MEGUIAR'S M83 User Manual

M83, BSP Dual Action Cleaner/Polisher (21-167A): M8301, M8332
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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-1861-5
Version number:
1.01
Revision date:
07/07/2012
Supersedes date:
28/10/2011
Transportation version number: 1.00 (28/10/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M83, BSP Dual Action Cleaner/Polisher (21-167A): M8301, M8332
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
M83, BSP Dual Action Cleaner/Polisher (21-167A): M8301, M8332
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No ingredients are assigned to the label.
Risk phrases None. Safety phrases
S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
Notes on labelling
R65 is not required on the label due to the product's viscosity. Updated per Regulation (EC) 648/2004 on detergents. Ingredients required per 648/2004: 15-30%: Aliphatic hydrocarbons; <5%: Non-ionic surfactant. Contains: Perfumes, methylchloroisothiazolinone, methylisothiazolinone. Nota P applied for CASRN 64742-48-9. Nota N applied for CASRN 64742-46-7.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Water 7732-18-5 EINECS 231-
791-2
50 - 70
Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
10 - 30 Xn:R65 - Nota 4,P (EU)
R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) STOT SE 3, H336; EUH066
(Self Classified) Aluminium oxide (REACH Reg. No.:01­2119529248-35)
1344-28-1 EINECS 215-
691-6
5 - 10
Kaolin, calcined 92704-41-1 EINECS 296-
473-8
3 - 7
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
1 - 5 Nota N (EU)
Xn:R20-65; R66 (Self
Classified)
Nota N (CLP)
Acute Tox. 4, H332; Asp. Tox.
1, H304; STOT SE 3, H336;
EUH066 (Self Classified) Glycerin 56-81-5 EINECS 200-
289-5
1 - 5
Processed oil Trade Secret 1 - 5 1-methyl-2-pyrrolidone (REACH Reg. No.:01-2119472430-46)
872-50-4 EINECS 212-
828-1
1 - 5 Repr.Cat.2:R61; Xi:R36-37-38
(EU)
Skin Irrit. 2, H315; Eye Irrit. 2,
H319; Repr. 1B, H360D; STOT
SE 3, H335 (CLP) Conditioners Trade Secret < 5 Titanium dioxide 13463-67-7 EINECS 236- <= 0.1
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675-5
Quartz 14808-60-7 EINECS 238-
878-4
<= 0.025 Xn:R48/20 (Vendor)
STOT RE 1, H372 (Self
Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Hydrocarbons. During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
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6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area or areas with little or no air movement. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (eg. gloves, respirators…) as required.
7.2. Conditions for safe storage including any incompatibilities
Store away from heat. Protect from sunlight. Store away from acids. Store away from strong bases. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Aluminium oxide 1344-28-1 Health and
Safety Comm. (UK)
TWA(as inhalable dust):10 mg/m³;TWA(as respirable dust):4 mg/m³
Titanium dioxide 13463-67-7 Health and
Safety Comm. (UK)
TWA(Inhalable):10 mg/m3;TWA(respirable):4
mg/m³ Silica, crystalline (airborne particles of respirable size)
14808-60-7 Health and
Safety Comm. (UK)
TWA(respirable):0.1 mg/m3
Glycerin 56-81-5 Health and TWA(as mist):10 mg/m3
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Safety Comm.
(UK) Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
1-methyl-2-pyrrolidone 872-50-4 Health and
Safety Comm.
(UK)
TWA:40 mg/m3(10 ppm);STEL:80 mg/m3(20 ppm)
Skin Notation
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Wear eye/face protection. The following eye protection(s) are recommended: Indirect vented goggles.
Skin/hand protection
Wear protective gloves. Gloves made from the following material(s) are recommended: Neoprene. Polymer laminate
Respiratory protection
In case of inadequate ventilation wear respiratory protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Sweet hydrocarbon odour; White, viscous, semi-pourable liquid
pH
7.9 - 8.9
Boiling point/boiling range
198.9 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
> 93.3 ºC [Test Method:Pensky-Martens Closed Cup] [Details:D93-90]
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Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Moderate
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
> 1
Viscosity
7 - 16 Pa-s
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
16.9 % weight
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong bases. Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
M83, BSP Dual Action Cleaner/Polisher (21-167A): M8301, M8332
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Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Dust created by cutting, grinding, sanding, or machining may cause eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, nose and throat pain. May cause target organ effects after inhalation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Target Organ Effects:
Prolonged or repeated exposure by ingestion may cause:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg Naphtha (petroleum), hydrotreated heavy
Dermal Rabbit LD50 > 3,000 mg/kg
Naphtha (petroleum), hydrotreated heavy
Inhalation-Vapor (4 hours)
Rat LC50 estimated to be 20 - 50 mg/l
Naphtha (petroleum), hydrotreated heavy
Ingestion Rat LD50 > 5,000 mg/kg
Aluminium oxide Inhalation-Dust/Mist
(4 hours)
Rabbit LC50 > 1.9 mg/l
Aluminium oxide Ingestion Rat LD50 > 5,000 mg/kg Kaolin, calcined Ingestion Rat LD50 > 2,000 mg/kg Distillates (petroleum), hydrotreated middle
Dermal Rabbit LD50 > 2,000 mg/kg
Distillates (petroleum), hydrotreated middle
Inhalation-Dust/Mist (4 hours)
Rat LC50 5 mg/l
Distillates (petroleum), hydrotreated middle
Ingestion Rat LD50 > 5,000 mg/kg
1-methyl-2-pyrrolidone Dermal Rabbit LD50 4,000 mg/kg 1-methyl-2-pyrrolidone Inhalation-Dust/Mist
(4 hours)
Rat LC50 > 5 mg/l
1-methyl-2-pyrrolidone Ingestion Rat LD50 4,320 mg/kg Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg Processed oil Ingestion LD50 estimated to be > 5,000
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Conditioners No data available Titanium dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium dioxide Inhalation-Dust/Mist
(4 hours)
Rat LC50 > 7 mg/l
Titanium dioxide Ingestion Rat LD50 > 10,000 mg/kg Quartz Ingestion LD50 estimated to be > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Mild irritant Aluminium oxide No data available Kaolin, calcined No data available Distillates (petroleum), hydrotreated middle Rabbit Minimal irritation 1-methyl-2-pyrrolidone Rabbit Minimal irritation Glycerin Rabbit No significant irritation Processed oil Human Minimal irritation Conditioners No data available Titanium dioxide No significant irritation Quartz No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Mild irritant Aluminium oxide No data available Kaolin, calcined No data available Distillates (petroleum), hydrotreated middle Not available Mild irritant 1-methyl-2-pyrrolidone Rabbit Severe irritant Glycerin Rabbit No significant irritation Processed oil Rabbit Mild irritant Conditioners No data available Titanium dioxide Mild irritant Quartz No data available
Skin Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Not sensitizing Aluminium oxide No data available Kaolin, calcined No data available Distillates (petroleum), hydrotreated middle No data available 1-methyl-2-pyrrolidone Human and animal Not sensitizing Glycerin Guinea pig Not sensitizing Processed oil Human Some positive data exist, but the data are not
sufficient for classification Conditioners No data available Titanium dioxide Not sensitizing Quartz No data available
Respiratory Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy No data available Aluminium oxide No data available Kaolin, calcined No data available Distillates (petroleum), hydrotreated middle No data available 1-methyl-2-pyrrolidone No data available Glycerin No data available Processed oil No data available Conditioners No data available Titanium dioxide No data available
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Quartz No data available
Germ Cell Mutagenicity
Name Route Value
Naphtha (petroleum), hydrotreated heavy Inhalation Not mutagenic Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but the data are not
sufficient for classification Aluminium oxide In Vitro Not mutagenic Kaolin, calcined No data available Distillates (petroleum), hydrotreated middle In Vitro Some positive data exist, but the data are not
sufficient for classification 1-methyl-2-pyrrolidone In vivo Not mutagenic 1-methyl-2-pyrrolidone In Vitro Some positive data exist, but the data are not
sufficient for classification Glycerin No data available Processed oil In Vitro Not mutagenic Processed oil In vivo Not mutagenic Conditioners No data available Titanium dioxide In Vitro Not mutagenic Titanium dioxide Ingestion Not mutagenic Quartz In vivo Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Naphtha (petroleum), hydrotreated heavy
Dermal Some positive data exist, but the data
are not sufficient for classification Naphtha (petroleum), hydrotreated heavy
Inhalation Some positive data exist, but the data
are not sufficient for classification Aluminium oxide Inhalation Not carcinogenic Kaolin, calcined No data available Distillates (petroleum), hydrotreated middle
Dermal Mouse Some positive data exist, but the data
are not sufficient for classification 1-methyl-2-pyrrolidone Inhalation Rat Not carcinogenic Glycerin Ingestion Mouse Some positive data exist, but the data
are not sufficient for classification Processed oil No data available Conditioners No data available Titanium dioxide Ingestion Not carcinogenic Titanium dioxide Inhalation Some positive data exist, but the data
are not sufficient for classification Quartz Inhalation Carcinogenic.
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation Not toxic to
reproduction and/or development
NOAEL
2.356 mg/l
Aluminium oxide No data available Kaolin, calcined No data available Distillates (petroleum), hydrotreated middle
No data available
1-methyl-2­pyrrolidone
Inhalation Some positive
developmental data exist, but the data are not sufficient for
Rat LOAEL 0.68
mg/l
during gestation
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classification 1-methyl-2­pyrrolidone
Dermal Toxic to reproduction
and/or development
NOAEL 237
mg/kg/day 1-methyl-2­pyrrolidone
Ingestion Toxic to female
reproduction
Rat LOAEL 50
mg/kg/day
2 generation
1-methyl-2­pyrrolidone
Ingestion Toxic to male
reproduction
Rat LOAEL 50
mg/kg/day
2 generation
1-methyl-2­pyrrolidone
Dermal Toxic to development Rat NOAEL 237
mg/kg/day
during organogenesis
1-methyl-2­pyrrolidone
Ingestion Toxic to reproduction
and/or development
LOAEL 50
mg/kg/day 1-methyl-2­pyrrolidone
Ingestion Toxic to development Rat NOAEL 160
mg/kg/day
2 generation
Glycerin Ingestion Not toxic to female
reproduction
Rat NOAEL
2,000
mg/kg/day
2 generation
Glycerin Ingestion Not toxic to male
reproduction
Rat NOAEL
2,000
mg/kg/day
2 generation
Glycerin Ingestion Not toxic to
development
Rat NOAEL
2,000
mg/kg/day
2 generation
Processed oil Ingestion Not toxic to female
reproduction
Rat NOAEL
4,800
mg/kg/day
13 weeks
Processed oil Ingestion Not toxic to male
reproduction
Rat NOAEL
4,800
mg/kg/day
13 weeks
Conditioners No data available Titanium dioxide No data available Quartz No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
NOEL 6.5 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 2.4 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL 2.5 mg/l
Naphtha Inhalation liver | kidney All data are NOAEL 0.610
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(petroleum), hydrotreated heavy
and/or bladder negative mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation muscles All data are
negative
NOAEL 0.61 mg/l
Aluminium oxide
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Kaolin, calcined
No data available
Distillates (petroleum), hydrotreated middle
Inhalation central nervous
system depression | respiratory irritation
Some positive data exist, but the data are not sufficient for classification
Not available NOAEL NA
Distillates (petroleum), hydrotreated middle
Ingestion central nervous
system depression
May cause drowsiness or dizziness
Not available NOAEL NA
1-methyl-2­pyrrolidone
Inhalation respiratory
irritation
All data are negative
Human NOAEL 0.05
mg/l
8 hours
Glycerin No data available Processed oil No data available Conditioners No data available Titanium dioxide
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Quartz Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Dermal nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 691 mg/kg
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 4.580 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 0.619 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation endocrine
system | muscles
Some positive data exist, but the data are not sufficient for
LOEL 0.616 mg/l
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classification Naphtha (petroleum), hydrotreated heavy
Inhalation kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
LOEL 0.57 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation bone, teeth,
nails, and/or hair | blood | liver
All data are
negative
NOAEL 5.62 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL 1.271 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation immune system All data are
negative
NOAEL 0.616 mg/l
Aluminium oxide
Inhalation pneumoconiosis May cause
damage to organs
though prolonged
or repeated
exposure
NOAEL N/A
Aluminium oxide
Inhalation pulmonary
fibrosis
Some positive
data exist, but the
data are not
sufficient for
classification
NOAEL N/A
Kaolin, calcined
No data available
Distillates (petroleum), hydrotreated middle
No data available
1-methyl-2­pyrrolidone
Inhalation bone marrow |
immune system | respiratory system
Some positive
data exist, but the
data are not
sufficient for
classification
NOAEL 0.5 mg/l
1-methyl-2­pyrrolidone
Ingestion endocrine
system
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 250
mg/kg/day
90 days
1-methyl-2­pyrrolidone
Ingestion kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 2,060
mg/kg/day
4 weeks
1-methyl-2­pyrrolidone
Ingestion nervous system Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 1,057
mg/kg/day
90 days
1-methyl-2­pyrrolidone
Ingestion hematopoietic
system
Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL 300
mg/kg/day
90 days
1-methyl-2­pyrrolidone
Ingestion liver Some positive
data exist, but the
Mouse NOAEL 150
mg/kg/day
3 months
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data are not
sufficient for
classification Glycerin Inhalation respiratory
system
