MEGUIAR'S MC203 User Manual

MC203, Motorcycle Leather Cleaner/Conditioner (20-175A): MC20306
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-8422-9
Version number:
2.00
Revision date:
22/04/2014
Supersedes date:
24/07/2012
Transportation version number: 1.00 (28/10/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
MC203, Motorcycle Leather Cleaner/Conditioner (20-175A): MC20306
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Motorcycle
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification, labelling, and packaging of substances and mixtures.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Dangerous for the environment; R52/53
For full text of R phrases, see Section 16.
2.2. Label elements
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CLP REGULATION (EC) No 1272/2008
Not applicable
PRECAUTIONARY STATEMENTS General:
P102 Keep out of reach of children.
SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-
isothiazol-3-one. May produce an allergic reaction.
Notes on labelling
Updated per Regulation (EC) No. 648/2004 on detergents. H304 is not required on the label due to the product's viscosity Ingredients required per 648/2004: 15-30%: Aliphatic hydrocarbons. <5%: Non-ionic surfactant. Contains: Perfumes, amyl cinnamal, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1). Nota N applied to CAS 64742-46-7 and 8009-03-8.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
None.
Contains:
No ingredients are assigned to the label.
Risk phrases
R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Safety phrases
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
Notes on labelling
R65 is not required on the label due to the product's viscosity. Updated per Regulation (EC) 648/2004 on detergents. Ingredients required per 648/2004: 15-30%: Aliphatic hydrocarbons. <5%: Non-ionic surfactant. Contains: Perfumes, amyl cinnamal, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1). Nota N applied to CAS 64742-46-7 and 8009-03-8.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 60 - 80 Paraffin Wax 8002-74-2 EINECS 232-
315-6
7 - 13
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
7 - 13 Nota N (EU)
Xn:R20-65; R66 (Self
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Classified)
Nota N (CLP) Acute Tox. 4, H332; Asp. Tox. 1, H304; STOT SE 3, H336; EUH066 (Self Classified)
Stearic Acid 57-11-4 EINECS 200-
313-4
3 - 7
Siloxanes and silicones, di-Me 63148-62-9 1 - 5 Petrolatum 8009-03-8 EINECS 232-
373-2
1 - 5 Nota N (EU)
Nota N (CLP)
Triethanolamine 102-71-6 EINECS 203-
049-8
1 - 5
PEG Stearate 9004-99-3 0.1 - 1.0 N:R50 (Self Classified)
Aquatic Acute 1, H400,M=1; Aquatic Chronic 3, H412 (Self Classified)
Isothymol 499-75-2 EINECS 207-
889-6
< 0.13 N:R51/53 (Self Classified)
Aquatic Chronic 2, H411 (Self Classified)
2-benzylideneheptanal 122-40-7 EINECS 204-
541-5
< 0.13 N:R50/53 (Self Classified)
Aquatic Acute 1, H400,M=1; Aquatic Chronic 2, H411 (Self Classified)
Zinc oxide 1314-13-2 EINECS 215-
222-5
< 0.025 N:R50/53 (EU)
Aquatic Acute 1, H400,M=10; Aquatic Chronic 1, H410,M=1
(CLP) Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;
R43 (EU)
Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
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Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion. Oxides of nitrogen. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
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SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment.
7.2. Conditions for safe storage including any incompatibilities
Protect from sunlight. Store away from heat.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Paraffin Wax 8002-74-2 Health and
Safety Comm. (UK)
TWA(as fume):2 mg/m3;STEL(as fume):6 mg/m3
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
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a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Rich leather odour; Creamy, ivory liquid
Odour threshold
No data available.
pH
7.5 - 8.5
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Not applicable.
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
0.96 [Ref Std:WATER=1]
Water solubility
Moderate
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
25 Pa-s - 40 Pa-s
Density
0.96 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
0.0 % weight
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Temperatures above the boiling point.
