MEGUIAR'S G96 User Manual

G96, Multi-Purpose Cleaner (24-165A): G9624
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
31-8467-8
Version number:
6.00
Revision date:
11/07/2014
Supersedes date:
11/07/2014
Transportation version number: 1.00 (01/05/2013)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G96, Multi-Purpose Cleaner (24-165A): G9624
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Substance or Mixture Corrosive to Metals, Category 1 - Met. Corr. 1; H290 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Corrosion/Irritation, Category 1 - Skin Corr. 1; H314
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Corrosive; C; R34
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For full text of R phrases, see Section 16.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
DANGER!
Symbols:
GHS05 (Corrosion) |
Pictograms
HAZARD STATEMENTS:
H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage.
PRECAUTIONARY STATEMENTS General:
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.
Prevention:
P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280D Wear protective gloves, protective clothing, and eye/face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
Notes on labelling
Updated per Regulation (EC) No. 648/2004 on detergents. Ingredients required per 648/2004 (not required on industrial label): <5%: Non-ionic surfactant. Contains: Perfumes. H314 based on pH.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
G96, Multi-Purpose Cleaner (24-165A): G9624
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Corrosive
Contains:
Sodium Metasilicate
Risk phrases
R34 Causes burns.
Safety phrases
S23C Do not breathe vapour or spray. S51 Use only in well ventilated areas. S36/37/39B Wear suitable protective clothing, gloves, and eye and face protection. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28C After contact with skin, wash immediately with plenty of water for 15 minutes. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S1/2 Keep locked up and out of reach of children.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents. Ingredients required per 648/2004 (not required on industrial label): <5%: Non-ionic surfactant. Contains: Perfumes. R34 was applied based on test data.
2.3. Other hazards
May cause chemical gastrointestinal burns. May cause chemical respiratory tract burns.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 78 - 98 Sodium Metasilicate 6834-92-0 EINECS 229-
912-9
1 - 5 C:R34; Xi:R37 (EU)
Skin Corr. 1B, H314; STOT SE 3, H335 (CLP) Met. Corr. 1, H290 (Self Classified)
N,N-Dimethyldecylamine N-oxide 2605-79-0 EINECS 220-
020-5
0.1 - 1 Xi:R38-41 (Vendor) N:R50 (Self Classified)
Skin Irrit. 2, H315; Eye Dam. 1, H318 (Vendor) Aquatic Acute 1, H400,M=1; Aquatic Chronic 1, H410,M=1 (Self Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
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4.1. Description of first aid measures
Inhalation
Remove person to fresh air. Get immediate medical attention.
Skin contact
Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate medical attention. Wash clothing before reuse.
Eye contact
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention.
If swallowed
Rinse mouth. Do not induce vomiting. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion.
5.3. Advice for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. For large spills, if necessary, get assistance from professional spill clean up team. For small spills, carefully neutralise spill by adding appropriate dilute acid such as vinegar. Work slowly to avoid boiling or spattering. Continue to add neutralising agent until reaction stops. Let cool before collecting. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it
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appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Clean up residue with water. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Keep only in original container. Store in a corrosive resistant container with a resistant inner liner. Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full face shield. Indirect vented goggles.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
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Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl rubber. Nitrile rubber.
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Nitrile boots. Apron - polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Light yellow. Citrus odour.
Odour threshold
No data available.
pH
13
Boiling point/boiling range
No data available.
Melting point
No data available.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Flash point > 93 °C (200 °F)
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
1 [Ref Std:WATER=1]
Water solubility
Complete
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
No data available.
Density
1 g/ml
9.2. Other information
Volatile organic compounds (VOC)
0.5 %
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
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Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not agree with the EU material classification in Section 2 and/or the ingredient classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition, statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from 3M assessments.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract corrosion: Signs/symptoms may include nasal discharge, severe nose and throat pain, chest tightness and pain, coughing up blood, wheezing, and breathlessness, possibly progressing to respiratory failure.
Skin contact
Corrosive (skin burns): Signs/symptoms may include localised redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction.
Eye contact
Corrosive (eye burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision.
Ingestion
Gastrointestinal corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain, nausea, vomiting, and diarrhea; blood in the faeces and/or vomitus may also be seen.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
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Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Sodium Metasilicate Dermal Rabbit LD50 > 4,640 mg/kg Sodium Metasilicate Ingestion Rat LD50 500 mg/kg N,N-Dimethyldecylamine N-oxide Dermal LD50 estimated to be > 5,000 mg/kg N,N-Dimethyldecylamine N-oxide Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Sodium Metasilicate Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Sodium Metasilicate Rabbit Corrosive
Skin Sensitisation
Name Species Value
Sodium Metasilicate Mouse Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Sodium Metasilicate In Vitro Not mutagenic Sodium Metasilicate In vivo Not mutagenic
Carcinogenicity
Name Route Species Value
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Sodium Metasilicate Ingestion Some positive developmental data exist,
but the data are not sufficient for classification
Mouse NOAEL 200
mg/kg/day
during
gestation
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Sodium Metasilicate Inhalation respiratory irritation May cause respiratory irritation official
classifica tion
NOAEL Not available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Sodium Metasilicate Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Dog LOAEL
2,400 mg/kg/day
4 weeks
Sodium Metasilicate Ingestion endocrine system Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL 804
mg/kg/day
3 months
Sodium Metasilicate Ingestion blood All data are negative Rat NOAEL 804
mg/kg/day
3 months
Sodium Metasilicate Ingestion heart | liver All data are negative Rat NOAEL
1,259
8 weeks
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mg/kg/day
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not agree with the EU material classification in Section 2 and/or the ingredient classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition, statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from 3M assessments.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Sodium Metasilicate
6834-92-0 Water flea Estimated 48 hours EC50 1,700 mg/l
Sodium Metasilicate
6834-92-0 Rainbow trout Estimated 96 hours LC50 281 mg/l
N,N­Dimethyldecyl amine N-oxide
2605-79-0 Water flea Estimated 48 hours EC50 2.23 mg/l
N,N­Dimethyldecyl amine N-oxide
2605-79-0 Ricefish Estimated 96 hours LC50 29.9 mg/l
N,N­Dimethyldecyl amine N-oxide
2605-79-0 Green algae Estimated 72 hours EC50 0.129 mg/l
N,N­Dimethyldecyl amine N-oxide
2605-79-0 Water flea Estimated 21 days NOEC 0.36 mg/l
N,N­Dimethyldecyl amine N-oxide
2605-79-0 Green algae Estimated 72 hours NOEC 0.005 mg/l
12.2. Persistence and degradability
No test data available.
Material CAS Nbr Test type Duration Study Type Test result Protocol
Sodium Metasilicate
6834-92-0 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.3 : Bioaccumulative potential
No test data available.
Material CAS Nbr Test type Duration Study Type Test result Protocol
Sodium Metasilicate
6834-92-0 Data not
available or
N/A N/A N/A N/A
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insufficient for classification
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
070601* Aqueous washing liquids and mother liquors 20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR: UN3266 Corrosive Liquid, Basic, Inorganic, N.O.S. (Contains Sodium Metasilicate); 8; III; (E); C5 IMDG: UN3266 Corrosive Liquid, Basic, Inorganic, N.O.S. (Contains Sodium Metasilicate); 8; III; EmS: F-A, S-B IATA: UN3266 Corrosive Liquid, Basic, Inorganic, N.O.S. (Contains Sodium Metasilicate); 8; III
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical
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notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R34 Causes burns. R37 Irritating to respiratory system. R38 Irritating to skin. R41 Risk of serious damage to eyes. R50 Very toxic to aquatic organisms.
Revision information:
Revision Changes: Section 3: Composition/ Information of ingredients table information was modified. Section 12: Component ecotoxicity information information was modified. Section 16: List of relevant R phrase information information was modified. Section 3: Composition/ Information of ingredients table information was modified. Section 13: EU waste code (product as sold) information information was modified. Section 12: Component ecotoxicity information information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Classification disclaimer information was deleted. Section 12: Classification Warning information was deleted. Section 5: Fire - Advice for fire fighters information information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. information was modified. Section 12: Classification Warning information was added. Section 11: Classification disclaimer information was added.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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