MEGUIAR'S G77 User Manual

G77, Gold Class Spray Wax (22-66A): G7716

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Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

29-9121-4

Version number:

2.00

Revision date:

03/10/2014

Supersedes date:

23/07/2012

Transportation version number: 1.00 (18/01/2012)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

G77, Gold Class Spray Wax (22-66A): G7716

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Automotive.

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[email protected]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008

CLASSIFICATION:

This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification,
labelling, and packaging of substances and mixtures.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

This product is not classified as hazardous according to EU Directive 1999/45/EC.

2.2. Label elements

CLP REGULATION (EC) No 1272/2008

Not applicable

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SUPPLEMENTAL INFORMATION

Supplemental Hazard Statements:

EUH208 Contains Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-

isothiazolin-3-one (3:1). May produce an allergic reaction.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Not applicable

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non-Hazardous Ingredients Mixture 95 - 100
Conditioners Mixture < 5
Mixture of: 5-chloro-2-methyl-4­isothiazolin-3-one and 2-methyl-4­isothiazolin-3-one (3:1)

55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;

R43 (EU)

Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,

H410,M=10 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

No need for first aid is anticipated.

Skin contact

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

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SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Material will not burn. Use a fire fighting agent suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide. During combustion.
Carbon dioxide. During combustion.

5.3. Advice for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Ventilate the area with fresh air. Observe precautions from other sections.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled
material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with
water. Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilities

Store away from acids. Store away from oxidising agents.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.

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Biological limit values

No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.

8.2. Exposure controls

8.2.1. Engineering controls

No engineering controls required.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety glasses with side shields.

Skin/hand protection

No protective gloves required. No chemical protective gloves are required.

Respiratory protection

Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state

Liquid.

Appearance/Odour

Fruity odour clear liquid.

Odour threshold

No data available.

pH

6.85 - 7.35

Boiling point/boiling range

100 ºC

Melting point

No data available.

Flammability (solid, gas)

Not applicable.

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

No flash point

Autoignition temperature

No data available.

Flammable Limits(LEL)

No data available.

Flammable Limits(UEL)

No data available.

Vapour pressure

No data available.

Relative density

1 [Ref Std:WATER=1]

Water solubility

Complete

Solubility- non-water

No data available.

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

Vapour density

No data available.

Decomposition temperature

No data available.

Viscosity

No data available.

Density

1 g/ml

9.2. Other information

Volatile organic compounds (VOC)

0 %

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SECTION 10: Stability and reactivity

10.1 Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

Strong oxidising agents.
Strong acids.

10.6 Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

No health effects are expected.

Skin contact

Contact with the skin during product use is not expected to result in significant irritation.

Eye contact

Contact with the eyes during product use is not expected to result in significant irritation.

Ingestion

No health effects are expected.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

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Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2­methyl-4-isothiazolin-3-one (3:1)

Dermal Rabbit LD50 87 mg/kg

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2­methyl-4-isothiazolin-3-one (3:1)

Inhalation­Dust/Mist
(4 hours)

Rat LC50 0.33 mg/l

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2­methyl-4-isothiazolin-3-one (3:1)

Ingestion Rat LD50 40 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

Rabbit Corrosive

Serious Eye Damage/Irritation

Name Species Value

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

Rabbit Corrosive

Skin Sensitisation

Name Species Value

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

Human
and
animal

Sensitising

Photosensitisation

Name Species Value

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

Human
and
animal

Not sensitizing

Respiratory Sensitisation

Name Species Value

Germ Cell Mutagenicity

Name Route Value

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

In vivo Not mutagenic

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

In Vitro Some positive data exist, but the data are not

sufficient for classification

Carcinogenicity

Name Route Species Value

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl­4-isothiazolin-3-one (3:1)

Dermal Mouse Not carcinogenic

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl­4-isothiazolin-3-one (3:1)

Ingestion Rat Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure

Duration

Mixture of: 5-chloro-2-methyl-4­isothiazolin-3-one and 2-methyl-4­isothiazolin-3-one (3:1)

Ingestion Not toxic to female reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of: 5-chloro-2-methyl-4­isothiazolin-3-one and 2-methyl-4­isothiazolin-3-one (3:1)

Ingestion Not toxic to male reproduction Rat NOAEL 10

mg/kg/day

2 generation

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Mixture of: 5-chloro-2-methyl-4­isothiazolin-3-one and 2-methyl-4­isothiazolin-3-one (3:1)

Ingestion Not toxic to development Rat NOAEL 15

mg/kg/day

during

organogenesis

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Mixture of: 5-chloro-2­methyl-4-isothiazolin-3­one and 2-methyl-4­isothiazolin-3-one (3:1)

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

similar
health
hazards

NOAEL Not
available

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Aspiration Hazard

Name Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from
3M assessments.

12.1. Toxicity

No product test data available.

Material CAS Nbr Organism Type Exposure Test endpoint Test result

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4­isothiazolin-3­one (3:1)

55965-84-9 Diatom Experimental 72 NOEC 0.01 mg/l

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4­isothiazolin-3­one (3:1)

55965-84-9 Diatom Experimental 72 hours EC50 0.021 mg/l

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2-

55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l

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methyl-4­isothiazolin-3­one (3:1)

12.2. Persistence and degradability

No test data available.

Material CAS Nbr Test type Duration Study Type Test result Protocol

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4­isothiazolin-3­one (3:1)

55965-84-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

12.3 : Bioaccumulative potential

No test data available.

Material CAS Nbr Test type Duration Study Type Test result Protocol

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4­isothiazolin-3­one (3:1)

55965-84-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effects

No information available.

The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

See Section 11.1 Information on toxicological effects

This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations
to insure proper classification. Dispose of waste product in a permitted industrial waste facility. Empty and clean product
containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to determine
available options and requirements.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC -

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2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

20 01 30 Detergents other than those mentioned in 20 01 29.

SECTION 14: Transportation information

ADR/IMDG/IATA: Not restricted for transport.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Global inventory status

Contact manufacturer for more information The components of this material are in compliance with the China "Measures on
Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for
additional information. The components of this material are in compliance with the provisions of Australia National
Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling
division for additional information. The components of this material are in compliance with the provisions of Philippines RA
6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components
of this product are in compliance with the chemical notification requirements of TSCA.

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

List of relevant R-phrases

R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Revision information:

Revision Changes:
Section 3: Composition/ Information of ingredients table information was modified.
Section 13: EU waste code (product as sold) information information was modified.
Section 9: Flammability (solid, gas) information information was modified.
Section 15: Regulations - Inventories information was modified.
Section 1: Address information was modified.
Copyright information was modified.

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Section 11: Acute Toxicity table information was modified.
Section 11: Carcinogenicity Table information was modified.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Germ Cell Mutagenicity Table information was modified.
Section 11: Skin Sensitization Table information was modified.
Section 11: Reproductive Toxicity Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Target Organs - Single Table information was modified.
Section 5: Fire - Extinguishing media information information was modified.
Section 5: Fire - Advice for fire fighters information information was modified.
Section 6: Accidental release personal information information was modified.
Section 6: Accidental release environmental information information was modified.
Section 6: Accidental release clean-up information information was modified.
Section 7: Conditions safe storage information was modified.
Section 8: Appropriate Engineering controls information information was modified.
Section 8: Personal Protection - Eye information information was modified.
Section 8: Personal Protection - Skin/hand information information was modified.
Section 13: 13.1. Waste disposal note information was modified.
Section 4: First aid for eye contact information information was modified.
Section 4: First aid for ingestion (swallowing) information information was modified.
Section 8: Eye/face protection information information was added.
Section 16: List of relevant R-phrases information was added.
Section 16: List of relevant R phrase information information was added.
Section 12: Component ecotoxicity information information was added.
Section 12: Persistence and Degradability information information was added.
Section 12:Bioccumulative potential information information was added.
Section 12: Component Ecotoxicity table Material column header information was added.
Section 12: Component Ecotoxicity table CAS No column header information was added.
Section 12: Component Ecotoxicity table Organism column header information was added.
Section 12: Component Ecotoxicity table Type column header information was added.
Section 12: Component Ecotoxicity table Exposure column header information was added.
Section 12: Component Ecotoxicity table End point column header information was added.
Section 12: Component Ecotoxicity table Result column header information was added.
Section 12: Persistence and degradability table Material column header information was added.
Section 12: Persistence and degradability table CAS No column header information was added.
Section 12: Persistence and degradability table Test Type column header information was added.
Section 12: Persistence and degradability table Duration column header information was added.
Section 12: Persistence and degradability table Test Result column header information was added.
Section 12: Persistence and degradability table Protocol column header information was added.
Section 12:Bioccumulative potential table Material column header information was added.
Section 12:Bioccumulative potential table CAS No column header information was added.
Section 12:Bioccumulative potential table CAS No column header information was added.
Section 12:Bioccumulative potential table Test Result column header information was added.
Section 12:Bioccumulative potential table Protocol column header information was added.
Section 12:Bioccumulative potential table Test Type column header information was added.
Label: CLP Classification - Header information was added.
Label: CLP Classification information was added.
Label: CLP Supplemental Hazard Statements - Header information was added.
Label: CLP Supplemental Information - Header information was added.
Contains statement for sensitizers information was added.
Contains statement for sensitizers information was added.
Contains statement for sensitizers information was added.
Section 11: Photosensitisation table - Name heading information was added.
Section 11: Photosensitisation table heading information was added.
Photosensitisation Table information was added.
Section 11: Photosensitisation table - Species heading information was added.

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Section 11: Photosensitisation table - Value heading information was added.
Section 2: 2.2 & 2.3. CLP REGULATION heading information was added.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. information was added.
Section 16: List of relevant H statements heading information was added.
Section 12: Persistence and degradability table Study Type column header information was added.
Section 12:Bioccumulative potential table Test Type column header information was added.
Section 9: Odour Threshold information was added.
Section 9: Solubility (non-water) information was added.
Section 09: Decomposition Temperature information was added.
Not applicable information was added.
Not applicable information was added.
Section 10: Hazardous decomposition products during combustion text information was added.
Section 11: Disclosed components not in tables text information was added.
Section 12: Classification Warning information was added.
Section 11: Classification disclaimer information was added.
Section 8: 8.1.1 Biological limit values table heading information was added.
Section 8: BLV information was added.
List of sensitizers information was added.
Section 9: Flammability (solid, gas) information information was added.
Section 2: Contains heading information was deleted.
Section 2: Safety phrases heading information was deleted.
Section 2: Risk phrases heading information was deleted.
Section 2: Symbols heading information was deleted.
Section 15: Symbol information information was deleted.
Section 15: Symbol information information was deleted.
Section 2: Label ingredient information information was deleted.
Section 12: Acute aquatic hazard information information was deleted.
Section 12: Chronic aquatic hazard heading information was deleted.
Section 12: Acute aquatic hazard heading information was deleted.
Section 12: Chronic aquatic hazard information information was deleted.
Prints No Data if Component ecotoxicity information is not present information was deleted.
Section 11: Aspiration Hazard Table information was deleted.
Section 11: Classification disclaimer information was deleted.
Section 11: Respiratory Sensitization Table information was deleted.
Section 12: Classification Warning information was deleted.
Risk phrase - None information was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk