MEGUIAR'S M39 User Manual

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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
26-8073-4
Version number:
2.00
Revision date:
04/09/2014
Supersedes date:
23/07/2012
Transportation version number: 1.00 (15/07/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M39, Heavy Duty Vinyl Cleaner (24-161B): M3916
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Irritant; Xi; R36/38
For full text of R phrases, see Section 16.
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2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
WARNING!
Symbols:
GHS07 (Exclamation mark) |
Pictograms
HAZARD STATEMENTS:
H319 Causes serious eye irritation. H315 Causes skin irritation.
PRECAUTIONARY STATEMENTS General:
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-
isothiazol-3-one. May produce an allergic reaction.
3% of the mixture consists of components of unknown acute oral toxicity.
Contains 1% of components with unknown hazards to the aquatic environment.
Notes on labelling
Updated per Regulation (EC) No. 648/2004 on detergents. Ingredients required per 648/2004 (not required on industrial label): <5%: Phosphates, anionic surfactant, amphoteric surfactant. Contains: Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1). This material is not considered corrosive per test data.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
Irritant
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Contains:
No ingredients are assigned to the label.
Risk phrases
R36/38 Irritating to eyes and skin.
Safety phrases
S51 Use only in well ventilated areas. S46 If swallowed, seek medical advice immediately and show this container or label. S2 Keep out of the reach of children.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents. Ingredients required per 648/2004 (not required on industrial label): <5%: Phosphates, anionic surfactant, amphoteric surfactant. Contains: Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1). This material is not considered corrosive per test data.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 75 - 95 Trisodium Phosphate 7601-54-9 EINECS 231-
509-8
3 - 7 Xi:R37-38-41 (Self Classified)
Skin Irrit. 2, H315; Eye Dam. 1, H318; STOT SE 3, H335 (Self Classified)
Pentapotassium triphosphate 13845-36-8 EINECS 237-
574-9
1 - 5
Glycerin 56-81-5 EINECS 200-
289-5
1 - 5
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;
R43 (EU)
Acute Tox. 3, H331; Acute Tox. 3, H311; Acute Tox. 3, H301; Skin Corr. 1B, H314; Skin Sens. 1A, H317; Aquatic Acute 1, H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP) Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
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Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Eye contact
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
5.3. Advice for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
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7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from strong bases. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Glycerin 56-81-5 Health and
Safety Comm. (UK)
TWA(as mist):10 mg/m3
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect vented goggles.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Neoprene. Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Mild chemical odour; Slightly hazy, white liquid
Odour threshold
No data available.
pH
11 - 12
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Flash point > 93 °C (200 °F)
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
Not applicable.
Relative density
1.01 [Ref Std:WATER=1]
Water solubility
Moderate
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
Not applicable.
Decomposition temperature
No data available.
Viscosity
No data available.
Density
1.01 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
0.5 % weight
VOC less H2O & exempt solvents
No data available.
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
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Hydrocarbons. Not specified. Carbon monoxide. Not specified. Carbon dioxide. Not specified. Irritant vapours or gases. Not specified.
SECTION 11: Toxicological information
The information below may not agree with the EU material classification in Section 2 and/or the ingredient classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition, statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from 3M assessments.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin contact
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye contact
Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Trisodium Phosphate Dermal Rat LD50 > 2,000 mg/kg Trisodium Phosphate Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 0.83 mg/l
Trisodium Phosphate Ingestion Rat LD50 > 2,000 mg/kg Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Inhalation­Dust/Mist (4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Trisodium Phosphate Rabbit Irritant
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Glycerin Rabbit No significant irritation Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Trisodium Phosphate Rabbit Corrosive Glycerin Rabbit No significant irritation Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Skin Sensitisation
Name Species Value
Glycerin Guinea
pig
Not sensitizing
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Sensitising
Photosensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Glycerin Ingestion Mouse Some positive data exist, but the data are not
sufficient for classification Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Mouse Not carcinogenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Glycerin Ingestion Not toxic to female reproduction Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to male reproduction Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to development Rat NOAEL
2,000 mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to female reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H-
Ingestion Not toxic to male reproduction Rat NOAEL 10
mg/kg/day
2 generation
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isothiazol-3-one Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to development Rat NOAEL 15
mg/kg/day
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Trisodium Phosphate Inhalation respiratory irritation May cause respiratory irritation similar
health hazards
NOAEL Not available
Mixture of 5-chloro-2­methyl-2H-isothiazol-3­one and 2-methyl-2H­isothiazol-3-one
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
similar health hazards
NOAEL Not available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Glycerin Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL 3.91
mg/l
14 days
Glycerin Inhalation heart | liver | kidney
and/or bladder
All data are negative Rat NOAEL 3.91
mg/l
14 days
Glycerin Ingestion endocrine system |
hematopoietic system | liver | kidney and/or bladder
All data are negative Rat NOAEL
10,000 mg/kg/day
2 years
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not agree with the EU material classification in Section 2 and/or the ingredient classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition, statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from 3M assessments.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Glycerin 56-81-5 Water flea Experimental 24 hours EC50 >10,000 mg/l Glycerin 56-81-5 Goldfish Experimental 24 hours LC50 >5,000 mg/l Pentapotassiu m triphosphate
13845-36-8 Ricefish Estimated 48 hours LC50 720 mg/l
Pentapotassiu m triphosphate
13845-36-8 Water flea Estimated 48 hours EC50 337 mg/l
Trisodium Phosphate
7601-54-9 Water flea Analogous
Compound
48 hours EC50 177 mg/l
Trisodium 7601-54-9 Western Analogous 96 hours LC50 186 mg/l
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Phosphate Mosquitofish Compound Non­Hazardous Ingredients
Mixture Field LC50 >1,001 mg/l
Non­Hazardous Ingredients
Mixture Field NOEC >1,001 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Pentapotassiu m triphosphate
13845-36-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Glycerin 56-81-5 Experimental
Biodegradation
14 days BOD 63 % weight OECD 301C - MITI
test (I) Trisodium Phosphate
7601-54-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
Mixture of 5­chloro-2-
55965-84-9 Experimental
Biodegradation
28 days CO2 evolution 48 % weight Other methods
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methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Pentapotassiu m triphosphate
13845-36-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Glycerin 56-81-5 Experimental
Bioconcentrati on
Log Kow -1.76 Other methods
Trisodium Phosphate
7601-54-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Estimated
Bioconcentrati on
Log Kow 0.5 Other methods
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Incinerate in a permitted waste incineration facility. Dispose of waste product in a permitted industrial waste facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
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The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR: Not restricted for transport. IMDG: Not restricted for transport. IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H301 Toxic if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R23 Toxic by inhalation. R24 Toxic in contact with skin. R25 Toxic if swallowed. R34 Causes burns. R36/38 Irritating to eyes and skin. R37 Irritating to respiratory system. R38 Irritating to skin. R41 Risk of serious damage to eyes.
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R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Revision information:
Revision Changes: Section 1: Product name information was modified. Section 8: Eye/face protection information information was modified. Page Heading: Product name information was modified. Section 9: pH information information was modified. Section 16: List of relevant R phrase information information was modified. Section 3: Composition/ Information of ingredients table information was modified. Section 13: EU waste code (product as sold) information information was modified. Section 9: Flammability (solid, gas) information information was modified. Section 15: Regulations - Inventories information was modified. Section 1: Address information was modified. Copyright information was modified. Section 9: Flash point information information was modified. Section 9: Property description for optional properties information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Serious Eye Damage/Irritation Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Skin Sensitization Table information was modified. Section 11: Reproductive Toxicity Table information was modified. Section 11: Skin Corrosion/Irritation Table information was modified. Section 11: Target Organs - Repeated Table information was modified. Section 11: Target Organs - Single Table information was modified. Section 11: Health Effects - Eye information information was modified. Section 11: Health Effects - Skin information information was modified. Section 11: Health Effects - Inhalation information information was modified. Section 11: Health Effects - Ingestion information information was modified. Section 5: Fire - Extinguishing media information information was modified. Section 5: Fire - Advice for fire fighters information information was modified. Section 6: Accidental release personal information information was modified. Section 6: Accidental release environmental information information was modified. Section 6: Accidental release clean-up information information was modified. Section 7: Precautions safe handling information information was modified. Section 7: Conditions safe storage information was modified. Section 8: Personal Protection - Eye information information was modified. Section 8: Personal Protection - Skin/hand information information was modified. Section 8: Personal Protection - Respiratory Information information was modified. Section 10: Hazardous decomposition or by-products table information was modified. Section 13: 13.1. Waste disposal note information was modified. Section 13: Standard Phrase Category Waste GHS information was modified. Section 4: First aid for eye contact information information was modified. Section 4: First aid for skin contact information information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. information was modified. Section 8: Respiratory protection - recommended respirators information information was added. Risk phrase information was added. Safety phrase information was added. Section 8: Respiratory protection - recommended respirators guide information was added. Section 2: Indication of danger heading information was added. Section 2: Indication of danger information information was added. Section 12: Component ecotoxicity information information was added. Section 12: Persistence and Degradability information information was added.
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Section 12:Bioccumulative potential information information was added. Section 12: Component Ecotoxicity table Material column header information was added. Section 12: Component Ecotoxicity table CAS No column header information was added. Section 12: Component Ecotoxicity table Organism column header information was added. Section 12: Component Ecotoxicity table Type column header information was added. Section 12: Component Ecotoxicity table Exposure column header information was added. Section 12: Component Ecotoxicity table End point column header information was added. Section 12: Component Ecotoxicity table Result column header information was added. Section 12: Persistence and degradability table Material column header information was added. Section 12: Persistence and degradability table CAS No column header information was added. Section 12: Persistence and degradability table Test Type column header information was added. Section 12: Persistence and degradability table Duration column header information was added. Section 12: Persistence and degradability table Test Result column header information was added. Section 12: Persistence and degradability table Protocol column header information was added. Section 12:Bioccumulative potential table Material column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table Test Result column header information was added. Section 12:Bioccumulative potential table Protocol column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Section 2: Label remarks information was added. Section 2: EU Detergent Regulation label remarks information was added. Label: Signal Word - Header information was added. Label: Signal Word information was added. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Label: CLP Classification information was added. Label: CLP Classification - Header information was added. Label: CLP Percent Unknown information was added. Label: CLP Percent Unknown information was added. Label: Graphic information was added. Label: Graphic information was added. Label: Symbol information was added. Label: Symbol information was added. Label: CLP Precautionary - General information was added. Label: CLP Precautionary - General - Header information was added. Label: CLP Precautionary - Response information was added. Label: CLP Precautionary - Response - Header information was added. Label: Precautionary Statement - Header information was added. Label: CLP Supplemental Hazard Statements - Header information was added. Label: CLP Supplemental Information - Header information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Section 2: Notes on labelling heading information was added. Section 15: Label remarks and EU Detergent information was added. CLP Remark(phrase) information was added. Section 11: Photosensitisation table - Name heading information was added. Section 11: Photosensitisation table heading information was added. Photosensitisation Table information was added. Section 11: Photosensitisation table - Species heading information was added. Section 11: Photosensitisation table - Value heading information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Section 12: Persistence and degradability table Study Type column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Section 9: Odour Threshold information was added.
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M39, Heavy Duty Vinyl Cleaner (24-161B): M3916
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Section 9: Solubility (non-water) information was added. Section 09: Decomposition Temperature information was added. Section 2: H phrase reference information was added. Section 11: Disclosed components not in tables text information was added. Section 12: Classification Warning information was added. Section 11: Classification disclaimer information was added. Section 8: 8.1.1 Biological limit values table heading information was added. Section 8: BLV information was added. Section 2: R phrase reference information was added. Label: Graphic information was added. Label: Graphic information was added. List of sensitizers information was added. Label: Graphic Text information was added. Section 9: Flammability (solid, gas) information information was added. Section 8: Eye/face protection text information was deleted. Section 2: Symbols heading information was deleted. Section 15: Symbol information information was deleted. Section 15: Symbol information information was deleted. Section 12: Acute aquatic hazard information information was deleted. Section 12: Chronic aquatic hazard heading information was deleted. Section 12: Acute aquatic hazard heading information was deleted. Section 12: Chronic aquatic hazard information information was deleted. Section 2: Special provisions concerning the labelling of certain substances heading information was deleted. Prints No Data if Component ecotoxicity information is not present information was deleted. Prints No Data if Persistence and Degradability information is not present information was deleted. Prints No Data if Bioccumulative potential information is not present information was deleted. Section 2: Additional label requirements phrase information was deleted. Section 8: mg/m³ key information was deleted. Section 8: ppm key information was deleted. Section 15: Ingredient information per Regulation EC No. 648/2004 information was deleted. Section 11: Aspiration Hazard Table information was deleted. Section 11: Classification disclaimer information was deleted. Section 11: Respiratory Sensitization Table information was deleted. Section 12: Classification Warning information was deleted. Section 2.1: Classification information information was deleted. Risk phrase - None information was deleted. Section 15: Ingredient information per Regulation EC No. 648/2004 heading information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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