MEGUIAR'S M66 User Manual

M66, Quick Detailer (21-141A): M6601

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Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

26-6693-1

Version number:

2.00

Revision date:

28/03/2014

Supersedes date:

20/04/2012

Transportation version number: 1.00 (12/12/2011)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

M66, Quick Detailer (21-141A): M6601

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

One-step cleaner/wax

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Indication of danger

R67

For full text of R phrases, see Section 16.

2.2. Label elements

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Symbol(s)

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None.

Contains:

No ingredients are assigned to the label.

Risk phrases

R67 Vapours may cause drowsiness and dizziness.

Safety phrases

S23A Do not breathe vapour.
S24 Avoid contact with skin.
S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or

label.

S2 Keep out of the reach of children.

Notes on labelling

R65 is not required on the label due to the product's viscosity.
Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004 (not required on industrial label): 5-15%: Aliphatic hydrocarbons. <5%: Non-ionic
surfactant. Contains: Perfumes, linalool, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1).
Nota P applied to CAS 64742-48-9 and 8052-41-3.

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non-Hazardous Ingredients Mixture 40 - 70
Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-

150-3

10 - 30 Xn:R65 - Nota 4,P (EU)

Xi:R38; R67 (Self Classified)

Asp. Tox. 1, H304 - Nota P
(CLP)
Skin Irrit. 2, H315; STOT SE 3,
H336 (Self Classified)

Distillates (petroleum), hydrotreated light 64742-47-8 EINECS 265-

149-8

5 - 10 Xn:R65 - Nota 4 (EU)

R10; R66; R67 (Self Classified)

Asp. Tox. 1, H304 (CLP)
Flam. Liq. 3, H226; STOT SE 3,

H336; EUH066 (Self Classified)
Conditioners Trade Secret < 5
Siloxanes and silicones, di-Me 63148-62-9 1 - 5
Kaolin, calcined 92704-41-1 EINECS 296-

473-8

1 - 5

Ceramic materials and wares, chemicals 66402-68-4 EINECS 266-

340-9

1 - 5

White mineral oil 8042-47-5 EINECS 232-

455-8

0.1 - 1 Xn:R65 (Self Classified)

Asp. Tox. 1, H304 (Self

Classified)
Stoddard solvent 8052-41-3 EINECS 232- 0.1 - 1 Xn:R48/20; Xn:R65 - Nota P

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489-3 (EU)

Xi:R38 (Self Classified)

Asp. Tox. 1, H304; STOT RE 1,

H372 - Nota P (CLP)

Skin Irrit. 2, H315 (Self

Classified)
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

55965-84-9 < 0.0015 T:R23-24-25; C:R34; N:R50/53;

R43 (EU)

Acute Tox. 3, H331; Acute Tox.

3, H311; Acute Tox. 3, H301;

Skin Corr. 1B, H314; Skin Sens.

1A, H317; Aquatic Acute 1,

H400,M=10; Aquatic Chronic 1,

H410,M=10 (CLP)

Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

Remove person to fresh air. If you feel unwell, get medical attention.

Skin contact

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish.

5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode. None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

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Formaldehyde During combustion.
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.

5.3. Advice for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. No unusual fire or explosion hazards are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition
source and could cause flammable gases or vapours in the spill area to burn or explode. Observe precautions from other
sections. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection,
ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water.
Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Vapours may travel long distances along the ground or floor to an ignition source and flash back. Do not use in a confined
area with minimal air exchange. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not
get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilities

Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Store away from heat. Store away
from acids. Store away from oxidising agents. Store away from areas where product may come into contact with food or
pharmaceuticals.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

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Ingredient CAS Nbr Agency Limit type Additional comments

Naphtha (petroleum),
hydrotreated heavy

64742-48-9 Manufacturer

determined

TWA:100 ppm

Health and Safety Comm. (UK) : UK Health and Safety Commission
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

Biological limit values

No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Eye protection not required.

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Nitrile rubber.
Polymer laminate

Respiratory protection

In case of inadequate ventilation wear respiratory protection. An exposure assessment may be needed to decide if a respirator
is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of
the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state

Liquid.

Appearance/Odour

Sweet, pleasant odour; Blue liquid

Odour threshold

No data available.

pH

7 - 8

Boiling point/boiling range

198.9 ºC

Melting point

Not applicable.

Flammability (solid, gas)

Not applicable.

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

Flash point > 93 °C (200 °F)

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Autoignition temperature

No data available.

Flammable Limits(LEL)

Not applicable.

Flammable Limits(UEL)

Not applicable.

Vapour pressure

No data available.

Relative density

0.96 - 0.99 [Ref Std:WATER=1]

Water solubility

Moderate

Solubility- non-water

No data available.

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

Vapour density

No data available.

Decomposition temperature

No data available.

Viscosity

23 - 28 Pa-s

Density

0.956 - 0.99 g/cm3

9.2. Other information

Volatile organic compounds (VOC)

14.66 % weight

SECTION 10: Stability and reactivity

10.1 Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

Heat.

10.5 Incompatible materials

Strong oxidising agents.
Strong acids.

10.6 Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

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11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

Intentional concentration and inhalation may be harmful or fatal. Respiratory tract irritation: Signs/symptoms may include
cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after
inhalation.

Skin contact

Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

Eye contact

Contact with the eyes during product use is not expected to result in significant irritation.

Ingestion

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.

Target Organ Effects:

Single exposure may cause:

Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Naphtha (petroleum), hydrotreated heavy Inhalation-

Vapor

LC50 estimated to be 20 - 50 mg/l

Naphtha (petroleum), hydrotreated heavy Dermal Rabbit LD50 > 3,000 mg/kg
Naphtha (petroleum), hydrotreated heavy Ingestion Rat LD50 > 5,000 mg/kg
Distillates (petroleum), hydrotreated light Dermal Rabbit LD50 > 3,160 mg/kg
Distillates (petroleum), hydrotreated light Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 3.0 mg/l

Distillates (petroleum), hydrotreated light Ingestion Rat LD50 > 5,000 mg/kg
Ceramic materials and wares, chemicals Dermal LD50 estimated to be > 5,000 mg/kg
Ceramic materials and wares, chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg
Kaolin, calcined Ingestion Rat LD50 > 2,000 mg/kg
Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg
Stoddard solvent Inhalation-

Vapor

LC50 estimated to be 20 - 50 mg/l

Stoddard solvent Dermal Rabbit LD50 > 3,000 mg/kg
Stoddard solvent Ingestion Rat LD50 > 5,000 mg/kg
White mineral oil Dermal Rabbit LD50 > 2,000 mg/kg
White mineral oil Ingestion Rat LD50 > 5,000 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Rabbit LD50 87 mg/kg

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Inhalation­Dust/Mist
(4 hours)

Rat LC50 0.33 mg/l

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat LD50 40 mg/kg

ATE = acute toxicity estimate

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Skin Corrosion/Irritation

Name Species Value

Naphtha (petroleum), hydrotreated heavy Rabbit Irritant
Distillates (petroleum), hydrotreated light Rabbit Mild irritant
Ceramic materials and wares, chemicals Rabbit No significant irritation
Siloxanes and silicones, di-Me Rabbit No significant irritation
Stoddard solvent Rabbit Irritant
White mineral oil Rabbit No significant irritation
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Rabbit Corrosive

Serious Eye Damage/Irritation

Name Species Value

Naphtha (petroleum), hydrotreated heavy Rabbit No significant irritation
Distillates (petroleum), hydrotreated light Rabbit Mild irritant
Ceramic materials and wares, chemicals Rabbit Mild irritant
Siloxanes and silicones, di-Me Rabbit No significant irritation
Stoddard solvent Rabbit No significant irritation
White mineral oil Rabbit Mild irritant
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Rabbit Corrosive

Skin Sensitisation

Name Species Value

Naphtha (petroleum), hydrotreated heavy Guinea

pig

Not sensitizing

Distillates (petroleum), hydrotreated light Guinea

pig

Not sensitizing

Stoddard solvent Guinea

pig

Not sensitizing

White mineral oil Guinea

pig

Not sensitizing

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Sensitising

Photosensitisation

Name Species Value

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Not sensitizing

Respiratory Sensitisation

Name Species Value

Germ Cell Mutagenicity

Name Route Value

Naphtha (petroleum), hydrotreated heavy In vivo Not mutagenic
Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but the data are not

sufficient for classification
Distillates (petroleum), hydrotreated light In Vitro Not mutagenic
Ceramic materials and wares, chemicals In Vitro Some positive data exist, but the data are not

sufficient for classification
Stoddard solvent In vivo Not mutagenic
Stoddard solvent In Vitro Some positive data exist, but the data are not

sufficient for classification
White mineral oil In Vitro Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In vivo Not mutagenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In Vitro Some positive data exist, but the data are not

sufficient for classification

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Carcinogenicity

Name Route Species Value

Naphtha (petroleum), hydrotreated heavy Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Naphtha (petroleum), hydrotreated heavy Inhalation Human

and
animal

Some positive data exist, but the data are not
sufficient for classification

Distillates (petroleum), hydrotreated light Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Ceramic materials and wares, chemicals Inhalation Multiple

animal
species

Some positive data exist, but the data are not
sufficient for classification

Stoddard solvent Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Stoddard solvent Inhalation Human

and
animal

Some positive data exist, but the data are not
sufficient for classification

White mineral oil Dermal Mouse Not carcinogenic
White mineral oil Inhalation Multiple

animal
species

Not carcinogenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Mouse Not carcinogenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure

Duration

Naphtha (petroleum), hydrotreated heavy Inhalation Not toxic to development Rat NOAEL 2.4

mg/l

during

organogenesis

Stoddard solvent Inhalation Not toxic to development Rat NOAEL 2.4

mg/l

during

organogenesis

White mineral oil Ingestion Not toxic to female reproduction Rat NOAEL

4,350
mg/kg/day

13 weeks

White mineral oil Ingestion Not toxic to male reproduction Rat NOAEL

4,350
mg/kg/day

13 weeks

White mineral oil Ingestion Not toxic to development Rat NOAEL

4,350
mg/kg/day

during

gestation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to female reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to male reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to development Rat NOAEL 15

mg/kg/day

during

organogenesis

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Naphtha (petroleum),
hydrotreated heavy

Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not
available

Naphtha (petroleum),
hydrotreated heavy

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not
available

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Naphtha (petroleum),
hydrotreated heavy

Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Dog NOAEL 6.5

mg/l

4 hours

Distillates (petroleum),
hydrotreated light

Inhalation central nervous

system depression

May cause drowsiness or
dizziness

NOAEL Not

available
Distillates (petroleum),
hydrotreated light

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not

available

Stoddard solvent Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not

available

Stoddard solvent Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not

available

Stoddard solvent Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Dog NOAEL 6.5

mg/l

4 hours

Mixture of 5-chloro-2­methyl-2H-isothiazol-3­one and 2-methyl-2H­isothiazol-3-one

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

similar
health
hazards

NOAEL Not

available

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Naphtha (petroleum),
hydrotreated heavy

Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL 4.6

mg/l

6 months

Naphtha (petroleum),
hydrotreated heavy

Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat LOAEL 1.9

mg/l

13 weeks

Naphtha (petroleum),
hydrotreated heavy

Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL 0.6

mg/l

90 days

Naphtha (petroleum),
hydrotreated heavy

Inhalation bone, teeth, nails,

and/or hair | blood |
liver | muscles

All data are negative Rat NOAEL 5.6

mg/l

12 weeks

Naphtha (petroleum),
hydrotreated heavy

Inhalation heart All data are negative Multiple

animal
species

NOAEL 1.3

mg/l

90 days

Ceramic materials and
wares, chemicals

Inhalation pulmonary fibrosis Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL not

available

Ceramic materials and
wares, chemicals

Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL not

available

occupational
exposure

Stoddard solvent Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL 4.6

mg/l

6 months

Stoddard solvent Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat LOAEL 1.9

mg/l

13 weeks

Stoddard solvent Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL 0.6

mg/l

90 days

Stoddard solvent Inhalation bone, teeth, nails,

and/or hair | blood |
liver | muscles

All data are negative Rat NOAEL 5.6

mg/l

12 weeks

Stoddard solvent Inhalation heart All data are negative Multiple

animal
species

NOAEL 1.3

mg/l

90 days

White mineral oil Ingestion hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL

1,381

mg/kg/day

90 days

White mineral oil Ingestion liver | immune

system

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL

1,336

mg/kg/day

90 days

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Aspiration Hazard

Name Value

Naphtha (petroleum), hydrotreated heavy Aspiration hazard
Distillates (petroleum), hydrotreated light Aspiration hazard
Stoddard solvent Aspiration hazard
White mineral oil Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.

12.1. Toxicity

No product test data available.

Material CAS Nbr Organism Type Exposure Test endpoint Test result

Ceramic
materials and
wares,
chemicals

66402-68-4 Data not

available or
insufficient for

classification
Distillates
(petroleum),
hydrotreated
light

64742-47-8 Data not

available or

insufficient for

classification
Kaolin,
calcined

92704-41-1 Data not

available or

insufficient for

classification
Naphtha
(petroleum),
hydrotreated
heavy

64742-48-9 Data not

available or

insufficient for

classification
Siloxanes and
silicones, di­Me

63148-62-9 Data not

available or

insufficient for

classification
Stoddard
solvent

8052-41-3 Data not

available or

insufficient for

classification
White mineral
oil

8042-47-5 Bluegill Experimental 96 hours Lethal Level

50%

>100 mg/l

White mineral
oil

8042-47-5 Water flea Experimental 21 days NOEC >100 mg/l

Mixture of 5­chloro-2­methyl-2H-

55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l

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isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l

12.2. Persistence and degradability

Material CAS Nbr Test type Duration Study Type Test result Protocol

Siloxanes and
silicones, di­Me

63148-62-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Kaolin,
calcined

92704-41-1 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Ceramic
materials and
wares,
chemicals

66402-68-4 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Distillates
(petroleum),
hydrotreated
light

64742-47-8 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

White mineral
oil

8042-47-5 Experimental

Biodegradation

28 days CO2 evolution 0 % weight OECD 301B -

Modified sturm or CO2
Naphtha
(petroleum),
hydrotreated
heavy

64742-48-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

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Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Experimental

Biodegradation

28 days CO2 evolution 48 % weight Other methods

Stoddard
solvent

8052-41-3 Estimated

Photolysis

Photolytic half­life (in air)

6.49 days (t
1/2)

Other methods

Stoddard
solvent

8052-41-3 Experimental

Biodegradation

28 days CO2 evolution 63 % weight OECD 301B -

Modified sturm or CO2

12.3 : Bioaccumulative potential

Material CAS Nbr Test type Duration Study Type Test result Protocol

Siloxanes and
silicones, di­Me

63148-62-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Kaolin,
calcined

92704-41-1 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Ceramic
materials and
wares,
chemicals

66402-68-4 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Distillates
(petroleum),
hydrotreated
light

64742-47-8 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

White mineral
oil

8042-47-5 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Naphtha
(petroleum),
hydrotreated
heavy

64742-48-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Estimated

Bioconcentrati
on

Log Kow 0.5 Other methods

Stoddard
solvent

8052-41-3 Experimental

BCF - Other

Bioaccumulati
on factor

1944 Other methods

Stoddard
solvent

8052-41-3 Experimental

Bioconcentrati
on

Log Kow 7.06 Other methods

12.4. Mobility in soil

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Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

Ingredient CAS Nbr PBT/vPvB status
White mineral oil 8042-47-5 Meets REACH PBT criteria

12.6. Other adverse effects

No information available.

The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

See Section 11.1 Information on toxicological effects

As a disposal alternative, Incinerate in a permitted waste incineration facility. Dispose of waste product in a permitted
industrial waste facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

20 01 29* Detergents containing dangerous substances

SECTION 14: Transportation information

ADR/IMDG/IATA: Not restricted for transport.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Global inventory status

Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

EUH066 Repeated exposure may cause skin dryness or cracking.
H226 Flammable liquid and vapour.

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H301 Toxic if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H336 May cause drowsiness or dizziness.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

List of relevant R-phrases

R10 Flammable.
R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R38 Irritating to skin.
R43 May cause sensitisation by skin contact.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R65 Harmful: May cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

Revision information:

Revision Changes:
Section 8: Skin protection - recommended gloves information information was modified.
Risk phrase information was modified.
Section 16: List of relevant R phrase information information was modified.
Section 3: Composition/ Information of ingredients table information was modified.
Section 9: Relative density information information was modified.
Section 9: Flammability (solid, gas) information information was modified.
Section 2: Label remarks information was modified.
Section 2: EU Detergent Regulation label remarks information was modified.
Copyright information was modified.
Section 8: Occupational exposure limit table information was modified.
Section 11: Aspiration Hazard Table information was modified.
Section 11: Acute Toxicity table information was modified.
Section 11: Carcinogenicity Table information was modified.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Germ Cell Mutagenicity Table information was modified.
Section 11: Skin Sensitization Table information was modified.
Section 11: Reproductive Toxicity Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Target Organs - Repeated Table information was modified.
Section 11: Target Organs - Single Table information was modified.
Section 11: Health Effects - Skin information information was modified.
Section 5: Fire - Extinguishing media information information was modified.
Section 5: Fire - Special hazards information information was modified.
Section 5: Fire - Advice for fire fighters information information was modified.
Section 6: Accidental release personal information information was modified.
Section 6: Accidental release environmental information information was modified.
Section 6: Accidental release clean-up information information was modified.
Section 7: Precautions safe handling information information was modified.

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Section 7: Conditions safe storage information was modified.
Section 8: Personal Protection - Eye information information was modified.
Section 8: Personal Protection - Skin/hand information information was modified.
Section 8: Personal Protection - Respiratory Information information was modified.
Section 13: 13.1. Waste disposal note information was modified.
Section 13: Standard Phrase Category Waste GHS information was modified.
Section 4: First aid for skin contact information information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. information was modified.
Section 8: Respiratory protection - recommended respirators guide information was added.
Section 2: Indication of danger heading information was added.
Section 2: Indication of danger information information was added.
Section 12: Component ecotoxicity information information was added.
Section 12: Persistence and Degradability information information was added.
Section 12:Bioccumulative potential information information was added.
Section 12: Component Ecotoxicity table Material column header information was added.
Section 12: Component Ecotoxicity table CAS No column header information was added.
Section 12: Component Ecotoxicity table Organism column header information was added.
Section 12: Component Ecotoxicity table Type column header information was added.
Section 12: Component Ecotoxicity table Exposure column header information was added.
Section 12: Component Ecotoxicity table End point column header information was added.
Section 12: Component Ecotoxicity table Result column header information was added.
Section 12: Persistence and degradability table Material column header information was added.
Section 12: Persistence and degradability table CAS No column header information was added.
Section 12: Persistence and degradability table Test Type column header information was added.
Section 12: Persistence and degradability table Duration column header information was added.
Section 12: Persistence and degradability table Test Result column header information was added.
Section 12: Persistence and degradability table Protocol column header information was added.
Section 12:Bioccumulative potential table Material column header information was added.
Section 12:Bioccumulative potential table CAS No column header information was added.
Section 12:Bioccumulative potential table CAS No column header information was added.
Section 12:Bioccumulative potential table Test Result column header information was added.
Section 12:Bioccumulative potential table Protocol column header information was added.
Section 12:Bioccumulative potential table Test Type column header information was added.
Section 11: Photosensitisation table - Name heading information was added.
Section 11: Photosensitisation table heading information was added.
Photosensitisation Table information was added.
Section 11: Photosensitisation table - Species heading information was added.
Section 11: Photosensitisation table - Value heading information was added.
Section 12: PBT/vPvB table CAS No. column heading information was added.
Section 12: PBT/vPvB table CAS No. column heading information was added.
Section 12: PBT/vPvB table PBT/vPvB Status column heading information was added.
Section 12: PBT/vPvB table row information was added.
Section 12: Persistence and degradability table Study Type column header information was added.
Section 12:Bioccumulative potential table Test Type column header information was added.
Section 9: Odour Threshold information was added.
Section 9: Solubility (non-water) information was added.
Section 09: Decomposition Temperature information was added.
Section 11: Single exposure may cause: heading information was added.
Section 11: Single exposure may cause standard phrases information was added.
Section 10: Hazardous decomposition products during combustion text information was added.
Section 11: Disclosed components not in tables text information was added.
Section 8: 8.1.1 Biological limit values table heading information was added.
Section 8: BLV information was added.
Section 2: R phrase reference information was added.
Label: Graphic information was added.

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Section 02: Graphic information information was added.
Section 9: Flammability (solid, gas) information information was added.
Section 8: Eye/face protection information information was deleted.
Section 8: Eye/face protection text information was deleted.
Section 8: Respiratory protection - recommended respirators information was deleted.
Section 15: Carcinogenicity heading information was deleted.
Section 15: Carcinogenicity information information was deleted.
Section 2: Symbols heading information was deleted.
Section 15: Symbol information information was deleted.
Section 15: Carcinogenicity table Regulation column heading information was deleted.
Section 15: Carcinogenicity table Ingredient column heading information was deleted.
Section 15: Carcinogenicity table CAS No column heading information was deleted.
Section 15: Carcinogenicity table Classification column heading information was deleted.
Section 12: Acute aquatic hazard information information was deleted.
Section 12: Chronic aquatic hazard heading information was deleted.
Section 12: Acute aquatic hazard heading information was deleted.
Section 12: Chronic aquatic hazard information information was deleted.
Prints No Data if Component ecotoxicity information is not present information was deleted.
Prints No Data if Persistence and Degradability information is not present information was deleted.
Prints No Data if Bioccumulative potential information is not present information was deleted.
Section 8: mg/m³ key information was deleted.
Section 8: ppm key information was deleted.
Section 15: Ingredient information per Regulation EC No. 648/2004 information was deleted.
Section 11: Carcinogenicity heading information was deleted.
Section 11: Respiratory Sensitization Table information was deleted.
Section 11: Health Effects - Other information information was deleted.
Section 11: Cancer Hazards information information was deleted.
Section 12: No PBT/vPvB information available warning information was deleted.
Section 15: Ingredient information per Regulation EC No. 648/2004 heading information was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk