MEGUIAR'S M135 User Manual

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M135, Synthetic Spray Detailer (20-163B): M13501, M13516
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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-6436-1
Version number:
1.02
Revision date:
23/07/2012
Supersedes date:
06/10/2011
Transportation version number: 1.00 (29/09/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M135, Synthetic Spray Detailer (20-163B): M13501, M13516
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
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No ingredients are assigned to the label.
Risk phrases None. Safety phrases None.
Special provisions concerning the labelling of certain substances
Safety data sheet available for professional user on request.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Water 7732-18-5 EINECS 231-
791-2
88 - 98
Conditioners Trade Secret < 5 Propan-2-ol 67-63-0 EINECS 200-
661-7
0.5 - 1.5 F:R11; Xi:R36; R67 (EU)
Flam. Liq. 2, H225; Eye Irrit. 2,
H319; STOT SE 3, H336 (CLP) Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
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SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Material will not burn.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Propan-2-ol 67-63-0 Health and
Safety Comm. (UK)
TWA:999 mg/m³(400 ppm);STEL:1250 mg/m³(500 ppm)
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million
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mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Gloves made from the following material(s) are recommended: Neoprene. Natural rubber.
Respiratory protection
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Sweet, pleasant odour; Slightly milky, water-like liquid
pH
4 - 5
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Not applicable.
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
No data available.
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
1.71 % weight
VOC less H2O & exempt solvents
942.46 g/l
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SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
Substance Condition
Carbon dioxide. Not specified. Carbon monoxide. Not specified. Irritant vapours or gases. Not specified.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Contact with the skin during product use is not expected to result in significant irritation.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
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Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg Propan-2-ol Dermal Rabbit LD50 12,870 mg/kg Propan-2-ol Inhalation-Vapor (4
hours)
Rat LC50 73 mg/l
Propan-2-ol Ingestion Rat LD50 4,710 mg/kg Conditioners Dermal LD50 > 2,000 mg/kg Conditioners Ingestion LD50 > 17,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Propan-2-ol No significant irritation Conditioners Minimal irritation
Serious Eye Damage/Irritation
Name Species Value
Propan-2-ol Moderate irritant Conditioners Mild irritant
Skin Sensitisation
Name Species Value
Propan-2-ol Not sensitizing Conditioners No data available
Respiratory Sensitisation
Name Species Value
Propan-2-ol No data available Conditioners No data available
Germ Cell Mutagenicity
Name Route Value
Propan-2-ol In vivo Not mutagenic Conditioners No data available
Carcinogenicity
Name Route Species Value
Propan-2-ol Not specified. Some positive data exist, but the data
are not sufficient for classification
Conditioners No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Propan-2-ol Ingestion Some positive
reproductive/develop mental data exist, but the data are not sufficient for classification
NOEL 400 mg/kg/day
Propan-2-ol Inhalation Some positive
reproductive/develop mental data exist, but the data are not
LOEL 9,001 mg/m3
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sufficient for classification
Conditioners No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Propan-2-ol Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Propan-2-ol Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
RD50 5,000 ppm
Propan-2-ol Ingestion central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Conditioners No data available
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Propan-2-ol Inhalation auditory system Some positive
data exist, but the data are not sufficient for classification
LOEL 969 mg/m3
Propan-2-ol Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
NOEL 1.2 mg/l
Propan-2-ol Inhalation nervous system All data are
negative
NOEL 12 mg/l
Propan-2-ol Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
NOEL N/A
Aspiration Hazard
Name Value
Propan-2-ol Not an aspiration hazard Conditioners Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
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12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in a permitted industrial waste facility.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 30 Detergents other than those mentioned in 20 01 29.
SECTION 14: Transportation information
ADR / IMDG / IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
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Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Aqua Isopropyl alcohol Propylene glycol propyl ether Perfumes Conditioner Silicic acid, diethoxyoctylsilyl trimethylsilyl ester Triethoxycaprylylsilane Dimethicone 2-Propoxy-1-propanol Acetic acid Dimethiconol 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]­Ethoxylated lauryl alcohol Silsesquioxanes, 3-[(2-aminoethyl)amino]propyl, polymers with di-Me siloxanes, hydroxy-terminated Magnesium nitrate Propylene glycol Alcohol ethoxylates Methylchloroisothiazolinone Copper-based stabilizers Magnesium chloride Methylisothiazolinone
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness.
List of relevant R-phrases
R11 Highly flammable. R36 Irritating to eyes. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 8: Respiratory protection - recommended respirators information was modified. Section 3: Composition/ Information of ingredients table was modified. Copyright was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified.
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Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 11: Health Effects - Skin information was modified. Section 6: Accidental release personal information was modified. Section 13: Standard Phrase Category Waste GHS was modified. Section 2: Notes on labelling heading was added. Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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