MEGUIAR'S M93 User Manual

M93, Marine Metal Polish (19-133E): M9314
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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-8062-3
Version number:
1.00
Revision date:
22/03/2012
Supersedes date:
Initial issue.
Transportation version number:
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M93, Marine Metal Polish (19-133E): M9314
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Marine
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
No ingredients are assigned to the label.
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Risk phrases
R67 Vapours may cause drowsiness and dizziness. R66 Repeated exposure may cause skin dryness or cracking.
Safety phrases
S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
S2 Keep out of the reach of children.
Notes on labelling
R65 is not required on the label due to the product's viscosity. Ingredients required per 648/2004: >30%: Aliphatic hydrocarbons. Contains: Perfumes, d-limonene, benzyl benzoate. Nota P applied to CASRN 64742-48-9.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Aluminium oxide (REACH Reg. No.:01­2119529248-35)
1344-28-1 EINECS 215-
691-6
15 - 40
Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
10 - 30 Xn:R65 - Nota 4,P (EU)
R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) STOT SE 3, H336; EUH066 (Self Classified)
Distillates (petroleum), hydrotreated light 64742-47-8 EINECS 265-
149-8
10 - 30 Xn:R65 - Nota 4 (EU)
R10; R66; R67 (Self Classified)
Asp. Tox. 1, H304 (CLP) Flam. Liq. 3, H226; STOT SE 3,
H336; EUH066 (Self Classified) Conditioners Trade Secret < 10 Ceramic materials and wares, chemicals 66402-68-4 EINECS 266-
340-9
1 - 5
Stearic acid 57-11-4 EINECS 200-
313-4
1 - 5
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
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Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Ventilate the area with fresh air.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray.
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Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Use personal protective equipment (eg. gloves, respirators…) as required. Keep out of reach of children. Vapours may travel long distances along the ground or floor to an ignition source and flash back.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. No special storage requirements.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Aluminium oxide 1344-28-1 Health and
Safety Comm. (UK)
TWA(as inhalable dust):10 mg/m³;TWA(as respirable
dust):4 mg/m³ Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half face piece or full face air-purifying respirator with organic vapour cartridges.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
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Physical state
Liquid.
Specific Physical Form:
Paste
Appearance/Odour
Pleasant, sweet odour; Soft, glossy, deep blue cream
pH
Not applicable.
Boiling point/boiling range
193.3 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
>= 93.3 ºC [Test Method:Pensky-Martens Closed Cup]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
0.89 [Ref Std:WATER=1]
Water solubility
Slight (less than 10%)
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
No data available.
Density
0.89 g/cm3
9.2. Other information Volatile organic compounds (VOC)
29.49 % weight
VOC less H2O & exempt solvents
502.12 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Temperatures above the boiling point.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
M93, Marine Metal Polish (19-133E): M9314
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classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Contact with the skin during product use is not expected to result in significant irritation.
Inhalation
No health effects are expected.
Ingestion
No health effects are expected.
Target Organ Effects:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Toxicological Data
Acute Toxicity
Name Route Species Value UN GHS Classification
Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy
No data available
Distillates (petroleum), hydrotreated light
No data available
Conditioners No data available Ceramic materials and wares, chemicals
No data available
Stearic acid No data available
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to be mild irritant
Category 3
Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy Mild irritant Category 3 Distillates (petroleum), hydrotreated light No data available Conditioners No data available Ceramic materials and wares, chemicals No data available Stearic acid No data available
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Serious Eye Damage/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to cause no significant irritation
Not classified
Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy No data available Distillates (petroleum), hydrotreated light Mild irritant Not classified Conditioners No data available Ceramic materials and wares, chemicals No data available Stearic acid No data available
Skin Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy No data available Distillates (petroleum), hydrotreated light No data available Conditioners No data available Ceramic materials and wares, chemicals No data available Stearic acid No data available
Respiratory Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy No data available Distillates (petroleum), hydrotreated light No data available Conditioners No data available Ceramic materials and wares, chemicals No data available Stearic acid No data available
Germ Cell Mutagenicity
Name Route Value UN GHS Classification
Overall product No data available Overall Germ Cell Mutagenicity
classification Not classified Overall product No test data available. Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy No data available Distillates (petroleum), hydrotreated light No data available Conditioners No data available Ceramic materials and wares, chemicals No data available Stearic acid No data available
Carcinogenicity
Name Route Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy
No data available
Distillates (petroleum), hydrotreated light
No data available
Conditioners No data available Ceramic materials and wares, chemicals
No data available
Stearic acid No data available
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Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
UN GHS Classification
Overall product No test data
available.
Not classified based on
component data Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy
No data available
Distillates (petroleum), hydrotreated light
No data available
Conditioners No data available Ceramic materials and wares, chemicals
No data available
Stearic acid No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
UN GHS Classification
Aluminium oxide
No data
available Naphtha (petroleum), hydrotreated heavy
Inhalation central
nervous system depression
May cause
drowsiness or
dizziness
NOAEL N/A
Category 3
Distillates (petroleum), hydrotreated light
Inhalation central
nervous system depression
May cause
drowsiness or
dizziness
NOAEL N/A
Category 3
Conditioners No data
available Ceramic materials and wares, chemicals
No data
available
Stearic acid Inhalation respiratory
irritation
Some positive
data exist, but
the data are not
sufficient for
classification
Irritation Positive
Not classified
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
UN GHS Classification
Overall product
No test data
available.
Category 2 based on component
data Aluminium oxide
Inhalation pneumocon
iosis
May cause damage to organs though prolonged or repeated exposure
NOAEL N/A
Category 2
Naphtha (petroleum), hydrotreated
No data available
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heavy Distillates (petroleum), hydrotreated light
No data available
Conditioners No data available Ceramic materials and wares, chemicals
No data available
Stearic acid No data available
Aspiration Hazard
Name Value UN GHS Classification
Overall product No test data available. Not classified based on
component and/or viscosity
data Aluminium oxide Not an aspiration hazard Not classified Naphtha (petroleum), hydrotreated heavy Aspiration hazard Category 1 Distillates (petroleum), hydrotreated light Aspiration hazard Category 1 Conditioners Not an aspiration hazard Not classified Ceramic materials and wares, chemicals Not an aspiration hazard Not classified Stearic acid Not an aspiration hazard Not classified
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
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SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Proper destruction may require the use of additional fuel during incineration processes. This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
120109* Machining emulsions and solutions free of halogens
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Alumina C10-12 Alkane/cycloalkane Hydrotreated light petroleum distillates Conditioner Stearic acid Quaternium-18 bentonite Aqua Perfumes Corrosion inhibitors Quartz d-Limonene Benzyl benzoate Colorant Isooctane
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
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EUH066 Repeated exposure may cause skin dryness or cracking. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H336 May cause drowsiness or dizziness.
List of relevant R-phrases
R10 Flammable. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
No revision information is available.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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