See section 16 for the full text of the R-phrases declared above
Occupational exposure limits, if available, are listed in section 8.
Hazards identification3.
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
ClassificationMuta. Cat. 2; R46:
:Human health hazardsMay cause heritable genetic damage.
See section 11 for more detailed information on health effects and symptoms.
4.
First-aid measures
First-aid measures
Eye contactCheck for and remove any contact lenses. In case of contact with eyes, rinse
:
immediately with plenty of water. Obtain medical attention if symptoms occur.
Wash with soap and water. Obtain medical attention if symptoms occur.
Skin contact
Inhalation
:
:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical
attention if symptoms appear.
Ingestion
: Do not induce vomiting. Never give anything by mouth to an unconscious person.
Get medical attention if symptoms appear.
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training.
See section 11 for more detailed information on health effects and symptoms.
Fire-fighting measures5.
NFPA
Health
1
Flammability
1
Reactivity
0
Extinguishing media
Suitable:
Not suitable:
Special exposure hazards
Hazardous thermal
Use an extinguishing agent suitable for the surrounding fire.
None known.
No specific hazard.
:
These products are carbon oxides.
:
decomposition products
Special protective
equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained
:
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
6.Accidental release measures
Personal precautions
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment.
:
Environmental precautions
Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and
sewers.
Methods for cleaning up:
If emergency personnel are unavailable, contain spilt material. For small spills, add
absorbent (soil may be used in the absence of other suitable materials), scoop up
material and place in a sealable, liquid-proof container for disposal. For large spills,
dyke spilt material or otherwise contain material to ensure runoff does not reach a
waterway. Place spilt material in an appropriate container for dispos
Date of issue
:
12/30/2006
Version
1.1
al.
Page: 3/11
Page 4
M72 - Marine Canvas Protectant Aerosol
y
pp
s
7.
Handling
Storage
Handling and storage
:
Wash thoroughly after handling.
Keep container tightly closed. Keep container in a cool, well-ventilated area.
:
Packaging materials
Recommended: Use original container.
8.Exposure controls/personal protection
Ingredient nameOccupational exposure limits
Europe
If this product contains ingredients with exposure limits, personal, workplace
:
atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.
Exposure controls
Occupational exposure
controls
: Use only with adequate ventilation. If user operations generate dust, fumes, vapour or
mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or
statutory limits.
Eye protection
Skin protection
Respiratory protection
Hand protection
:
Safety glasses.
:
Lab coat.
:
A respirator is not needed under normal and intended conditions of product use.
:
Natural rubber (latex).
Hygiene measures: Wash hands, forearms and face thoroughly after handling compounds and before
eating, smoking and using the lavatory and at the end of the day. During formulation,
follow good industrial hygiene practice.
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable level
s.
9.
Physical and chemical properties
General information
Appearance
Physical state
Liquid. (Aerosol foam.)
:
White.Colour
:
Mild. Ammonia.Odour
:
Important health, safety and environmental information
pH
Boiling point
Melting point
Flash point
:
12.4
Weighted average: 100.83°C (213.5°F)
:
Weighted average: -2.6°C (27.3°F)
:
The lowest known value is Closed cup: 12°C (53.6°F). (Tagliabue.). Open cup:
Rat
Rabbit
Mouse
Rabbit
Rat
Rat
Rabbit
Guinea pig
Rabbit
Rat
Carcinogenicity:
Mutagenicity:
Reproductive toxicity:
No known significant effects or critical hazards.
Contains material which may cause heritable genetic effects.
No known significant effects or critical hazards.
Denmark – Carcinogen list : Contains substance/substances listed under National Working Environment
Authorities Executive Order 140/1997.
Over-exposure signs/symptoms
No known significant effects or critical hazards.
Inhalation
Ingestion
Skin
Target organsContains material which causes damage to the following organs: blood, kidneys, liver,
:
No known significant effects or critical hazards.
:
No known significant effects or critical hazards.
:
:
lymphatic system, upper respiratory tract, skin, central nervous system (CNS), eye,
lens or cornea.
MobilityNot available.:
Other adverse effects: No known significant effects or critical hazards.
Disposal considerations13.
The generation of waste should be avoided or minimized wherever possible. Avoid
:Methods of disposal
dispersal of spilled material, runoff and contact with soil, waterways, drains and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal
legislation and any regional and local authority requirements.
Waste classification: Dispose of according to all federal, state and local applicable regulations.
