MEGUIAR'S MV83 User Manual

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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-5230-9
Version number:
1.02
Revision date:
26/04/2012
Supersedes date:
31/10/2011
Transportation version number: 1.00 (31/10/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
MV83, Velocity Liquid Mold Sealer (XP4-57A): MV8301
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Mold release agent
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Harmful. Flammable
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols
Xn Harmful.
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Contains:
Naphtha (petroleum), hydrotreated heavy
Risk phrases
R10 Flammable. R65 Harmful: May cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness. R66 Repeated exposure may cause skin dryness or cracking.
Safety phrases
S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
Notes on labelling
Nota P applied for CASRN 64742-48-9, 64742-82-1 and 8052-41-3.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
85 - 95 Xn:R65 - Nota 4,P (EU)
R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) STOT SE 3, H336; EUH066
(Self Classified) Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
68988-56-7 EINECS 273-
530-5
1 - 5
Stoddard Solvent 8052-41-3 EINECS 232-
489-3
1 - 5 Xn:R65 - Nota 4,P (EU)
R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P
(CLP)
STOT SE 3, H336; EUH066
(Self Classified) Siloxanes and silicones, di-Me 63148-62-9 1 - 5 Naphtha (petroleum), hydrodesulphurised heavy
64742-82-1 EINECS 265-
185-4
1 - 5 Xn:R65 - Nota 4,P (EU)
R10 (Vendor)
N:R51/53; R66; R67 (Self
Classified)
Asp. Tox. 1, H304 - Nota P
(CLP)
Flam. Liq. 3, H226 (Vendor)
STOT SE 3, H336; EUH066;
Aquatic Chronic 2, H411 (Self
Classified) Ethylbenzene 100-41-4 EINECS 202- 0.1 - 1.0 F:R11; Xn:R20 (EU)
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849-4
Flam. Liq. 2, H225; Acute Tox.
4, H332 (CLP) Toluene 108-88-3 EINECS 203-
625-9
<= 0.0045 Repr.Cat.3:R63; F:R11;
Xn:R48/20; Xn:R65; Xi:R38;
R67 - Nota 4 (EU)
Flam. Liq. 2, H225; Asp. Tox. 1,
H304; Skin Irrit. 2, H315; Repr.
2, H361d; STOT SE 3, H336;
STOT RE 1, H372 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Do not induce vomiting. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
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5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR-AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and Safety Data Sheet. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Do not use in a confined area or areas with little or no air movement. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use explosion-proof electrical/ventilating/lighting/equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (eg. gloves, respirators…) as required. Vapours may travel long distances along the ground or floor to an ignition source and flash back.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Protect from sunlight. Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
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Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Ethylbenzene 100-41-4 Health and
Safety Comm. (UK)
TWA:441 mg/m3(100 ppm);STEL:552 mg/m3(125 ppm)
Skin Notation
Toluene 108-88-3 Health and
Safety Comm. (UK)
TWA: 191 mg/m³ (50 ppm); STEL: 384 mg/m³ (100 ppm)
Skin Notation
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use explosion-proof ventilation equipment. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
As a good industrial hygiene practice:
Wear eye/face protection.
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Wear protective gloves. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
In case of inadequate ventilation wear respiratory protection. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Odourless; Clear liquid
pH
Not applicable.
Boiling point/boiling range
76.7 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Flammable liquid: Category 3.
Explosive properties
Not classified
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Oxidising properties
Not classified
Flash point
40.6 ºC [Test Method:Pensky-Martens Closed Cup] [Details:D93-90]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
0.75 [Ref Std:WATER=1]
Water solubility
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
1.5 mm²/sec [@ 25 ºC ]
Viscosity
1.2 mm²/sec [@ 40 ºC ]
Density
0.75 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
99.02 % weight
VOC less H2O & exempt solvents
742.64 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat. Sparks and/or flames.
10.5 Incompatible materials
Strong oxidising agents. Strong acids. Strong bases.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
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relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation
Intentional concentration and inhalation may be harmful or fatal. Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. Chemical (aspiration) pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish coloured skin (cyanosis), and may be fatal. May cause target organ effects after ingestion.
Target Organ Effects:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg Naphtha (petroleum), hydrotreated heavy
Dermal Rabbit LD50 > 3,000 mg/kg
Naphtha (petroleum), hydrotreated heavy
Inhalation-Vapor (4 hours)
Rat LC50 estimated to be 20 - 50 mg/l
Naphtha (petroleum), hydrotreated heavy
Ingestion Rat LD50 > 5,000 mg/kg
Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
No data available
Stoddard Solvent Dermal Rabbit LD50 > 3,000 mg/kg Stoddard Solvent Inhalation-Vapor (4
hours)
Rat LC50 estimated to be 20 - 50 mg/l
Stoddard Solvent Ingestion Rat LD50 > 5,000 mg/kg Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg Naphtha (petroleum), hydrodesulphurised heavy
Dermal Rabbit LD50 > 3,000 mg/kg
Naphtha (petroleum), hydrodesulphurised heavy
Inhalation-Vapor (4 hours)
Rat LC50 estimated to be 20 - 50 mg/l
Naphtha (petroleum), Ingestion Rat LD50 > 5,000 mg/kg
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hydrodesulphurised heavy Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation-Vapor (4
hours)
Rat LC50 17 mg/l
Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation-Vapor (4
hours)
Rat LC50 30 mg/l
Toluene Ingestion Rat LD50 2,600 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy No data available Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
No data available
Stoddard Solvent Mild irritant Siloxanes and silicones, di-Me Rabbit No significant irritation Naphtha (petroleum), hydrodesulphurised heavy Mild irritant Ethylbenzene Rabbit Mild irritant Toluene Rabbit Irritant
Serious Eye Damage/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy No data available Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
No data available
Stoddard Solvent Mild irritant Siloxanes and silicones, di-Me Rabbit No significant irritation Naphtha (petroleum), hydrodesulphurised heavy Mild irritant Ethylbenzene Rabbit Moderate irritant Toluene Rabbit Moderate irritant
Skin Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Not sensitizing Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
No data available
Stoddard Solvent Not sensitizing Siloxanes and silicones, di-Me No data available Naphtha (petroleum), hydrodesulphurised heavy Not sensitizing Ethylbenzene Human Not sensitizing Toluene Guinea pig Not sensitizing
Respiratory Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy No data available Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
No data available
Stoddard Solvent No data available Siloxanes and silicones, di-Me No data available Naphtha (petroleum), hydrodesulphurised heavy No data available Ethylbenzene No data available Toluene No data available
Germ Cell Mutagenicity
Name Route Value
Naphtha (petroleum), hydrotreated heavy Inhalation Not mutagenic Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but the data are not
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sufficient for classification Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
No data available
Stoddard Solvent Inhalation Not mutagenic Stoddard Solvent In Vitro Some positive data exist, but the data are not
sufficient for classification Siloxanes and silicones, di-Me No data available Naphtha (petroleum), hydrodesulphurised heavy Inhalation Not mutagenic Naphtha (petroleum), hydrodesulphurised heavy In Vitro Some positive data exist, but the data are not
sufficient for classification Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not
sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic
Carcinogenicity
Name Route Species Value
Naphtha (petroleum), hydrotreated heavy
Dermal Some positive data exist, but the data
are not sufficient for classification Naphtha (petroleum), hydrotreated heavy
Inhalation Some positive data exist, but the data
are not sufficient for classification Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
No data available
Stoddard Solvent Dermal Some positive data exist, but the data
are not sufficient for classification Stoddard Solvent Inhalation Some positive data exist, but the data
are not sufficient for classification Siloxanes and silicones, di-Me No data available Naphtha (petroleum), hydrodesulphurised heavy
Dermal Some positive data exist, but the data
are not sufficient for classification Naphtha (petroleum), hydrodesulphurised heavy
Inhalation Some positive data exist, but the data
are not sufficient for classification Ethylbenzene Inhalation Multiple animal
species
Carcinogenic.
