MEGUIAR'S M23 User Manual

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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-3375-4
Version number:
2.02
Revision date:
16/08/2012
Supersedes date:
07/07/2011
Transportation version number: 1.00 (25/10/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M23, Professional Odour Eliminator (20-137A): M2301
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Odour neutralizing agent
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
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No ingredients are assigned to the label.
Risk phrases None. Safety phrases None.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredient Mixture 80 - 100 Odour-eliminating agent Trade Secret 1 - 5 Propan-2-ol 67-63-0 EINECS 200-
661-7
1 - 5 F:R11; Xi:R36; R67 (EU)
Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336 (CLP)
Formaldehyde 50-00-0 EINECS 200-
001-8
<= 0.00225 Carc.Cat.3:R40; T:R23-24-25;
C:R34; R43 - Nota B,D (EU)
Acute Tox. 2, H330; Acute Tox. 3, H311; Acute Tox. 3, H301; Skin Corr. 1B, H314; Skin Sens. 1A, H317; Carc. 2, H351; STOT
SE 3, H335 - Nota B,D (CLP) Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
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SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from heat. Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
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8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Formaldehyde 50-00-0 Health and
Safety Comm. (UK)
TWA:2.5 mg/m3(2 ppm);STEL:2.5 mg/m3(2 ppm)
Propan-2-ol 67-63-0 Health and
Safety Comm. (UK)
TWA:999 mg/m³(400 ppm);STEL:1250 mg/m³(500 ppm)
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
None required.
Respiratory protection
Wear respiratory protection if ventilation is inadequate to prevent overexposure. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Clean and fresh odour; Clear, water-thin liquid
pH
9 - 9.9
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
>= 93.3 ºC [Test Method:Closed Cup] [Details:ASTM D56]
Autoignition temperature
No data available.
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Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
0.922 - 1.05 [Ref Std:WATER=1]
Water solubility
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
No data available.
Density
0.922 - 1.05 g/cm3 [Details:±]
9.2. Other information
Volatile organic compounds (VOC)
5.15 % weight
VOC less H2O & exempt solvents
462.29 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong oxidising agents. Strong acids. Strong bases.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
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Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Contact with the skin during product use is not expected to result in significant irritation.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg Propan-2-ol Dermal Rabbit LD50 12,870 mg/kg Propan-2-ol Inhalation-Vapor (4
hours)
Rat LC50 73 mg/l
Propan-2-ol Ingestion Rat LD50 4,710 mg/kg Formaldehyde Dermal Rabbit LD50 270 mg/kg Formaldehyde Inhalation-Gas (4
hours)
Rat LC50 470 ppm
Formaldehyde Ingestion Rat LD50 800 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Propan-2-ol Multiple animal species No significant irritation Formaldehyde Corrosive
Serious Eye Damage/Irritation
Name Species Value
Propan-2-ol Moderate irritant Formaldehyde Corrosive
Skin Sensitisation
Name Species Value
Propan-2-ol Guinea pig Not sensitizing Formaldehyde Sensitising
Respiratory Sensitisation
Name Species Value
Propan-2-ol No data available Formaldehyde Some positive data exist, but the data are not
sufficient for classification
Germ Cell Mutagenicity
Name Route Value
Propan-2-ol In Vitro Not mutagenic Propan-2-ol In vivo Not mutagenic Formaldehyde In vivo Mutagenic
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Carcinogenicity
Name Route Species Value
Propan-2-ol Inhalation Rat Some positive data exist, but the data
are not sufficient for classification
Formaldehyde Not specified. Carcinogenic.
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Propan-2-ol Ingestion Some positive
developmental data exist, but the data are not sufficient for classification
Rat NOAEL 400
mg/kg/day
during organogenesis
Propan-2-ol Inhalation Some positive
developmental data exist, but the data are not sufficient for classification
Rat LOAEL 9
mg/l
during gestation
Formaldehyde Ingestion Some positive
reproductive/develop mental data exist, but the data are not sufficient for classification
NOEL 100 mg/kg
Formaldehyde Inhalation Some positive
reproductive/develop mental data exist, but the data are not sufficient for classification
NOEL 10 ppm
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Propan-2-ol Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Propan-2-ol Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
RD50 5,000 ppm
Propan-2-ol Inhalation auditory system Some positive
data exist, but the data are not sufficient for classification
Guinea pig NOAEL 13.4
mg/l
24 hours
Propan-2-ol Ingestion central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Formaldehyde Inhalation respiratory
system
Causes damage to organs
LOAEL 128 ppm
Formaldehyde Inhalation respiratory
irritation
Some positive data exist, but the data are not
Irritation Positive
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sufficient for classification
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Propan-2-ol Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 12.3
mg/l
24 months
Propan-2-ol Inhalation nervous system All data are
negative
Rat NOAEL 12 mg/l 13 weeks
Propan-2-ol Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 400
mg/kg/day
12 weeks
Formaldehyde Dermal respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL N/A
Formaldehyde Inhalation respiratory
system
Causes damage to organs through prolonged or repeated exposure
NOAEL 0.3 ppm
Formaldehyde Inhalation hematopoietic
system
Some positive data exist, but the data are not sufficient for classification
LOEL 15 ppm
Formaldehyde Inhalation liver | nervous
system
Some positive data exist, but the data are not sufficient for classification
NOEL 10 ppm
Formaldehyde Inhalation endocrine
system | immune system | muscles | kidney and/or bladder
All data are negative
NOAEL 15 ppm
Formaldehyde Inhalation heart | vascular
system
All data are negative
NOAEL 14.3 ppm
Formaldehyde Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
LOAEL 82 mg/kg/day
Formaldehyde Ingestion liver Some positive
data exist, but the data are not sufficient for classification
NOEL 50 mg/kg/day
Formaldehyde Ingestion nervous system Some positive
data exist, but the data are not sufficient for classification
NOEL 21 mg/kg/day
Formaldehyde Ingestion immune system Some positive NOEL 20
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data exist, but the data are not sufficient for classification
mg/kg/day
Formaldehyde Ingestion heart | endocrine
system | hematopoietic system | respiratory system | vascular system
All data are negative
NOAEL 300 mg/kg/day
Formaldehyde Ingestion skin | muscles |
eyes
All data are negative
NOAEL 109 mg/kg/day
Formaldehyde Ocular eyes All data are
negative
NOAEL 14.3 ppm
Aspiration Hazard
Name Value
Propan-2-ol Not an aspiration hazard Formaldehyde Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
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No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in a permitted industrial waste facility. Proper destruction may require the use of additional fuel during incineration processes. As a disposal alternative, incinerate in a permitted waste incineration facility. Empty and clean product containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to determine available options and requirements.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 30 Detergents other than those mentioned in 20 01 29.
SECTION 14: Transportation information
ADR: Not restricted for transport. IMDG: Not restricted for transport. IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Formaldehyde 50-00-0 Carc. 2 Regulation (EC) No.
1272/2008, Table 3.1
Formaldehyde 50-00-0 Carc.Cat.3 Regulation (EC) No.
1272/2008, Table 3.2
Formaldehyde 50-00-0 Grp. 1: Carcinogenic to
humans
International Agency for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H225 Highly flammable liquid and vapour. H301 Toxic if swallowed. H311 Toxic in contact with skin.
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H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H330 Fatal if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer.
List of relevant R-phrases
R11 Highly flammable. R23 Toxic by inhalation. R24 Toxic in contact with skin. R25 Toxic if swallowed. R34 Causes burns. R36 Irritating to eyes. R40 Limited evidence of a carcinogenic effect. R43 May cause sensitisation by skin contact. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 8: Respiratory protection - recommended respirators information was modified. Section 8: Respiratory protection - recommended respirators was modified. Section 9: pH information was modified. Section 9: Evaporation Rate information was modified. Section 9: Viscosity information was modified. Section 15: Carcinogenicity information was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 9: n-octanol/water coefficient information was modified. Section 9: Boiling point information was modified. Section 9: Relative density information was modified. Section 9: Solubility in water text was modified. Section 13: EU waste code (product as sold) information was modified. Section 16: Regulations - Inventories - EU ONLY was modified. Copyright was modified. Section 9: Flash point information was modified. Section 9: Melting point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Vapour density value was modified. Section 9: Vapour pressure value was modified. Section 9: Density information was modified. Section 9: Property description for optional properties was modified. Section 8: Occupational exposure limit table was modified. Section 8: mg/m³ key was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified.
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Target Organs - Single Table was modified. Section 11: Health Effects - Skin information was modified. Section 5: Hazardous combustion products table was modified. Section 5: Fire - Extinguishing media information was modified. Section 6: Accidental release personal information was modified. Section 6: Accidental release clean-up information was modified. Section 7: Precautions safe handling information was modified. Section 7: Conditions safe storage was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 13: Standard Phrase Category Waste GHS was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 8: Respiratory protection - recommended respirators guide was added. Section 8: Skin/hand protection information was added. Section 12: Acute aquatic hazard information was added. Section 12: Chronic aquatic hazard heading was added. Section 12: Acute aquatic hazard heading was added. Section 12: Chronic aquatic hazard information was added. Section 8: Personal Protection - Respiratory Information was added. Section 9: Autoignition temperature information was added. Section 11: UN GHS Classification table heading was deleted. Section 8: Personal Protection - Skin/hand information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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