MEGUIAR'S M42 User Manual

M42, Marine Flagship Wash-n-Wax (21-51B): M4232

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Safety Data Sheet

Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

28-8295-9

Version number:

1.01

Revision date:

13/08/2012

Supersedes date:

06/03/2012

Transportation version number: 1.00 (06/03/2012)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

M42, Marine Flagship Wash-n-Wax (21-51B): M4232

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Marine

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

This product is not classified as hazardous according to EU Directive 1999/45/EC.

2.2. Label elements

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Symbols None.

Contains:

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No ingredients are assigned to the label.

Risk phrases None.
Safety phrases None.

Notes on labelling

Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004: 5-15%: Non-ionic surfactants, anionic surfactants, amphoteric surfactant. Contains:
Perfumes, amyl cinnamal, d-limonene, methylchloroisothiazolinone, methylisothiazolinone.

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non hazardous ingredient Mixture 70 - 90
Alcohols, C10-16, ethoxylated, sulphates,
sodium salts

68585-34-2 NLP 500-223-8 5 - 10 Xi:R36-38 (Self Classified)

Skin Irrit. 2, H315; Eye Irrit. 2,

H319 (Self Classified)
Alkanolamide Trade Secret 3 - 7
Anionic surfactant Trade Secret 1 - 5
Amides, coco, N,N-bis(hydroxyethyl) 68603-42-9 EINECS 271-

657-0

1 - 5 Xi:R41; R52 (Self Classified)

Eye Dam. 1, H318; Aquatic

Chronic 2, H411 (Self

Classified)
1-Propanaminium, 3-amino-N­(carboxymethyl)-N,N-dimethyl-, N-coco
acyl derivs., hydroxides, inner salts

61789-40-0 EINECS 263-

058-8

0.5 - 1.5 Xi:R41; N:R50 (Self Classified)

Eye Dam. 1, H318; Aquatic

Acute 1, H400,M=1; Aquatic

Chronic 3, H412 (Self

Classified)
Diethanolamine 111-42-2 EINECS 203-

868-0

0.1 - 1.0 Xn:R22-48/22; Xi:R38-41 (EU)

Acute Tox. 4, H302; Skin Irrit.

2, H315; Eye Dam. 1, H318;

STOT RE 2, H373 (CLP)

Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Eye contact

Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

Skin contact

Wash with soap and water. If signs/symptoms develop, get medical attention.

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Inhalation

Remove person to fresh air. If you are concerned, get medical advice.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Material will not burn.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.

5.3. Advice for fire-fighters

No unusual fire or explosion hazards are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water.
Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid eye contact. Keep out of reach of children. Do not handle until all safety precautions have been read and understood.

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Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Avoid release to the environment. Use personal protective
equipment (eg. gloves, respirators…) as required.

7.2. Conditions for safe storage including any incompatibilities

No special storage requirements.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Wear eye/face protection.
The following eye protection(s) are recommended: Indirect vented goggles.

Skin/hand protection

Gloves made from the following material(s) are recommended: Neoprene.
Nitrile rubber.

Respiratory protection

None required.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state

Liquid.

Appearance/Odour

Sweet, clean odour; Aqua green, pourable gel

pH

8.8 - 9.5

Boiling point/boiling range

100 ºC

Melting point

Not applicable.

Flammability (solid, gas)

Not classified

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

Not applicable.

Autoignition temperature

Not applicable.

Flammable Limits(LEL)

Not applicable.

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Flammable Limits(UEL)

Not applicable.

Vapour pressure

No data available.

Relative density

1.00 [Ref Std:WATER=1]

Water solubility

Complete

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

Vapour density

No data available.

Viscosity

4,000 - 6 Pa-s

Density

1 g/cm3

9.2. Other information

Volatile organic compounds (VOC)

0.0 % weight

VOC less H2O & exempt solvents

12.74 g/l

SECTION 10: Stability and reactivity

10.1 Reactivity

This material is considered to be non reactive under normal use conditions

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

Temperatures above the boiling point.

10.5 Incompatible materials

None known.

10.6 Hazardous decomposition products

Substance Condition

None known.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Eye contact

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Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Skin contact

May cause target organ effects after skin contact. Mild Skin Irritation: Signs/symptoms may include localized redness,
swelling, itching, and dryness.

Inhalation

No health effects are expected.

Ingestion

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.

Carcinogenicity:

Contains a chemical or chemicals which can cause cancer.

Toxicological Data

Acute Toxicity

Name Route Species Value

Overall product Ingestion No test data available; calculated ATE

>5,000 mg/kg
Alcohols, C10-16, ethoxylated,
sulphates, sodium salts

No data available

Amides, coco, N,N­bis(hydroxyethyl)

No data available

1-Propanaminium, 3-amino-N­(carboxymethyl)-N,N-dimethyl-, N­coco acyl derivs., hydroxides, inner
salts

No data available

Diethanolamine No data available

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Alcohols, C10-16, ethoxylated, sulphates, sodium
salts

Irritant

Amides, coco, N,N-bis(hydroxyethyl) Rabbit Mild irritant
1-Propanaminium, 3-amino-N-(carboxymethyl)­N,N-dimethyl-, N-coco acyl derivs., hydroxides,
inner salts

Mild irritant

Diethanolamine No data available

Serious Eye Damage/Irritation

Name Species Value

Alcohols, C10-16, ethoxylated, sulphates, sodium
salts

Severe irritant

Amides, coco, N,N-bis(hydroxyethyl) Rabbit Corrosive
1-Propanaminium, 3-amino-N-(carboxymethyl)­N,N-dimethyl-, N-coco acyl derivs., hydroxides,
inner salts

Corrosive

Diethanolamine No data available

Skin Sensitisation

Name Species Value

Alcohols, C10-16, ethoxylated, sulphates, sodium
salts

No data available

Amides, coco, N,N-bis(hydroxyethyl) No data available

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1-Propanaminium, 3-amino-N-(carboxymethyl)­N,N-dimethyl-, N-coco acyl derivs., hydroxides,
inner salts

No data available

Diethanolamine No data available

Respiratory Sensitisation

Name Species Value

Alcohols, C10-16, ethoxylated, sulphates, sodium
salts

No data available

Amides, coco, N,N-bis(hydroxyethyl) No data available
1-Propanaminium, 3-amino-N-(carboxymethyl)­N,N-dimethyl-, N-coco acyl derivs., hydroxides,
inner salts

No data available

Diethanolamine No data available

Germ Cell Mutagenicity

Name Route Value

Alcohols, C10-16, ethoxylated, sulphates, sodium
salts

No data available

Amides, coco, N,N-bis(hydroxyethyl) No data available
1-Propanaminium, 3-amino-N-(carboxymethyl)­N,N-dimethyl-, N-coco acyl derivs., hydroxides,
inner salts

No data available

Diethanolamine No data available

Carcinogenicity

Name Route Species Value

Alcohols, C10-16, ethoxylated,
sulphates, sodium salts

No data available

Amides, coco, N,N­bis(hydroxyethyl)

Dermal Multiple animal

species

Carcinogenic.

1-Propanaminium, 3-amino-N­(carboxymethyl)-N,N-dimethyl-, N­coco acyl derivs., hydroxides, inner
salts

No data available

Diethanolamine Dermal Mouse Carcinogenic.

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure Duration

Alcohols, C10-16,
ethoxylated,
sulphates, sodium
salts

No data available

Amides, coco, N,N­bis(hydroxyethyl)

No data available

1-Propanaminium, 3­amino-N­(carboxymethyl)­N,N-dimethyl-, N­coco acyl derivs.,
hydroxides, inner
salts

No data available

Diethanolamine No data available

Target Organ(s)

Specific Target Organ Toxicity - single exposure

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Name Route Target

Organ(s)

Value Species Test result Exposure

Duration

Alcohols,
C10-16,
ethoxylated,
sulphates,
sodium salts

No data available

Amides, coco,
N,N­bis(hydroxyet
hyl)

No data available

1­Propanaminiu
m, 3-amino­N­(carboxymeth
yl)-N,N­dimethyl-, N­coco acyl
derivs.,
hydroxides,
inner salts

Inhalation respiratory

irritation

Some positive
data exist, but the
data are not
sufficient for
classification

Irritation
Positive

Diethanolami
ne

No data available

Specific Target Organ Toxicity - repeated exposure

Name Route Target

Organ(s)

Value Species Test result Exposure

Duration

Alcohols,
C10-16,
ethoxylated,
sulphates,
sodium salts

No data available

Amides, coco,
N,N­bis(hydroxyet
hyl)

Dermal kidney and/or

bladder

Some positive
data exist, but the
data are not
sufficient for
classification

Rat NOAEL 50

mg/kg/day

14 weeks

1­Propanaminiu
m, 3-amino­N­(carboxymeth
yl)-N,N­dimethyl-, N­coco acyl
derivs.,
hydroxides,
inner salts

No data available

Diethanolami
ne

No data available

Aspiration Hazard

Name Value

Alcohols, C10-16, ethoxylated, sulphates, sodium salts Not an aspiration hazard
Amides, coco, N,N-bis(hydroxyethyl) Not an aspiration hazard
1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-coco
acyl derivs., hydroxides, inner salts

Not an aspiration hazard

Diethanolamine Not an aspiration hazard

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Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.

12.1. Toxicity

Acute aquatic hazard:

GHS Acute 3: Harmful to aquatic life.

Chronic aquatic hazard:

Not chronically toxic to aquatic life by GHS criteria.

No product test data available.
No component test data available.

12.2. Persistence and degradability

No test data available.

12.3 : Bioaccumulative potential

No test data available.

12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effects

No information available.

The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations

Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated &
disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

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EU waste code (product as sold)

20 01 29* Detergents containing dangerous substances

SECTION 14: Transportation information

ADR/IMDG/IATA: Not restricted for transport.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Carcinogenicity

Ingredient CAS Nbr Classification Regulation

Amides, coco, N,N-bis(hydroxyethyl) 68603-42-9 Grp. 2B: Possible human

carc.

International Agency
for Research on Cancer

Diethanolamine 111-42-2 Grp. 2B: Possible human

carc.

International Agency
for Research on Cancer

Global inventory status

Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.

List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC

The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:

Aqua
Sodium laureth sulfate
Cocamidopropyl betaine
Non-ionic surfactant
Alkanolamide
Anionic surfactant
Conditioner
Perfumes
Colorants
Triethoxycaprylylsilane
Silicic acid, diethoxyoctylsilyl trimethylsilyl ester
Benzophenone-1
Ceteareth
Lecithin
Dimethiconol
Amyl cinnamal
Phenoxyethanol
Butylparaben
Laureth
Ethylparaben
Methylparaben
Propylparaben
Silsesquioxanes, 3-[(2-aminoethyl)amino]propyl, polymers with di-Me siloxanes, hydroxy-terminated
Magnesium nitrate
d-Limonene
PEG
Diethanolamine
Sodium chloride
Sodium sulfite

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Methylchloroisothiazolinone
Copper-based stabilisers
Magnesium chloride
Methylisothiazolinone

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

List of relevant R-phrases

R22 Harmful if swallowed.
R36 Irritating to eyes.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R50 Very toxic to aquatic organisms.
R52 Harmful to aquatic organisms.

Revision information:

Revision Changes:
Section 8: Eye/face protection information was modified.
Section 12: Acute aquatic hazard information was modified.
Section 12: Chronic aquatic hazard information was modified.
Section 1: Initial issue message was modified.
Aspiration Hazard Table was modified.
Section 11: Acute Toxicity table was modified.
Carcinogenicity Table was modified.
Serious Eye Damage/Irritation Table was modified.
Germ Cell Mutagenicity Table was modified.
Skin Sensitisation Table was modified.
Respiratory Sensitisation Table was modified.
Reproductive Toxicity Table was modified.
Skin Corrosion/Irritation Table was modified.
Target Organs - Repeated Table was modified.
Target Organs - Single Table was modified.
Section 11: Health Effects - Eye information was modified.
Section 11: Health Effects - Skin information was modified.
Section 11: Health Effects - Inhalation information was modified.
Section 6: Accidental release clean-up information was modified.
Section 7: Precautions safe handling information was modified.
Section 13: Standard Phrase Category Waste GHS was modified.
Section 4: First aid for eye contact information was modified.
Section 4: First aid for skin contact information was modified.

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Section 4: First aid for inhalation information was modified.
Section 15: Symbol information was added.
Section 15: Symbol information was added.
Section 2: Label ingredient information was added.
Section 11: Carcinogenicity heading was added.
Section 11: Cancer Hazards information was added.
Section 8: Appropriate Engineering controls information was added.
Section 2.1: Classification information was added.
Risk phrase - None was added.
Risk phrase was deleted.
Safety phrase was deleted.
Section 2: Symbol was deleted.
Section 2: Label ingredient information was deleted.
Section 2: Indication of danger heading was deleted.
Section 2: Indication of danger information was deleted.
Section 11: UN GHS Classification table heading was deleted.
Section 8: Personal Protection - Skin/hand information was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk