M47, Hard Water Spot Remover (18-151B): M4716
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
Document group:
26-8185-6
Version number:
2.00
Revision date:
18/09/2014
Supersedes date:
17/08/2012
Transportation version number: 1.00 (15/11/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
M47, Hard Water Spot Remover (18-151B): M4716
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture
Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
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SIGNAL WORD
DANGER!
Symbols:
GHS05 (Corrosion) |
Pictograms
Ingredient CAS Nbr % by Wt
Amides, coco, N,N-bis(hydroxyethyl) 68603-25-8 1 - 5
HAZARD STATEMENTS:
H318 Causes serious eye damage.
PRECAUTIONARY STATEMENTS
General:
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
Prevention:
P280A Wear eye/face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTRE or doctor/physician.
SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-
isothiazol-3-one. May produce an allergic reaction.
4% of the mixture consists of components of unknown acute oral toxicity.
Contains 4% of components with unknown hazards to the aquatic environment.
Notes on labelling
Updated per Regulation (EC) No. 648/2004 on detergents.
Ingredients required per 648/2004: <5%: Non-ionic surfactant, EDTA and salts thereof. Contains: Perfumes, Colorants, Dlimonene, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1).
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Not applicable
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004: <5%: Non-ionic surfactant, EDTA and salts thereof. Contains: Perfumes, Colorants, Dlimonene, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1).
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2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 85 - 95
Amides, coco, N,N-bis(hydroxyethyl) 68603-25-8 1 - 5 Xn:R22; Xi:R41 (Vendor)
Acute Tox. 4, H302; Eye Dam.
1, H318 (Vendor)
Citric Acid 77-92-9 EINECS 201-
069-1
1 - 5 Xi:R36 (Self Classified)
Eye Irrit. 2, H319 (Self
Classified)
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;
R43 (EU)
Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
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5.1. Extinguishing media
Material will not burn.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Hydrogen gas. During combustion.
Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and
health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water.
Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or
smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic
acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from strong bases. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
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Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect vented goggles.
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Pleasant odour; Light, milky blue, watery liquid
Odour threshold
No data available.
pH
3.2 - 4
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Not applicable.
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Moderate
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
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Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
No data available.
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
0.0 % weight
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
Strong acids.
Strong bases.
Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Sprayed material may cause irritation of the respiratory system: Signs/symptoms may include cough, sneezing, nasal
discharge, hoarseness, wheezing, breathing difficulty, nose and throat pain, coughing up blood, and non respiratory effects
such as painful and watery eyes.
Skin contact
Contact with the skin during product use is not expected to result in significant irritation.
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Eye contact
Moderate eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Citric Acid Ingestion Rat LD50 3,000 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
InhalationDust/Mist
(4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Citric Acid Rabbit Mild irritant
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Citric Acid Rabbit Severe irritant
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Rabbit Corrosive
Skin Sensitisation
Name Species Value
Citric Acid Human Not sensitizing
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Human
and
animal
Sensitising
Photosensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Human
and
animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Citric Acid In Vitro Not mutagenic
Citric Acid In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
In Vitro Some positive data exist, but the data are not
sufficient for classification
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Carcinogenicity
Name Route Species Value
Citric Acid Ingestion Rat Not carcinogenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Dermal Mouse Not carcinogenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Ingestion Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Citric Acid Ingestion Not toxic to female reproduction Rat NOAEL 600
mg/kg/day
2 generation
Citric Acid Ingestion Not toxic to male reproduction Rat NOAEL 600
mg/kg/day
2 generation
Citric Acid Ingestion Not toxic to development Rat NOAEL 600
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
Ingestion Not toxic to female reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
Ingestion Not toxic to male reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
Ingestion Not toxic to development Rat NOAEL 15
mg/kg/day
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Citric Acid Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
NOAEL Not
available
Mixture of 5-chloro-2methyl-2H-isothiazol-3one and 2-methyl-2Hisothiazol-3-one
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Citric Acid Ingestion bone, teeth, nails,
and/or hair
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 600
mg/kg/day
90 days
Citric Acid Ingestion endocrine system |
hematopoietic
system
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
4,670
mg/kg/day
6 weeks
Citric Acid Ingestion kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
1,300
mg/kg/day
6 weeks
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
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The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from
3M assessments.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2methyl-2Hisothiazol-3one
55965-84-9 Diatom Experimental 72 hours EC50 0.021 mg/l
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2methyl-2Hisothiazol-3one
55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2methyl-2Hisothiazol-3one
55965-84-9 Diatom Experimental 72 hours NOEC 0.01 mg/l
Amides, coco,
N,Nbis(hydroxyeth
yl)
68603-25-8 Data not
available or
insufficient for
classification
Citric Acid 77-92-9 Water flea Experimental 48 hours EC50 655 mg/l
Citric Acid 77-92-9 Bluegill Experimental 96 hours LC50 1,516 mg/l
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Amides, coco,
N,Nbis(hydroxyeth
yl)
68603-25-8 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
Citric Acid 77-92-9 Experimental
Biodegradation
14 days BOD 77 % weight OECD 301C - MITI
test (I)
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2-
55965-84-9 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
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methyl-2Hisothiazol-3one
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Amides, coco,
N,Nbis(hydroxyeth
yl)
68603-25-8 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
Citric Acid 77-92-9 Experimental
Bioconcentrati
on
Log Kow -1.7 Other methods
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2methyl-2Hisothiazol-3one
55965-84-9 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations
to insure proper classification. Dispose of waste product in a permitted industrial waste facility. Empty and clean product
containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to determine
available options and requirements.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC 2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
070601* Aqueous washing liquids and mother liquors
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SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on
Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for
additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical
Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this
material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment
Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components
of this product are in compliance with the new substance notification requirements of CEPA. The components of this product
are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R22 Harmful if swallowed.
R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Revision information:
Revision Changes:
Section 8: Respiratory protection - recommended respirators information information was modified.
Section 16: List of relevant R phrase information information was modified.
Section 3: Composition/ Information of ingredients table information was modified.
Section 9: Flammability (solid, gas) information information was modified.
Section 15: Regulations - Inventories information was modified.
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Section 2: EU Detergent Regulation label remarks information was modified.
Section 1: Address information was modified.
Copyright information was modified.
Section 11: Acute Toxicity table information was modified.
Section 11: Carcinogenicity Table information was modified.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Germ Cell Mutagenicity Table information was modified.
Section 11: Skin Sensitization Table information was modified.
Section 11: Reproductive Toxicity Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Target Organs - Repeated Table information was modified.
Section 11: Target Organs - Single Table information was modified.
Section 11: Health Effects - Eye information information was modified.
Section 11: Health Effects - Inhalation information information was modified.
Section 5: Fire - Advice for fire fighters information information was modified.
Section 6: Accidental release personal information information was modified.
Section 6: Accidental release clean-up information information was modified.
Section 7: Precautions safe handling information information was modified.
Section 7: Conditions safe storage information was modified.
Section 8: Personal Protection - Skin/hand information information was modified.
Section 13: 13.1. Waste disposal note information was modified.
Section 13: Standard Phrase Category Waste GHS information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. information was modified.
Section 12: Other adverse effects information information was added.
Section 12: Component ecotoxicity information information was added.
Section 12: Persistence and Degradability information information was added.
Section 12:Bioccumulative potential information information was added.
Section 12: Component Ecotoxicity table Material column header information was added.
Section 12: Component Ecotoxicity table CAS No column header information was added.
Section 12: Component Ecotoxicity table Organism column header information was added.
Section 12: Component Ecotoxicity table Type column header information was added.
Section 12: Component Ecotoxicity table Exposure column header information was added.
Section 12: Component Ecotoxicity table End point column header information was added.
Section 12: Component Ecotoxicity table Result column header information was added.
Section 12: Persistence and degradability table Material column header information was added.
Section 12: Persistence and degradability table CAS No column header information was added.
Section 12: Persistence and degradability table Test Type column header information was added.
Section 12: Persistence and degradability table Duration column header information was added.
Section 12: Persistence and degradability table Test Result column header information was added.
Section 12: Persistence and degradability table Protocol column header information was added.
Section 12:Bioccumulative potential table Material column header information was added.
Section 12:Bioccumulative potential table CAS No column header information was added.
Section 12:Bioccumulative potential table CAS No column header information was added.
Section 12:Bioccumulative potential table Test Result column header information was added.
Section 12:Bioccumulative potential table Protocol column header information was added.
Section 12:Bioccumulative potential table Test Type column header information was added.
Label: Signal Word - Header information was added.
Label: Signal Word information was added.
Label: CLP Classification - Header information was added.
Label: CLP Classification information was added.
Label: CLP Classification information was added.
Label: CLP Classification - Header information was added.
Label: CLP Percent Unknown information was added.
Label: CLP Percent Unknown information was added.
Label: Graphic information was added.
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Label: Graphic information was added.
Label: Symbol information was added.
Label: Symbol information was added.
Label: CLP Precautionary - General information was added.
Label: CLP Precautionary - General - Header information was added.
Label: CLP Precautionary - Prevention information was added.
Label: CLP Precautionary - Prevention - Header information was added.
Label: CLP Precautionary - Response information was added.
Label: CLP Precautionary - Response - Header information was added.
Label: Precautionary Statement - Header information was added.
CLP: Ingredient table information was added.
Label: CLP Supplemental Hazard Statements - Header information was added.
Label: CLP Supplemental Information - Header information was added.
Contains statement for sensitizers information was added.
Contains statement for sensitizers information was added.
Contains statement for sensitizers information was added.
Section 2: Notes on labelling heading information was added.
Section 15: Label remarks and EU Detergent information was added.
CLP Remark(phrase) information was added.
Section 11: Photosensitisation table - Name heading information was added.
Section 11: Photosensitisation table heading information was added.
Photosensitisation Table information was added.
Section 11: Photosensitisation table - Species heading information was added.
Section 11: Photosensitisation table - Value heading information was added.
Section 2: 2.2 & 2.3. CLP REGULATION heading information was added.
Section 8: Appropriate Engineering controls information information was added.
Section 8: Personal Protection - Eye information information was added.
Section 8: Personal Protection - Respiratory Information information was added.
Label: CLP Ingredients table Ingredient heading information was added.
Label: CLP Ingredients table CAS No heading information was added.
Label: CLP Ingredients table Percent by Wt heading information was added.
Section 12: Persistence and degradability table Study Type column header information was added.
Section 12:Bioccumulative potential table Test Type column header information was added.
Section 9: Odour Threshold information was added.
Section 9: Solubility (non-water) information was added.
Section 09: Decomposition Temperature information was added.
Section 2: H phrase reference information was added.
Not applicable information was added.
Section 10: Hazardous decomposition products during combustion text information was added.
Section 11: Disclosed components not in tables text information was added.
Section 12: Classification Warning information was added.
Section 11: Classification disclaimer information was added.
Section 8: 8.1.1 Biological limit values table heading information was added.
Section 8: BLV information was added.
List of sensitizers information was added.
Section 9: Flammability (solid, gas) information information was added.
Section 8: Eye/face protection text information was deleted.
Section 8: Respiratory protection - recommended respirators information was deleted.
Section 2: Contains heading information was deleted.
Section 2: Safety phrases heading information was deleted.
Section 2: Risk phrases heading information was deleted.
Section 2: Symbols heading information was deleted.
Section 15: Symbol information information was deleted.
Section 15: Symbol information information was deleted.
Section 2: Label ingredient information information was deleted.
Section 12: Acute aquatic hazard information information was deleted.
M47, Hard Water Spot Remover (18-151B): M4716
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Section 12: Chronic aquatic hazard heading information was deleted.
Section 12: Acute aquatic hazard heading information was deleted.
Section 12: Chronic aquatic hazard information information was deleted.
Prints No Data if Component ecotoxicity information is not present information was deleted.
Prints No Data if Persistence and Degradability information is not present information was deleted.
Prints No Data if Bioccumulative potential information is not present information was deleted.
Section 15: Ingredient information per Regulation EC No. 648/2004 information was deleted.
Section 11: Aspiration Hazard Table information was deleted.
Section 11: Classification disclaimer information was deleted.
Section 11: Respiratory Sensitization Table information was deleted.
Section 12: Classification Warning information was deleted.
Risk phrase - None information was deleted.
Section 15: Ingredient information per Regulation EC No. 648/2004 heading information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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