MEGUIAR'S G37 User Manual

G3700, Headlight Lens Correction Kit
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-9641-3
Version number:
3.00
Revision date:
25/02/2014
Supersedes date:
17/12/2013
Transportation version number: 1.00 (26/09/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
G3700, Headlight Lens Correction Kit
1.2. Relevant identified uses of the substance or mixture and uses advised against
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet for each of these components is included. Please do not separate the component Safety Data Sheets from this cover page. The document numbers of the MSDSs for components of this product are:
28-8996-2, 32-2083-7
TRANSPORTATION INFORMATION
ADR/IMDG/IATA: Not restricted for transport.
KIT LABEL
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
DANGER!
G3700, Headlight Lens Correction Kit
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Symbols:
GHS07 (Exclamation mark) | GHS08 (Health Hazard) |
Pictograms
HAZARD STATEMENTS:
H315 Causes skin irritation.
H372 Causes damage to organs through prolonged or repeated exposure:
nervous system
PRECAUTIONARY STATEMENTS General:
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.
Prevention:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
Response:
P332 + P313 If skin irritation occurs: Get medical advice/attention.
Disposal:
P501 Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
EUH208 Contains Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H- benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-
hydroxyphenyl]-1-oxopropyl]-ω-hydroxy-. | Polymeric benzotriazole. | Bis(1,2,2,6,6­pentamethyl-4-piperidinyl) sebacate. | Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2­methyl-2H-isothiazol-3-one.May produce an allergic reaction.
Notes on labelling
Nota N applied CAS 64742-46-7
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
Harmful
Contains:
Consult the component labels for disclosable ingredients.
Risk phrases
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
G3700, Headlight Lens Correction Kit
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Safety phrases
S23C Do not breathe vapour or spray. S51 Use only in well ventilated areas. S46 If swallowed, seek medical advice immediately and show this container or label. S2 Keep out of the reach of children.
Special provisions concerning the labelling of certain substances
Contains Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate. Contains polymeric benzotriazole. May produce an allergic reaction.
Notes on labelling
Nota N applied CAS 64742-46-7
Revision information:
Revision Changes: Copyright information was modified. Safety phrase information was added. Section 2: Risk phrase information information was added. Label: Signal Word - Header information was added. Label: Signal Word information was added. Label: CLP Classification information was added. Label: CLP Classification - Header information was added. Label: CLP Target Organ Hazard Statement information was added. Label: Graphic information was added. Label: Graphic information was added. Label: Symbol information was added. Label: Symbol information was added. Label: CLP Precautionary - Disposal information was added. Label: CLP Precautionary - Disposal - Header information was added. Label: CLP Precautionary - General information was added. Label: CLP Precautionary - General - Header information was added. Label: CLP Precautionary - Prevention information was added. Label: CLP Precautionary - Prevention - Header information was added. Label: CLP Precautionary - Response information was added. Label: CLP Precautionary - Response - Header information was added. Label: Precautionary Statement - Header information was added. Section 2: Notes on labelling heading information was added. Section 15: Label remarks and EU Detergent information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Label: Graphic information was added. Label: Graphic Text information was added. Remark (phrase) information was deleted. Section 15: Symbol information information was deleted. Section 02: Graphic information information was deleted.
G171, Headlight Protectant (XP4-137A): G17104
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-8996-2
Version number:
3.00
Revision date:
21/02/2014
Supersedes date:
27/11/2013
Transportation version number: 1.00 (23/09/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G171, Headlight Protectant (XP4-137A): G17104
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification, labelling, and packaging of substances and mixtures.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
G171, Headlight Protectant (XP4-137A): G17104
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SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH208 Contains Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H- benzotriazol-2-yl)-5-(1,1-
dimethylethyl)-4- hydroxyphenyl]-1-oxopropyl]-ω-hydroxy-. | Polymeric benzotriazole. | Bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate. | Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H-isothiazol-3-one. May produce an allergic reaction.
Notes on labelling
Nota N applied to CAS 64742-46-7.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
None.
Contains:
No ingredients are assigned to the label.
Risk phrases None. Safety phrases None.
Special provisions concerning the labelling of certain substances
Contains Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate. Contains polymeric benzotriazole. May produce an allergic reaction.