Toluene Dermal Mouse Some positive data exist, but the data
are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data
are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data
are not sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation Not toxic to
reproduction and/or development
NOAEL
2.356 mg/l
Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
No data available
Stoddard Solvent Inhalation Not toxic to
reproduction and/or development
NOAEL
2.356 mg/l
Siloxanes and silicones, di-Me
No data available
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Naphtha (petroleum), hydrodesulphurised heavy
Inhalation Not toxic to
reproduction and/or development
NOAEL
2.356 mg/l
Ethylbenzene Inhalation Some positive
developmental data exist, but the data are not sufficient for classification
Rat NOAEL 4.3
mg/l
premating & during gestation
Toluene Inhalation Some positive female
reproductive data exist, but the data are not sufficient for classification
Human NOAEL Not
available
occupational exposure
Toluene Inhalation Some positive male
reproductive data exist, but the data are not sufficient for classification
Rat NOAEL 2.3
mg/l
1 generation
Toluene Ingestion Toxic to development Rat LOAEL 520
mg/kg/day
during gestation
Toluene Inhalation Toxic to development Human NOAEL Not
available
poisoning and/or abuse
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
NOEL 6.5 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 2.4 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL 2.5 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation liver | kidney
and/or bladder
All data are negative
NOAEL 0.610 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation muscles All data are
negative
NOAEL 0.61 mg/l
Silicic acid, sodium salt, reaction products with chlorotrimeth ylsilane and iso-Pr alc
No data available
Stoddard Solvent
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Stoddard Inhalation respiratory Some positive Irritation
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Solvent irritation data exist, but the
data are not sufficient for classification
Positive
Stoddard Solvent
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
NOEL 6.5 mg/l
Stoddard Solvent
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 2.4 mg/l
Stoddard Solvent
Inhalation heart All data are
negative
NOAEL 2.5
mg/l Stoddard Solvent
Inhalation liver | kidney
and/or bladder
All data are negative
NOAEL 0.610
mg/l Stoddard Solvent
Inhalation muscles All data are
negative
NOAEL 0.61
mg/l Siloxanes and silicones, di­Me
No data available
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation
Positive
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
NOEL 6.5 mg/l
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 2.4 mg/l
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation heart All data are
negative
NOAEL 2.5
mg/l
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation liver | kidney
and/or bladder
All data are negative
NOAEL 0.610
mg/l
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation muscles All data are
negative
NOAEL 0.61
mg/l
Ethylbenzene Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
Ethylbenzene Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for
Human and animal
NOAEL Not
available
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classification
Toluene Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
Toluene Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Human NOAEL Not
available
Toluene Inhalation immune system Some positive
data exist, but the data are not sufficient for classification
Mouse NOAEL 0.004
mg/l
3 hours
Toluene Ingestion central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
poisoning and/or abuse
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Dermal nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 691
mg/kg
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 4.580
mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 0.619
mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation endocrine
system | muscles
Some positive data exist, but the data are not sufficient for classification
LOEL 0.616
mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
LOEL 0.57 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation bone, teeth,
nails, and/or hair | blood | liver
All data are negative
NOAEL 5.62
mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL 1.271
mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation immune system All data are
negative
NOAEL 0.616
mg/l
Silicic acid, sodium salt, reaction
No data available
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products with chlorotrimeth ylsilane and iso-Pr alc Stoddard Solvent
Dermal nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 691
mg/kg
Stoddard Solvent
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 4.580
mg/l
Stoddard Solvent
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 0.619
mg/l
Stoddard Solvent
Inhalation endocrine
system | muscles
Some positive data exist, but the data are not sufficient for classification
LOEL 0.616
mg/l
Stoddard Solvent
Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
LOEL 0.57 mg/l
Stoddard Solvent
Inhalation bone, teeth,
nails, and/or hair | blood | liver
All data are negative
NOAEL 5.62
mg/l
Stoddard Solvent
Inhalation heart All data are
negative
NOAEL 1.271
mg/l Stoddard Solvent
Inhalation immune system All data are
negative
NOAEL 0.616
mg/l Naphtha (petroleum), hydrodesulph urised heavy
Dermal nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 691
mg/kg
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 4.580
mg/l
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 0.619
mg/l
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation endocrine
system | muscles
Some positive data exist, but the data are not sufficient for classification
LOEL 0.616
mg/l
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for
LOEL 0.57 mg/l
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classification Naphtha (petroleum), hydrodesulph urised heavy
Inhalation bone, teeth,
nails, and/or hair | blood | liver
All data are
negative
NOAEL 5.62 mg/l
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation heart All data are
negative
NOAEL 1.271 mg/l
Naphtha (petroleum), hydrodesulph urised heavy
