MEGUIAR'S M85 User Manual

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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-1809-4
Version number:
1.02
Revision date:
28/05/2012
Supersedes date:
21/11/2011
Transportation version number: 1.00 (25/07/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M85, Diamond Cut Compound 2.0 (21-97A): M8501, M8532
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
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No ingredients are assigned to the label.
Risk phrases None. Safety phrases
S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota P applied for CASRN 64742-48-9. Nota N applied for CASRN 64742-46-7.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non hazardous ingredient Mixture 50 - 70 Aluminium oxide (REACH Reg. No.:01­2119529248-35)
1344-28-1 EINECS 215-
691-6
7 - 13
Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
5 - 10 Xn:R65 - Nota 4,P (EU)
R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) STOT SE 3, H336; EUH066 (Self Classified)
Solvent naphtha (petroleum), medium aliph. 64742-88-7 EINECS 265-
191-7
5 - 10 Xn:R65 - Nota 4 (EU)
R10; R66; R67 (Self Classified)
Asp. Tox. 1, H304 (CLP) Flam. Liq. 3, H226; STOT SE 3, H336; EUH066 (Self Classified)
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
1 - 5 Nota N (EU)
Xn:R20-65; R66 (Self Classified)
Nota N (CLP) Acute Tox. 4, H332; Asp. Tox. 1, H304; STOT SE 3, H336; EUH066 (Self Classified)
Glycerin 56-81-5 EINECS 200-
289-5
1 - 5
Conditioners Trade Secret < 5 2-(2-Ethoxyethoxy)ethanol 111-90-0 EINECS 203-
919-7
1 - 5
Processed oil Trade Secret 0.5 - 1.5 Morpholine 110-91-8 EINECS 203-
815-1
< 1 C:R34; Xn:R20-21-22; R10
(EU)
Flam. Liq. 3, H226; Acute Tox.
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3, H311; Acute Tox. 4, H332; Acute Tox. 4, H302; Skin Corr.
1B, H314 (CLP) Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Hydrocarbons. During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
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exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Place in a closed container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not eat, drink or smoke when using this product. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from heat. Store away from oxidising agents. Store away from strong bases.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Morpholine 110-91-8 Health and
Safety Comm. (UK)
TWA: 36 mg/m³ (10 ppm); STEL: 72 mg/m³ (20 ppm)
Skin Notation
Aluminium oxide 1344-28-1 Health and
Safety Comm. (UK)
TWA(as inhalable dust):10 mg/m³;TWA(as respirable dust):4 mg/m³
Glycerin 56-81-5 Health and
Safety Comm. (UK)
TWA(as mist):10 mg/m3
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
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8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Gloves made from the following material(s) are recommended: Nitrile rubber. Polymer laminate
Respiratory protection
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece air-purifying respirator suitable for organic vapors/acid gases and particulates
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Sweet hydrocarbon odour; White, creamy viscous lotion
pH
8 - 8.8
Boiling point/boiling range
193.3 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
> 93.3 ºC [Test Method:Closed Cup]
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Moderate
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
> 1
Viscosity
25 - 40 Pa-s
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
16.9 % weight
VOC less H2O & exempt solvents
520.73 g/l
SECTION 10: Stability and reactivity
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10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Dust created by cutting, grinding, sanding, or machining may cause eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, nose and throat pain. May cause target organ effects after inhalation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Target Organ Effects:
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Prolonged or repeated exposure by ingestion may cause:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg
Aluminium oxide Inhalation-Dust/Mist
(4 hours)
Rabbit LC50 > 1.9 mg/l
Aluminium oxide Ingestion Rat LD50 > 5,000 mg/kg Naphtha (petroleum), hydrotreated heavy
Dermal Rabbit LD50 > 3,000 mg/kg
Naphtha (petroleum), hydrotreated heavy
Inhalation-Vapor (4 hours)
Rat LC50 estimated to be 20 - 50 mg/l
Naphtha (petroleum), hydrotreated heavy
Ingestion Rat LD50 > 5,000 mg/kg
Solvent naphtha (petroleum), medium aliph.
Dermal Rabbit LD50 > 3,000 mg/kg
Solvent naphtha (petroleum), medium aliph.
Inhalation-Vapor (4 hours)
Rat LC50 estimated to be 20 - 50 mg/l
Solvent naphtha (petroleum), medium aliph.
Ingestion Rat LD50 > 5,000 mg/kg
Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg 2-(2-Ethoxyethoxy)ethanol Dermal Rabbit LD50 9,143 mg/kg 2-(2-Ethoxyethoxy)ethanol Ingestion Rat LD50 5,400 mg/kg Distillates (petroleum), hydrotreated middle
Dermal Rabbit LD50 > 2,000 mg/kg
Distillates (petroleum), hydrotreated middle
Inhalation-Dust/Mist (4 hours)
Rat LC50 5 mg/l
Distillates (petroleum), hydrotreated middle
Ingestion Rat LD50 > 5,000 mg/kg
Processed oil Ingestion LD50 estimated to be > 5,000 Morpholine Dermal Rabbit LD50 310 mg/kg Morpholine Inhalation-Vapor (4
hours)
Rat LC50 8 mg/l
Morpholine Ingestion Rat LD50 1,050 mg/kg Conditioners No data available
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy Mild irritant Solvent naphtha (petroleum), medium aliph. Mild irritant Glycerin Rabbit No significant irritation 2-(2-Ethoxyethoxy)ethanol Minimal irritation Distillates (petroleum), hydrotreated middle Rabbit Minimal irritation Processed oil Minimal irritation Morpholine Corrosive Conditioners No data available
Serious Eye Damage/Irritation
Name Species Value
Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy Mild irritant
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Solvent naphtha (petroleum), medium aliph. Mild irritant Glycerin Rabbit No significant irritation 2-(2-Ethoxyethoxy)ethanol Moderate irritant Distillates (petroleum), hydrotreated middle Not available Mild irritant Processed oil Mild irritant Morpholine Corrosive Conditioners No data available
Skin Sensitisation
Name Species Value
Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy Not sensitizing Solvent naphtha (petroleum), medium aliph. Not sensitizing Glycerin Guinea pig Not sensitizing 2-(2-Ethoxyethoxy)ethanol Not sensitizing Distillates (petroleum), hydrotreated middle No data available Processed oil Human Some positive data exist, but the data are not
sufficient for classification Morpholine Guinea pig Not sensitizing Conditioners No data available
Respiratory Sensitisation
Name Species Value
Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy No data available Solvent naphtha (petroleum), medium aliph. No data available Glycerin No data available 2-(2-Ethoxyethoxy)ethanol No data available Distillates (petroleum), hydrotreated middle No data available Processed oil No data available Morpholine No data available Conditioners No data available
Germ Cell Mutagenicity
Name Route Value
Aluminium oxide In Vitro Not mutagenic Naphtha (petroleum), hydrotreated heavy Inhalation Not mutagenic Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but the data are not
sufficient for classification Solvent naphtha (petroleum), medium aliph. Inhalation Not mutagenic Solvent naphtha (petroleum), medium aliph. In Vitro Some positive data exist, but the data are not
sufficient for classification Glycerin No data available 2-(2-Ethoxyethoxy)ethanol In vivo Not mutagenic Distillates (petroleum), hydrotreated middle In Vitro Some positive data exist, but the data are not
sufficient for classification Processed oil In Vitro Not mutagenic Processed oil In vivo Not mutagenic Morpholine In Vitro Some positive data exist, but the data are not
sufficient for classification Morpholine In vivo Some positive data exist, but the data are not
sufficient for classification Conditioners No data available
Carcinogenicity
Name Route Species Value
Aluminium oxide Inhalation Not carcinogenic Naphtha (petroleum), hydrotreated heavy
Dermal Some positive data exist, but the data
are not sufficient for classification
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Naphtha (petroleum), hydrotreated heavy
Inhalation Some positive data exist, but the data
are not sufficient for classification Solvent naphtha (petroleum), medium aliph.
Dermal Some positive data exist, but the data
are not sufficient for classification Solvent naphtha (petroleum), medium aliph.
