MEGUIAR'S M47 User Manual

M47, Hard Water Spot Remover (18-151B): M4716

__________________________________________________________________________________________

Page: 1 of 14

Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

26-8185-6

Version number:

2.00

Revision date:

18/09/2014

Supersedes date:

17/08/2012

Transportation version number: 1.00 (15/11/2011)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

M47, Hard Water Spot Remover (18-151B): M4716

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Automotive.

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008

CLASSIFICATION:

Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318

For full text of H phrases, see Section 16.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

This product is not classified as hazardous according to EU Directive 1999/45/EC.

2.2. Label elements

CLP REGULATION (EC) No 1272/2008

M47, Hard Water Spot Remover (18-151B): M4716

__________________________________________________________________________________________

Page: 2 of 14

SIGNAL WORD

DANGER!

Symbols:

GHS05 (Corrosion) |

Pictograms

Ingredient CAS Nbr % by Wt
Amides, coco, N,N-bis(hydroxyethyl) 68603-25-8 1 - 5

HAZARD STATEMENTS:

H318 Causes serious eye damage.

PRECAUTIONARY STATEMENTS
General:

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.

Prevention:

P280A Wear eye/face protection.

Response:

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present

and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTRE or doctor/physician.

SUPPLEMENTAL INFORMATION

Supplemental Hazard Statements:

EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-

isothiazol-3-one. May produce an allergic reaction.

4% of the mixture consists of components of unknown acute oral toxicity.

Contains 4% of components with unknown hazards to the aquatic environment.

Notes on labelling

Updated per Regulation (EC) No. 648/2004 on detergents.
Ingredients required per 648/2004: <5%: Non-ionic surfactant, EDTA and salts thereof. Contains: Perfumes, Colorants, D­limonene, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1).

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Not applicable

Notes on labelling

Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004: <5%: Non-ionic surfactant, EDTA and salts thereof. Contains: Perfumes, Colorants, D­limonene, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1).

M47, Hard Water Spot Remover (18-151B): M4716

__________________________________________________________________________________________

Page: 3 of 14

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non-Hazardous Ingredients Mixture 85 - 95
Amides, coco, N,N-bis(hydroxyethyl) 68603-25-8 1 - 5 Xn:R22; Xi:R41 (Vendor)

Acute Tox. 4, H302; Eye Dam.
1, H318 (Vendor)

Citric Acid 77-92-9 EINECS 201-

069-1

1 - 5 Xi:R36 (Self Classified)

Eye Irrit. 2, H319 (Self

Classified)
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;

R43 (EU)

Acute Tox. 3, H331; Acute Tox.

3, H311; Acute Tox. 3, H301;

Skin Corr. 1B, H314; Skin Sens.

1A, H317; Aquatic Acute 1,

H400,M=10; Aquatic Chronic 1,

H410,M=10 (CLP)

Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

Remove person to fresh air. If you feel unwell, get medical attention.

Skin contact

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

M47, Hard Water Spot Remover (18-151B): M4716

__________________________________________________________________________________________

Page: 4 of 14

5.1. Extinguishing media

Material will not burn.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Hydrogen gas. During combustion.
Irritant vapours or gases. During combustion.

5.3. Advice for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and
health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water.
Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid eye contact. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or
smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic
acid etc.)

7.2. Conditions for safe storage including any incompatibilities

Store away from acids. Store away from strong bases. Store away from oxidising agents.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

M47, Hard Water Spot Remover (18-151B): M4716

__________________________________________________________________________________________

Page: 5 of 14

Occupational exposure limits

No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.

Biological limit values

No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect vented goggles.

Skin/hand protection

No chemical protective gloves are required.

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state

Liquid.

Appearance/Odour

Pleasant odour; Light, milky blue, watery liquid

Odour threshold

No data available.

pH

3.2 - 4

Boiling point/boiling range

100 ºC

Melting point

Not applicable.

Flammability (solid, gas)

Not applicable.

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

Not applicable.

Autoignition temperature

Not applicable.

Flammable Limits(LEL)

Not applicable.

Flammable Limits(UEL)

Not applicable.

Vapour pressure

No data available.

Relative density

1.00 [Ref Std:WATER=1]

Water solubility

Moderate

Solubility- non-water

No data available.

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.