Inhalation immune system All data are
negative
NOAEL 0.616 mg/l
Ethylbenzene Inhalation kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 1.1
mg/l
2 years
Ethylbenzene Inhalation liver Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL 1.1
mg/l
103 weeks
Ethylbenzene Inhalation hematopoietic
system
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 3.4
mg/l
28 days
Ethylbenzene Inhalation auditory system Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 2.4
mg/l
5 days
Ethylbenzene Inhalation endocrine
system
Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL 3.3
mg/l
103 weeks
Ethylbenzene Inhalation bone, teeth,
nails, and/or hair | muscles
All data are
negative
Multiple animal species
NOAEL 4.2 mg/l
90 days
Ethylbenzene Inhalation heart | immune
system | respiratory system
All data are
negative
Multiple animal species
NOAEL 3.3 mg/l
2 years
Ethylbenzene Ingestion liver | kidney
and/or bladder
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 680
mg/kg/day
6 months
Toluene Inhalation auditory system
| nervous system | eyes | olfactory system
Causes damage to
organs through
prolonged or
repeated exposure
Human NOAEL Not
available
poisoning and/or abuse
Toluene Inhalation respiratory
system
Some positive
data exist, but the
data are not
sufficient for
classification
Rat LOAEL 2.3
mg/l
15 months
Toluene Inhalation heart | liver |
kidney and/or
Some positive
data exist, but the
Rat NOAEL 11.3
mg/l
15 weeks
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bladder data are not
sufficient for
classification Toluene Inhalation endocrine
system
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 1.1
mg/l
4 weeks
Toluene Inhalation immune system Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL Not
available
20 days
Toluene Inhalation bone, teeth,
nails, and/or hair
Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL 1.1
mg/l
8 weeks
Toluene Inhalation hematopoietic
system | vascular system
Some positive
data exist, but the
data are not
sufficient for
classification
Human NOAEL Not
available
occupational exposure
Toluene Ingestion nervous system Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 625
mg/kg/day
13 weeks
Toluene Ingestion heart Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 2,500
mg/kg/day
13 weeks
Toluene Ingestion liver | kidney
and/or bladder
Some positive
data exist, but the
data are not
sufficient for
classification
Multiple animal species
NOAEL 2,500 mg/kg/day
13 weeks
Toluene Ingestion hematopoietic
system
Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL 600
mg/kg/day
14 days
Toluene Ingestion endocrine
system
Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL 105
mg/kg/day
28 days
Toluene Ingestion immune system Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL 105
mg/kg/day
4 weeks
Aspiration Hazard
Name Value
Naphtha (petroleum), hydrotreated heavy Not an aspiration hazard Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-Pr alc
Not an aspiration hazard
Stoddard Solvent Aspiration hazard Siloxanes and silicones, di-Me Not an aspiration hazard
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Naphtha (petroleum), hydrodesulphurised heavy Aspiration hazard Ethylbenzene Aspiration hazard Toluene Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as hazardous as per applicable regulations) shall be considered,stored,treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC -
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2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
070104* Other organic solvents, washing liquids and mother liquors
SECTION 14: Transportation information
ADR: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, +040C F1 IMDG: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, EmS: F-E, S-E IATA: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Ethylbenzene 100-41-4 Grp. 2B: Possible human
carc.
International Agency for Research on Cancer
Toluene 108-88-3 Gr. 3: Not classifiable International Agency
for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R38 Irritating to skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R63 Possible risk of harm to the unborn child. R65 Harmful: May cause lung damage if swallowed.
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R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 8: Respiratory protection - recommended respirators information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 9: Flammability (solid, gas) information was modified. Section 14: Transportation classification was modified. Section 2: Label remarks was modified. Copyright was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 11: Health Effects - Skin information was modified. Section 11: Health Effects - Inhalation information was modified. Section 11: Health Effects - Ingestion information was modified. Section 6: Accidental release personal information was modified. Section 6: Accidental release environmental information was modified. Section 6: Accidental release clean-up information was modified. Section 7: Precautions safe handling information was modified. Section 7: Conditions safe storage was modified. Section 8: Appropriate Engineering controls information was modified. Section 13: Standard Phrase Category Waste GHS was modified. Section 4: First aid for skin contact information was modified. Section 4: First aid for inhalation information was modified. Section 4: First aid for ingestion (swallowing) information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 12: Acute aquatic hazard information was added. Section 12: Chronic aquatic hazard heading was added. Section 12: Acute aquatic hazard heading was added. Section 12: Chronic aquatic hazard information was added. Section 11: Carcinogenicity heading was added. Section 11: Target Organ Effects heading was added. Section 11: Health Effects - Other information was added. Section 11: Cancer Hazards information was added. Section 8: Personal Protection - Eye information was added. Section 8: Personal Protection - Skin/hand information was added. Section 8: Personal Protection - Respiratory Information was added. Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
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Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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