MEGUIAR'S M70 User Manual

Emergency telephone number (United States): CALL

:

[phone]

SAFETY DATA SHEET

M70 - Marine Black Streak Remover

Conforms to EU Directive 91/155/EEC, as amended by 2001/58/EC, 2004/73/EC (29 ATP)

1.

Identification of the substance/preparation and company/undertaking

Identification of the substance or preparation

Product name :
Reference Number :
Date of previous issue
Date of issue

M70 - Marine Black Streak Remover
TBD

08/24/2005

:

12/30/2006

:

Company/undertaking identification

Information Contact :
Emergency telephone number Europe (Meguiar's) [phone] (Office hours).

Meguiar's Holland

Laan der Verenigde Naties 40

3314 DA Dordrecht

Holland

Tel: [phone]

Fax: [phone]

www.meguiarseurope.com

2.

Composition/information on ingredients

Meguiar's UK Ltd.

3 Lamport Court

Daventry NN11 8UF

Tel: [phone]

Fax: [phone]

www.meguiarseurope.com

Substance/preparation Preparation

Product safety department.

:

USA [phone] (24h collect).

Meguiar's France

3 rue de Verdun-Bât. D

Heartlands

78590 Noisy Le Roi

France

Tel: [phone]

Fax: [phone]

www.meguiars.fr

:

CAS

Meguiar's Hong Kong

Shaukeiwan, Hong Kong

Tel: [phone]

Fax: [phone]

% EC number ClassificationIngredient name

number

Suite 6-7,
20/F Marina House
68 Hing Man Street

Meguiar's USA

17991 Mitchell South

Irvine, CA 92614

Tel: [phone]

Fax: [phone]

Europe

Alcohols, C9-11, Ethoxylated 68439-46-3 1 - 5 Xi; R38, R41
Sodium carbonate 497-19-8 1 - 5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1 - 5 229-912-9 C; R34

Xi; R37

Tetrasodium EDT

A 64-02-8 0.5 - 1 200-573-9 Xi; R36/37/38

France

Alcohols, C9-11, Ethoxylated 68439-46-3 1 - 5 Xi; R38, R41
Sodium carbonate 497-19-8 1 - 5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1 - 5 229-912-9 C; R34

Xi; R37

Tetrasodium EDTA 64-02-8 0.5 - 1 200-573-9 Xi; R36/37/38

Netherlands

Alcohols, C9-11, Ethoxylated 68439-46-3 5-10 Xi; R38, R41
Sodium carbonate 497-19-8 1-5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1-5 229-912-9 C; R34

Xi; R37

Tetrasodium EDTA 64-02-8 1-5 200-573-9 Xi; R36/37/38

Germany

Date of issue

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12/30/2006

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Alcohols, C9-11, Ethoxylated 68439-46-3 1 - 5 Xi; R38, R41
Sodium carbonate 497-19-8 1 - 5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1 - 5 229-912-9 C; R34

Xi; R37

Tetrasodium EDTA 64-02-8 0.5 - 1 200-573-9 Xi; R36/37/38

United Kingdom (UK)

Alcohols, C9-11, Ethoxylated 68439-46-3 1 - 5 Xi; R38, R41
Sodium carbonate 497-19-8 1 - 5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1 - 5 229-912-9 C; R34

Xi; R37

Tetrasodium EDTA 64-02-8 0.5 - 1 200-573-9 Xi; R36/37/38

Switzerland

Alcohols, C9-11, Ethoxylated 68439-46-3 1 - 5 Xi; R38, R41
Sodium carbonate 497-19-8 1 - 5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1 - 5 229-912-9 C; R34

Xi; R37

Tetrasodium EDT

A 64-02-8 0.5 - 1 200-573-9 Xi; R36/37/38

Spain

Alcohols, C9-11, Ethoxylated 68439-46-3 1 - 5 Xi; R38, R41
Sodium carbonate 497-19-8 1 - 5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1 - 5 229-912-9 C; R34

Xi; R37

Tetrasodium EDTA 64-02-8 0.5 - 1 200-573-9 Xi; R36/37/38

Italy

Alcohols, C9-11, Ethoxylated 68439-46-3 1 - 5 Xi; R38, R41
Sodium carbonate 497-19-8 1 - 5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1 - 5 229-912-9 C; R34

Xi; R37

Tetrasodium EDTA 64-02-8 0.5 - 1 200-573-9 Xi; R36/37/38

Greece

Alcohols, C9-11, Ethoxylated 68439-46-3 1 - 5 Xi; R38, R41
Sodium carbonate 497-19-8 1 - 5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1 - 5 229-912-9 C; R34

Xi; R37

Tetrasodium EDTA 64-02-8 0.5 - 1 200-573-9 Xi; R36/37/38

Sweden

Alcohols, C9-11, Ethoxylated 68439-46-3 5-10 Xi; R38, R41
Sodium carbonate 497-19-8 1-5 207-838-8 Xi; R36
Disodium metasilicate 6834-92-0 1-5 229-912-9 C; R34

Xi; R37

Tetrasodium EDT

A 64-02-8 1-5 200-573-9 Xi; R36/37/38

See section 16 for the full text of the R-phrases declared above
Occupational exposure limits, if available, are listed in section 8.

Hazards identification3.

The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.

Classification Xi; R36:

:Human health hazards Irritating to eyes.

See section 11 for more detailed information on health effects and symptoms.

Date of issue

:

12/30/2006

Version

2

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4.

First-aid measures

First-aid measures

Eye contact Check for and remove any contact lenses. In case of contact with eyes, rinse

:

immediately with plenty of water. Get medical attention.

Skin contact

:

In case of contact, immediately flush skin copiously with water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical attention.

:

Inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical
attention.

:

Ingestion

Do not induce vomiting. Never give anything by mouth to an unconscious person.
Get medical attention.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

See section 11 for more detailed information on health effects and symptoms.

Fire-fighting measures5.

NFPA

Health

2

Flammability

0

Reactivity

0

Extinguishing media

Suitable :

Not suitable :
Special exposure hazards
Hazardous thermal

Use an extinguishing agent suitable for the surrounding fire.
None known.
No specific hazard.

:

These products are carbon oxides, nitrogen oxides. Some metallic oxides.

:

decomposition products
Special protective

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained

:

breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

6. Accidental release measures

Personal precautions

: Immediately contact emergency personnel. Keep unnecessary personnel away. Use

suitable protective equipment.

:

Environmental precautions

Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and
sewers.

Methods for cleaning up :

If emergency personnel are unavailable, contain spilt material. For small spills, add
absorbent (soil may be used in the absence of other suitable materials), scoop up
material and place in a sealable, liquid-proof container for disposal. For large spills,
dyke spilt material or otherwise contain material to ensure runoff does not reach a
waterway. Place spilt material in an appropriate container for dispos

7.

Handling
Storage

Handling and storage

:

Avoid contact with eyes. Wash thoroughly after handling.
Keep container tightly closed. Keep container in a cool, well-ventilated area.

:

Packaging materials

Recommended : Use original container.

8. Exposure controls/personal protection

Exposure limit values

Recommended monitoring

procedures

Not available.:

If this product contains ingredients with exposure limits, personal, workplace

:

atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.

al.

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:

12/30/2006

Version

2

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Exposure controls

Occupational exposure

controls

: No special ventilation requirements. Good general ventilation should be sufficient to

control airborne levels. If this product contains ingredients with exposure limits, use
process enclosures, local exhaust ventilation or other engineering controls to keep

s.

Eye protection

Skin protection

Respiratory protection

Hand protection

worker exposure below any recommended or statutory limit
Safety glasses.

:
:

Lab coat.

:

A respirator is not needed under normal and intended conditions of product use.

:

Natural rubber (latex).

Hygiene measures : Wash hands, forearms and face thoroughly after handling compounds and before

eating, smoking and using the lavatory and at the end of the day. During formulation,
follow good industrial hygiene practice.

Environmental exposure

controls

: Emissions from ventilation or work process equipment should be checked to ensure

they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable level

s.

9.

Physical and chemical properties

General information

Appearance

Liquid.

Physical state

:
:

Clear.Colour

:

Pleasant.Odour

Important health, safety and environmental information

pH

Boiling point

Melting point

Flash point Closed cup: 93°C (199.4°F). (Pensky-Martens.)

Vapour pressure

Specific gravity

Solubility

Vapour density

Evaporation rate Water

VOC Content : Not applicable.

10.

Stability and reactivity

Materials to avoid :

:

12.5
100°C (212°F)

:

Weighted average: 0.4°C (32.7°F)

:
:
:

Weighted average: 2.17 kPa (16.28 mm Hg) (at 20°C)

1.03

:
:

Soluble in water.

:

Water

:

:

The product is stable.Stability
Reactive with oxidizing materials and acids.

Toxicological information11.

Potential acute health effects

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

Irritating to eyes.:Eye contact

Date of issue

:

12/30/2006

Version

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Acute toxicity

Product/ingredient name

Test Result Route Species

Alcohols, C9-11, Ethoxylated LD50 1378 mg/kg Oral Rat

Sodium carbonate LD50

LD50

Disodium metasilicate LD50

LD50

4090 mg/kg
6600 mg/kg
1153 mg/kg
770 mg/kg

Oral
Oral
Oral
Oral

Potential chronic health effects

Carcinogenicity :

Mutagenicity :

Reproductive toxicity :

Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
No known significant effects or critical hazards.
No known significant effects or critical hazards.

Over-exposure signs/symptoms

No known significant effects or critical hazards.

Inhalation

Ingestion

Skin

:

No known significant effects or critical hazards.

:

No known significant effects or critical hazards.

:

Ecological information12.

Ecotoxicity data

Species Period ResultProduct/ingredient name

Alcohols, C9-11, Ethoxylated Fish (LC50)

Daphnia (EC50)
Algae (EC50)

Sodium carbonate Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)
Pimephales promelas (LC50)

Tetrasodium EDTA Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)
Lepomis macrochirus (LC50)
Lepomis macrochirus (LC50)

96 hour(s)
48 hour(s)
72 hour(s)
96 hour(s)
96 hour(s)
96 hour(s)
96 hour(s)
96 hour(s)
96 hour(s)
96 hour(s)

2.4 mg/l
1 to 10 mg/l
1 to 10 mg/l
300 mg/l
320 mg/l
<850 mg/l
486 mg/l
1030 mg/l
2070 mg/l
3092 mg/l

Other ecological information

Persistence/degradability

Mobility Not available.:
Other adverse effects : No known significant effects or critical hazards.

Rat
Mouse
Rat
Mouse

Disposal considerations13.

The generation of waste should be avoided or minimized wherever possible. Avoid

:Methods of disposal

dispersal of spilled material, runoff and contact with soil, waterways, drains and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal
legislation and any regional and local authority requirements.

Waste classification : Dispose of according to all federal, state and local applicable regulations.

The classification of the product may meet the criteria for a hazardous waste.Hazardous waste :

14. Transport information

Regulatory information

IATA / :ADNR/ADRIMDG/UN/

Not regulated by any transport mode.

Date of issue

:

12/30/2006

Version

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Regulatory information15.

EU regulations

Hazard symbol/symbols

:

Irritant

Risk phrases

Safety phrases S2- Keep out of the reach of children.

Product use Classification and labelling have been performed according to EU Directives

R36- Irritating to eyes.

:
:
:

67/548/EEC and 1999/45/EC (including amendments) and the intended use.

- Consumer applications.

Other EU regulations

3402.90.5030EU statistical classification

:

(Tariff Code)
National regulations

Germany

Employment restrictions in

:

Yes.

accordance with section 15b of
the Hazardous Substance
Ordinance

:

No.Hazardous incident

ordinance

:

1Hazard class for water

Switzerland

Poison class 4:
BAG T 619004:
VOC content Liberated.:

Italy

94% Not classified.Emission control directive :

Other information16.

Full text of R-phrases
referred to in sections 2 and
3 - Europe

referred to in sections 2 and
3 - Europe

referred to in sections 2 and
3 - France

Full text of classifications
referred to in sections 2 and
3 - France

R34- Causes burns.

:

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

C - Corrosive

:Full text of classifications

Xi - Irritant

R34- Causes burns.

:Full text of R-phrases

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

: C - Corrosive

Xi - Irritant

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referred to in sections 2 and
3 - Netherlands

Full text of classifications
referred to in sections 2 and
3 - Netherlands

referred to in sections 2 and
3 - Germany

Full text of classifications
referred to in sections 2 and
3 - Germany

referred to in sections 2 and
3 - United Kingdom (UK)

referred to in sections 2 and
3 - United Kingdom (UK)

referred to in sections 2 and
3 - Switzerland

Full text of classifications
referred to in sections 2 and
3 - Switzerland

Full text of R-phrases
referred to in sections 2 and
3 - Spain

referred to in sections 2 and
3 - Spain

referred to in sections 2 and
3 - Italy

Full text of classifications
referred to in sections 2 and
3 - Italy

Full text of R-phrases
referred to in sections 2 and
3 - Greece

M70 - Marine Black Streak Remov

R34- Causes burns.

:Full text of R-phrases

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

: C - Corrosive

Xi - Irritant

R34- Causes burns.

:Full text of R-phrases

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

: C - Corrosive

Xi - Irritant

R34- Causes burns.

:Full text of R-phrases

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

C - Corrosive

:Full text of classifications

Xi - Irritant

R34- Causes burns.

:Full text of R-phrases

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

: C - Corrosive

Xi - Irritant

: R34- Causes burns.

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

C - Corrosive

:Full text of classifications

Xi - Irritant

R34- Causes burns.

:Full text of R-phrases

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

: C - Corrosive

Xi - Irritant

: R34- Causes burns.

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

Date of issue

:

12/30/2006

Version

2

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Full text of classifications
referred to in sections 2 and

: C - Corrosive

Xi - Irritant

3 - Greece
Full text of R-phrases
referred to in sections 2 and
3 - Sweden

: R34- Causes burns.

R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.

Full text of classifications
referred to in sections 2 and

C - Corrosive

:

Xi - Irritant

3 - Sweden

2

History

12/30/2006

Date of issue

Date of previous issue

Version

:

08/24/2005

:
:

2

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the
user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist.