See section 16 for the full text of the R-phrases declared above
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
[1] Substance classified with a health or environmental hazard
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[2] Substance with a workplace exposure limit
Occupational exposure limits, if available, are listed in section 8.
M91 - Marine/RV Professional Compoun
4.
First-aid measures
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training.
Notes to physicianNo specific treatment. Treat symptomatically. Contact poison treatment specialist
See section 11 for more detailed information on health effects and symptoms.
5.
Extinguishing media
Hazardous combustion
products
Special protective
equipment for fire-fighters
First-aid measures
Eye contact:
Skin contact
Inhalation
Ingestion
Fire-fighting measures
NFPA
Health
Suitable:
Not suitable:
1
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Check for and remove any contact lenses. In case of contact with eyes, rinse
immediately with plenty of water. Obtain medical attention if symptoms occur.
Wash with soap and water. Obtain medical attention if symptoms occur.
:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical
:
attention if symptoms appear.
Do not induce vomiting. Never give anything by mouth to an unconscious person. Get
:
medical attention if symptoms appear.
:
immediately if large quantities have been ingested or inhaled.
Flammability
Use an extinguishing agent suitable for the surrounding fire.
None known.
:
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
:
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
1
Reactivity
0
6.Accidental release measures
Personal precautions
Environmental precautions
Large spill:
Small spill:
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see section 8).
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
:
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Approach the release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite
or diatomaceous earth and place in container for disposal according to local
regulations (see section 13). Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilt product.
Note: see section 1 for emergency contact information and section 13 for waste
disposal.
Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble or absorb with an inert dry material and place in an appropriate
waste disposal container. Dispose of via a licensed waste disposal contractor
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7.
Handling
Storage
Packaging materials
Handling and storage
:
Put on appropriate personal protective equipment (see section 8). Eating, drinking
and smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and
smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing
vapour or mist. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.
:
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible
materials (see section 10) and food and drink. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabelled containers.
Use appropriate containment to avoid environmental contamination.
Ethanol, 2-(2-Ethoxyethoxy)-MAK-Werte Liste (Germany, 7/2007).
PEAK: 100 mg/m³, 4 times per shift, 15 minute(s).
Form: aerosol / measured as the inhalable fraction
TWA: 50 mg/m³ 8 hour(s). Form: aerosol / measured as
the inhalable fraction
PEAK: 100 mg/m³, 4 times per shift, 15 minute(s).
Form: aerosol / measured as the inhalable fraction
TWA: 50 mg/m³ 8 hour(s). Form: aerosol / measured as
the inhalable fraction
If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.
: No special ventilation requirements. Good general ventilation should be sufficient to
control worker exposure to airborne contaminants. If this product contains ingredients
with exposure limits, use process enclosures, local exhaust ventilation or othe
engineering controls to keep worker exposure below any recommended or statutory
limits.
A respirator is not needed under normal and intended conditions of product use.
Disposable vinyl gloves.
:
Safety glasses.Eye protection
:
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g/kg
Hygiene measures: Wash hands, forearms and face thoroughly after handling compounds and before
eating, smoking and using the lavatory and at the end of the day.
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
9.
General information
Important health, safety and environmental information
10.
Conditions to avoidNo specific data.
Materials to avoid:
Hazardous decomposition
products
Physical and chemical properties
Appearance
Physical state
pH
Boiling point
Flash point
Relative density
Solubility
Vapour density
Evaporation rate<1 (Butyl acetate. = 1)
VOC Content:
:
Liquid.
Off-white.Colour
:
:
Sweet.Odour
:
8.5
100°C (212°F)
:
:
Closed cup: 93.33°C (200°F) [Pensky-Martens.]
:
1
:
Miscible in water.
:
1 [Air = 1]
:
17 %
Stability and reactivity
:
Hazardous polymerization may occur under certain conditions of storage or use.Stability
:
Reactive or incompatible with the following materials: oxidizing materials, acids and
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alkalis.
:
Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Toxicological information11.
Potential acute health effects
Inhalation: No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact: No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.Chronic effects:
No known significant effects or critical hazards.Carcinogenicity:
No known significant effects or critical hazards.Mutagenicity:
-
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No known significant effects or critical hazards.Teratogenicity:
Developmental effects: No known significant effects or critical hazards.
Fertility effects: No known significant effects or critical hazards.
Over-exposure signs/symptoms
InhalationNo specific data.
Ingestion
Skin
Eyes: No specific data.
Target organsContains material which causes damage to the following organs: lungs, upper
:
No specific data.
:
No specific data.
:
:
respiratory tract, skin, eye, lens or cornea.
Contains material which may cause damage to the following organs: kidneys.
Ecological information12.
Environmental effects: No known significant effects or critical hazards.
Aquatic ecotoxicity
Product/ingredient nameSpeciesExposureResult
Ethanol, 2-(2-Ethoxyethoxy)-Fish96 hoursAcute LC50 6010000 to 8080000 ug/L
Other adverse effects: No known significant effects or critical hazards.
Disposal considerations13.
:Methods of disposal
The generation of waste should be avoided or minimised wherever possible. Empty
containers or liners may retain some product residues. Disposal of this product,
solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local
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authority requirements. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.
Dispose of according to all federal, state and local applicable regulations.:Waste classification
Not applicableHazardous waste:
14.
International transport regulations
Transport information
UN/Not regulated by any transport mode.IATA /:ADNR/ ADRIMDG/
Regulatory information15.
EU regulations
Classification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC
(including amendments) and take into account the intended product use.
:
This product is not classified according to EU legislation.Risk phrases
Safety phrasesS2- Keep out of the reach of children.
Product useConsumer applications, Industrial applications.:
Europe inventory: All components are listed or exempted.
Other EU regulations
Additional warning phrases : Safety data sheet available for professional user on request.
National regulations
France
Social Security Code,
Articles L 461-1 to L 461-7
Reinforced medical
surveillance
:
:
: Act of July 11, 1977 determining the list of activities which require reinforced medical
lene Glycol Ethe
Dieth
surveillance: not applicable
RG 84
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Germany
Switzerland
Poison classNot regulated:
BAG T619000:
VOC contentLiberated.:
Italy
Other information16.
Full text of R-phrases
referred to in sections 2 and
3
referred to in sections 2 and
3
History
Date of issue
M91 - Marine/RV Professional Compoun
3 Appendix No. 4Hazard class for water:
98% Not classified.Emission control directive:
:
R65- Harmful: may cause lung damage if swallowed.
R36- Irritating to eyes.
Xn - Harmful
:Full text of classifications
Xi - Irritant
: 05/15/2008
1:Version
1
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the
user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist.
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Date of issue
:
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Version
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Page: 8/8
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