MEGUIAR'S M71 User Manual

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Safety Data Sheet
Copyright, 2011, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-6968-3
Version number:
1.00
Revision date:
19/07/2011
Supersedes date:
Initial issue.
Transportation version number: 1.00 (19/07/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M71, Marine Canvas Cleaner (20-51B): M7116
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Marine
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Irritant.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols
Xi Irritant.
Contains:
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No ingredients are assigned to the label.
Risk phrases
R36/38 Irritating to eyes and skin.
Safety phrases
S51 Use only in well ventilated areas. S23C Do not breathe vapour or spray. S46 If swallowed, seek medical advice immediately and show this container or label. S2 Keep out of the reach of children.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents. Ingredients required per 648/2004: <5% Non-ionic surfactants, cationic surfactant, EDTA and salts thereof, amphoteric surfactant. Contains: Perfumes, benzyl salicylate.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-hazardous ingredients Mixture 81 - 91 Sodium Metasilicate 6834-92-0 EINECS 229-
912-9
1 - 5 C:R34; Xi:R37 (EU)
Skin Corr. 1B, H314; STOT SE 3, H335 (CLP)
Alcohols, C9-11, ethoxylated 68439-46-3 1 - 5 Xn:R22; Xi:R38-41; R52 (Self
Classified)
Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Dam. 1, H318
(Self Classified) Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides
68478-94-4 0.5 - 1.5
Alcohols, C12-16, ethoxylated 68551-12-2 NLP 500-221-7 0.5 - 1.5
Sodium Carbonate 497-19-8 EINECS 207-
838-8
0.5 - 1.5 Xi:R36 (EU)
Eye Irrit. 2, H319 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
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medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
No need for first aid is anticipated.
If swallowed
No need for first aid is anticipated.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Cover, but do not seal for 48 hours. For large spills, if necessary, get assistance from professional spill clean up team. For small spills, carefully neutralise spill by adding appropriate dilute acid such as vinegar. Work slowly to avoid boiling or spattering. Continue to add neutralising agent until reaction stops. Let cool before collecting.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
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SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Vapours may travel long distances along the ground or floor to an ignition source and flash back. Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
8.2. Exposure controls
8.2.1. Engineering controls
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Indirect vented goggles.
Skin/hand protection
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Respiratory protection
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with P2 particulate filters.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Pleasant odour; Clear liquid
pH
12.5 - 13.5
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not available.
Explosive properties
Not determined.
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Oxidising properties
Not determined.
Flash point
> 93.3 ºC [Test Method:Pensky-Martens Closed Cup] [Details:D93-90]
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
No data available.
Density
1 g/cm3
9.2. Other information
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Temperatures above the boiling point.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
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Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Contact with the skin during product use is not expected toresult in significant irritation.
Inhalation
No health effects are expected.
Ingestion
No health effects are expected.
Toxicological Data
Acute Toxicity
Name Route Species Value UN GHS
Classification
Alcohols, C9-11, ethoxylated No data available Sodium Metasilicate No data available Sodium Carbonate No data available Alcohols, C12-16, ethoxylated No data available Poly(oxy-1,2-ethanediyl), α,α'­[[[3­(decyloxy)propyl]methyliminio]d i-2,1-ethanediyl]bis[ω-hydroxy-, branched, chlorides
No data available
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to cause no significant irritation
Not classified
Alcohols, C9-11, ethoxylated No data available Sodium Metasilicate No data available Sodium Carbonate No data available Alcohols, C12-16, ethoxylated No data available Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides
No data available
Serious Eye Damage/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to cause no significant irritation
Not classified
Alcohols, C9-11, ethoxylated No data available Sodium Metasilicate No data available Sodium Carbonate No data available Alcohols, C12-16, ethoxylated No data available
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Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides
No data available
Skin Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Alcohols, C9-11, ethoxylated No data available Sodium Metasilicate No data available Sodium Carbonate No data available Alcohols, C12-16, ethoxylated No data available Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides
No data available
Respiratory Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Alcohols, C9-11, ethoxylated No data available Sodium Metasilicate No data available Sodium Carbonate No data available Alcohols, C12-16, ethoxylated No data available Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides
No data available
Germ Cell Mutagenicity
Name Route Value UN GHS Classification
Overall product No data available Overall Germ Cell
Mutagenicity
classificationNot classified Overall product No test data available. Alcohols, C9-11, ethoxylated No data available Sodium Metasilicate No data available Sodium Carbonate No data available Alcohols, C12-16, ethoxylated No data available Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides
No data available
Carcinogenicity
Name Route Species Value UN GHS
Classification
Overall product No test data available. Not classified based
on component data Alcohols, C9-11, ethoxylated No data available Sodium Metasilicate No data available Sodium Carbonate No data available
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Alcohols, C12-16, ethoxylated No data available Poly(oxy-1,2-ethanediyl), α,α'­[[[3­(decyloxy)propyl]methyliminio]d i-2,1-ethanediyl]bis[ω-hydroxy-, branched, chlorides
No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test
result
Exposure Duration
UN GHS Classification
Overall product No test data
available.
