Page 1
SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
Material name
:
A00178 MST VANDALISM MRK RMVR 20net16
Material number
:
000000000001001632
Company
:
Zep Inc.
Address
:
1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Appearance
Aerosol containing a liquefied gas
Colour
colourless
Odour
aromatic
Flammable aerosols
:
Category 1
Gases under pressure
:
Liquefied gas
Skin irritation
:
Category 2
Eye irritation
:
Category 2A
Reproductive toxicity
:
Category 2
Specific target organ toxicity single exposure
:
Category 3 (Central nervous system)
Specific target organ toxicity repeated exposure
(Inhalation)
:
Category 2
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS Label element
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
H336 May cause drowsiness or dizziness.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs through prolonged or
repeated exposure if inhaled.
Precautionary statements
:
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after
use.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
P281 Use personal protective equipment as required.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH
Confirmed animal carcinogen with unknown relevance to
humans
2-butoxyethanol
111-76-2
OSHA
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
Potential Health Effects
Carcinogenicity:
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Substance / Mixture
:
Mixture
Chemical Name
CAS-No.
Concentration [%]
acetone
67-64-1
>= 50 - < 70
toluene
108-88-3
>= 10 - < 20
propane
74-98-6
>= 5 - < 10
2-butoxyethanol
111-76-2
>= 5 - < 10
butanone
78-93-3
>= 5 - < 10
butane
106-97-8
>= 5 - < 10
General advice
:
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
Remove person to fresh air. If signs/symptoms continue, get
medical attention.
In case of skin contact
:
In case of contact, immediately flush eyes or skin with plenty
of water for at least 15 minutes while removing contaminated
clothing and shoes.
Wash clothing before reuse.
Call a physician if irritation develops or persists.
In case of eye contact
:
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed
:
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Suitable extinguishing media
:
Carbon dioxide (CO2)
Foam
Dry chemical
Water
Unsuitable extinguishing
media
:
High volume water jet
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
SECTION 4. FIRST AID MEASURES
SECTION 5. FIREFIGHTING MEASURES
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information
:
Use a water spray to cool fully closed containers.
Standard procedure for chemical fires.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Advice on safe handling
:
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Do not breathe vapours or spray mist.
Always replace cap after use.
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Keep in a cool, well-ventilated place.
Electrical installations / working materials must comply with
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
the technological safety standards.
Materials to avoid
:
Strong oxidizing agents
Do not store near acids.
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
acetone
67-64-1
TWA
500 ppm
ACGIH
STEL
750 ppm
ACGIH
TWA
250 ppm
590 mg/m3
NIOSH REL
TWA
1,000 ppm
2,400 mg/m3
OSHA Z-1
TWA
750 ppm
1,800 mg/m3
OSHA P0
STEL
1,000 ppm
2,400 mg/m3
OSHA P0
toluene
108-88-3
TWA
20 ppm
ACGIH
TWA
100 ppm
375 mg/m3
NIOSH REL
ST
150 ppm
560 mg/m3
NIOSH REL
TWA
200 ppm
OSHA Z-2
CEIL
300 ppm
OSHA Z-2
Peak
500 ppm
OSHA Z-2
TWA
100 ppm
375 mg/m3
OSHA P0
STEL
150 ppm
560 mg/m3
OSHA P0
propane
74-98-6
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm
1,800 mg/m3
NIOSH REL
TWA
1,000 ppm
1,800 mg/m3
OSHA Z-1
TWA
1,000 ppm
1,800 mg/m3
OSHA P0
2-butoxyethanol
111-76-2
TWA
20 ppm
ACGIH
TWA
5 ppm
24 mg/m3
NIOSH REL
TWA
50 ppm
240 mg/m3
OSHA Z-1
TWA
25 ppm
120 mg/m3
OSHA P0
butanone
78-93-3
TWA
200 ppm
ACGIH
STEL
300 ppm
ACGIH
TWA
200 ppm
590 mg/m3
NIOSH REL
ST
300 ppm
NIOSH REL
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
885 mg/m3
TWA
200 ppm
590 mg/m3
OSHA Z-1
TWA
200 ppm
590 mg/m3
OSHA P0
STEL
300 ppm
885 mg/m3
OSHA P0
butane
106-97-8
TWA
800 ppm
1,900 mg/m3
NIOSH REL
TWA
800 ppm
1,900 mg/m3
OSHA P0
Component
CAS-No.
Control
parameters
Biological
specimen
Sampling
time
Permissible
concentration
Basis
2-PROPANONE
67-64-1
Acetone
Urine
End of
shift (As
soon as
possible
after
exposure
ceases)
50 mg/l
ACGIH BEI
METHYLBENZENE
108-88-3
Toluene
In blood
Prior to
last shift
of
workwee
k
0.02 mg/l
ACGIH BEI
METHYLBENZENE
Toluene
Urine
End of
shift (As
soon as
possible
after
exposure
ceases)
0.03 mg/l
ACGIH BEI
METHYLBENZENE
o-Cresol
Urine
End of
shift (As
soon as
possible
after
exposure
ceases)
0.3 mg/g
ACGIH BEI
Remarks:
Creatinine
2-BUTOXYETHANOL
111-76-2
Butoxyacetic
acid (BAA)
Urine
End of
shift (As
soon as
possible
after
exposure
ceases)
200 mg/g
ACGIH BEI
Remarks:
Creatinine
2-BUTANONE
78-93-3
MEK
Urine
End of
shift (As
soon as
possible
after
exposure
ceases)
2 mg/l
ACGIH BEI
Biological occupational exposure limits
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
Respiratory protection
:
In case of insufficient ventilation, wear suitable respiratory
equipment.
Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Safety glasses
Ensure that eyewash stations and safety showers are close to
the workstation location.
Skin and body protection
:
impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Appearance
:
Aerosol containing a liquefied gas
Colour
:
colourless
Odour
:
aromatic
Odour Threshold
:
no data available
pH : no data available
Melting point/freezing point
:
no data available
Boiling point
:
no data available
Flash point
:
not applicable
Evaporation rate
:
no data available
Flammability (solid, gas)
:
Extremely flammable aerosol.
Upper explosion limit
:
no data available
Lower explosion limit
:
no data available
Vapour pressure
:
no data available
Relative vapour density
:
no data available
Density
:
0.810 g/cm3
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
Water solubility
:
partly soluble
Partition coefficient: noctanol/water
:
no data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
no data available
Heat of combustion
:
35.04 kJ/g
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
Vapours may form explosive mixture with air.
No decomposition if stored and applied as directed.
Conditions to avoid
:
Heat, flames and sparks.
Extremes of temperature and direct sunlight.
Incompatible materials
:
Acids
Oxidizing agents
Hazardous decomposition
products
:
Carbon monoxide
Carbon dioxide (CO2)
Acute oral toxicity
:
Acute toxicity estimate : 4,978 mg/kg
Method: Calculation method
Acute inhalation toxicity
:
Acute toxicity estimate : > 10 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Acute dermal toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 Oral rat: 2,737 mg/kg
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Components:
butanone:
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
Acute inhalation toxicity
:
LC50 mouse: 32,000 mg/l
Exposure time: 4 h
LC50 : 38,000 mg/l
Acute dermal toxicity
:
LD50 Dermal rabbit: 6,480 mg/kg
Remarks: May cause skin irritation in susceptible persons.
Remarks: Eye irritation
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea
and vomiting., Concentrations substantially above the TLV value may cause narcotic
effects., Solvents may degrease the skin.
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
acetone:
toluene:
propane:
2-butoxyethanol:
butanone:
butane:
STOT - single exposure
no data available
STOT - repeated exposure
no data available
Aspiration toxicity
no data available
Further information
Product:
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
Partition coefficient: noctanol/water
:
Remarks: no data available
Partition coefficient: noctanol/water
:
Pow: 2.73
Partition coefficient: noctanol/water
:
log Pow: 0.29
Partition coefficient: noctanol/water
:
Pow: 2.89
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
no data available
Waste from residues
:
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Product:
Components:
toluene :
butanone :
butane :
Mobility in soil
no data available
Other adverse effects
no data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, 2.1, - Limited quantity
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
toluene
108-88-3
1000
*
SARA 311/312 Hazards
:
Sudden Release of Pressure Hazard
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
SARA 302
:
SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
SARA 313
:
The following components are subject to reporting levels
established by SARA Title III, Section 313:
toluene
108-88-3
17 %
SECTION 14. TRANSPORT INFORMATION
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
California Prop 65
WARNING: This product contains a chemical known to the
State of California to cause birth defects or other reproductive
harm.
toluene
108-88-3
TSCA
On TSCA Inventory
DSL
All components of this product are on the Canadian DSL.
AICS
On the inventory, or in compliance with the inventory
NZIoC
Not in compliance with the inventory
PICCS
On the inventory, or in compliance with the inventory
IECSC
On the inventory, or in compliance with the inventory
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Causes skin irritation. Causes serious eye irritation. May cause drowsiness or
dizziness. Suspected of damaging fertility or the unborn child. May cause damage to
organs through prolonged or repeated exposure if inhaled.
Precautionary statements
:
Prevention: Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Do not spray on an open
flame or other ignition source. Pressurized container: Do not pierce or burn, even after
use. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after
handling. Use only outdoors or in a well-ventilated area. Wear eye protection/ face
Flammability
Health
Instability
3
4
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
4
2
3*
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
The components of this product are reported in the following inventories:
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
OSHA GHS Label Information:
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SAFETY DATA SHEET
A00178 MST VANDALISM MRK RMVR 20net16
Version 1.0
Revision Date 02/18/2015
Print Date 06/01/2015
protection. Wear protective gloves. Use personal protective equipment as required.
Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove
victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If skin
irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical
advice/ attention. Take off contaminated clothing and wash before reuse.
Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked
up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Disposal: Dispose of contents/container in accordance with local regulation.
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
13 / 13
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