MEGUIAR'S M44 User Manual

M44, Mirror Glaze Colour Restorer (21-157A): M4416
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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-7142-4
Version number:
1.03
Revision date:
07/07/2012
Supersedes date:
16/01/2012
Transportation version number: 1.00 (29/07/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M44, Mirror Glaze Colour Restorer (21-157A): M4416
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Marine
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Harmful.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols
Xn Harmful.
Contains:
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Tripoli
Risk phrases
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Safety phrases
S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
S2 Keep out of the reach of children.
Notes on labelling
R65 is not required on the label due to the product's viscosity. Updated per Regulation (EC) 648/2004 on detergents.
Nota P applied to CASRN 64742-48-9. Nota N applied to CASRN 64742-46-7.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non hazardous ingredient Mixture 60 - 80 Tripoli 1317-95-9 7 - 13 Xn:R48/20 (Vendor)
STOT RE 1, H372 (Self Classified)
Distillates (petroleum), hydrotreated light 64742-47-8 EINECS 265-
149-8
7 - 13 Xn:R65 - Nota 4 (EU)
R10; R66; R67 (Self Classified)
Asp. Tox. 1, H304 (CLP) Flam. Liq. 3, H226; STOT SE 3, H336; EUH066 (Self Classified)
Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
5 - 10 Xn:R65 - Nota 4,P (EU)
R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) STOT SE 3, H336; EUH066 (Self Classified)
Kieselguhr, soda ash flux-calcined 68855-54-9 EINECS 272-
489-0
3 - 7
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
1 - 5 Nota N (EU)
Xn:R20-65; R66 (Self Classified)
Nota N (CLP) Acute Tox. 4, H332; Asp. Tox. 1, H304; STOT SE 3, H336; EUH066 (Self Classified)
Glycerin 56-81-5 EINECS 200-
289-5
1 - 5
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Conditioners Trade Secret 1 - 5 1-methyl-2-pyrrolidone (REACH Reg. No.:01-2119472430-46)
872-50-4 EINECS 212-
828-1
1 - 5 Repr.Cat.2:R61; Xi:R36-37-38
(EU)
Skin Irrit. 2, H315; Eye Irrit. 2, H319; Repr. 1B, H360D; STOT
SE 3, H335 (CLP) Solvent naphtha (petroleum), medium aliphatic
64742-88-7 EINECS 265-
191-7
1 - 5 Xn:R65 - Nota 4 (EU)
R10; R66; R67 (Self Classified)
Asp. Tox. 1, H304 (CLP)
Flam. Liq. 3, H226; STOT SE 3,
H336; EUH066 (Self Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Hydrocarbons. During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
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5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Seal the container.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Use personal protective equipment (eg. gloves, respirators…) as required. Keep out of reach of children. Vapours may travel long distances along the ground or floor to an ignition source and flash back. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Silica, crystalline (airborne particles of respirable size)
1317-95-9 Health and
Safety Comm. (UK)
TWA(respirable):0.1 mg/m3
Glycerin 56-81-5 Health and
Safety Comm. (UK)
TWA(as mist):10 mg/m3
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
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Silica, amorphous 68855-54-9 Health and
Safety Comm. (UK)
TWA(as inhalable dust):6 mg/m3;TWA(as respirable dust):2.4 mg/m3
1-methyl-2-pyrrolidone 872-50-4 Health and
Safety Comm. (UK)
TWA:103 mg/m3(25 ppm);STEL:309 mg/m3(75 ppm)
Skin Notation
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Gloves made from the following material(s) are recommended: Butyl rubber.
Respiratory protection
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Sweet, hydrocarbon-like odour; Light brown, viscous lotion
pH
8.9 - 9.5
Boiling point/boiling range
176.7 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
> 93.3 ºC [Test Method:Pensky-Martens Closed Cup]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
1.05 - 1.1 [Ref Std:WATER=1]
Water solubility
Moderate
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
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Vapour density
No data available.
Viscosity
20,000 - 32 Pa-s
Density
1.05 - 1.1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
14.30 %
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Temperatures above the boiling point.
10.5 Incompatible materials
Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
May cause target organ effects after skin contact. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation
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Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause target organ effects after ingestion.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg Tripoli No data available Naphtha (petroleum), hydrotreated heavy
No data available
Kieselguhr, soda ash flux-calcined No data available Distillates (petroleum), hydrotreated light
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Distillates (petroleum), hydrotreated middle
No data available
1-methyl-2-pyrrolidone No data available Glycerin No data available Conditioners No data available
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Tripoli No data available Naphtha (petroleum), hydrotreated heavy Mild irritant Kieselguhr, soda ash flux-calcined No data available Distillates (petroleum), hydrotreated light Mild irritant Solvent naphtha (petroleum), medium aliphatic Mild irritant Distillates (petroleum), hydrotreated middle No data available 1-methyl-2-pyrrolidone Mild irritant Glycerin No data available Conditioners No data available
Serious Eye Damage/Irritation
Name Species Value
Tripoli No data available Naphtha (petroleum), hydrotreated heavy No data available Kieselguhr, soda ash flux-calcined No data available Distillates (petroleum), hydrotreated light No data available Solvent naphtha (petroleum), medium aliphatic No data available Distillates (petroleum), hydrotreated middle No data available 1-methyl-2-pyrrolidone Severe irritant Glycerin No data available Conditioners No data available
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Skin Sensitisation
Name Species Value
Tripoli No data available Naphtha (petroleum), hydrotreated heavy No data available Kieselguhr, soda ash flux-calcined No data available Distillates (petroleum), hydrotreated light No data available Solvent naphtha (petroleum), medium aliphatic No data available Distillates (petroleum), hydrotreated middle No data available 1-methyl-2-pyrrolidone No data available Glycerin No data available Conditioners No data available
Respiratory Sensitisation
Name Species Value
Tripoli No data available Naphtha (petroleum), hydrotreated heavy No data available Kieselguhr, soda ash flux-calcined No data available Distillates (petroleum), hydrotreated light No data available Solvent naphtha (petroleum), medium aliphatic No data available Distillates (petroleum), hydrotreated middle No data available 1-methyl-2-pyrrolidone No data available Glycerin No data available Conditioners No data available
Germ Cell Mutagenicity
Name Route Value
Tripoli No data available Naphtha (petroleum), hydrotreated heavy No data available Kieselguhr, soda ash flux-calcined No data available Distillates (petroleum), hydrotreated light No data available Solvent naphtha (petroleum), medium aliphatic No data available Distillates (petroleum), hydrotreated middle No data available 1-methyl-2-pyrrolidone No data available Glycerin No data available Conditioners No data available
Carcinogenicity
Name Route Species Value
Tripoli Inhalation Carcinogenic. Naphtha (petroleum), hydrotreated heavy
No data available
Kieselguhr, soda ash flux-calcined No data available Distillates (petroleum), hydrotreated light
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Distillates (petroleum), hydrotreated middle
No data available
1-methyl-2-pyrrolidone No data available Glycerin No data available Conditioners No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Tripoli No data available Naphtha (petroleum), hydrotreated heavy
No data available
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Kieselguhr, soda ash flux-calcined
No data available
Distillates (petroleum), hydrotreated light
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Distillates (petroleum), hydrotreated middle
No data available
1-methyl-2­pyrrolidone
Dermal Toxic to reproduction
and/or development
NOAEL 237
mg/kg/day 1-methyl-2­pyrrolidone
Ingestion Toxic to reproduction
and/or development
LOAEL 50
mg/kg/day Glycerin No data available Conditioners No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Tripoli Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Naphtha (petroleum), hydrotreated heavy
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Kieselguhr, soda ash flux­calcined
No data available
Distillates (petroleum), hydrotreated light
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Solvent naphtha (petroleum), medium aliphatic
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Distillates (petroleum), hydrotreated light
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Solvent naphtha (petroleum), medium aliphatic
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Distillates (petroleum),
No data available
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hydrotreated middle 1-methyl-2­pyrrolidone
No data available
Glycerin No data available Conditioners No data available
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Tripoli Inhalation silicosis Causes damage to
organs through prolonged or repeated exposure
NOAEL N/A
Naphtha (petroleum), hydrotreated heavy
No data available
Kieselguhr, soda ash flux­calcined
No data available
Distillates (petroleum), hydrotreated light
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Distillates (petroleum), hydrotreated middle
No data available
1-methyl-2­pyrrolidone
Inhalation bone marrow |
immune system | respiratory system
Some positive data exist, but the data are not sufficient for classification
NOAEL 0.5 mg/l
Glycerin No data available Conditioners No data available
Aspiration Hazard
Name Value
Tripoli Not an aspiration hazard Naphtha (petroleum), hydrotreated heavy Aspiration hazard Kieselguhr, soda ash flux-calcined Not an aspiration hazard Distillates (petroleum), hydrotreated light Aspiration hazard Solvent naphtha (petroleum), medium aliphatic Aspiration hazard Distillates (petroleum), hydrotreated middle Not an aspiration hazard 1-methyl-2-pyrrolidone Not an aspiration hazard Glycerin Not an aspiration hazard Conditioners Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
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The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
GHS Acute 3: Harmful to aquatic life.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as hazardous as per applicable regulations) shall be considered,stored,treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Dispose of waste product in a permitted industrial waste facility.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
070601* Aqueous washing liquids and mother liquors
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
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SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Aqua Tripoli Hydrotreated light petroleum distillates C10-12 Alkane/cycloalkane Flux calcined diatomaceous earth Glycerin Medium aliphatic solvent naphtha Solvent refined hydrotreated middle distillate Methyl pyrrolidone Processed castor oil Conditioners PEG stearate Aminomethyl propanol Silica Perfume 2-Methylamino-2-methyl-1-propanol 2-Pyrrolidinone, dimethyl­Magnesium nitrate Sodium lauryl sulfate beta-Glucan Methylchloroisothiazolinone Magnesium chloride Copper-based stabilizers Methylisothiazolinone
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H360D May damage the unborn child. H372 Causes damage to organs through prolonged or repeated exposure.
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List of relevant R-phrases
R10 Flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R37 Irritating to respiratory system. R38 Irritating to skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R61 May cause harm to the unborn child. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 8: Respiratory protection - recommended respirators information was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 2: Label remarks was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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