MEGUIAR'S M68 User Manual

M68, Marine Non-Skid Deck Cleaner (16-157B): M6832

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Safety Data Sheet

Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

26-8114-6

Version number:

1.01

Revision date:

10/07/2012

Supersedes date:

29/07/2011

Transportation version number: 1.00 (29/07/2011)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

M68, Marine Non-Skid Deck Cleaner (16-157B): M6832

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Marine

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Indication of danger

Irritant.

2.2. Label elements

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Symbols

Xi Irritant.

Contains:

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No ingredients are assigned to the label.

Risk phrases

R36/38 Irritating to eyes and skin.

Safety phrases

S23C Do not breathe vapour or spray.
S51 Use only in well ventilated areas.
S46 If swallowed, seek medical advice immediately and show this container or label.
S2 Keep out of the reach of children.

Notes on labelling

Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004: <5% Non-ionic surfactants, cationic surfactant, EDTA and salts thereof, amphoteric
surfactant. Contains: Perfumes, hexyl cinnam-aldehyde.

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non hazardous ingredient Mixture 75 - 95
Sodium Metasilicate 6834-92-0 EINECS 229-

912-9

1 - 5 C:R34; Xi:R37 (EU)

Skin Corr. 1B, H314; STOT SE
3, H335 (CLP)
Met. Corr. 1, H290 (Self
Classified)

Alcohols, C9-11, ethoxylated 68439-46-3 1 - 5 Xn:R22; Xi:R38-41; R52 (Self

Classified)

Acute Tox. 4, H302; Skin Irrit.
2, H315; Eye Dam. 1, H318

(Self Classified)
Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched,
chlorides

68478-94-4 0.5 - 1.5

Alcohols, C12-16, ethoxylated 68551-12-2 NLP 500-221-7 0.5 - 1.5

Sodium Carbonate 497-19-8 EINECS 207-

838-8

0.5 - 1.5 Xi:R36 (EU)

Eye Irrit. 2, H319 (CLP)
Amides, coco, N,N-bis(hydroxyethyl) 68603-42-9 EINECS 271-

657-0

<= 0.5 Xi:R41; R52 (Self Classified)

Eye Dam. 1, H318; Aquatic

Chronic 2, H411 (Self

Classified)

Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

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SECTION 4: First aid measures

4.1. Description of first aid measures

Eye contact

Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

Skin contact

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Inhalation

Remove person to fresh air. If you feel unwell, get medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide.

5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.

5.3. Advice for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with
good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours
in the spill area to burn or explode.

6.2. Environmental precautions

Avoid release to the environment.

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6.3. Methods and material for containment and cleaning up

Collect as much of the spilled material as possible. Cover, but do not seal for 48 hours. For large spills, if necessary, get
assistance from professional spill clean up team. For small spills, carefully neutralise spill by adding appropriate dilute acid
such as vinegar. Work slowly to avoid boiling or spattering. Continue to add neutralising agent until reaction stops. Let cool
before collecting.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid eye contact. Do not handle until all safety precautions have been read and understood. Avoid breathing
dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Use personal protective equipment (eg. gloves, respirators…) as required. Keep
out of reach of children. Vapours may travel long distances along the ground or floor to an ignition source and flash back.
Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an
explosion hazard. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilities

Store away from acids. Store away from oxidising agents.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.

8.2. Exposure controls

8.2.1. Engineering controls

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Wear eye/face protection.
The following eye protection(s) are recommended: Indirect vented goggles.

Skin/hand protection

Wear protective gloves. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an
exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible
materials.

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of

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a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state

Liquid.

Appearance/Odour

Pleasant odour; Clear liquid

pH

12.5 - 13.5

Boiling point/boiling range

100 ºC

Melting point

Not applicable.

Flammability (solid, gas)

Not classified

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

> 93.3 ºC [Test Method:Pensky-Martens Closed Cup]
[Details:D93-90]

Autoignition temperature

Not applicable.

Flammable Limits(LEL)

Not applicable.

Flammable Limits(UEL)

Not applicable.

Vapour pressure

No data available.

Relative density

1.00 [Ref Std:WATER=1]

Water solubility

Complete

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

Vapour density

No data available.

Viscosity

No data available.

Density

1 g/cm3

9.2. Other information

SECTION 10: Stability and reactivity

10.1 Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

Temperatures above the boiling point.

10.5 Incompatible materials

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Strong acids.
Strong bases.
Strong oxidising agents.

10.6 Hazardous decomposition products

Substance Condition

None known.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Eye contact

Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Skin contact

Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

Inhalation

Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Ingestion

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.

Carcinogenicity:

Contains a chemical or chemicals which can cause cancer.

Toxicological Data

Acute Toxicity

Name Route Species Value

Overall product Ingestion No test data available; calculated ATE

>5,000 mg/kg
Alcohols, C9-11, ethoxylated No data available
Sodium Metasilicate No data available
Sodium Carbonate No data available
Alcohols, C12-16, ethoxylated No data available
Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di­2,1-ethanediyl]bis[ω-hydroxy-,
branched, chlorides

No data available

Amides, coco, N,N­bis(hydroxyethyl)

No data available

ATE = acute toxicity estimate

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Skin Corrosion/Irritation

Name Species Value

Alcohols, C9-11, ethoxylated No data available
Sodium Metasilicate No data available
Sodium Carbonate No data available
Alcohols, C12-16, ethoxylated No data available
Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides

No data available

Amides, coco, N,N-bis(hydroxyethyl) No data available

Serious Eye Damage/Irritation

Name Species Value

Alcohols, C9-11, ethoxylated No data available
Sodium Metasilicate No data available
Sodium Carbonate No data available
Alcohols, C12-16, ethoxylated No data available
Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides

No data available

Amides, coco, N,N-bis(hydroxyethyl) No data available

Skin Sensitisation

Name Species Value

Alcohols, C9-11, ethoxylated No data available
Sodium Metasilicate No data available
Sodium Carbonate No data available
Alcohols, C12-16, ethoxylated No data available
Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides

No data available

Amides, coco, N,N-bis(hydroxyethyl) No data available

Respiratory Sensitisation

Name Species Value

Alcohols, C9-11, ethoxylated No data available
Sodium Metasilicate No data available
Sodium Carbonate No data available
Alcohols, C12-16, ethoxylated No data available
Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides

No data available

Amides, coco, N,N-bis(hydroxyethyl) No data available

Germ Cell Mutagenicity

Name Route Value

Alcohols, C9-11, ethoxylated No data available
Sodium Metasilicate No data available
Sodium Carbonate No data available
Alcohols, C12-16, ethoxylated No data available
Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di-2,1­ethanediyl]bis[ω-hydroxy-, branched, chlorides

No data available

Amides, coco, N,N-bis(hydroxyethyl) No data available

Carcinogenicity

Name Route Species Value

Alcohols, C9-11, ethoxylated No data available

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Sodium Metasilicate No data available
Sodium Carbonate No data available
Alcohols, C12-16, ethoxylated No data available
Poly(oxy-1,2-ethanediyl), α,α'-[[[3­(decyloxy)propyl]methyliminio]di­2,1-ethanediyl]bis[ω-hydroxy-,
branched, chlorides

No data available

Amides, coco, N,N­bis(hydroxyethyl)

No data available

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure Duration

Alcohols, C9-11,
ethoxylated

No data available

Sodium Metasilicate No data available
Sodium Carbonate No data available
Alcohols, C12-16,
ethoxylated

No data available

Poly(oxy-1,2­ethanediyl), α,α'-[[[3­(decyloxy)propyl]met
hyliminio]di-2,1­ethanediyl]bis[ω­hydroxy-, branched,
chlorides

No data available

Amides, coco, N,N­bis(hydroxyethyl)

No data available

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target

Organ(s)

Value Species Test result Exposure

Duration

Alcohols, C9­11,
ethoxylated

No data available

Sodium
Metasilicate

No data available

Sodium
Carbonate

No data available

Alcohols,
C12-16,
ethoxylated

No data available

Poly(oxy-1,2­ethanediyl),
α,α'-[[[3­(decyloxy)pro
pyl]methylimi
nio]di-2,1­ethanediyl]bis
[ω-hydroxy-,
branched,
chlorides

No data available

Amides, coco,
N,N­bis(hydroxyet
hyl)

No data available

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Specific Target Organ Toxicity - repeated exposure

Name Route Target

Organ(s)

Value Species Test result Exposure

Duration

Alcohols, C9­11,
ethoxylated

No data available

Sodium
Metasilicate

Ingestion kidney and/or

bladder

Some positive
data exist, but the
data are not
sufficient for
classification

LOAEL 2,400
mg/kg/day

Sodium
Carbonate

No data available

Alcohols,
C12-16,
ethoxylated

No data available

Poly(oxy-1,2­ethanediyl),
α,α'-[[[3­(decyloxy)pro
pyl]methylimi
nio]di-2,1­ethanediyl]bis
[ω-hydroxy-,
branched,
chlorides

No data available

Amides, coco,
N,N­bis(hydroxyet
hyl)

No data available

Aspiration Hazard

Name Value

Alcohols, C9-11, ethoxylated Not an aspiration hazard
Sodium Metasilicate Not an aspiration hazard
Sodium Carbonate Not an aspiration hazard
Alcohols, C12-16, ethoxylated Not an aspiration hazard
Poly(oxy-1,2-ethanediyl), α,α'-[[[3-(decyloxy)propyl]methyliminio]di­2,1-ethanediyl]bis[ω-hydroxy-, branched, chlorides

Not an aspiration hazard

Amides, coco, N,N-bis(hydroxyethyl) Not an aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.

12.1. Toxicity

Acute aquatic hazard:

Not acutely toxic to aquatic life by GHS criteria.

Chronic aquatic hazard:

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Not chronically toxic to aquatic life by GHS criteria.

No product test data available.
No component test data available.

12.2. Persistence and degradability

No test data available.

12.3 : Bioaccumulative potential

No test data available.

12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effects

No information available.

The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations

Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as hazardous as per applicable regulations) shall be considered,stored,treated &
disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities. Dispose of waste product in a permitted
industrial waste facility.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

20 01 29* Detergents containing dangerous substances

SECTION 14: Transportation information

ADR/IMDG/IATA: Not restricted for transport.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Carcinogenicity

Ingredient CAS Nbr Classification Regulation

Amides, coco, N,N-bis(hydroxyethyl) 68603-42-9 Grp. 2B: Possible human International Agency

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carc. for Research on Cancer

Global inventory status

Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.

List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC

The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:

Aqua
Ethoxylated C9-11 alcohols
Sodium metasilicate
Sodium carbonate
Ethoxylated C12-16 alcohols
Poly(oxy-1,2-ethanediyl)alpha,alpha-[[[3-(decyloxy)propyl]methylimino]di-2,1-ethanediyl]bis[omega-hydroxy-branched,
chlorides
Tetrasodium EDTA
Lauramine oxide
Cocamide DEA
Perfumes
Hexyl cinnam-aldehyde
Colorant

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H411 Toxic to aquatic life with long lasting effects.

List of relevant R-phrases

R22 Harmful if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R37 Irritating to respiratory system.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R52 Harmful to aquatic organisms.

Revision information:

Revision Changes:
Section 8: Respiratory protection - recommended respirators information was modified.
Risk phrase was modified.
Safety phrase was modified.
Section 8: Respiratory protection - recommended respirators was modified.
Section 9: pH information was modified.

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Section 1: Product use information was modified.
Section 2: Symbol was modified.
Section 9: Evaporation Rate information was modified.
Section 9: Viscosity information was modified.
Section 16: List of relevant R phrase information was modified.
Section 3: Composition/ Information of ingredients table was modified.
Section 9: n-octanol/water coefficient information was modified.
Section 9: Boiling point information was modified.
Section 9: Relative density information was modified.
Section 9: Solubility in water text was modified.
Section 13: EU waste code (product as sold) information was modified.
Section 9: Flammability (solid, gas) information was modified.
Section 9: Explosive properties information was modified.
Section 9: Oxidising properties information was modified.
Copyright was modified.
Section 9: Flash point information was modified.
Section 9: Melting point information was modified.
Section 9: Flammable limits (LEL) information was modified.
Section 9: Flammable limits (UEL) information was modified.
Section 9: Vapour density value was modified.
Section 9: Vapour pressure value was modified.
Section 9: Density information was modified.
Section 1: Initial issue message was modified.
Aspiration Hazard Table was modified.
Section 11: Acute Toxicity table was modified.
Carcinogenicity Table was modified.
Serious Eye Damage/Irritation Table was modified.
Germ Cell Mutagenicity Table was modified.
Skin Sensitisation Table was modified.
Respiratory Sensitisation Table was modified.
Reproductive Toxicity Table was modified.
Skin Corrosion/Irritation Table was modified.
Target Organs - Repeated Table was modified.
Target Organs - Single Table was modified.
Section 11: Health Effects - Eye information was modified.
Section 11: Health Effects - Skin information was modified.
Section 11: Health Effects - Inhalation information was modified.
Section 11: Health Effects - Ingestion information was modified.
Section 5: Hazardous combustion products table was modified.
Section 5: Fire - Extinguishing media information was modified.
Section 7: Precautions safe handling information was modified.
Section 8: Personal Protection - Skin/hand information was modified.
Section 10: Hazardous decomposition or by-products table was modified.
Section 13: Standard Phrase Category Waste GHS was modified.
Section 4: First aid for eye contact information was modified.
Section 4: First aid for skin contact information was modified.
Section 4: First aid for inhalation information was modified.
Section 4: First aid for ingestion (swallowing) information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. was modified.
Section 8: Respiratory protection - recommended respirators guide was added.
Section 15: Carcinogenicity heading was added.
Section 15: Carcinogenicity information was added.
Section 15: Carcinogenicity table Regulation column heading was added.
Section 15: Carcinogenicity table Ingredient column heading was added.
Section 15: Carcinogenicity table CAS No column heading was added.

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Section 15: Carcinogenicity table Classification column heading was added.
Section 12: Acute aquatic hazard information was added.
Section 12: Chronic aquatic hazard heading was added.
Section 12: Acute aquatic hazard heading was added.
Section 12: Chronic aquatic hazard information was added.
Section 11: Carcinogenicity heading was added.
Section 11: Cancer Hazards information was added.
Section 8: Personal Protection - Eye information was added.
Section 9: Autoignition temperature information was added.
Section 11: UN GHS Classification table heading was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk