MEGUIAR'S G82 User Manual

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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
29-9787-2
Version number:
1.01
Revision date:
07/07/2012
Supersedes date:
09/01/2012
Transportation version number: 1.00 (09/01/2012)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G82, Perfect Clarity Glass Cleaner (24-53D): G8224
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
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No ingredients are assigned to the label.
Risk phrases None. Safety phrases None.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents. Ingredients required per 648/2004: Contains: Perfumes, methylchloroisothiazolinone, methylisothiazolinone.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-hazardous ingredients Mixture 76 - 96 Propan-2-ol 67-63-0 EINECS 200-
661-7
1 - 5 F:R11; Xi:R36; R67 (EU)
Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336 (CLP)
2-Butoxyethanol 111-76-2 EINECS 203-
905-0
1 - 5 Xn:R20-21-22; Xi:R36-38 (EU)
Acute Tox. 3, H331; Acute Tox. 3, H311; Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2,
H319 (CLP) Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
No need for first aid is anticipated.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
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SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Place in a closed container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from heat. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
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Ingredient CAS Nbr Agency Limit type Additional comments
2-Butoxyethanol 111-76-2 Health and
Safety Comm. (UK)
TWA:123 mg/m3(25 ppm);STEL:246 mg/m3(50 ppm)
Skin Notation
Propan-2-ol 67-63-0 Health and
Safety Comm. (UK)
TWA:999 mg/m³(400 ppm);STEL:1250 mg/m³(500 ppm)
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Gloves made from the following material(s) are recommended: Butyl rubber. Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Sweet odour; off-white
pH
4.5 - 5.5
Boiling point/boiling range
No data available.
Melting point
No data available.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Flash point > 93 °C (200 °F)
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
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Vapour pressure
No data available.
Relative density
0.99 [Ref Std:WATER=1]
Water solubility
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
No data available.
Density
0.99 g/ml
9.2. Other information
Volatile organic compounds (VOC)
4.00 %
VOC less H2O & exempt solvents
802.04 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
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Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause target organ effects after ingestion.
Target Organ Effects:
Blood effects: Signs/symptoms may include generalised weakness and fatigue, skin pallor, changes in blood clotting time, internal bleeding, and hemoglobinemia.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg Propan-2-ol Dermal Rabbit LD50 12,870 mg/kg Propan-2-ol Inhalation-Vapor (4
hours)
Rat LC50 73 mg/l
Propan-2-ol Ingestion Rat LD50 4,710 mg/kg 2-Butoxyethanol Dermal Rabbit LD50 400 mg/kg 2-Butoxyethanol Inhalation-Vapor (4
hours)
Rat LC50 2 mg/l
2-Butoxyethanol Ingestion Rat LD50 530 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Propan-2-ol No significant irritation 2-Butoxyethanol Irritant
Serious Eye Damage/Irritation
Name Species Value
Propan-2-ol Moderate irritant 2-Butoxyethanol Severe irritant
Skin Sensitisation
Name Species Value
Propan-2-ol Not sensitizing 2-Butoxyethanol Not sensitizing
Respiratory Sensitisation
Name Species Value
Propan-2-ol No data available 2-Butoxyethanol No data available
Germ Cell Mutagenicity
Name Route Value
Propan-2-ol In vivo Not mutagenic 2-Butoxyethanol In Vitro Some positive data exist, but the data are not
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sufficient for classification
Carcinogenicity
Name Route Species Value
Propan-2-ol Not specified. Some positive data exist, but the data
are not sufficient for classification
2-Butoxyethanol Not specified. Some positive data exist, but the data
are not sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Propan-2-ol Ingestion Some positive
reproductive/develop mental data exist, but the data are not sufficient for classification
NOEL 400 mg/kg/day
Propan-2-ol Inhalation Some positive
reproductive/develop mental data exist, but the data are not sufficient for classification
LOEL 9,001 mg/m3
2-Butoxyethanol Dermal Not toxic to
reproduction and/or development
NOEL 1,760 mg/kg
2-Butoxyethanol Ingestion Some positive
reproductive/develop mental data exist, but the data are not sufficient for classification
NOAEL 100 mg/kg/day
2-Butoxyethanol Inhalation Some positive
reproductive/develop mental data exist, but the data are not sufficient for classification
NOAEL 50 ppm
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Propan-2-ol Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Propan-2-ol Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
RD50 5,000 ppm
Propan-2-ol Ingestion central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
2­Butoxyethano l
Dermal blood Some positive
data exist, but the data are not
NOAEL N/A
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sufficient for
classification 2­Butoxyethano l
Dermal liver Some positive
data exist, but the
data are not
sufficient for
classification
LOAEL 72 mg/kg
2­Butoxyethano l
Dermal endocrine
system
Some positive
data exist, but the
data are not
sufficient for
classification
LOEL 451 mg/kg
2­Butoxyethano l
Dermal kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
LOAEL 451 mg/kg
2­Butoxyethano l
Inhalation blood May cause
damage to organs
NOAEL N/A
2­Butoxyethano l
Inhalation central nervous
system depression
May cause
drowsiness or
dizziness
LOAEL 100 ppm
2­Butoxyethano l
Inhalation respiratory
irritation
Some positive
data exist, but the
data are not
sufficient for
classification
Irritation Positive
2­Butoxyethano l
Ingestion blood Causes damage to
organs
NOAEL N/A
2­Butoxyethano l
Ingestion central nervous
system depression | kidney and/or bladder
Some positive
data exist, but the
data are not
sufficient for
classification
LOAEL 530 mg/kg
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Propan-2-ol Inhalation auditory system Some positive
data exist, but the data are not sufficient for classification
LOEL 969 mg/m3
Propan-2-ol Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
NOEL 1.2 mg/l
Propan-2-ol Inhalation nervous system All data are
negative
NOEL 12 mg/l
Propan-2-ol Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
NOEL N/A
2­Butoxyethano l
Dermal blood Some positive
data exist, but the data are not sufficient for
NOAEL N/A
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classification 2­Butoxyethano l
Dermal endocrine
system
All data are
negative
NOEL 150 mg/kg/day
2­Butoxyethano l
Inhalation blood May cause
damage to organs
though prolonged
or repeated
exposure
NOAEL 0.12 mg/l
2­Butoxyethano l
Inhalation endocrine
system
Some positive
data exist, but the
data are not
sufficient for
classification
LOAEL 385 ppm
2­Butoxyethano l
Inhalation liver | kidney
and/or bladder
Some positive
data exist, but the
data are not
sufficient for
classification
NOEL 31 ppm
2­Butoxyethano l
Ingestion blood Causes damage to
organs through
prolonged or
repeated exposure
NOAEL N/A
2­Butoxyethano l
Ingestion kidney and/or
bladder
Some positive
data exist, but the
data are not
sufficient for
classification
NOAEL N/A
Aspiration Hazard
Name Value
Propan-2-ol Not an aspiration hazard 2-Butoxyethanol Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
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12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Incinerate in a permitted waste incineration facility. Dispose of waste product in a permitted industrial waste facility. Proper destruction may require the use of additional fuel during incineration processes.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
2-Butoxyethanol 111-76-2 Gr. 3: Not classifiable International Agency
for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
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List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
Aqua Butoxyethanol Isopropyl alcohol Perfumes Propylene glycol Diethylhexyl sodium sulfosuccinate Magnesium nitrate Methylchloroisothiazolinone Copper-based stabilizers Magnesium chloride Methylisothiazolinone
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H225 Highly flammable liquid and vapour. H302 Harmful if swallowed. H311 Toxic in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H336 May cause drowsiness or dizziness.
List of relevant R-phrases
R11 Highly flammable. R20 Harmful by inhalation. R21 Harmful in contact with skin. R22 Harmful if swallowed. R36 Irritating to eyes. R38 Irritating to skin. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 1: Product name was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 8: Respiratory protection - recommended respirators was modified. Page Heading: Product name was modified. Section 3: Composition/ Information of ingredients table was modified. Section 1: Initial issue message was modified. Section 8: Occupational exposure limit table was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified.
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Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 7: Precautions safe handling information was modified. Section 8: Respiratory protection - recommended respirators guide was added. Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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