Notes on labelling
Nota N applied CAS 64742-46-7
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 60 - 80 Siloxanes and silicones, di-Me 63148-62-9 10 - 30 Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
5 - 10 Nota N (EU)
Xn:R20-65; R66 (Self Classified)
Nota N (CLP) Acute Tox. 4, H332; Asp. Tox. 1, H304; STOT SE 3, H336;
EUH066 (Self Classified) Acrylic polymer Trade Secret 1 - 5 Processed oil Trade Secret 1 - 5 Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H­benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4­hydroxyphenyl]-1-oxopropyl]-ω-hydroxy-
104810-48-2 0.1 - 1 N:R51/53; R43 (EU)
Skin Sens. 1, H317; Aquatic
G171, Headlight Protectant (XP4-137A): G17104
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Chronic 2, H411 (CLP) Polymeric benzotriazole 104810-47-1 0.1 - 1 N:R51/53; R43 (EU)
Skin Sens. 1, H317; Aquatic
Chronic 2, H411 (CLP) Bis(1,2,2,6,6-pentamethyl-4­piperidyl)sebacate
41556-26-7 EINECS 255-
437-1
0.1 - 1 N:R50/53; R43 (Self Classified)
Skin Sens. 1, H317; Aquatic
Acute 1, H400,M=1; Aquatic
Chronic 1, H410,M=1 (Self
Classified) Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;
R43 (EU)
Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish.
5.2. Special hazards arising from the substance or mixture
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Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (eg. gloves, respirators…) as required.
7.2. Conditions for safe storage including any incompatibilities
Protect from sunlight. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
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8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
Select and use respiratory protection to prevent an inhalation exposure based on the results of an exposure assessment. Consult with your respirator manufacturer for selection of appropriate types of respirators. Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Semi-pourable creamy gel; Pleasant odour
Odour threshold
No data available.
pH
8.5 - 9.5
Boiling point/boiling range
No data available.
Melting point
No data available.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
> 93.3 ºC
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Relative density
0.93 - 1.03 [Ref Std:WATER=1]
Water solubility
Complete
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
4 - 7 Pa-s
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Density
0.93 - 1.03 g/ml
9.2. Other information
Hazardous air pollutants
0.0000820 % weight [Test Method:Calculated]
Volatile organic compounds (VOC)
0.4 % weight [Test Method:calculated per CARB title 2]
Volatile organic compounds (VOC)
16 g/l [Test Method:calculated SCAQMD rule 443.1]
VOC less H2O & exempt solvents
5 g/l [Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong oxidising agents. Strong acids. Strong bases.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin contact
Contact with the skin during product use is not expected to result in significant irritation. Allergic skin reaction (non-photo
G171, Headlight Protectant (XP4-137A): G17104
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induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg Distillates (petroleum), hydrotreated middle Dermal Rabbit LD50 > 2,000 mg/kg Distillates (petroleum), hydrotreated middle Inhalation-
Dust/Mist (4 hours)
Rat LC50 4.6 mg/l
Distillates (petroleum), hydrotreated middle Ingestion Rat LD50 > 5,000 mg/kg Processed oil Ingestion LD50 estimated to be > 5,000 Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H- benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4- hydroxyphenyl]-1-oxopropyl]-ω-hydroxy-
Dermal Rat LD50 > 2,000 mg/kg
Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H- benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4- hydroxyphenyl]-1-oxopropyl]-ω-hydroxy-
Inhalation­Dust/Mist (4 hours)
Rat LC50 > 5.8 mg/l
Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H- benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4- hydroxyphenyl]-1-oxopropyl]-ω-hydroxy-
Ingestion Rat LD50 > 2,000 mg/kg
Polymeric benzotriazole Dermal Rat LD50 > 2,000 mg/kg Polymeric benzotriazole Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 5.8 mg/l
Polymeric benzotriazole Ingestion Rat LD50 > 2,000 mg/kg Bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate Ingestion Rat LD50 3,125 mg/kg Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Inhalation­Dust/Mist (4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Siloxanes and silicones, di-Me Rabbit No significant irritation Distillates (petroleum), hydrotreated middle Rabbit Minimal irritation Processed oil Human Minimal irritation Bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate Rabbit No significant irritation Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Siloxanes and silicones, di-Me Rabbit No significant irritation Distillates (petroleum), hydrotreated middle Not
available
Mild irritant
Processed oil Rabbit Mild irritant
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