The classification of the product may meet the criteria for a hazardous waste.Hazardous waste:
14.Transport information
Regulatory
Proper shipping name
UN numberClassPGLabel
information
UN / IMDG / IATA
Class
AEROSOLS, [NON-FLAMMABLE, (each not
exceeding 1 L capacity)] (Petroleum gases,
UN19502.2-
liquified)
ADNR Class
AEROSOLS, [NON-FLAMMABLE, (each not
2-
UN1950
exceeding 1 L capacity)] (Petroleum gases,
liquified)
2
2
ADR/RID Class2
AEROSOLS, [NON-FLAMMABLE, (each not
UN1950exceeding 1 L capacity)] (Petroleum gases,
liquified)
Regulatory information15.
EU regulations
Hazard symbol/symbols
:
Toxic
:
Risk phrases
Safety phrasesS53- Avoid exposure - obtain special instructions before use.
R46- May cause heritable genetic damage.
:
S2- Keep out of the reach of children.
Contains
Product useClassification and labelling have been performed according to EU Directives
:
Petroleum
:
ases, liquifie
270-704-
67/548/EEC and 1999/45/EC (including amendments) and the intended use.
- Consumer applications.
Other EU regulations
Additional warning phrases : Pressurised container: protect from sunlight and do not expose to temperature
exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked
flame or any incandescent material. Keep away from sources of ignition. - Do not
smoke.
Child protectionYes, applicable.
Tactile warning of dangerYes, applicable.
:
:
Restricted to professional users.Restrictions on the
:
Marketing and Use
Directive
2
Date of issue
:
12/30/2006
Version
1.1
Page: 8/11
Page 9
(Tariff Code)
National regulations
France
Professional
disease/diseases
Germany
Employment restrictions in
accordance with section 15b of
the Hazardous Substance
Ordinance
ordinance
Switzerland
Poison classNot regulated:
BAG T619000:
VOC contentVOC (w/w): 3%:
Full text of R-phrases
referred to in sections 2 and
3 - Europe
referred to in sections 2 and
3 - Europe
referred to in sections 2 and
3 - France
Full text of classifications
referred to in sections 2 and
3 - France
referred to in sections 2 and
3 - Netherlands
Full text of classifications
referred to in sections 2 and
3 - Netherlands
R12- Extremely flammable.
:
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
F+ - Extremely flammable
:Full text of classifications
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
R12- Extremely flammable.
:Full text of R-phrases
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
: F+ - Extremely flammable
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
R12- Extremely flammable.
:Full text of R-phrases
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
: F+ - Extremely flammable
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
Date of issue
:
12/30/2006
Version
1.1
Page: 9/11
Page 10
referred to in sections 2 and
3 - Germany
Full text of classifications
referred to in sections 2 and
3 - Germany
referred to in sections 2 and
3 - United Kingdom (UK)
referred to in sections 2 and
3 - United Kingdom (UK)
referred to in sections 2 and
3 - Switzerland
Full text of classifications
referred to in sections 2 and
3 - Switzerland
Full text of R-phrases
referred to in sections 2 and
3 - Spain
referred to in sections 2 and
3 - Spain
referred to in sections 2 and
3 - Italy
Full text of classifications
referred to in sections 2 and
3 - Italy
M72 - Marine Canvas Protectant Aerosol
R12- Extremely flammable.
:Full text of R-phrases
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
: F+ - Extremely flammable
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
R12- Extremely flammable.
:Full text of R-phrases
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
F+ - Extremely flammable
:Full text of classifications
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
R12- Extremely flammable.
:Full text of R-phrases
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
: F+ - Extremely flammable
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
: R12- Extremely flammable.
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
F+ - Extremely flammable
:Full text of classifications
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
R12- Extremely flammable.
:Full text of R-phrases
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
: F+ - Extremely flammable
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
Date of issue
:
12/30/2006
Version
1.1
Page: 10/11
Page 11
M72 - Marine Canvas Protectant Aerosol
Full text of R-phrases
referred to in sections 2 and
3 - Greece
Full text of classifications
referred to in sections 2 and
3 - Greece
Full text of R-phrases
referred to in sections 2 and
3 - Sweden
Full text of classifications
referred to in sections 2 and
3 - Sweden
:
R12- Extremely flammable.
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
:
F+ - Extremely flammable
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
: R12- Extremely flammable.
R11- Highly flammable.
R46- May cause heritable genetic damage.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R67- Vapours may cause drowsiness and dizziness.
F+ - Extremely flammable
:
F - Highly flammable
Muta. Cat.2 - Mutagen Category 2
Xn - Harmful
Xi - Irritant
1
History
12/30/2006
Date of issue
Date of previous issue
Version
:
01/27/2006
:
:
1.1
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the
user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist.
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