Not classified based on
component data Alcohols, C9-11, ethoxylated
No data available
Sodium Metasilicate
No data available
Sodium Carbonate No data available Alcohols, C12-16, ethoxylated
No data available
Poly(oxy-1,2­ethanediyl), α,α'­[[[3­(decyloxy)propyl] methyliminio]di­2,1­ethanediyl]bis[ω­hydroxy-, branched, chlorides
No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test
result
Exposure Duration
UN GHS Classification
Overall product
No test data available.
Not classified based on
component data Alcohols, C9-11, ethoxylated
No data available
Sodium Metasilicate
No data
available Sodium Carbonate
No data
available Alcohols, C12-16, ethoxylated
No data
available
Poly(oxy­1,2­ethanediyl), α,α'-[[[3­(decyloxy)pr
No data
available
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opyl]methyli minio]di­2,1­ethanediyl]b is[ω­hydroxy-, branched, chlorides
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test
result
Exposure Duration
UN GHS Classification
Overall product
No test data
available.
Not classified based on
component data Alcohols, C9-11, ethoxylated
No data available
Sodium Metasilicate
Ingestion kidney
and/or bladder
Some positive data exist, but the data are not sufficient for classification
LOAEL 2400 mg/kg/day
Not classified
Sodium Carbonate
No data
available Alcohols, C12-16, ethoxylated
No data
available
Poly(oxy­1,2­ethanediyl), α,α'-[[[3­(decyloxy)pr opyl]methyli minio]di­2,1­ethanediyl]b is[ω­hydroxy-, branched, chlorides
No data
available
Aspiration Hazard
Name Value UN GHS Classification
Overall product No test data available. Not classified based on
component and/or viscosity
data Alcohols, C9-11, ethoxylated Not an aspiration hazard Not classified Sodium Metasilicate Not an aspiration hazard Not classified Sodium Carbonate Not an aspiration hazard Not classified Alcohols, C12-16, ethoxylated Not an aspiration hazard Not classified Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1-ethanediyl]bis[ω­hydroxy-, branched, chlorides
Not an aspiration hazard Not classified
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Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
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SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Aqua Ethoxylated C9-11 alcohols Sodium metasilicate Sodium carbonate Ethoxylated C12-16 alcohols Poly(oxy-1,2-ethanediyl)alpha,alpha-[[[3-(decyloxy)propyl]methylimino]di-2,1-ethanediyl]bis[omega-hydroxy-branched, chlorides Tetrasodium EDTA Lauramine oxide Cocamide DEA Perfumes Polysorbate 20 Benzyl salicylate Colorant
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation.
List of relevant R-phrases
R22 Harmful if swallowed. R34 Causes burns. R36 Irritating to eyes. R37 Irritating to respiratory system. R38 Irritating to skin. R41 Risk of serious damage to eyes. R52 Harmful to aquatic organisms.
Revision information:
No revision information is available.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
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product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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