MEGUIAR'S M09 User Manual

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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-6174-8
Version number:
3.00
Revision date:
23/01/2014
Supersedes date:
25/09/2013
Transportation version number: 1.00 (27/10/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M09, Swirl Remover (21-165A): M0901, M0916
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Irritant; Xi; R38
For full text of R phrases, see Section 16.
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2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
WARNING!
Symbols:
GHS07 (Exclamation mark) |
Pictograms
HAZARD STATEMENTS:
H315 Causes skin irritation.
PRECAUTIONARY STATEMENTS
Prevention:
P260 Do not breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
7% of the mixture consists of components of unknown acute dermal toxicity.
Contains 23% of components with unknown hazards to the aquatic environment.
Notes on labelling
H304 is not required on the label due to the product's viscosity Nota P applied for CASRN 64742-48-9. Nota N applied for CASRN 64742-46-7.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
Irritant
Contains:
No ingredients are assigned to the label.
Risk phrases
R38 Irritating to skin.
Safety phrases
S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
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label.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota P applied for CASRN 64742-48-9. Nota N applied for CASRN 64742-46-7.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-hazardous ingredients Mixture 50 - 70 Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
10 - 30 Xn:R65 - Nota 4,P (EU)
Xi:R38; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) Skin Irrit. 2, H315; STOT SE 3, H336 (Self Classified)
Kaolin, calcined 92704-41-1 EINECS 296-
473-8
3 - 7
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
3 - 7 Nota N (EU)
Xn:R20-65; R52/53; R66 (Self Classified)
Nota N (CLP) Acute Tox. 4, H332; Asp. Tox. 1, H304; STOT SE 3, H336;
EUH066 (Self Classified) Conditioners Trade Secret <= 5 Ceramic materials and wares, chemicals 66402-68-4 EINECS 266-
340-9
1 - 5
Processed oil Trade Secret 1 - 5 Glycerin 56-81-5 EINECS 200-
289-5
1 - 5
Morpholine 110-91-8 EINECS 203-
815-1
< 1 C:R34; Xn:R20-21-22; R10
(EU)
Flam. Liq. 3, H226; Acute Tox.
3, H311; Acute Tox. 4, H332;
Acute Tox. 4, H302; Skin Corr.
1B, H314 (CLP) Polyethylene glycol stearate 9004-99-3 <= 0.5 N:R50 (Self Classified)
Aquatic Acute 1, H400,M=1;
Aquatic Chronic 3, H412 (Self
Classified) Titanium dioxide 13463-67-7 EINECS 236-
675-5
<= 0.1
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
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For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Hydrocarbons. During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Observe precautions from other sections. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
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6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Do not use in a confined area with minimal air exchange. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Morpholine 110-91-8 Health and
Safety Comm. (UK)
TWA: 36 mg/m³ (10 ppm); STEL: 72 mg/m³ (20 ppm)
Skin Notation
Titanium dioxide 13463-67-7 Health and
Safety Comm. (UK)
TWA(Inhalable):10 mg/m3;TWA(respirable):4 mg/m³
Glycerin 56-81-5 Health and
Safety Comm. (UK)
TWA(as mist):10 mg/m3
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
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Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Wear protective gloves. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Pleasant, sweet odour; White, viscous lotion
Odour threshold
No data available.
pH
7.9 - 8.5
Boiling point/boiling range
193.3 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
>= 93.3 ºC [Test Method:Pensky-Martens Closed Cup] [Details:D93-90]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
0.98 [Ref Std:WATER=1]
Water solubility
Moderate
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
7 Pa-s - 12 Pa-s
Density
0.98 g/cm3
9.2. Other information
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Volatile organic compounds (VOC)
15.40 % weight
VOC less H2O & exempt solvents
545.41 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Temperatures above the boiling point.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin contact
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
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Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Naphtha (petroleum), hydrotreated heavy Inhalation-
Vapor
LC50 estimated to be 20 - 50 mg/l
Naphtha (petroleum), hydrotreated heavy Dermal Rabbit LD50 > 3,000 mg/kg Naphtha (petroleum), hydrotreated heavy Ingestion Rat LD50 > 5,000 mg/kg Distillates (petroleum), hydrotreated middle Dermal Rabbit LD50 > 2,000 mg/kg Kaolin, calcined Ingestion Rat LD50 > 2,000 mg/kg Distillates (petroleum), hydrotreated middle Inhalation-
Dust/Mist (4 hours)
Rat LC50 4.6 mg/l
Distillates (petroleum), hydrotreated middle Ingestion Rat LD50 > 5,000 mg/kg Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg Ceramic materials and wares, chemicals Dermal LD50 estimated to be > 5,000 mg/kg Ceramic materials and wares, chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Processed oil Ingestion LD50 estimated to be > 5,000 Polyethylene glycol stearate Data not available or insufficient for classification Morpholine Dermal Rabbit LD50 310 mg/kg Morpholine Inhalation-
Vapor
Rat LC50 estimated to be 10 - 20 mg/l
Morpholine Ingestion Rat LD50 1,050 mg/kg Conditioners Data not available or insufficient for classification Titanium dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium dioxide Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 6.82 mg/l
Titanium dioxide Ingestion Rat LD50 > 10,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Rabbit Irritant Kaolin, calcined Data not available or insufficient for classification Distillates (petroleum), hydrotreated middle Rabbit Minimal irritation Glycerin Rabbit No significant irritation Ceramic materials and wares, chemicals Rabbit No significant irritation Processed oil Human Minimal irritation Polyethylene glycol stearate Data not available or insufficient for classification Morpholine official
classifica tion
Corrosive
Conditioners Data not available or insufficient for classification Titanium dioxide Rabbit No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Rabbit No significant irritation Kaolin, calcined Data not available or insufficient for classification Distillates (petroleum), hydrotreated middle Not
available
Mild irritant
Glycerin Rabbit No significant irritation Ceramic materials and wares, chemicals Rabbit Mild irritant Processed oil Rabbit Mild irritant Polyethylene glycol stearate Data not available or insufficient for classification Morpholine Rabbit Corrosive Conditioners Data not available or insufficient for classification
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Titanium dioxide Rabbit No significant irritation
Skin Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Guinea
pig
Not sensitizing
Kaolin, calcined Data not available or insufficient for classification Distillates (petroleum), hydrotreated middle Data not available or insufficient for classification Glycerin Guinea
pig
Not sensitizing
Ceramic materials and wares, chemicals Data not available or insufficient for classification Processed oil Human Some positive data exist, but the data are not
sufficient for classification Polyethylene glycol stearate Data not available or insufficient for classification Morpholine Guinea
pig
Not sensitizing
Conditioners Data not available or insufficient for classification Titanium dioxide Human
and animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Data not available or insufficient for classification Kaolin, calcined Data not available or insufficient for classification Distillates (petroleum), hydrotreated middle Data not available or insufficient for classification Glycerin Data not available or insufficient for classification Ceramic materials and wares, chemicals Data not available or insufficient for classification Processed oil Data not available or insufficient for classification Polyethylene glycol stearate Data not available or insufficient for classification Morpholine Data not available or insufficient for classification Conditioners Data not available or insufficient for classification Titanium dioxide Data not available or insufficient for classification
Germ Cell Mutagenicity
Name Route Value
Naphtha (petroleum), hydrotreated heavy In vivo Not mutagenic Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but the data are not
sufficient for classification Kaolin, calcined Data not available or insufficient for classification Distillates (petroleum), hydrotreated middle In Vitro Some positive data exist, but the data are not
sufficient for classification Glycerin Data not available or insufficient for classification Ceramic materials and wares, chemicals In Vitro Some positive data exist, but the data are not
sufficient for classification Processed oil In Vitro Not mutagenic Processed oil In vivo Not mutagenic Polyethylene glycol stearate Data not available or insufficient for classification Morpholine In Vitro Some positive data exist, but the data are not
sufficient for classification Morpholine In vivo Some positive data exist, but the data are not
sufficient for classification Conditioners Data not available or insufficient for classification Titanium dioxide In Vitro Not mutagenic Titanium dioxide In vivo Not mutagenic
Carcinogenicity
Name Route Species Value
Naphtha (petroleum), hydrotreated heavy Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Naphtha (petroleum), hydrotreated heavy Inhalation Human
and animal
Some positive data exist, but the data are not sufficient for classification
Kaolin, calcined Data not available or insufficient for classification Distillates (petroleum), hydrotreated middle Dermal Mouse Some positive data exist, but the data are not
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sufficient for classification
Glycerin Ingestion Mouse Some positive data exist, but the data are not
sufficient for classification
Ceramic materials and wares, chemicals Inhalation Multiple
animal species
Some positive data exist, but the data are not sufficient for classification
Processed oil Data not available or insufficient for classification Polyethylene glycol stearate Data not available or insufficient for classification Morpholine Ingestion Multiple
animal species
Not carcinogenic
Morpholine Inhalation Rat Not carcinogenic Conditioners Data not available or insufficient for classification Titanium dioxide Ingestion Multiple
animal species
Not carcinogenic
Titanium dioxide Inhalation Rat Carcinogenic.
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy Inhalation Not toxic to development Rat NOAEL 2.4
mg/l
during organogenesis
Kaolin, calcined Data not available or insufficient for
classification
Distillates (petroleum), hydrotreated middle Data not available or insufficient for
classification
Glycerin Ingestion Not toxic to female reproduction Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to male reproduction Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to development Rat NOAEL
2,000 mg/kg/day
2 generation
Ceramic materials and wares, chemicals Data not available or insufficient for
classification
Processed oil Ingestion Not toxic to female reproduction Rat NOAEL
4,800 mg/kg/day
13 weeks
Processed oil Ingestion Not toxic to male reproduction Rat NOAEL
4,800 mg/kg/day
13 weeks
Polyethylene glycol stearate Data not available or insufficient for
classification
Morpholine Data not available or insufficient for
classification
Conditioners Data not available or insufficient for
classification
Titanium dioxide Data not available or insufficient for
classification
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human and animal
NOAEL Not available
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
NOAEL Not available
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Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive data exist, but the
data are not sufficient for classification
Dog NOAEL 6.5
mg/l
4 hours
Distillates (petroleum), hydrotreated middle
Inhalation central nervous
system depression | respiratory irritation
Some positive data exist, but the data are not sufficient for classification
Not available
NOAEL NA
Distillates (petroleum), hydrotreated middle
Ingestion central nervous
system depression
May cause drowsiness or dizziness
Not available
NOAEL NA
Kaolin, calcined Data not available or insufficient
for classification
Glycerin Data not available or insufficient
for classification
Processed oil Data not available or insufficient
for classification Polyethylene glycol stearate
Data not available or insufficient
for classification Morpholine Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
NOAEL Not available
Conditioners Data not available or insufficient
for classification
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive data exist, but the
data are not sufficient for classification
Rat LOAEL 4.6
mg/l
6 months
Naphtha (petroleum), hydrotreated heavy
Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL 1.9
mg/l
13 weeks
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Multiple animal species
NOAEL 0.6 mg/l
90 days
Naphtha (petroleum), hydrotreated heavy
Inhalation bone, teeth, nails,
and/or hair | blood | liver | muscles
All data are negative Rat NOAEL 5.6
mg/l
12 weeks
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are negative Multiple
animal species
NOAEL 1.3 mg/l
90 days
Kaolin, calcined Data not available or insufficient
for classification Distillates (petroleum), hydrotreated middle
Data not available or insufficient
for classification Glycerin Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 3.91
mg/l
14 days
Glycerin Inhalation heart | liver | kidney
and/or bladder
All data are negative Rat NOAEL 3.91
mg/l
14 days
Glycerin Ingestion endocrine system |
hematopoietic system | liver | kidney and/or bladder
All data are negative Rat NOAEL
10,000 mg/kg/day
2 years
Ceramic materials and wares, chemicals
Inhalation pulmonary fibrosis Some positive data exist, but the
data are not sufficient for
classification
Multiple animal species
NOAEL not available
Ceramic materials and wares, chemicals
Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL not
available
occupational exposure
Processed oil Ingestion heart |
hematopoietic system | liver
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
4,800 mg/kg/day
13 weeks
Processed oil Ingestion kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Mouse NOAEL
13,000 mg/kg/day
13 weeks
Polyethylene glycol stearate
Data not available or insufficient
for classification
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Morpholine Dermal liver | kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Guinea pig
LOAEL 900 mg/kg/day
13 days
Morpholine Dermal hematopoietic
system
All data are negative Guinea
pig
NOAEL 900 mg/kg/day
13 days
Morpholine Inhalation eyes Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
occupational exposure
Morpholine Inhalation respiratory system May cause damage to organs
though prolonged or repeated
exposure
Rat NOAEL 0.09
mg/l
13 weeks
Morpholine Inhalation liver | kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 64
mg/l
5 days
Morpholine Inhalation heart | endocrine
system
All data are negative Rat NOAEL 0.9
mg/l
13 weeks
Morpholine Inhalation nervous system All data are negative Rat NOAEL 0.53
mg/l
104 weeks
Morpholine Ingestion kidney and/or
bladder
May cause damage to organs
though prolonged or repeated
exposure
Rat LOAEL 160
mg/kg/day
30 days
Morpholine Ingestion liver | respiratory
system
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 160
mg/kg/day
30 days
Morpholine Ingestion hematopoietic
system
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 800
mg/kg/day
30 days
Morpholine Ingestion endocrine system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 323
mg/kg/day
4 weeks
Conditioners Data not available or insufficient
for classification Titanium dioxide Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL
0.010 mg/l
2 years
Titanium dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not
available
occupational exposure
Aspiration Hazard
Name Value
Naphtha (petroleum), hydrotreated heavy Aspiration hazard Kaolin, calcined Not an aspiration hazard Distillates (petroleum), hydrotreated middle Aspiration hazard Glycerin Not an aspiration hazard Ceramic materials and wares, chemicals Not an aspiration hazard Processed oil Not an aspiration hazard Polyethylene glycol stearate Not an aspiration hazard Morpholine Not an aspiration hazard Conditioners Not an aspiration hazard Titanium dioxide Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
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No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
120109* Machining emulsions and solutions free of halogens
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Morpholine 110-91-8 Gr. 3: Not classifiable International Agency
for Research on Cancer
Titanium dioxide 13463-67-7 Grp. 2B: Possible human
carc.
International Agency for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification
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requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H400 Very toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.
List of relevant R-phrases
R10 Flammable. R20 Harmful by inhalation. R21 Harmful in contact with skin. R22 Harmful if swallowed. R34 Causes burns. R38 Irritating to skin. R50 Very toxic to aquatic organisms. R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 3: Composition/ Information of ingredients table information was modified. Copyright information was modified. Section 11: Acute Toxicity table information was modified. Section 6: Accidental release clean-up information information was modified. Section 7: Precautions safe handling information information was modified. Section 8: Personal Protection - Skin/hand information information was modified. Section 13: 13.1. Waste disposal note information was modified. Risk phrase information was added. Section 2: Indication of danger heading information was added. Section 2: Indication of danger information information was added. Label: Signal Word - Header information was added. Label: Signal Word information was added. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Label: CLP Classification information was added. Label: CLP Classification - Header information was added. Label: CLP Percent Unknown information was added. Label: CLP Percent Unknown information was added. Label: Graphic information was added.
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Label: Graphic information was added. Label: Symbol information was added. Label: Symbol information was added. Label: CLP Precautionary - Prevention information was added. Label: CLP Precautionary - Prevention - Header information was added. Label: CLP Precautionary - Response information was added. Label: CLP Precautionary - Response - Header information was added. Label: Precautionary Statement - Header information was added. Section 2: Notes on labelling heading information was added. Section 15: Label remarks and EU Detergent information was added. CLP Remark(phrase) information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Section 8: Personal Protection - Eye information information was added. Section 8: Personal Protection - Respiratory Information information was added. Section 2: H phrase reference information was added. Section 11: Disclosed components not in tables text information was added. Section 2: R phrase reference information was added. Label: Graphic information was added. Label: Graphic Text information was added. Section 8: Eye/face protection text information was deleted. Section 8: Respiratory protection - recommended respirators information was deleted. Section 8: Skin protection - protective clothing text information was deleted. Section 2.1: Classification information information was deleted. Risk phrase - None information was deleted. Section 02: Graphic information information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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