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Light.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin contact
Dermal Defatting: Signs/symptoms may include localised redness, itching, drying and cracking of skin.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Distillates (petroleum), hydrotreated middle Dermal Rabbit LD50 > 2,000 mg/kg Distillates (petroleum), hydrotreated middle Inhalation-
Dust/Mist (4 hours)
Rat LC50 4.6 mg/l
Distillates (petroleum), hydrotreated middle Ingestion Rat LD50 > 5,000 mg/kg Paraffin Wax Dermal Rabbit LD50 > 5,000 mg/kg Paraffin Wax Ingestion Rat LD50 > 5,000 mg/kg Stearic Acid Dermal Rabbit LD50 > 2,000 mg/kg Stearic Acid Ingestion Rat LD50 > 5,000 mg/kg Petrolatum Dermal LD50 estimated to be > 5,000 mg/kg Petrolatum Ingestion Rat LD50 > 5,000 mg/kg
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Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg Triethanolamine Dermal Rabbit LD50 > 2,000 mg/kg Triethanolamine Ingestion Rat LD50 9,000 mg/kg Zinc oxide Dermal LD50 estimated to be > 5,000 mg/kg Zinc oxide Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 5.7 mg/l
Zinc oxide Ingestion Rat LD50 > 5,000 mg/kg Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Inhalation­Dust/Mist (4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Distillates (petroleum), hydrotreated middle Rabbit Minimal irritation Stearic Acid Rabbit Mild irritant Siloxanes and silicones, di-Me Rabbit No significant irritation Triethanolamine Rabbit Minimal irritation Zinc oxide Human
and animal
No significant irritation
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Distillates (petroleum), hydrotreated middle Not
available
Mild irritant
Stearic Acid Moderate irritant Siloxanes and silicones, di-Me Rabbit No significant irritation Triethanolamine Rabbit Mild irritant Zinc oxide Rabbit Mild irritant Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Skin Sensitisation
Name Species Value
Triethanolamine Human Some positive data exist, but the data are not
sufficient for classification
Zinc oxide Guinea
pig
Some positive data exist, but the data are not
sufficient for classification Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Sensitising
Photosensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
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Distillates (petroleum), hydrotreated middle In Vitro Some positive data exist, but the data are not
sufficient for classification Stearic Acid In Vitro Not mutagenic Triethanolamine In Vitro Not mutagenic Triethanolamine In vivo Not mutagenic Zinc oxide In Vitro Some positive data exist, but the data are not
sufficient for classification Zinc oxide In vivo Some positive data exist, but the data are not
sufficient for classification Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Distillates (petroleum), hydrotreated middle Dermal Mouse Some positive data exist, but the data are not
sufficient for classification Stearic Acid Ingestion Rat Not carcinogenic Triethanolamine Dermal Multiple
animal species
Not carcinogenic
Triethanolamine Ingestion Mouse Some positive data exist, but the data are not
sufficient for classification Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Mouse Not carcinogenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Triethanolamine Ingestion Not toxic to development Mouse NOAEL
1,125 mg/kg/day
during
organogenesis
Zinc oxide Ingestion Some positive
reproductive/developmental data exist, but the data are not sufficient for classification
Multiple animal species
NOAEL 125 mg/kg/day
premating & during gestation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to female reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to male reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to development Rat NOAEL 15
mg/kg/day
during organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Distillates (petroleum), hydrotreated middle
Inhalation central nervous
system depression | respiratory irritation
Some positive data exist, but the data are not sufficient for classification
Not available
NOAEL NA
Distillates (petroleum), hydrotreated middle
Ingestion central nervous
system depression
May cause drowsiness or dizziness
Not available
NOAEL NA
Stearic Acid Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
NOAEL Not available
Mixture of 5-chloro-2­methyl-2H-isothiazol-3-
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
similar health
NOAEL Not available
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one and 2-methyl-2H­isothiazol-3-one
classification hazards
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Stearic Acid Ingestion blood Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL Not
available
6 weeks
Triethanolamine Dermal kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Multiple animal species
NOAEL 2,000 mg/kg/day
2 years
Triethanolamine Dermal liver Some positive data exist, but the
data are not sufficient for classification
Mouse NOAEL
4,000 mg/kg/day
13 weeks
Triethanolamine Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL
1,000 mg/kg/day
2 years
Triethanolamine Ingestion liver Some positive data exist, but the
data are not sufficient for classification
Guinea pig
NOAEL 1,600 mg/kg/day
24 weeks
Zinc oxide Ingestion nervous system Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL 600
mg/kg/day
10 days
Zinc oxide Ingestion endocrine system |
hematopoietic system | kidney and/or bladder
Some positive data exist, but the data are not sufficient for classification
Other NOAEL 500
mg/kg/day
6 months
Aspiration Hazard
Name Value
Distillates (petroleum), hydrotreated middle Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l
Mixture of 5­chloro-2­methyl-2H-
55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l
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isothiazol-3­one and 2­methyl-2H­isothiazol-3­one Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l
2­benzylidenehe ptanal
122-40-7 Ricefish Experimental 96 hours LC50 0.91 mg/l
2­benzylidenehe ptanal
122-40-7 Water flea Experimental 48 hours EC50 0.28 mg/l
2­benzylidenehe ptanal
122-40-7 Green Algae Experimental 72 hours EC50 2.3 mg/l
Isothymol 499-75-2 Fathead
minnow
Estimated 96 hours LC50 3.1 mg/l
Paraffin Wax 8002-74-2 Green algae Experimental 96 hours EC50 >1,000 mg/l Paraffin Wax 8002-74-2 Water flea Experimental 48 hours EC50 >10,000 mg/l Paraffin Wax 8002-74-2 Rainbow trout Experimental 96 hours LC50 >1,000 mg/l PEG Stearate 9004-99-3 Green algae Estimated 72 hours EC50 0.64 mg/l PEG Stearate 9004-99-3 Water flea Estimated 48 hours EC50 0.72 mg/l PEG Stearate 9004-99-3 Zebra Fish Estimated 96 hours LC50 0.65 mg/l Petrolatum 8009-03-8 Rainbow trout Estimated 96 hours LC50 >1,000 mg/l Stearic Acid 57-11-4 Ricefish Laboratory 96 hours LC50 125 mg/l Triethanolamine102-71-6 Green algae Experimental 72 hours EC50 216 mg/l
Triethanolamine102-71-6 Water flea Experimental 48 hours EC50 609.98 mg/l
Triethanolamine102-71-6 Goldfish Experimental 24 hours LC50 5,000 mg/l
Non­Hazardous Ingredients
Mixture Field LC50 >1,001 mg/l
Zinc oxide 1314-13-2 Chinook
Salmon
Experimental 96 hours LC50 0.23 mg/l
Zinc oxide 1314-13-2 Water flea Experimental 48 hours EC50 3.2 mg/l Zinc oxide 1314-13-2 Green Algae Experimental 72 hours EC50 0.046 mg/l Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l
2- 122-40-7 Green Algae Experimental 72 hours NOEC 0.21 mg/l
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benzylidenehe ptanal 2­benzylidenehe ptanal
122-40-7 Water flea Experimental 21 days NOEC 0.014 mg/l
PEG Stearate 9004-99-3 Green algae Estimated 72 hours NOEC 0.25 mg/l Triethanolamine102-71-6 Water flea Experimental 21 days NOEC 16 mg/l
Zinc oxide 1314-13-2 Green Algae Experimental 72 hours NOEC 0.021 mg/l Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for
classification Distillates (petroleum), hydrotreated middle
64742-46-7 Data not
available or
insufficient for
classification
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Distillates (petroleum), hydrotreated middle
64742-46-7 Data not
available or insufficient for classification
N/A N/A N/A N/A
Petrolatum 8009-03-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
Isothymol 499-75-2 Estimated
Biodegradation
28 days BOD 11 % weight OECD 301C - MITI
test (I)
PEG Stearate 9004-99-3 Estimated
Biodegradation
28 days CO2 evolution 85.3 % weight OECD 301B -
Modified sturm or CO2
Paraffin Wax 8002-74-2 Estimated
Biodegradation
28 days BOD 40 % weight OECD 301F -
Manometric respirometry
Stearic Acid 57-11-4 Experimental
Biodegradation
28 days CO2 evolution 89 % weight OECD 301B -
Modified sturm or CO2
Triethanolamine102-71-6 Experimental
Biodegradation
19 days Dissolv.
Organic Carbon Deplet
96 % weight 40CFR 796.3240-Mod.
OECD Scree
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Experimental
Biodegradation
28 days CO2 evolution 48 % weight Other methods
Zinc oxide 1314-13-2 Data not
available or
N/A N/A N/A N/A
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insufficient for
classification 2­benzylidenehe ptanal
122-40-7 Estimated
Photolysis
Photolytic half­life (in air)
17 days (t 1/2) Other methods
2­benzylidenehe ptanal
122-40-7 Experimental
Biodegradation
28 days BOD 90 % weight OECD 301F -
Manometric respirometry
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Siloxanes and silicones, di­Me
63148-62-9 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
PEG Stearate 9004-99-3 Estimated
Bioconcentrati
on
Bioaccumulati on factor
5.5 Estimated: Bioconcentration factor
Petrolatum 8009-03-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Paraffin Wax 8002-74-2 Estimated
Bioconcentrati on
Log Kow 10.2 Estimated: Octanol-
water partition coefficient
Triethanolamine102-71-6 Experimental
Bioaccumulati on
Log Kow -2.3 Estimated: Octanol-
water partition coefficient
Distillates (petroleum), hydrotreated middle
64742-46-7 Estimated
Bioconcentrati on
Log Kow 4.61 Estimated: Octanol-
water partition coefficient
Stearic Acid 57-11-4 Experimental
Bioconcentrati on
Log Kow 8.23 Other methods
Isothymol 499-75-2 Experimental
Bioconcentrati on
Log Kow 3.49 Other methods
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Estimated
Bioconcentrati on
Log Kow 0.5 Other methods
Zinc oxide 1314-13-2 Experimental
BCF - Other
56 days Bioaccumulati
on factor
<217 OECD 305E -
Bioaccumulation flow­through fish test
2­benzylidenehe ptanal
122-40-7 Estimated
Bioconcentrati on
Bioaccumulati on factor
705 Estimated:
Bioconcentration factor
12.4. Mobility in soil
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Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Dispose of waste product in a permitted industrial waste facility. If no other disposal options are available, waste product may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Triethanolamine 102-71-6 Gr. 3: Not classifiable International Agency
for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
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15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H301 Toxic if swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H331 Toxic if inhaled. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects.
List of relevant R-phrases
R20 Harmful by inhalation. R23 Toxic by inhalation. R24 Toxic in contact with skin. R25 Toxic if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking.
Revision information:
Revision Changes: Section 8: Respiratory protection - recommended respirators information information was modified. Section 16: List of relevant R phrase information information was modified. Section 3: Composition/ Information of ingredients table information was modified. Section 13: EU waste code (product as sold) information information was modified. Section 9: Flammability (solid, gas) information information was modified. Section 2: Label remarks information was modified. Section 16: Regulations - Inventories - EU ONLY information was modified. Section 2: EU Detergent Regulation label remarks information was modified. Section 1: Address information was modified. Copyright information was modified. Section 11: Aspiration Hazard Table information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Serious Eye Damage/Irritation Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Skin Sensitization Table information was modified. Section 11: Reproductive Toxicity Table information was modified.
