Method 01489 User Manual

SAFETY DATA SHEET
Issue Date 20-May-2015
Revision Date 20-May-2015
Version 1
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1. PRODUCT AND COMPANY IDENTIFICATION
Product Name
4x Laundry Detergent
Product Code
MSDS-AC
Recommended Use
Consumer use Detergent
Supplier Address
Method Products Inc. 637 Commercial St Suite 300 San Francisco, CA 94111
866-963-8463
2. HAZARDS IDENTIFICATION
ATTENTION
Emergency Overview
May produce an allergic reaction
May cause skin irritation and/or dermatitis
Appearance translucent, amber
Physical state Liquid.
Odor Pleasant
Potential health effects
Principle Routes of Exposure
Skin Contact
Acute toxicity
Eyes
Avoid contact with eyes. Direct contact with eyes poses risk of serious damage
Skin
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. May cause inflammation
Inhalation
Not an expected route of exposure.
Ingestion
Intentional ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea
CHRONIC EFFECTS
Avoid repeated exposure. Repeated contact may cause allergic reactions in very susceptible persons
Aggravated Medical Conditions
Allergies Skin disorders
Interactions with Other Chemicals
Irritants Sensitizers Epoxies
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Environmental hazard
See Section 12: Ecological Information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS No
Weight-%
Sulfuric acid, mono-C10-16-alkyl esters, sodium
salts
68585-47-7
10-30
Genapol LA060
68551-12-2
5-10
Sodium Lauryl Sulfate Solid (95%)
151-21-3
5-10
PEG 600 Decyl Ether
26183-52-8
1-5
PEG 300 Monoctyl Ether
27252-75-1
1-5
Soya methyl ester ethoxylate
864529-51-1
1-5
Potassium Cocoate
61789-30-8
1-5
subtisilin
9014-01-1
0.1-1
C11-15 Pareth 90
68131-40-8
<0.1
Benzisothiazolinone
2634-33-5
<0.1
Alpha Amylase Concentrate (Bacterial)
9000-90-2
<0.1
Methylisothiazolinone
2682-20-4
<0.1
4. FIRST AID MEASURES
General advice
If symptoms persist, call a physician.
Eye Contact
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Skin Contact
Wash off immediately with plenty of water.
Inhalation
Remove to fresh air.
Ingestion
Do NOT induce vomiting. Clean mouth with water and drink plenty of water. Get medical attention
Note to physicians
Treat symptomatically
Self-protection of the first aider
Use personal protective equipment as required
5. FIRE-FIGHTING MEASURES
Flammable properties
Not flammable
Flash Point
Not determined
Method
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment
Explosion data
Sensitivity to Mechanical Impact
None
Sensitivity to Static Discharge
None
Specific hazards arising from the product
In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal decomposition can lead to release of irritating and toxic gases and vapors
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Protective equipment and precautions for firefighters
Wear self contained breathing apparatus for fire fighting if necessary
NFPA
Health hazards 1
Flammability 0
Stability 0
Physical and Chemical Properties -
HMIS
Health hazards 1
Flammability 0
Physical hazards 0
Personal protection -
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Avoid contact with eyes.
Environmental precautions
Avoid release to the environment
Methods for containment
Prevent further leakage or spillage if safe to do so
Methods for cleaning up
Take up mechanically, placing in appropriate containers for disposal.
7. HANDLING AND STORAGE
Advice on safe handling
Avoid contact with eyes. Keep container closed when not in use.
Storage Conditions
Keep out of the reach of children. Keep container tightly closed in a dry and well-ventilated place
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
For Household Settings
This product is safe for consumers and other users under normal and reasonably foreseen use.
For Occupational Settings
Use safety goggles if splash hazards exist. Avoid prolonged contact with skin and clothing. Always follow good hygienic work practices.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
Liquid
Odor
Pleasant
Color
translucent and Colored
Property
Values
Remarks • Method
pH
7.9 - 8.3
Melting point / freezing point
< 0 °C
Boiling point / boiling range
> 100 °C
Flash Point
Not established
Evaporation rate
> 1.00 (water = 1)
Flammability (solid, gas)
Flammability Limit in Air
Upper Flammability Limit
Not flammable
Lower flammability limit
Not flammable
Vapor pressure
2.27 kPa @ 20 °C
Vapor density
Not established
Specific Gravity
1.06
Water solubility
completely soluble
Autoignition temperature
Not established
Decomposition temperature
Not established
Kinematic viscosity
Not Determined
Dynamic viscosity
80 - 150 cP @ 25°C
Explosive properties
Not an explosive
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Oxidizing properties
None
VOC Content (%)
0
Bulk density
No information available
10. STABILITY AND REACTIVITY
Stability
Stable under recommended storage conditions
Incompatible materials
None known based on information supplied
Conditions to Avoid
None known based on information supplied
Hazardous Decomposition Products
None known based on information supplied
Hazardous polymerization
Hazardous polymerization does not occur
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product Information
Product does not present an acute toxicity hazard based on known or supplied information
Eye Contact
Direct contact with eyes poses risk of serious damage
Skin Contact
Prolonged or repeated contact may dry skin and cause irritation
Ingestion
Intentional ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea
Chemical Name
Oral LD50
Dermal LD50
Inhalation LC50
Sodium Lauryl Sulfate Solid (95%)
= 977 mg/kg ( Rat )
= 580 mg/kg ( Rat )
Chronic toxicity
Chronic toxicity
Avoid repeated exposure. Repeated contact may cause allergic reactions in very susceptible persons
Target Organ Effects
Not expected
12. ECOLOGICAL INFORMATION
Ecotoxicity
Considering the limited amount applied during normal use and the size of the container, the risk of adverse environmental effects is considered small.
Chemical Name
Algae/aquatic plants
Fish
Crustacea
Sodium Lauryl Sulfate Solid (95%)
117: 96 h Pseudokirchneriella
subcapitata mg/L EC50
10.2 - 22.5: 96 h Pimephales
promelas mg/L LC50 semi-static 4.3
- 8.5: 96 h Oncorhynchus mykiss mg/L LC50 static
1.8: 48 h Daphnia magna mg/L EC50
Lactic Acid
3.5: 70 h Pseudokirchneriella subcapitata mg/L EC50
100 - 180: 96 h Lepomis
macrochirus mg/L LC50 static 100 -
180: 96 h Oncorhynchus mykiss
mg/L LC50 static 320: 96 h
Brachydanio rerio mg/L LC50
semi-static
180 - 320: 48 h Daphnia magna
mg/L EC50 Static 240: 48 h Daphnia magna mg/L EC50
Isopropanolamine
23: 72 h Desmodesmus subspicatus
mg/L EC50
108.82: 48 h Daphnia magna Straus mg/L EC50
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Phenoxyethanol
500: 72 h Desmodesmus
subspicatus mg/L EC50
220 - 460: 96 h Leuciscus idus mg/L
LC50 static 337 - 352: 96 h
Pimephales promelas mg/L LC50
flow-through
500: 48 h Daphnia magna mg/L
EC50
Calcium Chloride
10650: 96 h Lepomis macrochirus
mg/L LC50 static
2400: 48 h Daphnia magna mg/L
LC50
Propylene Glycol
41 - 47: 96 h Oncorhynchus mykiss
mL/L LC50 static 710: 96 h
Pimephales promelas mg/L LC50
Disodium Distyrylbiphenyl
Disulfonate
10.0 - 11.0: 96 h Desmodesmus
subspicatus mg/L EC50 10: 72 h
Desmodesmus subspicatus mg/L
EC50
76: 96 h Brachydanio rerio mg/L
LC50 static
1000: 48 h Daphnia magna mg/L
EC50
Persistence and degradability
The surface active components used in this product are readily biodegradable.
Chemical Name
Partition coefficient
Sodium Lauryl Sulfate Solid (95%)
1.6
Benzisothiazolinone
1.3
13. DISPOSAL CONSIDERATIONS
Contaminated packaging
Dispose of in accordance with federal, state and local regulations. Recover or recycle if possible.
14. TRANSPORT INFORMATION
DOT
Not regulated
TDG
Not regulated
MEX
Not regulated
ICAO (air)
Not regulated
IATA
Not regulated
IMDG
Not regulated
RID
Not regulated
ADR
Not regulated
ADN
Not regulated
15. REGULATORY INFORMATION
International Inventories
Chemical Name
TSCA
DSL
NDSL
EINECS
ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Sulfuric acid,
mono-C10-16-alkyl esters,
sodium salts
Present
X
Present
Present
X
Present
X
X
Genapol LA060
Present
X
Present
X
Present
X
X
Sodium Lauryl Sulfate Solid
(95%)
Present
X
Present
Present
X
Present
X
X
PEG 300 Monoctyl Ether
Present
X
Present
X
Present
X
Soya methyl ester ethoxylate
Present
X
Potassium Cocoate
Present
X
Present
Present
X
Present
X
X
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subtisilin
Present
X
Present
X
Present
X
X
C11-15 Pareth 90
Present
X
Present
X
Present
X
X
Benzisothiazolinone
Present
X
Present
Present
X
Present
X
X
Alpha Amylase Concentrate
(Bacterial)
Present
X
Present
X
Present
X
X
Methylisothiazolinone
Present
X
Present
Present
X
Present
X
X
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute health hazard
Yes
Chronic Health Hazard
No
Fire hazard
No
Sudden release of pressure hazard
No
Reactive Hazard
No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
US State Regulations
California Proposition 65
Complies
U.S. State Right-to-Know Regulations
Chemical Name
Massachusetts
New Jersey
Pennsylvania
Glycerin
X
X
X
International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR
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WHMIS Hazard Class
Non-controlled
WHMIS Note
Class D2B - Skin/Eye Irritation reversible damage
16. OTHER INFORMATION
Issue Date
20-May-2015
Revision Date
20-May-2015
Revision Note
No information available
End of Safety Data Sheet
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