G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 1 of 11
Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
Document group:
31-9700-1
Version number:
3.00
Revision date:
11/08/2014
Supersedes date:
27/03/2014
Transportation version number: 1.00 (29/11/2013)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture
Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification,
labelling, and packaging of substances and mixtures.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
Not applicable
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 2 of 11
SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-
isothiazol-3-one. May produce an allergic reaction.
Notes on labelling
Updated per Regulation (EC) No. 648/2004 on detergents.
Ingredients required per 648/2004: 5-15%: Anionic surfactant. <5%: Amphoteric surfactant. Contains: Perfumes, d-limonene,
linalool, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1).
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Not applicable
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004: 5-15%: Anionic surfactant. <5%: Amphoteric surfactant. Contains: Perfumes, d-limonene,
linalool, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1).
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 70 - 90
Anionic surfactant Trade Secret 5 - 10
Amphoteric surfactant Trade Secret 1 - 5
Sodium Chloride 7647-14-5 EINECS 231-
598-3
0.5 - 1.5
2,4-Dihydroxybenzophenone 131-56-6 EINECS 205-
029-4
< 0.2 Xi:R36; N:R50/53 (Self
Classified)
Eye Irrit. 2, H319; Aquatic
Acute 1, H400,M=1; Aquatic
Chronic 1, H410,M=1 (Self
Classified)
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;
R43 (EU)
Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 3 of 11
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Material will not burn. Use a fire fighting agent suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition
source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS
for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled
material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 4 of 11
water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
Store away from heat.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect vented goggles.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 5 of 11
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Pleasantly fruity, sweet, clean smell; Bright yellow, viscous
liquid
Odour threshold
No data available.
pH
8 - 9.5
Boiling point/boiling range
No data available.
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
No flash point
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1 [Ref Std:WATER=1]
Water solubility
Complete
Solubility- non-water
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
No data available.
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
0 % weight
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
None known.
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 6 of 11
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye contact
Moderate eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Sodium Chloride Dermal Rabbit LD50 > 10,000 mg/kg
Sodium Chloride Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 10.5 mg/l
Sodium Chloride Ingestion Rat LD50 3,000 mg/kg
2,4-Dihydroxybenzophenone Ingestion Rat LD50 8,600 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
InhalationDust/Mist
(4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
2,4-Dihydroxybenzophenone Rabbit No significant irritation
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3- Rabbit Corrosive
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 7 of 11
one
Serious Eye Damage/Irritation
Name Species Value
2,4-Dihydroxybenzophenone Rabbit Severe irritant
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Rabbit Corrosive
Skin Sensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Human
and
animal
Sensitising
Photosensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Human
and
animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Dermal Mouse Not carcinogenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Ingestion Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
Ingestion Not toxic to female reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
Ingestion Not toxic to male reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
Ingestion Not toxic to development Rat NOAEL 15
mg/kg/day
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Mixture of 5-chloro-2methyl-2H-isothiazol-3one and 2-methyl-2Hisothiazol-3-one
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL Not
available
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 8 of 11
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from
3M assessments.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
2,4Dihydroxybenz
ophenone
131-56-6 Ricefish Estimated 96 hours LC50 3.8 mg/l
2,4Dihydroxybenz
ophenone
131-56-6 Green algae Estimated 72 hours EC50 0.67 mg/l
2,4Dihydroxybenz
ophenone
131-56-6 Water flea Estimated 24 hours EC50 0.28 mg/l
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2methyl-2Hisothiazol-3one
55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2methyl-2Hisothiazol-3one
55965-84-9 Diatom Experimental 72 hours EC50 0.021 mg/l
Sodium
Chloride
7647-14-5 Water flea Experimental 48 hours EC50 4,135 mg/l
Sodium
Chloride
7647-14-5 Fathead
minnow
Experimental 96 hours LC50 7,650 mg/l
Sodium
Chloride
7647-14-5 Algae or other
aquatic plants
Experimental 96 hours EC50 2,430 mg/l
2,4Dihydroxybenz
131-56-6 Green algae Analogous
Compound
72 hours NOEC 0.18 mg/l
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 9 of 11
ophenone
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2methyl-2Hisothiazol-3one
55965-84-9 Diatom Experimental 72 hours NOEC 0.01 mg/l
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
NonHazardous
Ingredients
Mixture Data not
available or
insufficient for
classification
N/A N/A N/A N/A
Sodium
Chloride
7647-14-5 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
2,4Dihydroxybenz
ophenone
131-56-6 Experimental
Biodegradation
28 days BOD 0 % weight OECD 301C - MITI
test (I)
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2methyl-2Hisothiazol-3one
55965-84-9 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
NonHazardous
Ingredients
Mixture Data not
available or
insufficient for
classification
N/A N/A N/A N/A
Sodium
Chloride
7647-14-5 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
2,4Dihydroxybenz
ophenone
131-56-6 Estimated BCF
- Other
70 days Bioaccumulati
on factor
160 Other methods
Mixture of 5chloro-2methyl-2Hisothiazol-3one and 2methyl-2Hisothiazol-3one
55965-84-9 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 10 of 11
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations
to insure proper classification. Dispose of waste product in a permitted industrial waste facility. Empty and clean product
containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to determine
available options and requirements.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC 2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 30 Detergents other than those mentioned in 20 01 29.
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the provisions of
Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply.
Contact the selling division for additional information. The components of this product are in compliance with the new
substance notification requirements of CEPA. The components of this product are in compliance with the chemical
notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164
__________________________________________________________________________________________
Page: 11 of 11
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Revision information:
Revision Changes:
Section 8: Eye/face protection information information was modified.
Section 16: List of relevant R phrase information information was modified.
Section 3: Composition/ Information of ingredients table information was modified.
Section 12: Component ecotoxicity information information was modified.
Section 12: Persistence and Degradability information information was modified.
Section 12:Bioccumulative potential information information was modified.
Section 1: Address information was modified.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 5: Fire - Extinguishing media information information was modified.
Section 5: Fire - Advice for fire fighters information information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. information was modified.
Section 12: Classification Warning information was added.
Section 11: Classification disclaimer information was added.
Section 11: Classification disclaimer information was deleted.
Section 12: Classification Warning information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
Loading...