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Section 11: Skin Corrosion/Irritation Table information was modified. Section 11: Target Organs - Repeated Table information was modified. Section 11: Target Organs - Single Table information was modified. Section 11: Health Effects - Skin information information was modified. Section 11: Health Effects - Inhalation information information was modified. Section 11: Health Effects - Ingestion information information was modified. Section 5: Fire - Extinguishing media information information was modified. Section 6: Accidental release personal information information was modified. Section 6: Accidental release clean-up information information was modified. Section 7: Precautions safe handling information information was modified. Section 7: Conditions safe storage information was modified. Section 8: Personal Protection - Eye information information was modified. Section 8: Personal Protection - Skin/hand information information was modified. Section 13: 13.1. Waste disposal note information was modified. Section 13: Standard Phrase Category Waste GHS information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. information was modified. Risk phrase information was added. Safety phrase information was added. Section 2: Indication of danger heading information was added. Section 2: Indication of danger information information was added. Section 12: Component ecotoxicity information information was added. Section 12: Persistence and Degradability information information was added. Section 12:Bioccumulative potential information information was added. Section 12: Component Ecotoxicity table Material column header information was added. Section 12: Component Ecotoxicity table CAS No column header information was added. Section 12: Component Ecotoxicity table Organism column header information was added. Section 12: Component Ecotoxicity table Type column header information was added. Section 12: Component Ecotoxicity table Exposure column header information was added. Section 12: Component Ecotoxicity table End point column header information was added. Section 12: Component Ecotoxicity table Result column header information was added. Section 12: Persistence and degradability table Material column header information was added. Section 12: Persistence and degradability table CAS No column header information was added. Section 12: Persistence and degradability table Test Type column header information was added. Section 12: Persistence and degradability table Duration column header information was added. Section 12: Persistence and degradability table Test Result column header information was added. Section 12: Persistence and degradability table Protocol column header information was added. Section 12:Bioccumulative potential table Material column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table Test Result column header information was added. Section 12:Bioccumulative potential table Protocol column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Label: CLP Precautionary - General information was added. Label: CLP Precautionary - General - Header information was added. Label: Precautionary Statement - Header information was added. Label: CLP Supplemental Hazard Statements - Header information was added. Label: CLP Supplemental Information - Header information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Section 2: Notes on labelling heading information was added. Section 15: Label remarks and EU Detergent information was added. CLP Remark(phrase) information was added.
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Section 11: Photosensitisation table - Name heading information was added. Section 11: Photosensitisation table heading information was added. Photosensitisation Table information was added. Section 11: Photosensitisation table - Species heading information was added. Section 11: Photosensitisation table - Value heading information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Section 8: Personal Protection - Respiratory Information information was added. Section 12: Persistence and degradability table Study Type column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Section 9: Odour Threshold information was added. Section 9: Solubility (non-water) information was added. Section 09: Decomposition Temperature information was added. Not applicable information was added. Section 10: Hazardous decomposition products during combustion text information was added. Section 11: Disclosed components not in tables text information was added. Section 8: 8.1.1 Biological limit values table heading information was added. Section 8: BLV information was added. Section 2: R phrase reference information was added. Label: Graphic information was added. List of sensitizers information was added. Section 02: Graphic information information was added. Section 9: Flammability (solid, gas) information information was added. Section 8: Eye/face protection text information was deleted. Section 8: Respiratory protection - recommended respirators information was deleted. Section 2: Symbols heading information was deleted. Section 15: Symbol information information was deleted. Section 15: Symbol information information was deleted. Prints No Data if Component ecotoxicity information is not present information was deleted. Prints No Data if Persistence and Degradability information is not present information was deleted. Prints No Data if Bioccumulative potential information is not present information was deleted. Section 8: mg/m³ key information was deleted. Section 8: ppm key information was deleted. Section 15: Ingredient information per Regulation EC No. 648/2004 information was deleted. Section 11: Respiratory Sensitization Table information was deleted. Section 2.1: Classification information information was deleted. Risk phrase - None information was deleted. Section 15: Ingredient information per Regulation EC No. 648/2004 heading information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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