MEGUIAR'S M07 User Manual

M07, Show Car Glaze (XP3-131C): M0716, M0764
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-3393-7
Version number:
4.00
Revision date:
17/04/2014
Supersedes date:
28/11/2013
Transportation version number: 1.00 (20/07/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M07, Show Car Glaze (XP3-131C): M0716, M0764
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
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SIGNAL WORD
WARNING!
Symbols:
GHS07 (Exclamation mark) |
Pictograms
HAZARD STATEMENTS:
H315 Causes skin irritation.
PRECAUTIONARY STATEMENTS General:
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.
Prevention:
P260 Do not breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing.
Response:
P332 + P313 If skin irritation occurs: Get medical advice/attention. P331 Do NOT induce vomiting. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.
SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-
isothiazol-3-one. May produce an allergic reaction.
5% of the mixture consists of components of unknown acute oral toxicity.
Contains 20% of components with unknown hazards to the aquatic environment.
Notes on labelling
H304 is not required on the label due to the product's viscosity Nota P applied to CASRN 64742-48-9.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Not applicable
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota P applied to CASRN 64742-48-9.
2.3. Other hazards
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None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 50 - 70 Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
10 - 30 Xn:R65 - Nota 4,P (EU)
Xi:R38; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) Skin Irrit. 2, H315; STOT SE 3,
H336 (Self Classified) Diatomaceous Earth 61790-53-2 5 - 10 White mineral oil (petroleum) 8042-47-5 EINECS 232-
455-8
5 - 10 Xn:R65 (Self Classified)
Asp. Tox. 1, H304 (Self
Classified) Glycerin 56-81-5 EINECS 200-
289-5
3 - 7
Conditioners Trade Secret <= 5 Quartz 14464-46-1 EINECS 238-
455-4
< 0.5 Xn:R48/20 (Vendor)
STOT RE 2, H373 (Vendor) Quartz 14808-60-7 EINECS 238-
878-4
< 0.5 Xn:R48/20 (Vendor)
STOT RE 1, H372 (Self
Classified) Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;
R43 (EU)
Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
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medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Hydrocarbons. During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
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Do not use in a confined area with minimal air exchange. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Quartz 14464-46-1 Health and
Safety Comm. (UK)
TWA(respirable):0.1 mg/m3
Quartz 14808-60-7 Health and
Safety Comm. (UK)
TWA(respirable):0.1 mg/m3
Glycerin 56-81-5 Health and
Safety Comm. (UK)
TWA(as mist):10 mg/m3
Diatomaceous Earth 61790-53-2 Health and
Safety Comm. (UK)
TWA(as respirable dust):1.2 mg/m3
Silicon dioxide 61790-53-2 Health and
Safety Comm. (UK)
TWA(as inhalable dust):6 mg/m3
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety glasses with side shields.
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Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Sweet Odour; Yellow green
Odour threshold
No data available.
pH
5.50 - 6.50
Boiling point/boiling range
198.9 ºC
Melting point
No data available.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
> 93.3 ºC [Test Method:Closed Cup]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Relative density
0.96 g/cm3 [Ref Std:WATER=1]
Water solubility
Moderate
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
5 - 8 Pa-s
Density
0.96 g/ml
9.2. Other information
Volatile organic compounds (VOC)
14.47 %
Volatile organic compounds (VOC)
216.00 g/l
SECTION 10: Stability and reactivity
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10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin contact
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
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the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Naphtha (petroleum), hydrotreated heavy Inhalation-
Vapor
LC50 estimated to be 20 - 50 mg/l
Naphtha (petroleum), hydrotreated heavy Dermal Rabbit LD50 > 3,000 mg/kg Naphtha (petroleum), hydrotreated heavy Ingestion Rat LD50 > 5,000 mg/kg White mineral oil (petroleum) Dermal Rabbit LD50 > 2,000 mg/kg White mineral oil (petroleum) Ingestion Rat LD50 > 5,000 mg/kg Diatomaceous Earth Dermal Rabbit LD50 > 5,000 mg/kg Diatomaceous Earth Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 0.691 mg/l
Diatomaceous Earth Ingestion Rat LD50 > 5,110 mg/kg Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg Quartz Dermal LD50 estimated to be > 5,000 mg/kg Quartz Ingestion LD50 estimated to be > 5,000 mg/kg Quartz Ingestion LD50 estimated to be > 5,000 mg/kg Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Inhalation­Dust/Mist (4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Rabbit Irritant White mineral oil (petroleum) Rabbit No significant irritation Diatomaceous Earth Rabbit No significant irritation Glycerin Rabbit No significant irritation Quartz No significant irritation Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Rabbit No significant irritation White mineral oil (petroleum) Rabbit Mild irritant Diatomaceous Earth Rabbit No significant irritation Glycerin Rabbit No significant irritation Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Skin Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Guinea
pig
Not sensitizing
White mineral oil (petroleum) Guinea
pig
Not sensitizing
Diatomaceous Earth Human
and animal
Not sensitizing
Glycerin Guinea
pig
Not sensitizing
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Sensitising
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Photosensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Naphtha (petroleum), hydrotreated heavy In vivo Not mutagenic Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but the data are not
sufficient for classification White mineral oil (petroleum) In Vitro Not mutagenic Diatomaceous Earth In Vitro Not mutagenic Quartz In Vitro Some positive data exist, but the data are not
sufficient for classification Quartz In vivo Some positive data exist, but the data are not
sufficient for classification Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Naphtha (petroleum), hydrotreated heavy Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Naphtha (petroleum), hydrotreated heavy Inhalation Human
and animal
Some positive data exist, but the data are not sufficient for classification
White mineral oil (petroleum) Dermal Mouse Not carcinogenic White mineral oil (petroleum) Inhalation Multiple
animal species
Not carcinogenic
Diatomaceous Earth Not
specified.
Mouse Some positive data exist, but the data are not
sufficient for classification
Glycerin Ingestion Mouse Some positive data exist, but the data are not
sufficient for classification
Quartz Inhalation Human
and animal
Carcinogenic.
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Mouse Not carcinogenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy Inhalation Not toxic to development Rat NOAEL 2.4
mg/l
during
organogenesis
White mineral oil (petroleum) Ingestion Not toxic to female reproduction Rat NOAEL
4,350 mg/kg/day
13 weeks
White mineral oil (petroleum) Ingestion Not toxic to male reproduction Rat NOAEL
4,350 mg/kg/day
13 weeks
White mineral oil (petroleum) Ingestion Not toxic to development Rat NOAEL
4,350
during
gestation
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mg/kg/day
Diatomaceous Earth Ingestion Not toxic to female reproduction Rat NOAEL 509
mg/kg/day
1 generation
Diatomaceous Earth Ingestion Not toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Diatomaceous Earth Ingestion Not toxic to development Rat NOAEL
1,350 mg/kg/day
during
organogenesis
Glycerin Ingestion Not toxic to female reproduction Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to male reproduction Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to development Rat NOAEL
2,000 mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to female reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to male reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to development Rat NOAEL 15
mg/kg/day
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human and animal
NOAEL Not available
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
NOAEL Not available
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive data exist, but the
data are not sufficient for classification
Dog NOAEL 6.5
mg/l
4 hours
Mixture of 5-chloro-2­methyl-2H-isothiazol-3­one and 2-methyl-2H­isothiazol-3-one
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
similar health hazards
NOAEL Not available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive data exist, but the
data are not sufficient for classification
Rat LOAEL 4.6
mg/l
6 months
Naphtha (petroleum), hydrotreated heavy
Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL 1.9
mg/l
13 weeks
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Multiple animal species
NOAEL 0.6 mg/l
90 days
Naphtha (petroleum), hydrotreated heavy
Inhalation bone, teeth, nails,
and/or hair | blood | liver | muscles
All data are negative Rat NOAEL 5.6
mg/l
12 weeks
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are negative Multiple
animal species
NOAEL 1.3 mg/l
90 days
White mineral oil (petroleum)
Ingestion hematopoietic
system
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL
1,381 mg/kg/day
90 days
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White mineral oil (petroleum)
Ingestion liver | immune
system
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL
1,336 mg/kg/day
90 days
Diatomaceous Earth Inhalation respiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational exposure
Glycerin Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL 3.91
mg/l
14 days
Glycerin Inhalation heart | liver | kidney
and/or bladder
All data are negative Rat NOAEL 3.91
mg/l
14 days
Glycerin Ingestion endocrine system |
hematopoietic system | liver | kidney and/or bladder
All data are negative Rat NOAEL
10,000 mg/kg/day
2 years
Quartz Inhalation silicosis Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
occupational exposure
Aspiration Hazard
Name Value
Naphtha (petroleum), hydrotreated heavy Aspiration hazard White mineral oil (petroleum) Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Glycerin 56-81-5 Water flea Experimental 24 hours EC50 >10,000 mg/l Glycerin 56-81-5 Goldfish Experimental 24 hours LC50 >5,000 mg/l White mineral oil (petroleum)
8042-47-5 Bluegill Experimental 96 hours Lethal Level
50%
>100 mg/l
White mineral oil (petroleum)
8042-47-5 Water flea Experimental 21 days NOEC >100 mg/l
Diatomaceous Earth
61790-53-2 Data not
available or insufficient for
classification Naphtha (petroleum), hydrotreated heavy
64742-48-9 Data not
available or
insufficient for
classification Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2-
55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l
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methyl-2H­isothiazol-3­one Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l
Quartz 14464-46-1 Data not
available or
insufficient for
classification Quartz 14808-60-7 Data not
available or
insufficient for
classification
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Diatomaceous Earth
61790-53-2 Data not
available or insufficient for classification
N/A N/A N/A N/A
Glycerin 56-81-5 Experimental
Biodegradation
14 days BOD 63 % weight OECD 301C - MITI
test (I) White mineral oil (petroleum)
8042-47-5 Experimental
Biodegradation
28 days CO2 evolution 0 % weight OECD 301B -
Modified sturm or CO2 Naphtha (petroleum), hydrotreated heavy
64742-48-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
Mixture of 5­chloro-2­methyl-2H­isothiazol-3-
55965-84-9 Experimental
Biodegradation
28 days CO2 evolution 48 % weight Other methods
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one and 2­methyl-2H­isothiazol-3­one Quartz 14464-46-1 Data not
available or insufficient for classification
N/A N/A N/A N/A
Quartz 14808-60-7 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Diatomaceous Earth
61790-53-2 Data not
available or insufficient for classification
N/A N/A N/A N/A
Glycerin 56-81-5 Experimental
Bioconcentrati on
Log Kow -1.76 Other methods
White mineral oil (petroleum)
8042-47-5 Data not
available or insufficient for classification
N/A N/A N/A N/A
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Estimated
Bioconcentrati on
Log Kow 0.5 Other methods
Quartz 14464-46-1 Data not
available or insufficient for classification
N/A N/A N/A N/A
Quartz 14808-60-7 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
Ingredient CAS Nbr PBT/vPvB status White mineral oil (petroleum) 8042-47-5 Meets REACH PBT criteria
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12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 13* Solvents
SECTION 14: Transportation information
ADR: Not restricted for transport. IMDG: Not restricted for transport. IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Quartz 14464-46-1 Grp. 1: Carcinogenic to
humans
International Agency for Research on Cancer
Quartz 14808-60-7 Grp. 1: Carcinogenic to
humans
International Agency for Research on Cancer
Global inventory status
Contact manufacturer for more information
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
M07, Show Car Glaze (XP3-131C): M0716, M0764
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H301 Toxic if swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H331 Toxic if inhaled. H336 May cause drowsiness or dizziness. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R23 Toxic by inhalation. R24 Toxic in contact with skin. R25 Toxic if swallowed. R34 Causes burns. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R65 Harmful: May cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 16: List of relevant R phrase information information was modified. Section 3: Composition/ Information of ingredients table information was modified. Section 12: Component ecotoxicity information information was modified. Section 12: Persistence and Degradability information information was modified. Section 12:Bioccumulative potential information information was modified. Section 2: Label remarks information was modified. Section 1: Address information was modified. Copyright information was modified. Label: CLP Precautionary - General information was modified. Label: CLP Precautionary - Response information was modified. Section 15: Label remarks and EU Detergent information was modified. Section 8: Occupational exposure limit table information was modified. Section 11: Aspiration Hazard Table information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Serious Eye Damage/Irritation Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Skin Sensitization Table information was modified. Section 11: Reproductive Toxicity Table information was modified. Section 11: Skin Corrosion/Irritation Table information was modified. Section 11: Target Organs - Repeated Table information was modified. Section 11: Target Organs - Single Table information was modified. Section 5: Fire - Special hazards information information was modified. Section 6: Accidental release environmental information information was modified. Section 13: Standard Phrase Category Waste GHS information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. information was modified. Section 15: Carcinogenicity heading information was added. Section 15: Carcinogenicity information information was added.
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Section 15: Carcinogenicity table Regulation column heading information was added. Section 15: Carcinogenicity table Ingredient column heading information was added. Section 15: Carcinogenicity table CAS No column heading information was added. Section 15: Carcinogenicity table Classification column heading information was added. Section 11: Photosensitisation table - Name heading information was added. Section 11: Photosensitisation table heading information was added. Photosensitisation Table information was added. Section 11: Photosensitisation table - Species heading information was added. Section 11: Photosensitisation table - Value heading information was added. Not applicable information was added. Section 11: Disclosed components not in tables text information was added. Section 8: 8.1.1 Biological limit values table heading information was added. Section 8: BLV information was added. Safety phrase information was deleted. Section 2: Contains heading information was deleted. Section 2: Safety phrases heading information was deleted. Section 2: Risk phrases heading information was deleted. Section 2: Label ingredient information information was deleted. Label: CLP Percent Unknown information was deleted. Label: CLP Percent Unknown information was deleted. Section 11: Respiratory Sensitization Table information was deleted. Risk phrase - None information was deleted. Label: Graphic information was deleted. Section 02: Graphic information information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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