G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 1 of 10
Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
Document group:
27-9368-5
Version number:
1.02
Revision date:
12/07/2012
Supersedes date:
21/02/2012
Transportation version number: 1.00 (20/07/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
G41, Natural Shine Protectant (21-127A): G4116, G4100
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture
Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 2 of 10
No ingredients are assigned to the label.
Risk phrases None.
Safety phrases None.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004: 5-15%: Aliphatic hydrocarbons. <5%: Non-ionic surfactant. Contains: Perfumes, hexyl
cinnam-aldehyde, citronellol, linalool, 2-(4-tert-butylbenzyl)propionaldehyde, d-limonene, methylchloroisothiazolinone,
methylisothiazolinone.
Nota N applied for CAS# 64742-46-7
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-hazardous ingredients Mixture 60 - 80
Siloxanes and silicones, di-Me 63148-62-9 7 - 13
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
5 - < 10 Nota N (EU)
Xn:R20-65; R66 (Self
Classified)
Nota N (CLP)
Acute Tox. 4, H332; Asp. Tox.
1, H304; STOT SE 3, H336;
EUH066 (Self Classified)
Conditioners Trade Secret < 5
Alcohols, C11-14-iso-, C13-rich,
ethoxylated
78330-21-9 0.5 - 1.5 Xn:R22; Xi:R41 (Self
Classified)
Acute Tox. 4, H302; Eye Dam.
1, H318 (Self Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 3 of 10
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde During combustion.
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled
material as possible. Clean up residue with detergent and water. Place in a closed container approved for transportation by
appropriate authorities. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or
smoke when using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
Store away from heat. Protect from sunlight.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 4 of 10
personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Wear eye/face protection.
The following eye protection(s) are recommended: Indirect vented goggles.
Skin/hand protection
Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Sweet fragrance; White, milky liquid
pH
9 - 9.8
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
215.6 ºC [Test Method:Pensky-Martens Closed Cup]
[Details:ASTM D93-90]
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
> 1 [Ref Std:AIR=1]
G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 5 of 10
Viscosity
1.5 - 2.5 Pa-s
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
0.20 % weight
VOC less H2O & exempt solvents
383.22 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
Light.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Skin contact
Contact with the skin during product use is not expected to result in significant irritation.
Inhalation
G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 6 of 10
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg
Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg
Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg
Distillates (petroleum), hydrotreated
middle
Dermal Rabbit LD50 > 2,000 mg/kg
Distillates (petroleum), hydrotreated
middle
Inhalation-Dust/Mist
(4 hours)
Rat LC50 5 mg/l
Distillates (petroleum), hydrotreated
middle
Ingestion Rat LD50 > 5,000 mg/kg
Alcohols, C11-14-iso-, C13-rich,
ethoxylated
Ingestion Rat LD50 1,350 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Siloxanes and silicones, di-Me Rabbit No significant irritation
Distillates (petroleum), hydrotreated middle Rabbit Minimal irritation
Alcohols, C11-14-iso-, C13-rich, ethoxylated Mild irritant
Serious Eye Damage/Irritation
Name Species Value
Siloxanes and silicones, di-Me Rabbit No significant irritation
Distillates (petroleum), hydrotreated middle Not available Mild irritant
Alcohols, C11-14-iso-, C13-rich, ethoxylated Severe irritant
Skin Sensitisation
Name Species Value
Siloxanes and silicones, di-Me No data available
Distillates (petroleum), hydrotreated middle No data available
Alcohols, C11-14-iso-, C13-rich, ethoxylated Some positive data exist, but the data are not
sufficient for classification
Respiratory Sensitisation
Name Species Value
Siloxanes and silicones, di-Me No data available
Distillates (petroleum), hydrotreated middle No data available
Alcohols, C11-14-iso-, C13-rich, ethoxylated No data available
Germ Cell Mutagenicity
Name Route Value
Siloxanes and silicones, di-Me No data available
Distillates (petroleum), hydrotreated middle In Vitro Some positive data exist, but the data are not
sufficient for classification
Alcohols, C11-14-iso-, C13-rich, ethoxylated No data available
Carcinogenicity
Name Route Species Value
G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 7 of 10
Siloxanes and silicones, di-Me No data available
Distillates (petroleum), hydrotreated
middle
Dermal Mouse Some positive data exist, but the data
are not sufficient for classification
Alcohols, C11-14-iso-, C13-rich,
ethoxylated
No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Siloxanes and
silicones, di-Me
No data available
Distillates
(petroleum),
hydrotreated middle
No data available
Alcohols, C11-14iso-, C13-rich,
ethoxylated
No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Siloxanes and
silicones, diMe
No data available
Distillates
(petroleum),
hydrotreated
middle
Inhalation central nervous
system
depression |
respiratory
irritation
Some positive
data exist, but the
data are not
sufficient for
classification
Not available NOAEL NA
Distillates
(petroleum),
hydrotreated
middle
Ingestion central nervous
system
depression
May cause
drowsiness or
dizziness
Not available NOAEL NA
Alcohols,
C11-14-iso-,
C13-rich,
ethoxylated
Inhalation respiratory
irritation
Some positive
data exist, but the
data are not
sufficient for
classification
Irritation
Positive
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Distillates
(petroleum),
hydrotreated
middle
No data available
Alcohols,
C11-14-iso-,
C13-rich,
ethoxylated
No data available
Aspiration Hazard
Name Value
Siloxanes and silicones, di-Me Not an aspiration hazard
Distillates (petroleum), hydrotreated middle Aspiration hazard
Alcohols, C11-14-iso-, C13-rich, ethoxylated Not an aspiration hazard
G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 8 of 10
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available.
No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations
to insure proper classification. Empty and clean product containers may be disposed as non-hazardous waste. Consult your
specific regulations and service providers to determine available options and requirements.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC 2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor
G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 9 of 10
EU waste code (product as sold)
20 01 30 Detergents other than those mentioned in 20 01 29.
SECTION 14: Transportation information
ADR / IMDG / IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004:
Aqua
Dimethicone
Solvent refined hydrotreated middle distillate
Conditioners
Alcohols, C11-14-iso-, C-13-rich, ethoxylated
Aminomethyl propanol
Perfumes
Poly(oxy-1,2-ethanediyl), .alpha.-[3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl].omega.-hydroxyPolymeric benzotriazole
Polyethylene glycol
Hexyl cinnam-aldehyde
Citronellol
Linalool
2-(4-tert-Butylbenzyl)propionaldehyde
d-Limonene
Magnesium nitrate
Sodium lauryl sulfate
Methylchloroisothiazolinone
Copper-based stabilizers
Magnesium chloride
Methylisothiazolinone
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
G41, Natural Shine Protectant (21-127A): G4116, G4100
__________________________________________________________________________________________
Page: 10 of 10
H336 May cause drowsiness or dizziness.
List of relevant R-phrases
R20 Harmful by inhalation.
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R65 Harmful: May cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
Revision information:
Revision Changes:
Section 1: Product name was modified.
Page Heading: Product name was modified.
Section 3: Composition/ Information of ingredients table was modified.
Section 13: EU waste code (product as sold) information was modified.
Aspiration Hazard Table was modified.
Section 11: Acute Toxicity table was modified.
Carcinogenicity Table was modified.
Serious Eye Damage/Irritation Table was modified.
Germ Cell Mutagenicity Table was modified.
Skin Sensitisation Table was modified.
Respiratory Sensitisation Table was modified.
Reproductive Toxicity Table was modified.
Skin Corrosion/Irritation Table was modified.
Target Organs - Repeated Table was modified.
Target Organs - Single Table was modified.
Section 11: Health Effects - Eye information was modified.
Section 7: Precautions safe handling information was modified.
Section 4: First aid for eye contact information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. was modified.
Section 8: Personal Protection - Eye information was added.
Section 8: Personal Protection - Respiratory Information was added.
Section 8: Respiratory protection information was deleted.
Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
Loading...