Inhalation Some positive data exist, but the data
are not sufficient for classification Glycerin Ingestion Mouse Some positive data exist, but the data
are not sufficient for classification 2-(2-Ethoxyethoxy)ethanol No data available Distillates (petroleum), hydrotreated middle
Dermal Mouse Some positive data exist, but the data
are not sufficient for classification Processed oil No data available Morpholine Ingestion Multiple animal
species
Not carcinogenic
Morpholine Inhalation Rat Not carcinogenic Conditioners No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Aluminium oxide No data available Naphtha (petroleum), hydrotreated heavy
Inhalation Not toxic to
reproduction and/or development
NOAEL
2.356 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation Not toxic to
reproduction and/or development
NOAEL
2.356 mg/l
Glycerin Ingestion Not toxic to female
reproduction
Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to male
reproduction
Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to
development
Rat NOAEL
2,000 mg/kg/day
2 generation
2-(2­Ethoxyethoxy)ethano l
Dermal Not toxic to
reproduction and/or development
NOAEL 5,500
mg/kg/day 2-(2­Ethoxyethoxy)ethano l
Inhalation Not toxic to
reproduction and/or development
NOAEL
0.561 mg/l
2-(2­Ethoxyethoxy)ethano l
Ingestion Some positive
reproductive/develop mental data exist, but the data are not sufficient for classification
NOEL 2,200
mg/kg/day
Distillates (petroleum), hydrotreated middle
No data available
Processed oil Ingestion Not toxic to female
reproduction
Rat NOAEL
4,800
mg/kg/day
13 weeks
Processed oil Ingestion Not toxic to male
reproduction
Rat NOAEL
4,800
mg/kg/day
13 weeks
Morpholine No data available Conditioners No data available
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Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Aluminium oxide
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Naphtha (petroleum), hydrotreated heavy
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
NOEL 6.5 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 2.4 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL 2.5 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation liver | kidney
and/or bladder
All data are negative
NOAEL 0.610 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation muscles All data are
negative
NOAEL 0.61 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Solvent naphtha (petroleum), medium aliph.
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Solvent naphtha (petroleum), medium aliph.
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
NOEL 6.5 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 2.4 mg/l
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Solvent naphtha (petroleum), medium aliph.
Inhalation heart All data are
negative
NOAEL 2.5 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation liver | kidney
and/or bladder
All data are negative
NOAEL 0.610 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation muscles All data are
negative
NOAEL 0.61 mg/l
Glycerin No data available 2-(2­Ethoxyethoxy )ethanol
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Distillates (petroleum), hydrotreated middle
Inhalation central nervous
system depression | respiratory irritation
Some positive data exist, but the data are not sufficient for classification
Not available NOAEL NA
Distillates (petroleum), hydrotreated middle
Ingestion central nervous
system depression
May cause drowsiness or dizziness
Not available NOAEL NA
Processed oil No data available Morpholine Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Conditioners No data available
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Aluminium oxide
Inhalation pneumoconiosis May cause
damage to organs though prolonged or repeated exposure
NOAEL N/A
Aluminium oxide
Inhalation pulmonary
fibrosis
Some positive data exist, but the data are not sufficient for classification
NOAEL N/A
Naphtha (petroleum), hydrotreated heavy
Dermal nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 691 mg/kg
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 4.580 mg/l
Naphtha (petroleum), hydrotreated
Inhalation respiratory
system
Some positive data exist, but the data are not
NOEL 0.619 mg/l
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heavy sufficient for
classification Naphtha (petroleum), hydrotreated heavy
Inhalation endocrine
system | muscles
Some positive
data exist, but the
data are not
sufficient for
classification
LOEL 0.616 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
LOEL 0.57 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation bone, teeth,
nails, and/or hair | blood | liver
All data are
negative
NOAEL 5.62 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL 1.271 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation immune system All data are
negative
NOAEL 0.616 mg/l
Solvent naphtha (petroleum), medium aliph.
Dermal nervous system Some positive
data exist, but the
data are not
sufficient for
classification
LOEL 691 mg/kg
Solvent naphtha (petroleum), medium aliph.
Inhalation nervous system Some positive
data exist, but the
data are not
sufficient for
classification
LOEL 4.580 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation respiratory
system
Some positive
data exist, but the
data are not
sufficient for
classification
NOEL 0.619 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation endocrine
system | muscles
Some positive
data exist, but the
data are not
sufficient for
classification
LOEL 0.616 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
LOEL 0.57 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation bone, teeth,
nails, and/or hair | blood | liver
All data are
negative
NOAEL 5.62 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation heart All data are
negative
NOAEL 1.271 mg/l
Solvent naphtha (petroleum), medium aliph.
Inhalation immune system All data are
negative
NOAEL 0.616 mg/l
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Glycerin Inhalation respiratory
system
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 3.91
mg/l
14 days
Glycerin Inhalation heart | liver |
kidney and/or bladder
All data are
negative
Rat NOAEL 3.91
mg/l
14 days
Glycerin Ingestion endocrine
system | hematopoietic system | liver | kidney and/or bladder
All data are
negative
Rat NOAEL 10,000
mg/kg/day
2 years
2-(2­Ethoxyethoxy )ethanol
Dermal kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
NOEL 300 mg/kg/day
2-(2­Ethoxyethoxy )ethanol
Ingestion kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
NOAEL 2,700 mg/kg/day
2-(2­Ethoxyethoxy )ethanol
Ingestion liver Some positive
data exist, but the
data are not
sufficient for
classification
NOAEL 167 mg/kg/day
2-(2­Ethoxyethoxy )ethanol
Ingestion heart |
hematopoietic system | nervous system
Some positive
data exist, but the
data are not
sufficient for
classification
NOEL 2,700 mg/kg/day
2-(2­Ethoxyethoxy )ethanol
Ingestion endocrine
system
Some positive
data exist, but the
data are not
sufficient for
classification
NOEL 250 mg/kg/day
Distillates (petroleum), hydrotreated middle
No data available
Processed oil Ingestion heart |
hematopoietic system | liver
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 4,800
mg/kg/day
13 weeks
Processed oil Ingestion kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL 13,000
mg/kg/day
13 weeks
Morpholine Dermal liver | kidney
and/or bladder
Some positive
data exist, but the
data are not
sufficient for
classification
LOAEL 900 mg/kg/day
Morpholine Dermal hematopoietic
system
All data are
negative
Guinea pig NOAEL 900
mg/kg/day
13 days
Morpholine Inhalation eyes Causes damage to NOAEL N/A
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organs through
prolonged or
repeated exposure Morpholine Inhalation respiratory
system
May cause
damage to organs
though prolonged
or repeated
exposure
NOAEL 0.09 mg/l
Morpholine Inhalation liver | kidney
and/or bladder
Some positive
data exist, but the
data are not
sufficient for
classification
Rat LOAEL 64 mg/l 5 days
Morpholine Inhalation heart | endocrine
system
All data are
negative
Rat NOAEL 0.9
mg/l
13 weeks
Morpholine Inhalation nervous system All data are
negative
Rat NOAEL 0.53
mg/l
104 weeks
Morpholine Ingestion kidney and/or
bladder
May cause
damage to organs
though prolonged
or repeated
exposure
LOAEL 160 mg/kg/day
Morpholine Ingestion liver |
respiratory system
Some positive
data exist, but the
data are not
sufficient for
classification
NOAEL 160 mg/kg/day
Morpholine Ingestion hematopoietic
system
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 800
mg/kg/day
30 days
Morpholine Ingestion endocrine
system
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 323
mg/kg/day
4 weeks
Conditioners No data available
Aspiration Hazard
Name Value
Aluminium oxide Not an aspiration hazard Naphtha (petroleum), hydrotreated heavy Aspiration hazard Solvent naphtha (petroleum), medium aliph. Aspiration hazard Glycerin Not an aspiration hazard 2-(2-Ethoxyethoxy)ethanol Not an aspiration hazard Distillates (petroleum), hydrotreated middle Aspiration hazard Processed oil Not an aspiration hazard Morpholine Not an aspiration hazard Conditioners Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
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ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as hazardous as per applicable regulations) shall be considered,stored,treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 13* Solvents
SECTION 14: Transportation information
ADR / IMDG / IATA: Not restricted for transport.
SECTION 15: Regulatory information
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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Morpholine 110-91-8 Gr. 3: Not classifiable International Agency
for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness.
List of relevant R-phrases
R10 Flammable. R20 Harmful by inhalation. R21 Harmful in contact with skin. R22 Harmful if swallowed. R34 Causes burns. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 8: Respiratory protection - recommended respirators information was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 2: Label remarks was modified. Section 16: Regulations – Inventories – EU ONLY was modified. Copyright was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified.
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Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 11: Health Effects - Eye information was modified. Section 11: Health Effects - Inhalation information was modified. Section 11: Health Effects - Ingestion information was modified. Section 11: Health Effects - Other information was modified. Section 5: Fire - Extinguishing media information was modified. Section 5: Fire - Special hazards information was modified. Section 5: Fire - Advice for fire fighters information was modified. Section 6: Accidental release personal information was modified. Section 6: Accidental release clean-up information was modified. Section 7: Precautions safe handling information was modified. Section 7: Conditions safe storage was modified. Section 10.1: Reactivity information was modified. Section 13: Standard Phrase Category Waste GHS was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 12: Acute aquatic hazard information was added. Section 12: Chronic aquatic hazard heading was added. Section 12: Acute aquatic hazard heading was added. Section 12: Chronic aquatic hazard information was added. Section 2: Special provisions concerning the labelling of certain substances heading was deleted. Section 2: Additional label requirements phrase was deleted. Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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