard cannot be excluded in the event of unprofess ional handling or disposal. , Harm ful to aquatic life with long lasting effec ts .
W as te from residues
:
Dispos e of in accordanc e with l ocal regulations . The product shoul d not be allowed to enter drains , water courses or the s oi l . Do not contam inate ponds , wat erways or ditc hes with chem ical or us ed cont ainer.
Contaminated packaging
:
Empty rem ai ning contents . Dispos e of as unused product . Do not re
-use empty c ontainers.
Do not burn, or use a cut ting torch on, the empty drum .
Transportation Regulation: 49 CFR (USA):
No data availabl e
Persistence and degradability
No data availabl e
Bioaccum u l ative potential
Product:
Components: butane :
Mobility in soil
No data availabl e
Other adverse effects
No data availabl e
Product:
SECTI ON 13. DISPOSAL CONSIDERATI ONS
Disposal me thods
SECTI ON 14. TRANSPORT INFORMATION
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Page 10
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
ORM-D, CONSUME R COMMODITY
Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, 2.1, - Limited quant ity
Transportation Regulation: IATA (Cargo Air): UN1950, Aeros ols, flammabl e, 2.1, - Limit ed quantit y
Transportation Regulation: IATA (Passenger Air): UN1950, Aeros ols, flammabl e, 2.1, - Limit ed quantit y
Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, 2.1, - Limited quant ity
TS CA li st
:
No subs tanc es are subjec t to a Signi ficant New Use Rule.
No subs tanc es are subjec t to TSCA 12(b) ex port not ificat ion requirements.
Components
CAS
Component RQ
(lbs)
Calculated product RQ
(lbs)
acetone
67-64-1
5000
*
SARA 311/312 Hazards
:
Sudden Releas e of Press ure Hazard Ac ute Health Hazard Fire Haz ard
SARA 302
:
No chemicals i n this material are subjec t to the reporti ng requirement s of SARA Tit l e III, Sec tion 302.
SARA 313
:
This mat erial does not contai n any chemi cal component s wit h known CAS num bers t hat exceed the threshold (De Mi ni m i s) reporting levels established by SARA Title III, S ect ion 313.
Calif ornia Prop 65
This produc t does not contain any chemic als k nown to Stat e of California t o cause cancer, birth defec ts, or any other reproductive harm.
The product as delivered t o the c ust omer conforms to pack aging requirement s for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation class ifications noted above are for referenc e onl y, and not a c erti ficati on or warrant y of th e s uit ability of the packaging for shipm ent under thes e al ternati ve t ransport regul ations .
SECTI ON 15. REGULATORY INFORMATION
EPCRA - Emerg ency P la n n ing an d Co mmu n ity Right-to-Kn o w Ac t
CERCLA Repo rtable Q u anti ty
*: Calc ulated RQ exceeds reasonably attainable upper limit.
SARA 304 Ex tremely Haza rdous Substances Re p o r tabl e Qu anti ty
This mat erial does not contai n any component s wit h a s ec tion 304 EHS RQ.
-No.
10 / 12
Page 11
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
TSCA
On TSCA Invent ory
DSL
This produc t cont ains one or s everal com ponents that are not on t he Canadian DSL nor NDSL.
NFPA:
HMIS III:
Hazard pictogram s
:
Signal w ord
:
Danger:
Hazard statem ents
:
E xtrem ely flam m able aerosol. Contains gas under pressure; m ay explode i f heated. Causes sk in irritation.
C auses serious eye irritation. M ay cause drowsiness or
di zzi n ess.
P recautionary statements
:
Prevention
: Keep away from heat/sparks/open flames/hot surfa ces. No sm oking.
Do
not spray on an open flame or other ignition source.
P ressurized container: Do not pierce or burn, even after use. Avoid breathing dust/ fum e/ gas/ mist/ vapours/ spray. Wash sk in thoroughly after handling.
U se only outdoors or in a w ell-ventilated area.
Wear protective gloves/ eye protection/ face protection.
Response
: I F ON SKI N: Wash with plenty of soap and w ater.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. C all a POI S ON CEN TE R /doctor if you feel
unwell.
IF IN E YES: R inse cautiously w ith water for several m inutes. Rem ove
contact lenses, if present and easy to do. Continue rinsing.
If skin irritation occurs: Get
medic al advice/ att ention.
If eye irritation persists: Get m edical advice/ attention.
Take
off contam inated clothing and w ash before reuse.
Storage
: Store in a w ell-ventilated place. Keep container tightl y closed.
Store locked
up.
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Dis posal: Dispose of contents/container in accordance with local regulation.
Flammability
Health
Instability
3
4
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
4
2
3
0 = not significant, 1 =Slight, 2 =
Moderate, 3 = High
4 = Extreme,
* = Chronic
The components of this product are reported in the following inventories:
For informat ion on the country notific ati on st atus for other regions pleas e cont act t he
manufacturer’s regulatory group.
Inventory Acronym and Vali dity Are a Legend:
TSCA (USA ), DSL (Canada), NDSL (Canada)
SECTI ON 16. OTHER INFORMATION
Further i n formation
OSHA - GHS Label Information:
11 / 12
Page 12
SAFETY DATA SHEET
A00329 MST SI-DRY SILICONE 16net 11
Vers ion 4.0
Print Date 12/09/ 2016
Version:
4.0
Revision Date:
08/15/2016
Print Date:
12/09/2016
W e beli eve the s t atement s , tec hni cal informat i on and recommendations contained herein are reliable, but t hey are given wit hout warranty or guarant ee of any k ind. The information in this docum ent appli es t o t his spec ific materi al as suppli ed. It m ay not b e vali d for this mat erial if it is used in com bi nation with any ot her mat eri al s . Us ers should make their own invest i gat i ons to determine the suitability and appli cability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufact urer, s upplier or di st ributor.
Zep Inc . markets prod uc ts under wel l recogni zed and es t abl i shed bra nd names suc h as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Mis ty®, Next Dime nsion™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk ®, Origin al B ike S pirit s® , Bl ue Coral® , B lack Magi c® , Rai n -X®, Niagara Nation al™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
12 / 12
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