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 3.91
mg/l
14 days
Glycerin Inhalation heart | liver |
kidney and/or bladder
All data are
negative
Rat NOAEL 3.91
mg/l
14 days
Glycerin Ingestion endocrine
system | hematopoietic system | liver | kidney and/or bladder
All data are
negative
Rat NOAEL 10,000
mg/kg/day
2 years
Processed oil Ingestion heart |
hematopoietic system | liver
Some positive
data exist, but the
data are not
sufficient for
classification
Rat NOAEL 4,800
mg/kg/day
13 weeks
Processed oil Ingestion kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
Mouse NOAEL 13,000
mg/kg/day
13 weeks
Conditioners No data available Titanium dioxide
Inhalation respiratory
system
Some positive
data exist, but the
data are not
sufficient for
classification
NOEL 10 mg/m3
Titanium dioxide
Inhalation pulmonary
fibrosis
All data are
negative
NOAEL N/A
Quartz Inhalation silicosis Causes damage to
organs through
prolonged or
repeated exposure
NOAEL N/A
Aspiration Hazard
Name Value
Naphtha (petroleum), hydrotreated heavy Aspiration hazard Aluminium oxide Not an aspiration hazard Kaolin, calcined Not an aspiration hazard Distillates (petroleum), hydrotreated middle Aspiration hazard 1-methyl-2-pyrrolidone Not an aspiration hazard Glycerin Not an aspiration hazard Processed oil Not an aspiration hazard Conditioners Not an aspiration hazard Titanium dioxide Not an aspiration hazard Quartz Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
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are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
GHS Acute 3: Harmful to aquatic life.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as hazardous as per applicable regulations) shall be considered,stored,treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
070699 Wastes not otherwise specified 20 01 29* Detergents containing dangerous substances
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SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Quartz 14808-60-7 Grp. 1: Carcinogenic to
humans
International Agency for Research on Cancer
Titanium dioxide 13463-67-7 Grp. 2B: Possible human
carc.
International Agency for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Aqua C10-12 Alkane/cycloalkane Alumina Kaolin, calcined Glycerin Methyl pyrrolidone Solvent refined hydrotreated middle distillate Processed castor oil Polymer Morpholine Non-ionic surfactant Benzaldehyde 2-Pyrrolidinone, dimethyl­Magnesium nitrate Sodium lauryl sulfate beta-Glucan 2-Methoxyethanol Isooctane Ethylenediamine N-Ethylmorpholine Methylchloroisothiazolinone Magnesium chloride Copper-based stabilizers Methylisothiazolinone
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15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H360D May damage the unborn child. H372 Causes damage to organs through prolonged or repeated exposure.
List of relevant R-phrases
R20 Harmful by inhalation. R36 Irritating to eyes. R37 Irritating to respiratory system. R38 Irritating to skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R61 May cause harm to the unborn child. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 8: Respiratory protection - recommended respirators information was modified. Section 8: Respiratory protection - recommended respirators was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 12: Chronic aquatic hazard information was modified. Section 2: Label remarks was modified. Section 16: Regulations – Inventories – EU ONLY was modified. Copyright was modified. Section 1: Initial issue message was modified. Section 8: Occupational exposure limit table was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 11: Health Effects - Eye information was modified. Section 11: Health Effects - Skin information was modified. Section 11: Health Effects - Inhalation information was modified.
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Section 11: Health Effects - Ingestion information was modified. Section 11: Health Effects - Other information was modified. Section 5: Fire - Extinguishing media information was modified. Section 6: Accidental release personal information was modified. Section 6: Accidental release environmental information was modified. Section 6: Accidental release clean-up information was modified. Section 7: Precautions safe handling information was modified. Section 7: Conditions safe storage was modified. Section 13: Standard Phrase Category Waste GHS was modified. Section 4: First aid for skin contact information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 8: Respiratory protection - recommended respirators guide was added. Section 11: Carcinogenicity heading was added. Section 11: Cancer Hazards information was added. Section 8: Personal Protection - Eye information was added. Section 8: Personal Protection - Respiratory Information was added. Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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