MEGUIAR'S MV84 User Manual

MV84, Velocity Liquid Mold Release (XP4-57C): MV8401

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Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

28-3460-4

Version number:

3.00

Revision date:

21/02/2014

Supersedes date:

20/09/2013

Transportation version number: 1.00 (26/07/2011)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

MV84, Velocity Liquid Mold Release (XP4-57C): MV8401

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Mold release agent

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008

CLASSIFICATION:

Flammable Liquid, Category 3 - Flam. Liq. 3; H226
Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315
Aspiration Hazard, Category 1 - Asp. Tox. 1; H304
Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H336
Specific Target Organ Toxicity-Repeated Exposure, Category 2 - STOT RE 2; H373

For full text of H phrases, see Section 16.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Indication of danger

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Flammable; R10
Harmful; Xn; R65
Irritant; Xi; R38
R67
Dangerous for the environment; R52/53

For full text of R phrases, see Section 16.

2.2. Label elements

CLP REGULATION (EC) No 1272/2008

SIGNAL WORD

DANGER!

Symbols:

GHS02 (Flame) |GHS07 (Exclamation mark) | GHS08 (Health Hazard) |

Pictograms

Ingredient CAS Nbr % by Wt
Naphtha (petroleum), hydrotreated heavy 64742-48-9 80 - 95
Stoddard solvent 8052-41-3 1 - 5

HAZARD STATEMENTS:

H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.

H373 May cause damage to organs through prolonged or repeated exposure: nervous system

PRECAUTIONARY STATEMENTS
General:

P102 Keep out of reach of children.
P101 If medical advice is needed, have product container or label at hand.

Prevention:

P210A Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P271 Use only outdoors or in a well-ventilated area.

Response:

P332 + P313 If skin irritation occurs: Get medical advice/attention.
P331 Do NOT induce vomiting.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.
P370 + P378G In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry

chemical or carbon dioxide to extinguish.

Storage:

P405 Store locked up.

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Disposal:

P501 Dispose of contents/container in accordance with applicable local/regional/national/international

regulations.

5% of the mixture consists of components of unknown acute oral toxicity.
5% of the mixture consists of components of unknown acute dermal toxicity.
7% of the mixture consists of components of unknown acute inhalation toxicity.
Contains 98% of components with unknown hazards to the aquatic environment.

Notes on labelling

Nota P applied for CASRN 64742-48-9 and 8052-41-3.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Symbol(s)

Harmful

Contains:

Naphtha (petroleum), hydrotreated heavy

Risk phrases

R10 Flammable.
R38 Irritating to skin.
R65 Harmful: May cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Safety phrases

S23A Do not breathe vapour.
S24 Avoid contact with skin.
S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or

label.
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
S2 Keep out of the reach of children.

Notes on labelling

Nota P applied to CAS 64742-48-9 and 8052-41-3.

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-

150-3

80 - 95 Xn:R65 - Nota 4,P (EU)

Xi:R38; R67 (Self Classified)

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Asp. Tox. 1, H304 - Nota P
(CLP)
Skin Irrit. 2, H315; STOT SE 3,

H336 (Self Classified)
Silicone Trade Secret 1 - 5
Siloxanes and silicones, di-Me 63148-62-9 1 - 5
Silicic acid, sodium salt, reaction products
with chlorotrimethylsilane and iso-Pr alc

68988-56-7 EINECS 273-

530-5

1 - 5

Stoddard solvent 8052-41-3 EINECS 232-

489-3

1 - 5 Xn:R48/20; Xn:R65 - Nota P

(EU)

Xi:R38 (Self Classified)

Asp. Tox. 1, H304; STOT RE 1,

H372 - Nota P (CLP)

Skin Irrit. 2, H315 (Self

Classified)
N-(n-octyl)-2-pyrrolidinone 2687-94-7 0.1 - 1 C:R34; N:R51/53 (EU)

Skin Corr. 1B, H314; Aquatic

Chronic 2, H411 (CLP)
Ethylbenzene 100-41-4 EINECS 202-

849-4

0.1 - 1.0 F:R11; Xn:R20 (EU)
R52 (Self Classified)

Flam. Liq. 2, H225; Acute Tox.
4, H332 (CLP)

Toluene 108-88-3 EINECS 203-

625-9

<= 0.005 Repr.Cat.3:R63; F:R11;

Xn:R48/20; Xn:R65; Xi:R38;
R67 - Nota 4 (EU)

Flam. Liq. 2, H225; Asp. Tox. 1,
H304; Skin Irrit. 2, H315; Repr.
2, H361d; STOT SE 3, H336;
STOT RE 1, H372 (CLP)

Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

Remove person to fresh air. If you feel unwell, get medical attention.

Skin contact

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye contact

Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If swallowed

Do not induce vomiting. Get immediate medical attention.

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4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide to
extinguish.

5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.

Hazardous Decomposition or By-Products

Substance Condition

Formaldehyde During combustion.
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.

5.3. Advice for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate
the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust
vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause
flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding
physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is
recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible
using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue
with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air. Read and follow
safety precautions on the solvent label and Safety Data Sheet. Seal the container. Dispose of collected material as soon as
possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

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7.1. Precautions for safe handling

For industrial or professional use only. Do not use in a confined area with minimal air exchange. Do not handle until all
safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static
discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink
or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine,
chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (eg. gloves,
respirators…) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process
using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation.

7.2. Conditions for safe storage including any incompatibilities

Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids.
Store away from strong bases. Store away from oxidising agents.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

Ingredient CAS Nbr Agency Limit type Additional comments

Ethylbenzene 100-41-4 Health and

Safety Comm.
(UK)

TWA:441 mg/m3(100
ppm);STEL:552 mg/m3(125
ppm)

Skin Notation

Toluene 108-88-3 Health and

Safety Comm.
(UK)

TWA: 191 mg/m³ (50 ppm);
STEL: 384 mg/m³ (100 ppm)

Skin Notation

Naphtha (petroleum),
hydrotreated heavy

64742-48-9 Manufacturer

determined

TWA:100 ppm

Health and Safety Comm. (UK) : UK Health and Safety Commission
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect vented goggles.

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the

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results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl rubber.
Fluoroelastomer
Polymer laminate

Respiratory protection

Wear respiratory protection if ventilation is inadequate to prevent overexposure. An exposure assessment may be needed to
decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program.
Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state

Liquid.

Appearance/Odour

Crystal clear liquid; Hydrocarbon odour

Odour threshold

No data available.

pH

Not applicable.

Boiling point/boiling range

76.7 ºC

Melting point

Not applicable.

Flammability (solid, gas)

Not applicable.

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

40.6 ºC [Test Method:Pensky-Martens Closed Cup]
[Details:D93-90]

Autoignition temperature

No data available.

Flammable Limits(LEL)

No data available.

Flammable Limits(UEL)

No data available.

Vapour pressure

No data available.

Relative density

0.71 - 0.81 [Ref Std:WATER=1]

Water solubility

Nil

Solubility- non-water

No data available.

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

Vapour density

No data available.

Decomposition temperature

No data available.

Viscosity

0.001 Pa-s

Density

0.71 - 0.81 g/cm3

9.2. Other information

Volatile organic compounds (VOC)

96.39 % weight

VOC less H2O & exempt solvents

732.57 g/l

SECTION 10: Stability and reactivity

10.1 Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section

10.2 Chemical stability

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Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

Heat.
Sparks and/or flames.

10.5 Incompatible materials

Strong acids.
Strong bases.
Strong oxidising agents.

10.6 Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

May be harmful if inhaled. Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge,
headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.

Skin contact

May be harmful in contact with skin.
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

Eye contact

Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Ingestion

Chemical (aspiration) pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth,
difficulty breathing, bluish coloured skin (cyanosis), and may be fatal. Gastrointestinal irritation: Signs/symptoms may
include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause target organ effects after ingestion.

Target Organ Effects:

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Single exposure may cause:

Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

Carcinogenicity:

Contains a chemical or chemicals which can cause cancer.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Dermal No data available; calculated ATE3,196.2 mg/kg
Overall product Inhalation-

Vapor(4 hr)

No data available; calculated ATE26.6 mg/l

Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Naphtha (petroleum), hydrotreated heavy Inhalation-

Vapor

LC50 estimated to be 20 - 50 mg/l

Naphtha (petroleum), hydrotreated heavy Dermal Rabbit LD50 > 3,000 mg/kg
Naphtha (petroleum), hydrotreated heavy Ingestion Rat LD50 > 5,000 mg/kg
Stoddard solvent Inhalation-

Vapor

LC50 estimated to be 20 - 50 mg/l

Stoddard solvent Dermal Rabbit LD50 > 3,000 mg/kg
Stoddard solvent Ingestion Rat LD50 > 5,000 mg/kg
Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg
Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg
N-(n-octyl)-2-pyrrolidinone Dermal Rabbit LD50 > 2,000 mg/kg
N-(n-octyl)-2-pyrrolidinone Ingestion Rat LD50 2,050 mg/kg
Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg
Ethylbenzene Inhalation-

Vapor (4
hours)

Rat LC50 17.4 mg/l

Ethylbenzene Ingestion Rat LD50 4,769 mg/kg
Toluene Dermal Rat LD50 12,000 mg/kg
Toluene Inhalation-

Vapor (4
hours)

Rat LC50 30 mg/l

Toluene Ingestion Rat LD50 2,600 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Naphtha (petroleum), hydrotreated heavy Rabbit Irritant
Stoddard solvent Rabbit Irritant
Siloxanes and silicones, di-Me Rabbit No significant irritation
Ethylbenzene Rabbit Mild irritant
Toluene Rabbit Irritant

Serious Eye Damage/Irritation

Name Species Value

Naphtha (petroleum), hydrotreated heavy Rabbit No significant irritation
Stoddard solvent Rabbit No significant irritation
Siloxanes and silicones, di-Me Rabbit No significant irritation
Ethylbenzene Rabbit Moderate irritant
Toluene Rabbit Moderate irritant

Skin Sensitisation

Name Species Value

Naphtha (petroleum), hydrotreated heavy Guinea

pig

Not sensitizing

Stoddard solvent Guinea

pig

Not sensitizing

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Ethylbenzene Human Not sensitizing
Toluene Guinea

pig

Not sensitizing

Respiratory Sensitisation

Name Species Value

Germ Cell Mutagenicity

Name Route Value

Naphtha (petroleum), hydrotreated heavy In vivo Not mutagenic
Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but the data are not

sufficient for classification
Stoddard solvent In vivo Not mutagenic
Stoddard solvent In Vitro Some positive data exist, but the data are not

sufficient for classification
Ethylbenzene In vivo Not mutagenic
Ethylbenzene In Vitro Some positive data exist, but the data are not

sufficient for classification
Toluene In Vitro Not mutagenic
Toluene In vivo Not mutagenic

Carcinogenicity

Name Route Species Value

Naphtha (petroleum), hydrotreated heavy Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Naphtha (petroleum), hydrotreated heavy Inhalation Human

and
animal

Some positive data exist, but the data are not
sufficient for classification

Stoddard solvent Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Stoddard solvent Inhalation Human

and
animal

Some positive data exist, but the data are not
sufficient for classification

Ethylbenzene Inhalation Multiple

animal
species

Carcinogenic.

Toluene Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Toluene Ingestion Rat Some positive data exist, but the data are not

sufficient for classification

Toluene Inhalation Mouse Some positive data exist, but the data are not

sufficient for classification

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure

Duration

Naphtha (petroleum), hydrotreated heavy Inhalation Not toxic to development Rat NOAEL 2.4

mg/l

during
organogenesis

Stoddard solvent Inhalation Not toxic to development Rat NOAEL 2.4

mg/l

during
organogenesis

Ethylbenzene Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Rat NOAEL 4.3

mg/l

premating &
during
gestation

Toluene Inhalation Some positive female reproductive data

exist, but the data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Toluene Inhalation Some positive male reproductive data

exist, but the data are not sufficient for
classification

Rat NOAEL 2.3

mg/l

1 generation

Toluene Ingestion Toxic to development Rat LOAEL 520

mg/kg/day

during
gestation

Toluene Inhalation Toxic to development Human NOAEL Not

available

poisoning
and/or abuse

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Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Naphtha (petroleum),
hydrotreated heavy

Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not
available

Naphtha (petroleum),
hydrotreated heavy

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not
available

Naphtha (petroleum),
hydrotreated heavy

Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Dog NOAEL 6.5

mg/l

4 hours

Stoddard solvent Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not
available

Stoddard solvent Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not
available

Stoddard solvent Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Dog NOAEL 6.5

mg/l

4 hours

Ethylbenzene Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Human
and
animal

NOAEL Not
available

Toluene Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

Toluene Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL Not

available

Toluene Inhalation immune system Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL

0.004 mg/l

3 hours

Toluene Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

poisoning
and/or abuse

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Naphtha (petroleum),
hydrotreated heavy

Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL 4.6

mg/l

6 months

Naphtha (petroleum),
hydrotreated heavy

Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat LOAEL 1.9

mg/l

13 weeks

Naphtha (petroleum),
hydrotreated heavy

Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL 0.6
mg/l

90 days

Naphtha (petroleum),
hydrotreated heavy

Inhalation bone, teeth, nails,

and/or hair | blood |
liver | muscles

All data are negative Rat NOAEL 5.6

mg/l

12 weeks

Naphtha (petroleum),
hydrotreated heavy

Inhalation heart All data are negative Multiple

animal
species

NOAEL 1.3
mg/l

90 days

Stoddard solvent Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL 4.6

mg/l

6 months

Stoddard solvent Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat LOAEL 1.9

mg/l

13 weeks

Stoddard solvent Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL 0.6
mg/l

90 days

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Stoddard solvent Inhalation bone, teeth, nails,

and/or hair | blood |
liver | muscles

All data are negative Rat NOAEL 5.6

mg/l

12 weeks

Stoddard solvent Inhalation heart All data are negative Multiple

animal
species

NOAEL 1.3
mg/l

90 days

Ethylbenzene Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 1.1

mg/l

2 years

Ethylbenzene Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL 1.1

mg/l

103 weeks

Ethylbenzene Inhalation hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 3.4

mg/l

28 days

Ethylbenzene Inhalation auditory system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 2.4

mg/l

5 days

Ethylbenzene Inhalation endocrine system Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL 3.3

mg/l

103 weeks

Ethylbenzene Inhalation bone, teeth, nails,

and/or hair |
muscles

All data are negative Multiple

animal
species

NOAEL 4.2
mg/l

90 days

Ethylbenzene Inhalation heart | immune

system | respiratory
system

All data are negative Multiple

animal
species

NOAEL 3.3
mg/l

2 years

Ethylbenzene Ingestion liver | kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 680

mg/kg/day

6 months

Toluene Inhalation auditory system |

nervous system |
eyes | olfactory
system

Causes damage to organs through
prolonged or repeated exposure

Human NOAEL Not

available

poisoning
and/or abuse

Toluene Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL 2.3

mg/l

15 months

Toluene Inhalation heart | liver | kidney

and/or bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 11.3

mg/l

15 weeks

Toluene Inhalation endocrine system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 1.1

mg/l

4 weeks

Toluene Inhalation immune system Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL Not

available

20 days

Toluene Inhalation bone, teeth, nails,

and/or hair

Some positive data exist, but the
data are not sufficient for
classification

Mouse NOAEL 1.1

mg/l

8 weeks

Toluene Inhalation hematopoietic

system | vascular
system

Some positive data exist, but the
data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Toluene Ingestion nervous system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 625

mg/kg/day

13 weeks

Toluene Ingestion heart Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL

2,500
mg/kg/day

13 weeks

Toluene Ingestion liver | kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Multiple
animal
species

NOAEL
2,500
mg/kg/day

13 weeks

Toluene Ingestion hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Mouse NOAEL 600

mg/kg/day

14 days

Toluene Ingestion endocrine system Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL 105

mg/kg/day

28 days

Toluene Ingestion immune system Some positive data exist, but the

data are not sufficient for

Mouse NOAEL 105

mg/kg/day

4 weeks

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classification

Aspiration Hazard

Name Value

Naphtha (petroleum), hydrotreated heavy Aspiration hazard
Stoddard solvent Aspiration hazard
Ethylbenzene Aspiration hazard
Toluene Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.

12.1. Toxicity

No product test data available.

Material CAS Nbr Organism Type Exposure Test endpoint Test result

Ethylbenzene 100-41-4 Water flea Experimental 24 hours EC50 1.81 mg/l
Ethylbenzene 100-41-4 Rainbow trout Experimental 96 hours LC50 4.2 mg/l
Ethylbenzene 100-41-4 Green Algae Experimental 96 hours EC50 3.6 mg/l
Naphtha
(petroleum),
hydrotreated
heavy

64742-48-9 Data not

available or
insufficient for

classification
Siloxanes and
silicones, di­Me

63148-62-9 Data not

available or

insufficient for

classification
Stoddard
solvent

8052-41-3 Data not

available or

insufficient for

classification
Silicic acid,
sodium salt,
reaction
products with
chlorotrimethyl
silane and iso­Pr alc

68988-56-7 Data not

available or

insufficient for

classification

12.2. Persistence and degradability

Material CAS Nbr Test type Duration Study Type Test result Protocol

Stoddard
solvent

8052-41-3 Estimated

Photolysis

Photolytic half­life (in air)

6.49 days (t
1/2)

Other methods

Ethylbenzene 100-41-4 Experimental

Photolysis

Photolytic half­life (in air)

4.26 days (t
1/2)

Other methods

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Siloxanes and
silicones, di­Me

63148-62-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Silicic acid,
sodium salt,
reaction
products with
chlorotrimethyl
silane and iso­Pr alc

68988-56-7 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Ethylbenzene 100-41-4 Laboratory

Biodegradation

14 days BOD 81 % weight Other methods

Stoddard
solvent

8052-41-3 Experimental

Biodegradation

28 days CO2 evolution 63 % weight OECD 301B -

Modified sturm or CO2
Naphtha
(petroleum),
hydrotreated
heavy

64742-48-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

12.3 : Bioaccumulative potential

Material CAS Nbr Test type Duration Study Type Test result Protocol

Siloxanes and
silicones, di­Me

63148-62-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Silicic acid,
sodium salt,
reaction
products with
chlorotrimethyl
silane and iso­Pr alc

68988-56-7 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Stoddard
solvent

8052-41-3 Experimental

BCF - Other

Bioaccumulati
on factor

1944 Other methods

Naphtha
(petroleum),
hydrotreated
heavy

64742-48-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Ethylbenzene 100-41-4 Experimental

BCF - Other

Bioaccumulati
on factor

15 Other methods

12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effects

No information available.

SECTION 13: Disposal considerations

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13.1 Waste treatment methods

See Section 11.1 Information on toxicological effects

Incinerate in a permitted waste incineration facility. As a disposal alternative, Dispose of waste product in a permitted
industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated &
disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

120199 Wastes not otherwise specified

SECTION 14: Transportation information

ADR: UN1268 Petroleum Distillates, N.O.S.; 3; III; (D/E); F1
IMDG: UN1268 Petroleum Distillates, N.O.S.; 3; III; EmS: F-E, S-E
IATA: UN1268 Petroleum Distillates, N.O.S.; 3; III

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Carcinogenicity

Ingredient CAS Nbr Classification Regulation

Ethylbenzene 100-41-4 Grp. 2B: Possible human

carc.

International Agency
for Research on Cancer

Toluene 108-88-3 Gr. 3: Not classifiable International Agency

for Research on Cancer

Global inventory status

Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.

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H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

List of relevant R-phrases

R10 Flammable.
R11 Highly flammable.
R20 Harmful by inhalation.
R34 Causes burns.
R38 Irritating to skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R52 Harmful to aquatic organisms.
R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R63 Possible risk of harm to the unborn child.
R65 Harmful: May cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.

Revision information:

Revision Changes:
Section 8: Eye/face protection information information was modified.
Section 8: Skin protection - recommended gloves information information was modified.
Section 8: Respiratory protection - recommended respirators information information was modified.
Section 3: Composition/ Information of ingredients table information was modified.
Section 12: Component ecotoxicity information information was modified.
Section 12: Persistence and Degradability information information was modified.
Section 12:Bioccumulative potential information information was modified.
Section 2: Label remarks information was modified.
Copyright information was modified.
Section 11: Aspiration Hazard Table information was modified.
Section 11: Acute Toxicity table information was modified.
Section 11: Carcinogenicity Table information was modified.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Germ Cell Mutagenicity Table information was modified.
Section 11: Skin Sensitization Table information was modified.
Section 11: Reproductive Toxicity Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Target Organs - Repeated Table information was modified.
Section 11: Target Organs - Single Table information was modified.
Section 11: Health Effects - Eye information information was modified.
Section 11: Health Effects - Skin information information was modified.
Section 11: Health Effects - Inhalation information information was modified.
Section 6: Accidental release clean-up information information was modified.
Section 7: Precautions safe handling information information was modified.
Section 7: Conditions safe storage information was modified.
Section 8: Personal Protection - Eye information information was modified.
Section 8: Personal Protection - Skin/hand information information was modified.
Section 8: Personal Protection - Respiratory Information information was modified.
Section 13: 13.1. Waste disposal note information was modified.
Section 4: First aid for eye contact information information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. information was modified.
Label: Signal Word - Header information was added.
Label: Signal Word information was added.
Label: CLP Classification - Header information was added.
Label: CLP Classification information was added.

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Label: CLP Classification information was added.
Label: CLP Classification - Header information was added.
Label: CLP Percent Unknown information was added.
Label: CLP Percent Unknown information was added.
Label: CLP Percent Unknown information was added.
Label: CLP Percent Unknown information was added.
Label: Graphic information was added.
Label: Graphic information was added.
Label: Symbol information was added.
Label: Symbol information was added.
Label: CLP Precautionary - Disposal information was added.
Label: CLP Precautionary - Disposal - Header information was added.
Label: CLP Precautionary - General information was added.
Label: CLP Precautionary - General - Header information was added.
Label: CLP Precautionary - Prevention information was added.
Label: CLP Precautionary - Prevention - Header information was added.
Label: CLP Precautionary - Response information was added.
Label: CLP Precautionary - Response - Header information was added.
Label: CLP Precautionary - Storage information was added.
Label: CLP Precautionary - Storage - Header information was added.
Label: Precautionary Statement - Header information was added.
CLP: Ingredient table information was added.
Section 2: Notes on labelling heading information was added.
Section 15: Label remarks and EU Detergent information was added.
Section 2: 2.2 & 2.3. CLP REGULATION heading information was added.
Label: CLP Ingredients table Ingredient heading information was added.
Label: CLP Ingredients table CAS No heading information was added.
Label: CLP Ingredients table Percent by Wt heading information was added.
Section 2: H phrase reference information was added.
Label: CLP Target Organ Hazard Statement Heading information was added.
Label: CLP Target Organ Hazard Statement information was added.
Section 11: Disclosed components not in tables text information was added.
Section 8: Eye/face protection text information was deleted.
Section 8: Respiratory protection - recommended respirators information was deleted.
Section 8: Skin protection - protective clothing text information was deleted.
Section 11: Respiratory Sensitization Table information was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk