MEGUIAR'S M04 User Manual

M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 1 of 12
Safety Data Sheet
Copyright, 2011, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-6043-5
Version number:
1.01
Revision date:
05/12/2011
Supersedes date:
28/07/2011
Transportation version number: 1.00 (28/07/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
M04, Heavy Cut Cleaner (11-83B): M0416
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
No ingredients are assigned to the label.
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 2 of 12
Risk phrases
R67 Vapours may cause drowsiness and dizziness.
Safety phrases
S2 Keep out of the reach of children.
Notes on labelling
R65 is not required on the label due to the product's viscosity. Updated per Regulation (EC) 648/2004 on detergents.
Nota N applied for CASRN 64742-46-7.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non hazardous ingredient Mixture 50 - 70 Distillates (petroleum), hydrotreated light 64742-47-8 EINECS 265-
149-8
10 - 30 Xn:R65 - Nota 4,H (EU)
R66; R67 (Self Classified)
Asp. Tox. 1, H304 (CLP) STOT SE 3, H336 (Self
Classified) Aluminium oxide (REACH Reg. No.:01­2119529248-35)
1344-28-1 EINECS 215-
691-6
10 - 30
Conditioners Trade Secret < 5 Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
1 - 5 Nota H,N (EU)
Xn:R20-65; R66 (Self
Classified)
Nota H,N (CLP)
Acute Tox. 4, H332; Asp. Tox.
1, H304; STOT SE 3, H336 (Self
Classified) Sorbitan, (Z)-9-octadecenoate (2:3) 8007-43-0 EINECS 232-
360-1
0.5 - 1.5
Processed oil Trade Secret 0.5 - 1.5
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 3 of 12
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid breathing of dust created by cutting, sanding, grinding or machining. Vapours may travel long distances along the ground or floor to an ignition source and flash back. For industrial or professional use only. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 4 of 12
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Aluminium oxide 1344-28-1 Health and
Safety Comm. (UK)
TWA(as inhalable dust):10 mg/m³;TWA(as respirable dust):4 mg/m³
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapour cartridges and P2 particulate prefilters.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Sweet odour; White, viscous, semi-pourable liquid
pH
Not applicable.
Boiling point/boiling range
198.9 ºC
Melting point
Not applicable.
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 5 of 12
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
> 93.3 ºC [Test Method:Pensky-Martens Closed Cup] [Details:D93-90]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Moderate
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
7,000 - 16 Pa-s
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
16.15 % weight
VOC less H2O & exempt solvents
438.91 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Temperatures above the boiling point.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 6 of 12
relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Dust created by cutting, grinding, sanding, or machining may cause eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Contact with the skin during product use is not expected to result in significant irritation.
Inhalation
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, nose and throat pain.
Ingestion
No health effects are expected.
Toxicological Data
Acute Toxicity
Name Route Species Value UN GHS Classification
Aluminium oxide No data available Distillates (petroleum), hydrotreated light
No data available
Distillates (petroleum), hydrotreated middle
No data available
Processed oil No data available Sorbitan, (Z)-9-octadecenoate (2:3) No data available Conditioners No data available
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to be mild irritant
Category 3
Aluminium oxide No data available Distillates (petroleum), hydrotreated light No data available Distillates (petroleum), hydrotreated middle No data available Processed oil No data available Sorbitan, (Z)-9-octadecenoate (2:3) No data available Conditioners No data available
Serious Eye Damage/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to cause no significant irritation
Not classified
Aluminium oxide No data available Distillates (petroleum), hydrotreated light No data available Distillates (petroleum), hydrotreated middle No data available
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 7 of 12
Processed oil No data available Sorbitan, (Z)-9-octadecenoate (2:3) No data available Conditioners No data available
Skin Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Aluminium oxide No data available Distillates (petroleum), hydrotreated light No data available Distillates (petroleum), hydrotreated middle No data available Processed oil No data available Sorbitan, (Z)-9-octadecenoate (2:3) No data available Conditioners No data available
Respiratory Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Aluminium oxide No data available Distillates (petroleum), hydrotreated light No data available Distillates (petroleum), hydrotreated middle No data available Processed oil No data available Sorbitan, (Z)-9-octadecenoate (2:3) No data available Conditioners No data available
Germ Cell Mutagenicity
Name Route Value UN GHS Classification
Overall product No data available Overall Germ Cell Mutagenicity
classification Not classified Overall product No test data available. Aluminium oxide No data available Distillates (petroleum), hydrotreated light No data available Distillates (petroleum), hydrotreated middle No data available Processed oil No data available Sorbitan, (Z)-9-octadecenoate (2:3) No data available Conditioners No data available
Carcinogenicity
Name Route Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Aluminium oxide No data available Distillates (petroleum), hydrotreated light
No data available
Distillates (petroleum), hydrotreated middle
No data available
Processed oil No data available Sorbitan, (Z)-9-octadecenoate (2:3) No data available Conditioners No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
UN GHS Classification
Overall product No test data
available.
Not classified based on component data
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 8 of 12
Aluminium oxide No data available Distillates (petroleum), hydrotreated light
No data available
Distillates (petroleum), hydrotreated middle
No data available
Processed oil No data available Sorbitan, (Z)-9­octadecenoate (2:3)
No data available
Conditioners No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
UN GHS Classification
Aluminium oxide
No data
available Distillates (petroleum), hydrotreated light
No data
available
Distillates (petroleum), hydrotreated middle
No data
available
Processed oil No data
available Sorbitan, (Z)­9­octadecenoate (2:3)
No data
available
Conditioners No data
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
UN GHS Classification
Overall product
No test data
available.
Category 2 based on component
data Aluminium oxide
No data available
Distillates (petroleum), hydrotreated light
No data available
Distillates (petroleum), hydrotreated middle
No data available
Processed oil No data available Sorbitan, (Z)­9­octadecenoate (2:3)
No data available
Conditioners No data available
Aspiration Hazard
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 9 of 12
Name Value UN GHS Classification
Overall product No test data available. Not classified based on
component and/or viscosity
data Aluminium oxide Not an aspiration hazard Not classified Distillates (petroleum), hydrotreated light Not an aspiration hazard Not classified Distillates (petroleum), hydrotreated middle Not an aspiration hazard Not classified Processed oil Not an aspiration hazard Not classified Sorbitan, (Z)-9-octadecenoate (2:3) Not an aspiration hazard Not classified Conditioners Not an aspiration hazard Not classified
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered,stored,treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Proper destruction may require the use of
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 10 of 12
additional fuel during incineration processes.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Aqua Alumina Hydrotreated light petroleum distillates Solvent refined hydrotreated middle distillate Processed castor oil Sorbitan sesquioleate 9-Octadecenoic acid (Z)-, ester with 1,2,3,-propanetriol Polyglyceryl oleate Propylene glycol Diethylhexyl sodium sulfosuccinate Non-ionic surfactant Perfumes Magnesium nitrate Methylchloroisothiazolinone Copper-based stabilizers Magnesium chloride Methylisothiazolinone
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H304 May be fatal if swallowed and enters airways. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness.
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 11 of 12
List of relevant R-phrases
R20 Harmful by inhalation. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Risk phrase was modified. Safety phrase was modified. Section 9: pH information was modified. Section 9: Evaporation Rate information was modified. Section 9: Viscosity information was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 9: n-octanol/water coefficient information was modified. Section 9: Boiling point information was modified. Section 9: Relative density information was modified. Section 9: Solubility in water text was modified. Section 13: EU waste code (product as sold) information was modified. Section 9: Flammability (solid, gas) information was modified. Section 9: Explosive properties information was modified. Section 9: Oxidising properties information was modified. Section 2: Label remarks was modified. Copyright was modified. Section 9: Flash point information was modified. Section 9: Melting point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Vapour density value was modified. Section 9: Vapour pressure value was modified. Section 9: Density information was modified. Section 9: Property description for optional properties was modified. Section 1: Initial issue message was modified. Section 8: Occupational exposure limit table was modified. Section 8: mg/m³ key was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 11: Health Effects - Skin information was modified. Section 5: Hazardous combustion products table was modified. Section 7: Precautions safe handling information was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 13: Standard Phrase Category Waste GHS was modified. Section 4: First aid for ingestion (swallowing) information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 9: Autoignition temperature information was added.
M04, Heavy Cut Cleaner (11-83B): M0416
__________________________________________________________________________________________
Page: 12 of 12
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
Loading...