MEGUIAR'S G3300 User Manual

G3300, Paint Restoration Kit

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Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

30-2515-2

Version number:

4.00

Revision date:

15/09/2014

Supersedes date:

15/09/2014

Transportation version number: 1.00 (24/01/2012)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING

1.1. Product identifier

G3300, Paint Restoration Kit

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Automotive.

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety
Data Sheet for each of these components is included. Please do not separate the component Safety Data Sheets from
this cover page. The document numbers of the MSDSs for components of this product are:

29-8038-1, 27-6190-6, 27-7631-8, 31-9700-1, 26-6709-5

TRANSPORTATION INFORMATION

ADR/IMDG/IATA: See Component SDS for transportation information.

KIT LABEL

2.2. Label elements

CLP REGULATION (EC) No 1272/2008

G3300, Paint Restoration Kit

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SIGNAL WORD

DANGER!

Symbols:

GHS07 (Exclamation mark) | GHS08 (Health Hazard) |

Pictograms

HAZARD STATEMENTS:

H315 Causes skin irritation.

H372 Causes damage to organs through prolonged or repeated exposure:

nervous system

PRECAUTIONARY STATEMENTS
General:

P102 Keep out of reach of children.
P101 If medical advice is needed, have product container or label at hand.

Prevention:

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

Response:

P332 + P313 If skin irritation occurs: Get medical advice/attention.

Disposal:

P501 Dispose of contents/container in accordance with applicable local/regional/national/international

regulations.

EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-

one.May produce an allergic reaction.

Refer to Safety Data Sheet for component % unknown values (www.3M.com/msds).

Notes on labelling

Nota P applied to CAS 8052-41-3. Nota N applied to CAS 64742-46-7.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Symbol(s)

Harmful

Contains:

Consult the component labels for disclosable ingredients.

Risk phrases

G3300, Paint Restoration Kit

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R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Safety phrases

S23C Do not breathe vapour or spray.
S51 Use only in well ventilated areas.
S24 Avoid contact with skin.
S46 If swallowed, seek medical advice immediately and show this container or label.
S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or

label.

S2 Keep out of the reach of children.

Notes on labelling

R65 is not required on the label due to the product's viscosity.

Nota P applied CASRN 8052-41-3. Nota N applied CASRN 64742-46-7.

Revision information:

Revision Changes:
Label: CLP Precautionary - General information was modified.
Label: Graphic information was added.
Label: Graphic Text information was added.
Section 02: Graphic information information was deleted.
Safety phrase information was modified.
Section 2: Risk phrase information information was modified.

G70, Gold Class Liquid Wax (22-169A): G7016

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Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

26-6709-5

Version number:

3.00

Revision date:

04/02/2014

Supersedes date:

29/11/2013

Transportation version number: 1.00 (08/07/2011)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

G70, Gold Class Liquid Wax (22-169A): G7016

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Automotive.

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008

CLASSIFICATION:

Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315
Specific Target Organ Toxicity-Repeated Exposure, Category 1 - STOT RE 1; H372

For full text of H phrases, see Section 16.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Indication of danger

Harmful; Xn; R48/20

For full text of R phrases, see Section 16.

G70, Gold Class Liquid Wax (22-169A): G7016

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2.2. Label elements

CLP REGULATION (EC) No 1272/2008

SIGNAL WORD

DANGER!

Symbols:

GHS07 (Exclamation mark) | GHS08 (Health Hazard) |

Pictograms

Ingredient CAS Nbr % by Wt
Solvent naphtha (petroleum), medium aliphatic 64742-88-7 10 - 30

HAZARD STATEMENTS:

H315 Causes skin irritation.

H372 Causes damage to organs through prolonged or repeated exposure: nervous system

PRECAUTIONARY STATEMENTS
General:

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.

Prevention:

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Response:

P332 + P313 If skin irritation occurs: Get medical advice/attention.
P331 Do NOT induce vomiting.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

Disposal:

P501 Dispose of contents/container in accordance with applicable local/regional/national/international

regulations.

SUPPLEMENTAL INFORMATION

Supplemental Hazard Statements:

EUH208 Contains Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-

isothiazolin-3-one (3:1). May produce an allergic reaction.

4% of the mixture consists of components of unknown acute oral toxicity.

Contains 34% of components with unknown hazards to the aquatic environment.

Notes on labelling

H304 is not required on the label due to the product's viscosity

G70, Gold Class Liquid Wax (22-169A): G7016

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Nota P applied to CAS 8052-41-3.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Symbol(s)

Harmful

Contains:

Solvent naphtha (petroleum), medium aliphatic

Risk phrases

R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Safety phrases

S23A Do not breathe vapour.
S51 Use only in well ventilated areas.
S24 Avoid contact with skin.
S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or

label.

S2 Keep out of the reach of children.

Notes on labelling

R65 is not required on the label due to the product's viscosity.

Nota P applied to CAS 8052-41-3.

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non-Hazardous Ingredients Mixture 50 - 70
Solvent naphtha (petroleum), medium
aliphatic

64742-88-7 EINECS 265-

191-7

10 - 30 Xn:R48/20; Xn:R65 (EU)

Xi:R38; R10 (Self Classified)

Asp. Tox. 1, H304; STOT RE 1,
H372 (CLP)
Flam. Liq. 3, H226; Skin Irrit. 2,
H315 (Self Classified)

Distillates (petroleum), hydrotreated light 64742-47-8 EINECS 265-

149-8

5 - 10 Xn:R65 - Nota 4 (EU)

R10; R66; R67 (Self Classified)

Asp. Tox. 1, H304 (CLP)
Flam. Liq. 3, H226; STOT SE 3,

H336; EUH066 (Self Classified)
Siloxanes and silicones, di-Me 63148-62-9 1 - 5
Ceramic materials and wares, chemicals 66402-68-4 EINECS 266-

340-9

1 - 5

Organic Salt (NJTSR# 04499600-6842) Trade Secret 1 - 5
Conditioners Trade Secret < 5

G70, Gold Class Liquid Wax (22-169A): G7016

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White mineral oil (petroleum) 8042-47-5 EINECS 232-

455-8

0.1 - 1.0 Xn:R65 (Self Classified)

Asp. Tox. 1, H304 (Self

Classified)
Stoddard solvent 8052-41-3 EINECS 232-

489-3

0.1 - 1 Xn:R48/20; Xn:R65 - Nota P
(EU)
Xi:R38 (Self Classified)

Asp. Tox. 1, H304; STOT RE 1,
H372 - Nota P (CLP)
Skin Irrit. 2, H315 (Self
Classified)

Mixture of: 5-chloro-2-methyl-4­isothiazolin-3-one and 2-methyl-4­isothiazolin-3-one (3:1)

55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;

R43 (EU)

Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)

Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

Remove person to fresh air. If you feel unwell, get medical attention.

Skin contact

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

In case of fire: Use a dry chemical extinguisher to extinguish.

G70, Gold Class Liquid Wax (22-169A): G7016

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5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Formaldehyde During combustion.
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.

5.3. Advice for fire-fighters

No unusual fire or explosion hazards are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and
health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic
absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not
remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed
container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a
qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and
Safety Data Sheet. Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Do not use in a confined area with minimal air exchange. Keep out of reach of children. Avoid breathing
dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilities

Store in a well-ventilated place. Keep container tightly closed. Store away from heat. Store away from acids. Store away
from oxidising agents.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

G70, Gold Class Liquid Wax (22-169A): G7016

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No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety glasses with side shields.

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Neoprene.

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state

Liquid.

Appearance/Odour

Pleasant odour; Creamy, off-white lotion

Odour threshold

No data available.

pH

6.8 - 8

Boiling point/boiling range

100 ºC

Melting point

Not applicable.

Flammability (solid, gas)

Not applicable.

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

Flash point > 93 °C (200 °F)

Autoignition temperature

No data available.

Flammable Limits(LEL)

No data available.

Flammable Limits(UEL)

No data available.

Vapour pressure

No data available.

Relative density

0.912 - 1 [Ref Std:WATER=1]

Water solubility

Slight (less than 10%)

Solubility- non-water

No data available.

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

G70, Gold Class Liquid Wax (22-169A): G7016

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Vapour density

> 1 [Ref Std:AIR=1]

Decomposition temperature

No data available.

Viscosity

13 - 25 Pa-s

Density

0.912 - 1 g/cm3

9.2. Other information

Volatile organic compounds (VOC)

14.90 % weight

VOC less H2O & exempt solvents

No data available.

SECTION 10: Stability and reactivity

10.1 Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

Heat.

10.5 Incompatible materials

Strong acids.
Strong oxidising agents.

10.6 Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain. May cause target organ effects after inhalation.

Skin contact

Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

G70, Gold Class Liquid Wax (22-169A): G7016

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Eye contact

Contact with the eyes during product use is not expected to result in significant irritation.

Ingestion

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
May cause target organ effects after ingestion.

Target Organ Effects:

Single exposure may cause:

Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Solvent naphtha (petroleum), medium aliphatic Inhalation-

Vapor

LC50 estimated to be 20 - 50 mg/l

Solvent naphtha (petroleum), medium aliphatic Dermal Rabbit LD50 > 3,000 mg/kg
Solvent naphtha (petroleum), medium aliphatic Ingestion Rat LD50 > 5,000 mg/kg
Distillates (petroleum), hydrotreated light Dermal Rabbit LD50 > 3,160 mg/kg
Distillates (petroleum), hydrotreated light Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 3.0 mg/l

Distillates (petroleum), hydrotreated light Ingestion Rat LD50 > 5,000 mg/kg
Ceramic materials and wares, chemicals Dermal LD50 estimated to be > 5,000 mg/kg
Ceramic materials and wares, chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg
Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg
Organic Salt (NJTSR# 04499600-6842) Data not available or insufficient for classification
Conditioners Data not available or insufficient for classification
Stoddard solvent Inhalation-

Vapor

LC50 estimated to be 20 - 50 mg/l

Stoddard solvent Dermal Rabbit LD50 > 3,000 mg/kg
Stoddard solvent Ingestion Rat LD50 > 5,000 mg/kg
White mineral oil (petroleum) Dermal Rabbit LD50 > 2,000 mg/kg
White mineral oil (petroleum) Ingestion Rat LD50 > 5,000 mg/kg
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2­methyl-4-isothiazolin-3-one (3:1)

Dermal Rabbit LD50 87 mg/kg

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2­methyl-4-isothiazolin-3-one (3:1)

Inhalation­Dust/Mist
(4 hours)

Rat LC50 0.33 mg/l

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2­methyl-4-isothiazolin-3-one (3:1)

Ingestion Rat LD50 40 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Solvent naphtha (petroleum), medium aliphatic Rabbit Irritant
Distillates (petroleum), hydrotreated light Rabbit Mild irritant
Ceramic materials and wares, chemicals Rabbit No significant irritation
Siloxanes and silicones, di-Me Rabbit No significant irritation
Organic Salt (NJTSR# 04499600-6842) Data not available or insufficient for classification
Conditioners Data not available or insufficient for classification
Stoddard solvent Rabbit Irritant
White mineral oil (petroleum) Rabbit No significant irritation
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

Rabbit Corrosive

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Serious Eye Damage/Irritation

Name Species Value

Solvent naphtha (petroleum), medium aliphatic Rabbit No significant irritation
Distillates (petroleum), hydrotreated light Rabbit Mild irritant
Ceramic materials and wares, chemicals Rabbit Mild irritant
Siloxanes and silicones, di-Me Rabbit No significant irritation
Organic Salt (NJTSR# 04499600-6842) Data not available or insufficient for classification
Conditioners Data not available or insufficient for classification
Stoddard solvent Rabbit No significant irritation
White mineral oil (petroleum) Rabbit Mild irritant
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

Rabbit Corrosive

Skin Sensitisation

Name Species Value

Solvent naphtha (petroleum), medium aliphatic Guinea

pig

Not sensitizing

Distillates (petroleum), hydrotreated light Guinea

pig

Not sensitizing

Ceramic materials and wares, chemicals Data not available or insufficient for classification
Siloxanes and silicones, di-Me Data not available or insufficient for classification
Organic Salt (NJTSR# 04499600-6842) Data not available or insufficient for classification
Conditioners Data not available or insufficient for classification
Stoddard solvent Guinea

pig

Not sensitizing

White mineral oil (petroleum) Guinea

pig

Not sensitizing

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

Human
and
animal

Sensitising

Photosensitisation

Name Species Value

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

Human
and
animal

Not sensitizing

Respiratory Sensitisation

Name Species Value

Solvent naphtha (petroleum), medium aliphatic Data not available or insufficient for classification
Distillates (petroleum), hydrotreated light Data not available or insufficient for classification
Ceramic materials and wares, chemicals Data not available or insufficient for classification
Siloxanes and silicones, di-Me Data not available or insufficient for classification
Organic Salt (NJTSR# 04499600-6842) Data not available or insufficient for classification
Conditioners Data not available or insufficient for classification
Stoddard solvent Data not available or insufficient for classification
White mineral oil (petroleum) Data not available or insufficient for classification
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

Data not available or insufficient for classification

Germ Cell Mutagenicity

Name Route Value

Solvent naphtha (petroleum), medium aliphatic In vivo Not mutagenic
Solvent naphtha (petroleum), medium aliphatic In Vitro Some positive data exist, but the data are not

sufficient for classification
Distillates (petroleum), hydrotreated light In Vitro Not mutagenic
Ceramic materials and wares, chemicals In Vitro Some positive data exist, but the data are not

sufficient for classification
Siloxanes and silicones, di-Me Data not available or insufficient for classification
Organic Salt (NJTSR# 04499600-6842) Data not available or insufficient for classification
Conditioners Data not available or insufficient for classification
Stoddard solvent In vivo Not mutagenic
Stoddard solvent In Vitro Some positive data exist, but the data are not

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sufficient for classification
White mineral oil (petroleum) In Vitro Not mutagenic
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

In vivo Not mutagenic

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin­3-one (3:1)

In Vitro Some positive data exist, but the data are not

sufficient for classification

Carcinogenicity

Name Route Species Value

Solvent naphtha (petroleum), medium aliphatic Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Solvent naphtha (petroleum), medium aliphatic Inhalation Human

and
animal

Some positive data exist, but the data are not
sufficient for classification

Distillates (petroleum), hydrotreated light Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Ceramic materials and wares, chemicals Inhalation Multiple

animal
species

Some positive data exist, but the data are not
sufficient for classification

Siloxanes and silicones, di-Me Data not available or insufficient for classification
Organic Salt (NJTSR# 04499600-6842) Data not available or insufficient for classification
Conditioners Data not available or insufficient for classification
Stoddard solvent Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Stoddard solvent Inhalation Human

and
animal

Some positive data exist, but the data are not
sufficient for classification

White mineral oil (petroleum) Dermal Mouse Not carcinogenic
White mineral oil (petroleum) Inhalation Multiple

animal
species

Not carcinogenic

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl­4-isothiazolin-3-one (3:1)

Dermal Mouse Not carcinogenic

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl­4-isothiazolin-3-one (3:1)

Ingestion Rat Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure

Duration

Solvent naphtha (petroleum), medium
aliphatic

Inhalation Not toxic to development Rat NOAEL 2.4

mg/l

during
organogenesis

Distillates (petroleum), hydrotreated light Data not available or insufficient for

classification

Ceramic materials and wares, chemicals Data not available or insufficient for

classification

Siloxanes and silicones, di-Me Data not available or insufficient for

classification

Organic Salt (NJTSR# 04499600-6842) Data not available or insufficient for

classification

Conditioners Data not available or insufficient for

classification

Stoddard solvent Inhalation Not toxic to development Rat NOAEL 2.4

mg/l

during
organogenesis

White mineral oil (petroleum) Ingestion Not toxic to female reproduction Rat NOAEL

4,350
mg/kg/day

13 weeks

White mineral oil (petroleum) Ingestion Not toxic to male reproduction Rat NOAEL

4,350
mg/kg/day

13 weeks

White mineral oil (petroleum) Ingestion Not toxic to development Rat NOAEL

4,350
mg/kg/day

during
gestation

Mixture of: 5-chloro-2-methyl-4­isothiazolin-3-one and 2-methyl-4­isothiazolin-3-one (3:1)

Ingestion Not toxic to female reproduction Rat NOAEL 10

mg/kg/day

2 generation

G70, Gold Class Liquid Wax (22-169A): G7016

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Mixture of: 5-chloro-2-methyl-4­isothiazolin-3-one and 2-methyl-4­isothiazolin-3-one (3:1)

Ingestion Not toxic to male reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of: 5-chloro-2-methyl-4­isothiazolin-3-one and 2-methyl-4­isothiazolin-3-one (3:1)

Ingestion Not toxic to development Rat NOAEL 15

mg/kg/day

during
organogenesis

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Solvent naphtha
(petroleum), medium
aliphatic

Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not
available

Solvent naphtha
(petroleum), medium
aliphatic

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not
available

Solvent naphtha
(petroleum), medium
aliphatic

Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Dog NOAEL 6.5

mg/l

4 hours

Distillates (petroleum),
hydrotreated light

Inhalation central nervous

system depression

May cause drowsiness or
dizziness

NOAEL Not

available
Distillates (petroleum),
hydrotreated light

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not

available

Ceramic materials and
wares, chemicals

Data not available or insufficient

for classification
Siloxanes and silicones, di­Me

Data not available or insufficient

for classification
Organic Salt (NJTSR#
04499600-6842)

Data not available or insufficient

for classification
Conditioners Data not available or insufficient

for classification
Stoddard solvent Inhalation central nervous

system depression

May cause drowsiness or

dizziness

Human
and
animal

NOAEL Not
available

Stoddard solvent Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for

classification

NOAEL Not
available

Stoddard solvent Inhalation nervous system Some positive data exist, but the

data are not sufficient for

classification

Dog NOAEL 6.5

mg/l

4 hours

White mineral oil
(petroleum)

Data not available or insufficient

for classification
Mixture of: 5-chloro-2­methyl-4-isothiazolin-3­one and 2-methyl-4­isothiazolin-3-one (3:1)

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for

classification

similar
health
hazards

NOAEL Not
available

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Solvent naphtha
(petroleum), medium
aliphatic

Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL 4.6

mg/l

6 months

Solvent naphtha
(petroleum), medium
aliphatic

Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat LOAEL 1.9

mg/l

13 weeks

Solvent naphtha
(petroleum), medium
aliphatic

Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL 0.6
mg/l

90 days

Solvent naphtha
(petroleum), medium
aliphatic

Inhalation bone, teeth, nails,

and/or hair | blood |
liver | muscles

All data are negative Rat NOAEL 5.6

mg/l

12 weeks

Solvent naphtha
(petroleum), medium

Inhalation heart All data are negative Multiple

animal

NOAEL 1.3
mg/l

90 days

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aliphatic species
Distillates (petroleum),
hydrotreated light

Data not available or insufficient

for classification
Ceramic materials and
wares, chemicals

Inhalation pulmonary fibrosis Some positive data exist, but the

data are not sufficient for

classification

Multiple
animal
species

NOAEL not
available

Ceramic materials and
wares, chemicals

Inhalation respiratory system Some positive data exist, but the

data are not sufficient for

classification

Human NOAEL not

available

occupational
exposure

Organic Salt (NJTSR#
04499600-6842)

Data not available or insufficient

for classification
Conditioners Data not available or insufficient

for classification
Stoddard solvent Inhalation nervous system Some positive data exist, but the

data are not sufficient for

classification

Rat LOAEL 4.6

mg/l

6 months

Stoddard solvent Inhalation kidney and/or

bladder

Some positive data exist, but the

data are not sufficient for

classification

Rat LOAEL 1.9

mg/l

13 weeks

Stoddard solvent Inhalation respiratory system Some positive data exist, but the

data are not sufficient for

classification

Multiple
animal
species

NOAEL 0.6
mg/l

90 days

Stoddard solvent Inhalation bone, teeth, nails,

and/or hair | blood |
liver | muscles

All data are negative Rat NOAEL 5.6

mg/l

12 weeks

Stoddard solvent Inhalation heart All data are negative Multiple

animal
species

NOAEL 1.3
mg/l

90 days

White mineral oil
(petroleum)

Ingestion hematopoietic

system

Some positive data exist, but the

data are not sufficient for

classification

Rat NOAEL

1,381
mg/kg/day

90 days

White mineral oil
(petroleum)

Ingestion liver | immune

system

Some positive data exist, but the

data are not sufficient for

classification

Rat NOAEL

1,336
mg/kg/day

90 days

Mixture of: 5-chloro-2­methyl-4-isothiazolin-3­one and 2-methyl-4­isothiazolin-3-one (3:1)

Data not available or insufficient

for classification

Aspiration Hazard

Name Value

Solvent naphtha (petroleum), medium aliphatic Aspiration hazard
Distillates (petroleum), hydrotreated light Aspiration hazard
Ceramic materials and wares, chemicals Not an aspiration hazard
Siloxanes and silicones, di-Me Not an aspiration hazard
Organic Salt (NJTSR# 04499600-6842) Not an aspiration hazard
Conditioners Not an aspiration hazard
Stoddard solvent Aspiration hazard
White mineral oil (petroleum) Aspiration hazard
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one
(3:1)

Not an aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.

12.1. Toxicity

G70, Gold Class Liquid Wax (22-169A): G7016

__________________________________________________________________________________________

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No product test data available.

Material CAS Nbr Organism Type Exposure Test endpoint Test result

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4­isothiazolin-3­one (3:1)

55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4­isothiazolin-3­one (3:1)

55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4­isothiazolin-3­one (3:1)

55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4­isothiazolin-3­one (3:1)

55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l

Conditioners Trade Secret Data not

available or
insufficient for

classification
Ceramic
materials and
wares,
chemicals

66402-68-4 Data not

available or

insufficient for

classification
Distillates
(petroleum),
hydrotreated
light

64742-47-8 Data not

available or

insufficient for

classification
Solvent
naphtha
(petroleum),
medium
aliphatic

64742-88-7 Data not

available or

insufficient for

classification

Siloxanes and
silicones, di-

63148-62-9 Data not

available or

G70, Gold Class Liquid Wax (22-169A): G7016

__________________________________________________________________________________________

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Me insufficient for

classification
Organic Salt
(NJTSR#
04499600-

6842)

Trade Secret Data not

available or

insufficient for

classification
Stoddard
solvent

8052-41-3 Data not

available or

insufficient for

classification
White mineral
oil (petroleum)

8042-47-5 Bluegill Experimental 96 hours Lethal Level

50%

>100 mg/l

White mineral
oil (petroleum)

8042-47-5 Water flea Experimental 21 days NOEC >100 mg/l

12.2. Persistence and degradability

Material CAS Nbr Test type Duration Study Type Test result Protocol

Siloxanes and
silicones, di­Me

63148-62-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Ceramic
materials and
wares,
chemicals

66402-68-4 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Distillates
(petroleum),
hydrotreated
light

64742-47-8 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Organic Salt
(NJTSR#
04499600-

6842)

Trade Secret Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Conditioners Trade Secret Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Solvent
naphtha
(petroleum),
medium
aliphatic

64742-88-7 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

White mineral
oil (petroleum)

8042-47-5 Experimental

Biodegradation

28 days CO2 evolution 0 % weight OECD 301B -

Modified sturm or CO2
Stoddard
solvent

8052-41-3 Estimated

Photolysis

Photolytic half­life (in air)

6.49 days (t
1/2)

Other methods

Stoddard
solvent

8052-41-3 Experimental

Biodegradation

28 days CO2 evolution 63 % weight OECD 301B -

Modified sturm or CO2
Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4-

55965-84-9 Experimental

Biodegradation

28 days CO2 evolution 48 % weight Other methods

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isothiazolin-3­one (3:1)

12.3 : Bioaccumulative potential

Material CAS Nbr Test type Duration Study Type Test result Protocol

Siloxanes and
silicones, di­Me

63148-62-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Ceramic
materials and
wares,
chemicals

66402-68-4 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Distillates
(petroleum),
hydrotreated
light

64742-47-8 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Organic Salt
(NJTSR#
04499600-

6842)

Trade Secret Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Conditioners Trade Secret Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Solvent
naphtha
(petroleum),
medium
aliphatic

64742-88-7 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

White mineral
oil (petroleum)

8042-47-5 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Stoddard
solvent

8052-41-3 Experimental

BCF - Other

Bioaccumulati
on factor

1944 Other methods

Mixture of: 5­chloro-2­methyl-4­isothiazolin-3­one and 2­methyl-4­isothiazolin-3­one (3:1)

55965-84-9 Estimated

Bioconcentrati
on

Log Kow 0.5 Other methods

12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

Ingredient CAS Nbr PBT/vPvB status
White mineral oil (petroleum) 8042-47-5 Meets REACH PBT criteria

12.6. Other adverse effects

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__________________________________________________________________________________________

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No information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

See Section 11.1 Information on toxicological effects

Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during
incineration processes. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

20 01 13* Solvents

SECTION 14: Transportation information

ADR/IMDG/IATA: Not restricted for transport.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Global inventory status

Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

EUH066 Repeated exposure may cause skin dryness or cracking.
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H336 May cause drowsiness or dizziness.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

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List of relevant R-phrases

R10 Flammable.
R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R38 Irritating to skin.
R43 May cause sensitisation by skin contact.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R65 Harmful: May cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

Revision information:

Revision Changes:
Section 8: Respiratory protection - recommended respirators information information was modified.
Safety phrase information was modified.
Section 3: Composition/ Information of ingredients table information was modified.
Section 12: Component ecotoxicity information information was modified.
Section 12: Persistence and Degradability information information was modified.
Section 12:Bioccumulative potential information information was modified.
Copyright information was modified.
Label: CLP Precautionary - General information was modified.
Label: CLP Precautionary - Prevention information was modified.
Label: CLP Precautionary - Response information was modified.
Aspiration Hazard Table information was modified.
Section 11: Acute Toxicity table information was modified.
Carcinogenicity Table information was modified.
Serious Eye Damage/Irritation Table information was modified.
Germ Cell Mutagenicity Table information was modified.
Skin Sensitisation Table information was modified.
Respiratory Sensitisation Table information was modified.
Reproductive Toxicity Table information was modified.
Skin Corrosion/Irritation Table information was modified.
Target Organs - Repeated Table information was modified.
Target Organs - Single Table information was modified.
Section 11: Health Effects - Skin information information was modified.
Section 6: Accidental release environmental information information was modified.
Section 7: Precautions safe handling information information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. information was modified.
List of sensitizers information was modified.
Section 2: Label remarks information was added.
Section 15: Label remarks and EU Detergent information was added.
Section 11: Photosensitisation table - Name heading information was added.
Section 11: Photosensitisation table heading information was added.
Photosensitisation Table information was added.
Section 11: Photosensitisation table - Species heading information was added.
Section 11: Photosensitisation table - Value heading information was added.
Section 11: Disclosed components not in tables text information was added.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the

G70, Gold Class Liquid Wax (22-169A): G7016

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product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk

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Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

27-6190-6

Version number:

4.00

Revision date:

15/09/2014

Supersedes date:

04/02/2014

Transportation version number: 1.00 (22/08/2011)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

A33, Quik Detailer (19-187B): A3316, A3332

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Automotive.

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008

CLASSIFICATION:

This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification,
labelling, and packaging of substances and mixtures.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

This product is not classified as hazardous according to EU Directive 1999/45/EC.

2.2. Label elements

CLP REGULATION (EC) No 1272/2008

Not applicable

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SUPPLEMENTAL INFORMATION

Supplemental Hazard Statements:

EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-

isothiazol-3-one. May produce an allergic reaction.

Notes on labelling

Updated per Regulation (EC) No. 648/2004 on detergents.
Ingredients required per 648/2004 (not required for industrial label): Contains: Perfumes, Mixture of
methylchloroisothiazolinone and methylisothiazolinone (3:1).

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Not applicable

Notes on labelling

Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004 (not required for industrial label): Contains: Perfumes, Mixture of
methylchloroisothiazolinone and methylisothiazolinone (3:1).

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non-Hazardous Ingredients Mixture 90 - 98
1-propoxypropan-2-ol 1569-01-3 EINECS 216-

372-4

0.5 - 1.5 Xi:R36; R10; R66; R67 (Self
Classified)

Flam. Liq. 3, H226; Eye Irrit. 2,
H319; STOT SE 3, H336;
EUH066 (Self Classified)

Propane-1,2-diol 57-55-6 EINECS 200-

338-0

0.5 - 1.5

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;

R43 (EU)

Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)

Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

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Remove person to fresh air. If you feel unwell, get medical attention.

Skin contact

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Material will not burn. Use a fire fighting agent suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Aldehydes. During combustion.
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.

5.3. Advice for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Ventilate the area with fresh air.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled
material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with
water. Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

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7.1. Precautions for safe handling

Do not use in a confined area with minimal air exchange. Keep out of reach of children. Avoid breathing
dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilities

Store away from acids. Store away from oxidising agents.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.

Ingredient CAS Nbr Agency Limit type Additional comments

Propane-1,2-diol 57-55-6 Health and

Safety Comm.
(UK)

TWA(as particulate):10
mg/m3;TWA(as total vapour
and particulates):474
mg/m3(150 ppm)

Health and Safety Comm. (UK) : UK Health and Safety Commission
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

Biological limit values

No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety glasses with side shields.

Skin/hand protection

No chemical protective gloves are required.

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:

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Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state

Liquid.

Appearance/Odour

Pleasant odour; Light milky blue, watery liquid

Odour threshold

No data available.

pH

7.5 - 8.5

Boiling point/boiling range

100 ºC

Melting point

Not applicable.

Flammability (solid, gas)

Not applicable.

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

No flash point

Autoignition temperature

Not applicable.

Flammable Limits(LEL)

Not applicable.

Flammable Limits(UEL)

Not applicable.

Relative density

1.0 [Ref Std:WATER=1]

Water solubility

Complete

Solubility- non-water

No data available.

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

Vapour density

No data available.

Decomposition temperature

No data available.

Viscosity

No data available.

Density

1 g/cm3

9.2. Other information

Volatile organic compounds (VOC)

1.32 % weight

SECTION 10: Stability and reactivity

10.1 Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

Strong acids.
Strong oxidising agents.

10.6 Hazardous decomposition products

Substance Condition

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None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin contact

Contact with the skin during product use is not expected to result in significant irritation.

Eye contact

Sprayed material may cause eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy
vision.

Ingestion

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
1-propoxypropan-2-ol Dermal Rabbit LD50 2,805 mg/kg
1-propoxypropan-2-ol Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 11.8 mg/l

1-propoxypropan-2-ol Ingestion Rat LD50 2,500 mg/kg
Propane-1,2-diol Dermal Rabbit LD50 20,800 mg/kg
Propane-1,2-diol Ingestion Rat LD50 22,000 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Rabbit LD50 87 mg/kg

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Inhalation­Dust/Mist
(4 hours)

Rat LC50 0.33 mg/l

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat LD50 40 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

1-propoxypropan-2-ol Rabbit Minimal irritation
Propane-1,2-diol Rabbit No significant irritation

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Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Rabbit Corrosive

Serious Eye Damage/Irritation

Name Species Value

1-propoxypropan-2-ol Rabbit Severe irritant
Propane-1,2-diol Rabbit No significant irritation
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Rabbit Corrosive

Skin Sensitisation

Name Species Value

Propane-1,2-diol Human Some positive data exist, but the data are not

sufficient for classification
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Sensitising

Photosensitisation

Name Species Value

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Not sensitizing

Respiratory Sensitisation

Name Species Value

Germ Cell Mutagenicity

Name Route Value

1-propoxypropan-2-ol In Vitro Not mutagenic
Propane-1,2-diol In Vitro Not mutagenic
Propane-1,2-diol In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In vivo Not mutagenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In Vitro Some positive data exist, but the data are not

sufficient for classification

Carcinogenicity

Name Route Species Value

Propane-1,2-diol Dermal Mouse Not carcinogenic
Propane-1,2-diol Ingestion Multiple

animal
species

Not carcinogenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Mouse Not carcinogenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure

Duration

1-propoxypropan-2-ol Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Rat NOAEL 3.6

mg/l

during

organogenesis

Propane-1,2-diol Ingestion Not toxic to female reproduction Mouse NOAEL

10,100
mg/kg/day

2 generation

Propane-1,2-diol Ingestion Not toxic to male reproduction Mouse NOAEL

10,100
mg/kg/day

2 generation

Propane-1,2-diol Ingestion Not toxic to development Multiple NOAEL during

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animal
species

1,230
mg/kg/day

organogenesis

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to female reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to male reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to development Rat NOAEL 15

mg/kg/day

during

organogenesis

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

1-propoxypropan-2-ol Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Multiple
animal
species

LOAEL 10.8
mg/l

6 hours

1-propoxypropan-2-ol Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not
available

1-propoxypropan-2-ol Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Rat LOAEL

1,770 mg/kg

not applicable

Propane-1,2-diol Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

poisoning

and/or abuse
Mixture of 5-chloro-2­methyl-2H-isothiazol-3­one and 2-methyl-2H­isothiazol-3-one

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

similar
health
hazards

NOAEL Not
available

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

1-propoxypropan-2-ol Inhalation liver | kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 9.5

mg/l

11 days

Propane-1,2-diol Ingestion hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Multiple
animal
species

NOAEL
1,370
mg/kg/day

117 days

Propane-1,2-diol Ingestion kidney and/or

bladder

All data are negative Dog NOAEL

5,000
mg/kg/day

104 weeks

Aspiration Hazard

Name Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from
3M assessments.

12.1. Toxicity

No product test data available.

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Material CAS Nbr Organism Type Exposure Test endpoint Test result

1­propoxypropan

-2-ol

1569-01-3 Water flea Experimental 48 hours EC50 >100 mg/l

1­propoxypropan

-2-ol

1569-01-3 Rainbow trout Experimental 96 hours LC50 >100 mg/l

1­propoxypropan

-2-ol

1569-01-3 Green algae Experimental 96 hours EC50 1,466 mg/l

Propane-1,2­diol

57-55-6 Green algae Experimental 96 hours EC50 19,000 mg/l

Propane-1,2­diol

57-55-6 Water flea Experimental 48 hours LC50 4,919 mg/l

Propane-1,2­diol

57-55-6 Fathead

minnow

Experimental 96 hours LC50 710 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l

12.2. Persistence and degradability

Material CAS Nbr Test type Duration Study Type Test result Protocol

1­propoxypropan

-2-ol

1569-01-3 Experimental

Biodegradation

20 days BOD 64 % weight Other methods

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Propane-1,2­diol

57-55-6 Experimental

Biodegradation

28 days BOD 90 % weight OECD 301C - MITI

test (I)
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Experimental

Biodegradation

28 days CO2 evolution 48 % weight Other methods

12.3 : Bioaccumulative potential

Material CAS Nbr Test type Duration Study Type Test result Protocol

1­propoxypropan

-2-ol

1569-01-3 Estimated

Bioconcentrati
on

Bioaccumulati
on factor

3 Estimated:

Bioconcentration factor

Propane-1,2­diol

57-55-6 Experimental

Bioaccumulati
on

Log Kow -0.92 Other methods

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Estimated

Bioconcentrati
on

Log Kow 0.5 Other methods

12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effects

No information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

See Section 11.1 Information on toxicological effects

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty and
clean product containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to
determine available options and requirements.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

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20 01 30 Detergents other than those mentioned in 20 01 29.

SECTION 14: Transportation information

ADR / IMDG / IATA: Not restricted for transport.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Global inventory status

Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

EUH066 Repeated exposure may cause skin dryness or cracking.
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

List of relevant R-phrases

R10 Flammable.
R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

Revision information:

Revision Changes:
Section 3: Composition/ Information of ingredients table information was modified.
Section 12: Component ecotoxicity information information was modified.
Section 12: Persistence and Degradability information information was modified.
Section 12:Bioccumulative potential information information was modified.
Section 1: Address information was modified.
Section 11: Acute Toxicity table information was modified.
Section 11: Carcinogenicity Table information was modified.

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Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Germ Cell Mutagenicity Table information was modified.
Section 11: Skin Sensitization Table information was modified.
Photosensitisation Table information was modified.
Section 11: Reproductive Toxicity Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Target Organs - Repeated Table information was modified.
Section 11: Target Organs - Single Table information was modified.
Section 11: Health Effects - Eye information information was modified.
Section 5: Fire - Extinguishing media information information was modified.
Section 5: Fire - Advice for fire fighters information information was modified.
Section 13: Standard Phrase Category Waste GHS information was modified.
List of sensitizers information was modified.
Section 8: Occupational exposure limit table information was added.
Not applicable information was added.
Not applicable information was added.
Section 12: Classification Warning information was added.
Section 11: Classification disclaimer information was added.
Section 8: 8.1.1 Biological limit values table heading information was added.
Section 8: BLV information was added.
Section 2: Contains heading information was deleted.
Section 2: Safety phrases heading information was deleted.
Section 2: Risk phrases heading information was deleted.
Section 15: Symbol information information was deleted.
Section 2: Label ingredient information information was deleted.
Section 11: Aspiration Hazard Table information was deleted.
Section 11: Classification disclaimer information was deleted.
Section 11: Respiratory Sensitization Table information was deleted.
Section 12: Classification Warning information was deleted.
Risk phrase - None information was deleted.
Label: Graphic information was deleted.
Section 02: Graphic information information was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk

Meguiar's Ultimate Compound, G172

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Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

27-7631-8

Version number:

5.00

Revision date:

11/08/2014

Supersedes date:

03/03/2014

Transportation version number: 1.00 (18/08/2010)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

Meguiar's Ultimate Compound, G172

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Automotive.

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008

CLASSIFICATION:

Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315
Specific Target Organ Toxicity-Repeated Exposure, Category 1 - STOT RE 1; H372

For full text of H phrases, see Section 16.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Indication of danger

Harmful; Xn; R48/20

For full text of R phrases, see Section 16.

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2.2. Label elements

CLP REGULATION (EC) No 1272/2008

SIGNAL WORD

DANGER!

Symbols:

GHS07 (Exclamation mark) | GHS08 (Health Hazard) |

Pictograms

Ingredient CAS Nbr % by Wt
NUC - Medium Aliphatic Solvent Naphtha 64742-88-7 7 - 13

HAZARD STATEMENTS:

H315 Causes skin irritation.

H372 Causes damage to organs through prolonged or repeated exposure: nervous system

PRECAUTIONARY STATEMENTS
General:

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.

Prevention:

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

Response:

P332 + P313 If skin irritation occurs: Get medical advice/attention.

Disposal:

P501 Dispose of contents/container in accordance with applicable local/regional/national/international

regulations.

SUPPLEMENTAL INFORMATION

Supplemental Hazard Statements:

EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-

isothiazol-3-one. May produce an allergic reaction.

13% of the mixture consists of components of unknown acute inhalation toxicity.
Contains 22% of components with unknown hazards to the aquatic environment.

Notes on labelling

H304 is not required on the label due to the product's viscosity
Nota N applied to CAS 64742-46-7.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

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Symbol(s)

Harmful

Contains:

NUC - Medium Aliphatic Solvent Naphtha

Risk phrases

R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Safety phrases

S23C Do not breathe vapour or spray.
S51 Use only in well ventilated areas.
S46 If swallowed, seek medical advice immediately and show this container or label.
S2 Keep out of the reach of children.

Notes on labelling

R65 is not required on the label due to the product's viscosity.

Nota N applied to CAS 64742-46-7.

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non-Hazardous Ingredients Trade Secret 60 - 90
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-

148-2

7 - 13 Nota N (EU)

Xn:R20-65; R66 (Self
Classified)

Nota N (CLP)
Acute Tox. 4, H332; Asp. Tox.
1, H304; STOT SE 3, H336;
EUH066 (Self Classified)

NUC - Medium Aliphatic Solvent Naphtha 64742-88-7 EINECS 265-

191-7

7 - 13 Xn:R48/20; Xn:R65 (EU)

Xi:R38; R10 (Self Classified)

Asp. Tox. 1, H304; STOT RE 1,
H372 (CLP)
Flam. Liq. 3, H226; Skin Irrit. 2,
H315 (Self Classified)

Aluminium Oxide 1344-28-1 EINECS 215-

691-6

1 - 10

Conditioners Trade Secret < 5
Glycerin 56-81-5 EINECS 200-

289-5

0.1 - 1.0

PEG Stearate 9004-99-3 0.1 - 1 N:R50 (Self Classified)

Aquatic Acute 1, H400,M=1;
Aquatic Chronic 3, H412 (Self

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Classified)

Triethanolamine 102-71-6 EINECS 203-

049-8

0.1 - 1.0

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;

R43 (EU)

Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,

H410,M=10 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

Remove person to fresh air. If you feel unwell, get medical attention.

Skin contact

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.

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5.3. Advice for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition
source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS
for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water.
Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on
clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising
agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilities

Store in a well-ventilated place. Keep container tightly closed. Store away from heat. Store away from acids. Store away
from strong bases. Store away from oxidising agents.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

Ingredient CAS Nbr Agency Limit type Additional comments

Aluminium Oxide 1344-28-1 Health and

Safety Comm.
(UK)

TWA(as inhalable dust):10
mg/m³;TWA(as respirable
dust):4 mg/m³

Glycerin 56-81-5 Health and

Safety Comm.
(UK)

TWA(as mist):10 mg/m3

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Health and Safety Comm. (UK) : UK Health and Safety Commission
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

Biological limit values

No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety glasses with side shields.

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl rubber.

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state

Liquid.

Appearance/Odour

Sweet hydrocarbon Odour; Creamy White

Odour threshold

No data available.

pH

8

Boiling point/boiling range

193.3 ºC

Melting point

No data available.

Flammability (solid, gas)

Not applicable.

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

> 93.3 ºC [Test Method:Closed Cup]

Autoignition temperature

No data available.

Flammable Limits(LEL)

No data available.

Flammable Limits(UEL)

No data available.

Relative density

1.18 [Ref Std:WATER=1]

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Water solubility

Moderate

Solubility- non-water

No data available.

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

Vapour density

No data available.

Decomposition temperature

No data available.

Viscosity

22 - 40 Pa-s

Density

1.18 g/ml

9.2. Other information

Volatile organic compounds (VOC)

10.80 %

Volatile organic compounds (VOC)

259.60 g/l

SECTION 10: Stability and reactivity

10.1 Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

Heat.

10.5 Incompatible materials

Strong acids.
Strong oxidising agents.
Strong bases.

10.6 Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose

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and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system:
Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, nose and throat pain. May cause target
organ effects after inhalation.

Skin contact

Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

Eye contact

Dust created by cutting, grinding, sanding, or machining may cause eye irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.

Ingestion

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
May cause target organ effects after ingestion.

Target Organ Effects:

Single exposure may cause:

Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Inhalation-

Dust/Mist(4
hr)

No data available; calculated ATE >12.5 mg/l

Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
NUC - Medium Aliphatic Solvent Naphtha Inhalation-

Vapor

LC50 estimated to be 20 - 50 mg/l

NUC - Medium Aliphatic Solvent Naphtha Dermal Rabbit LD50 > 3,000 mg/kg
Distillates (petroleum), hydrotreated middle Dermal Rabbit LD50 > 2,000 mg/kg
NUC - Medium Aliphatic Solvent Naphtha Ingestion Rat LD50 > 5,000 mg/kg
Distillates (petroleum), hydrotreated middle Inhalation-

Dust/Mist
(4 hours)

Rat LC50 4.6 mg/l

Distillates (petroleum), hydrotreated middle Ingestion Rat LD50 > 5,000 mg/kg
Aluminium Oxide Dermal LD50 estimated to be > 5,000 mg/kg
Aluminium Oxide Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 2.3 mg/l

Aluminium Oxide Ingestion Rat LD50 > 5,000 mg/kg
Triethanolamine Dermal Rabbit LD50 > 2,000 mg/kg
Triethanolamine Ingestion Rat LD50 9,000 mg/kg
Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg
Glycerin Ingestion Rat LD50 > 5,000 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Rabbit LD50 87 mg/kg

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Inhalation­Dust/Mist
(4 hours)

Rat LC50 0.33 mg/l

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat LD50 40 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

NUC - Medium Aliphatic Solvent Naphtha Rabbit Irritant

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Distillates (petroleum), hydrotreated middle Rabbit Minimal irritation
Aluminium Oxide Rabbit No significant irritation
Triethanolamine Rabbit Minimal irritation
Glycerin Rabbit No significant irritation
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Rabbit Corrosive

Serious Eye Damage/Irritation

Name Species Value

NUC - Medium Aliphatic Solvent Naphtha Rabbit No significant irritation
Distillates (petroleum), hydrotreated middle Not

available

Mild irritant

Aluminium Oxide Rabbit No significant irritation
Triethanolamine Rabbit Mild irritant
Glycerin Rabbit No significant irritation
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Rabbit Corrosive

Skin Sensitisation

Name Species Value

NUC - Medium Aliphatic Solvent Naphtha Guinea

pig

Not sensitizing

Triethanolamine Human Some positive data exist, but the data are not

sufficient for classification

Glycerin Guinea

pig

Not sensitizing

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Sensitising

Photosensitisation

Name Species Value

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Not sensitizing

Respiratory Sensitisation

Name Species Value

Germ Cell Mutagenicity

Name Route Value

NUC - Medium Aliphatic Solvent Naphtha In vivo Not mutagenic
NUC - Medium Aliphatic Solvent Naphtha In Vitro Some positive data exist, but the data are not

sufficient for classification

Distillates (petroleum), hydrotreated middle In Vitro Some positive data exist, but the data are not

sufficient for classification
Aluminium Oxide In Vitro Not mutagenic
Triethanolamine In Vitro Not mutagenic
Triethanolamine In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In vivo Not mutagenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In Vitro Some positive data exist, but the data are not

sufficient for classification

Carcinogenicity

Name Route Species Value

NUC - Medium Aliphatic Solvent Naphtha Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

NUC - Medium Aliphatic Solvent Naphtha Inhalation Human

and
animal

Some positive data exist, but the data are not
sufficient for classification

Distillates (petroleum), hydrotreated middle Dermal Mouse Some positive data exist, but the data are not

sufficient for classification

Aluminium Oxide Inhalation Rat Not carcinogenic

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Triethanolamine Dermal Multiple

animal
species

Not carcinogenic

Triethanolamine Ingestion Mouse Some positive data exist, but the data are not

sufficient for classification

Glycerin Ingestion Mouse Some positive data exist, but the data are not

sufficient for classification
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Mouse Not carcinogenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure

Duration

NUC - Medium Aliphatic Solvent Naphtha Inhalation Not toxic to development Rat NOAEL 2.4

mg/l

during

organogenesis

Triethanolamine Ingestion Not toxic to development Mouse NOAEL

1,125
mg/kg/day

during

organogenesis

Glycerin Ingestion Not toxic to female reproduction Rat NOAEL

2,000
mg/kg/day

2 generation

Glycerin Ingestion Not toxic to male reproduction Rat NOAEL

2,000
mg/kg/day

2 generation

Glycerin Ingestion Not toxic to development Rat NOAEL

2,000
mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to female reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to male reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to development Rat NOAEL 15

mg/kg/day

during

organogenesis

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

NUC - Medium Aliphatic
Solvent Naphtha

Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not
available

Distillates (petroleum),
hydrotreated middle

Inhalation central nervous

system depression |
respiratory irritation

Some positive data exist, but the
data are not sufficient for
classification

Not
available

NOAEL NA

NUC - Medium Aliphatic
Solvent Naphtha

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not
available

NUC - Medium Aliphatic
Solvent Naphtha

Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Dog NOAEL 6.5

mg/l

4 hours

Distillates (petroleum),
hydrotreated middle

Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Not
available

NOAEL NA

Mixture of 5-chloro-2­methyl-2H-isothiazol-3­one and 2-methyl-2H­isothiazol-3-one

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

similar
health
hazards

NOAEL Not
available

Specific Target Organ Toxicity - repeated exposure

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Name Route Target Organ(s) Value Species Test result Exposure

Duration

NUC - Medium Aliphatic
Solvent Naphtha

Inhalation nervous system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL 4.6

mg/l

6 months

NUC - Medium Aliphatic
Solvent Naphtha

Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat LOAEL 1.9

mg/l

13 weeks

NUC - Medium Aliphatic
Solvent Naphtha

Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL 0.6
mg/l

90 days

NUC - Medium Aliphatic
Solvent Naphtha

Inhalation bone, teeth, nails,

and/or hair | blood |
liver | muscles

All data are negative Rat NOAEL 5.6

mg/l

12 weeks

NUC - Medium Aliphatic
Solvent Naphtha

Inhalation heart All data are negative Multiple

animal
species

NOAEL 1.3
mg/l

90 days

Aluminium Oxide Inhalation pneumoconiosis |

pulmonary fibrosis

Some positive data exist, but the
data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Triethanolamine Dermal kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Multiple
animal
species

NOAEL
2,000
mg/kg/day

2 years

Triethanolamine Dermal liver Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL

4,000
mg/kg/day

13 weeks

Triethanolamine Ingestion kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat LOAEL

1,000
mg/kg/day

2 years

Triethanolamine Ingestion liver Some positive data exist, but the

data are not sufficient for
classification

Guinea
pig

NOAEL
1,600
mg/kg/day

24 weeks

Glycerin Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 3.91

mg/l

14 days

Glycerin Inhalation heart | liver | kidney

and/or bladder

All data are negative Rat NOAEL 3.91

mg/l

14 days

Glycerin Ingestion endocrine system |

hematopoietic
system | liver |
kidney and/or
bladder

All data are negative Rat NOAEL

10,000
mg/kg/day

2 years

Aspiration Hazard

Name Value

NUC - Medium Aliphatic Solvent Naphtha Aspiration hazard
Distillates (petroleum), hydrotreated middle Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from
3M assessments.

12.1. Toxicity

No product test data available.

Material CAS Nbr Organism Type Exposure Test endpoint Test result

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Glycerin 56-81-5 Water flea Experimental 24 hours EC50 >10,000 mg/l
Glycerin 56-81-5 Goldfish Experimental 24 hours LC50 >5,000 mg/l
Aluminium
Oxide

1344-28-1 Water flea Experimental 48 hours EC50 >100 mg/l

Aluminium
Oxide

1344-28-1 Green algae Experimental 72 hours EC50 >100 mg/l

Aluminium
Oxide

1344-28-1 Fish Experimental 96 hours LC50 >100 mg/l

Aluminium
Oxide

1344-28-1 Green algae Experimental 72 hours NOEC >100 mg/l

Distillates
(petroleum),
hydrotreated
middle

64742-46-7 Data not

available or
insufficient for

classification
PEG Stearate 9004-99-3 Water flea Estimated 48 hours EC50 0.72 mg/l
PEG Stearate 9004-99-3 Zebra Fish Estimated 96 hours LC50 0.65 mg/l
PEG Stearate 9004-99-3 Green algae Estimated 72 hours EC50 0.64 mg/l
PEG Stearate 9004-99-3 Green algae Estimated 72 hours NOEC 0.25 mg/l
NUC ­Medium
Aliphatic
Solvent
Naphtha

64742-88-7 Data not

available or

insufficient for

classification

Triethanolamine102-71-6 Green algae Experimental 72 hours EC50 216 mg/l

Triethanolamine102-71-6 Water flea Experimental 48 hours EC50 609.98 mg/l

Triethanolamine102-71-6 Goldfish Experimental 24 hours LC50 5,000 mg/l

Triethanolamine102-71-6 Water flea Experimental 21 days NOEC 16 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l

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Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l

12.2. Persistence and degradability

Material CAS Nbr Test type Duration Study Type Test result Protocol

Glycerin 56-81-5 Experimental

Biodegradation

14 days BOD 63 % weight OECD 301C - MITI

test (I)
Aluminium
Oxide

1344-28-1 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Distillates
(petroleum),
hydrotreated
middle

64742-46-7 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

PEG Stearate 9004-99-3 Estimated

Biodegradation

28 days CO2 evolution 85.3 % weight OECD 301B -

Modified sturm or CO2
NUC ­Medium
Aliphatic
Solvent
Naphtha

64742-88-7 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Triethanolamine102-71-6 Experimental

Biodegradation

19 days Dissolv.

Organic
Carbon Deplet

96 % weight 40CFR 796.3240-Mod.

OECD Scree

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Experimental

Biodegradation

28 days CO2 evolution 48 % weight Other methods

12.3 : Bioaccumulative potential

Material CAS Nbr Test type Duration Study Type Test result Protocol

Glycerin 56-81-5 Experimental

Bioconcentrati
on

Log Kow -1.76 Other methods

Aluminium
Oxide

1344-28-1 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Distillates
(petroleum),
hydrotreated
middle

64742-46-7 Estimated

Bioconcentrati
on

Log Kow 4.61 Estimated: Octanol-

water partition

coefficient

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PEG Stearate 9004-99-3 Estimated

Bioconcentrati
on

Bioaccumulati
on factor

5.5 Estimated:
Bioconcentration factor

NUC ­Medium
Aliphatic
Solvent
Naphtha

64742-88-7 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Triethanolamine102-71-6 Experimental

Bioaccumulati
on

Log Kow -2.3 Estimated: Octanol-

water partition
coefficient

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Estimated

Bioconcentrati
on

Log Kow 0.5 Other methods

12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effects

No information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

See Section 11.1 Information on toxicological effects

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a
permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

20 01 29* Detergents containing dangerous substances

SECTION 14: Transportation information

ADR: Not restricted for transport.
IMDG: Not restricted for transport.
IATA: Not restricted for transport.

SECTION 15: Regulatory information

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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Carcinogenicity

Ingredient CAS Nbr Classification Regulation

Triethanolamine 102-71-6 Gr. 3: Not classifiable International Agency

for Research on Cancer

Global inventory status

Contact manufacturer for more information The components of this material are in compliance with the China "Measures on
Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for
additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical
Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this
material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment
Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components
of this product are in compliance with the new substance notification requirements of CEPA. The components of this product
are in compliance with the chemical notification requirements of TSCA.

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

EUH066 Repeated exposure may cause skin dryness or cracking.
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

List of relevant R-phrases

R10 Flammable.
R20 Harmful by inhalation.
R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R38 Irritating to skin.
R43 May cause sensitisation by skin contact.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R50 Very toxic to aquatic organisms.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R65 Harmful: May cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.

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Revision information:

Revision Changes:
Section 2: Label ingredient information information was modified.
Section 3: Composition/ Information of ingredients table information was modified.
Section 12: Component ecotoxicity information information was modified.
Section 12: Persistence and Degradability information information was modified.
Section 12:Bioccumulative potential information information was modified.
Section 1: Address information was modified.
CLP: Ingredient table information was modified.
Section 8: Occupational exposure limit table information was modified.
Section 11: Aspiration Hazard Table information was modified.
Section 11: Acute Toxicity table information was modified.
Section 11: Carcinogenicity Table information was modified.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Germ Cell Mutagenicity Table information was modified.
Section 11: Skin Sensitization Table information was modified.
Photosensitisation Table information was modified.
Section 11: Reproductive Toxicity Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Target Organs - Repeated Table information was modified.
Section 11: Target Organs - Single Table information was modified.
Section 11: Health Effects - Eye information information was modified.
List of sensitizers information was modified.
Section 12: Classification Warning information was added.
Section 11: Classification disclaimer information was added.
Section 8: 8.1.1 Biological limit values table heading information was added.
Section 8: BLV information was added.
Section 11: Classification disclaimer information was deleted.
Section 12: Classification Warning information was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk

G10, Smooth Surface Clay Bar Replacement: G1001

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Page: 1 of 11

Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

29-8038-1

Version number:

3.00

Revision date:

11/08/2014

Supersedes date:

02/09/2013

Transportation version number: 1.00 (23/01/2012)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

G10, Smooth Surface Clay Bar Replacement: G1001

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Automotive.

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008

CLASSIFICATION:

This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification,
labelling, and packaging of substances and mixtures.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

This product is not classified as hazardous according to EU Directive 1999/45/EC.

2.2. Label elements

CLP REGULATION (EC) No 1272/2008

Not applicable

G10, Smooth Surface Clay Bar Replacement: G1001

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Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Not applicable

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Calcium Carbonate 471-34-1 EINECS 207-

439-9

40 - 60

Butene, homopolymer (products derived
from either/or But-1-ene/But-2-ene)

9003-29-6 NLP 500-004-7 20 - 40

NUC - Silica 7631-86-9 EINECS 231-

545-4

10 - 30

Talc 14807-96-6 EINECS 238-

877-9

10 30

Pigments Trade Secret < 5
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

No need for first aid is anticipated.

Skin contact

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Material will not burn. Non-combustible. Use a fire fighting agent suitable for surrounding fire.

5.2. Special hazards arising from the substance or mixture

G10, Smooth Surface Clay Bar Replacement: G1001

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None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide. During combustion.
Carbon dioxide. During combustion.

5.3. Advice for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Observe precautions from other sections.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate
authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid eye contact. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.

7.2. Conditions for safe storage including any incompatibilities

Store in a dry place.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

Ingredient CAS Nbr Agency Limit type Additional comments

Talc 14807-96-6 Health and

Safety Comm.
(UK)

TWA(as respirable dust):1
mg/m³

Limestone 471-34-1 Health and

Safety Comm.
(UK)

TWA(as inhalable dust):10
mg/m3;TWA(as respirable
dust):4
mg/m3;TWA(Inhalable):10
mg/m3;TWA(respirable):4
mg/m3

Silicon dioxide 7631-86-9 Health and TWA(as inhalable dust):6

G10, Smooth Surface Clay Bar Replacement: G1001

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Safety Comm.
(UK)

mg/m3;TWA(as respirable
dust):2.4 mg/m3

Health and Safety Comm. (UK) : UK Health and Safety Commission
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

Biological limit values

No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.

8.2. Exposure controls

8.2.1. Engineering controls

Not applicable.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety glasses with side shields.

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Nitrile rubber.

Respiratory protection

Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state

Solid.

Specific Physical Form:

Clay

Appearance/Odour

Typical odour; white

Odour threshold

No data available.

pH

Not applicable.

Boiling point/boiling range

Not applicable.

Melting point

No data available.

Flammability (solid, gas)

Not classified

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

No flash point

Autoignition temperature

No data available.

Flammable Limits(LEL)

No data available.

Flammable Limits(UEL)

No data available.

Vapour pressure

Not applicable.

Relative density

2 [Ref Std:WATER=1]

Water solubility

Nil

Solubility- non-water

No data available.

G10, Smooth Surface Clay Bar Replacement: G1001

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Partition coefficient: n-octanol/water

No data available.

Evaporation rate

Not applicable.

Vapour density

Not applicable.

Decomposition temperature

No data available.

Viscosity

Not applicable.

Density

2 g/ml

9.2. Other information

Volatile organic compounds (VOC)

0 %

SECTION 10: Stability and reactivity

10.1 Reactivity

This material is considered to be non reactive under normal use conditions

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

None known.

10.6 Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

No health effects are expected.

Skin contact

Prolonged or repeated exposure may cause:

Dermal Defatting: Signs/symptoms may include localised redness, itching, drying and cracking of skin.

G10, Smooth Surface Clay Bar Replacement: G1001

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Eye contact

Contact with the eyes during product use is not expected to result in significant irritation.

Ingestion

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and
diarrhoea.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Calcium Carbonate Dermal Rat LD50 > 2,000 mg/kg
Calcium Carbonate Inhalation-

Dust/Mist
(4 hours)

Rat LC50 3.0 mg/l

Calcium Carbonate Ingestion Rat LD50 6,450 mg/kg
Butene, homopolymer (products derived from either/or But-1­ene/But-2-ene)

Dermal Rat LD50 > 10,250 mg/kg

Butene, homopolymer (products derived from either/or But-1­ene/But-2-ene)

Ingestion Rat LD50 > 34,600 mg/kg

Talc Dermal LD50 Not available
Talc Ingestion LD50 Not available
NUC - Silica Dermal Rabbit LD50 > 5,000 mg/kg
NUC - Silica Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 0.691 mg/l

NUC - Silica Ingestion Rat LD50 > 5,110 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Calcium Carbonate Rabbit No significant irritation
Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene) Rabbit Minimal irritation
NUC - Silica Rabbit No significant irritation
Talc Rabbit No significant irritation

Serious Eye Damage/Irritation

Name Species Value

Calcium Carbonate Rabbit No significant irritation
Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene) Rabbit Mild irritant
NUC - Silica Rabbit No significant irritation
Talc Rabbit No significant irritation

Skin Sensitisation

Name Species Value

NUC - Silica Human

and
animal

Not sensitizing

Respiratory Sensitisation

Name Species Value

Talc Human Not sensitizing

Germ Cell Mutagenicity

Name Route Value

NUC - Silica In Vitro Not mutagenic
Talc In Vitro Not mutagenic
Talc In vivo Not mutagenic

G10, Smooth Surface Clay Bar Replacement: G1001

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Carcinogenicity

Name Route Species Value

NUC - Silica Not

specified.

Mouse Some positive data exist, but the data are not

sufficient for classification

Talc Inhalation Rat Some positive data exist, but the data are not

sufficient for classification

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure

Duration

Calcium Carbonate Ingestion Not toxic to development Rat NOAEL 625

mg/kg/day

premating &
during
gestation

NUC - Silica Ingestion Not toxic to female reproduction Rat NOAEL 509

mg/kg/day

1 generation

NUC - Silica Ingestion Not toxic to male reproduction Rat NOAEL 497

mg/kg/day

1 generation

NUC - Silica Ingestion Not toxic to development Rat NOAEL

1,350
mg/kg/day

during
organogenesis

Talc Ingestion Not toxic to development Rat NOAEL

1,600 mg/kg

during
organogenesis

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Calcium Carbonate Inhalation respiratory system All data are negative Rat NOAEL

0.812 mg/l

90 minutes

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Calcium Carbonate Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Butene, homopolymer
(products derived from
either/or But-1-ene/But-2­ene)

Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 0.07

mg/l

2 weeks

Butene, homopolymer
(products derived from
either/or But-1-ene/But-2­ene)

Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 0.7

mg/l

2 weeks

Talc Inhalation pneumoconiosis Causes damage to organs through

prolonged or repeated exposure

Human NOAEL Not

available

occupational
exposure

Talc Inhalation pulmonary fibrosis |

respiratory system

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 18

mg/m3

113 weeks

NUC - Silica Inhalation respiratory system |

silicosis

All data are negative Human NOAEL Not

available

occupational
exposure

Aspiration Hazard

Name Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

G10, Smooth Surface Clay Bar Replacement: G1001

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The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from
3M assessments.

12.1. Toxicity

No product test data available.

Material CAS Nbr Organism Type Exposure Test endpoint Test result

Butene,
homopolymer
(products
derived from
either/or But-1­ene/But-2-ene)

9003-29-6 Data not

available or
insufficient for
classification

NUC - Silica 7631-86-9 Data not

available or
insufficient for

classification
Calcium
Carbonate

471-34-1 Rainbow trout Experimental 21 days NOEC >100 mg/l

Calcium
Carbonate

471-34-1 Western

Mosquitofish

Experimental 96 hours LC50 >100 mg/l

Talc 14807-96-6 Data not

available or

insufficient for

classification

12.2. Persistence and degradability

Material CAS Nbr Test type Duration Study Type Test result Protocol

Butene,
homopolymer
(products
derived from
either/or But-1­ene/But-2-ene)

9003-29-6 Estimated

Biodegradation

28 days CO2 evolution <6.5 % weight OECD 301B -

Modified sturm or CO2

NUC - Silica 7631-86-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Calcium
Carbonate

471-34-1 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Talc 14807-96-6 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

12.3 : Bioaccumulative potential

Material CAS Nbr Test type Duration Study Type Test result Protocol

Butene, 9003-29-6 Estimated Bioaccumulati <83 Estimated:

G10, Smooth Surface Clay Bar Replacement: G1001

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homopolymer
(products
derived from
either/or But-1­ene/But-2-ene)

Bioconcentrati
on

on factor Bioconcentration factor

NUC - Silica 7631-86-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Calcium
Carbonate

471-34-1 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Talc 14807-96-6 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effects

No information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

See Section 11.1 Information on toxicological effects

This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations
to insure proper classification. Dispose of waste product in a permitted industrial waste facility. If no other disposal options
are available, waste product may be placed in a landfill properly designed for industrial waste.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

120199 Wastes not otherwise specified

SECTION 14: Transportation information

ADR/IMDG/IATA: Not restricted for transport.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Carcinogenicity

G10, Smooth Surface Clay Bar Replacement: G1001

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Ingredient CAS Nbr Classification Regulation

NUC - Silica 7631-86-9 Gr. 3: Not classifiable International Agency

for Research on Cancer

Talc 14807-96-6 Gr. 3: Not classifiable International Agency

for Research on Cancer

Global inventory status

Contact manufacturer for more information The components of this material are in compliance with the China "Measures on
Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for
additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical
Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this
material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment
Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components
of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may
apply. Contact the selling division for additional information. The components of this material are in compliance with the
provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional
information. The components of this product are in compliance with the new substance notification requirements of CEPA.
The components of this product are in compliance with the chemical notification requirements of TSCA.

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

Revision information:

Revision Changes:
Section 15: Carcinogenicity information information was modified.
Section 3: Composition/ Information of ingredients table information was modified.
Section 12: Component ecotoxicity information information was modified.
Section 12: Persistence and Degradability information information was modified.
Section 12:Bioccumulative potential information information was modified.
Section 1: Address information was modified.
Copyright information was modified.
Section 8: Occupational exposure limit table information was modified.
Section 11: Acute Toxicity table information was modified.
Section 11: Carcinogenicity Table information was modified.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Germ Cell Mutagenicity Table information was modified.
Section 11: Skin Sensitization Table information was modified.
Section 11: Respiratory Sensitization Table information was modified.
Section 11: Reproductive Toxicity Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Target Organs - Repeated Table information was modified.
Section 11: Target Organs - Single Table information was modified.
Section 5: Fire - Extinguishing media information information was modified.
Section 5: Fire - Advice for fire fighters information information was modified.
Section 8: Personal Protection - Eye information information was modified.
Section 8: Personal Protection - Skin/hand information information was modified.
Section 13: 13.1. Waste disposal note information was modified.
Section 13: Standard Phrase Category Waste GHS information was modified.
Label: CLP Classification - Header information was added.
Label: CLP Classification information was added.
Section 2: 2.2 & 2.3. CLP REGULATION heading information was added.
Not applicable information was added.
Not applicable information was added.

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Section 11: Disclosed components not in tables text information was added.
Section 12: Classification Warning information was added.
Section 11: Classification disclaimer information was added.
Section 8: 8.1.1 Biological limit values table heading information was added.
Section 8: BLV information was added.
Section 8: Eye/face protection text information was deleted.
Section 8: Skin protection - protective clothing text information was deleted.
Section 2: Contains heading information was deleted.
Section 2: Safety phrases heading information was deleted.
Section 2: Risk phrases heading information was deleted.
Section 15: Symbol information information was deleted.
Section 2: Label ingredient information information was deleted.
Section 8: mg/m³ key information was deleted.
Section 8: ppm key information was deleted.
Section 11: Aspiration Hazard Table information was deleted.
Section 11: Classification disclaimer information was deleted.
Section 12: Classification Warning information was deleted.
Risk phrase - None information was deleted.
Label: Graphic information was deleted.
Section 02: Graphic information information was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk

G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164

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Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

31-9700-1

Version number:

3.00

Revision date:

11/08/2014

Supersedes date:

27/03/2014

Transportation version number: 1.00 (29/11/2013)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Automotive.

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008

CLASSIFICATION:

This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification,
labelling, and packaging of substances and mixtures.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

This product is not classified as hazardous according to EU Directive 1999/45/EC.

2.2. Label elements

CLP REGULATION (EC) No 1272/2008

Not applicable

G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164

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SUPPLEMENTAL INFORMATION

Supplemental Hazard Statements:

EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-

isothiazol-3-one. May produce an allergic reaction.

Notes on labelling

Updated per Regulation (EC) No. 648/2004 on detergents.
Ingredients required per 648/2004: 5-15%: Anionic surfactant. <5%: Amphoteric surfactant. Contains: Perfumes, d-limonene,
linalool, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1).

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Not applicable

Notes on labelling

Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004: 5-15%: Anionic surfactant. <5%: Amphoteric surfactant. Contains: Perfumes, d-limonene,
linalool, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1).

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non-Hazardous Ingredients Mixture 70 - 90
Anionic surfactant Trade Secret 5 - 10
Amphoteric surfactant Trade Secret 1 - 5
Sodium Chloride 7647-14-5 EINECS 231-

598-3

0.5 - 1.5

2,4-Dihydroxybenzophenone 131-56-6 EINECS 205-

029-4

< 0.2 Xi:R36; N:R50/53 (Self

Classified)

Eye Irrit. 2, H319; Aquatic
Acute 1, H400,M=1; Aquatic
Chronic 1, H410,M=1 (Self

Classified)
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;

R43 (EU)

Acute Tox. 3, H331; Acute Tox.

3, H311; Acute Tox. 3, H301;

Skin Corr. 1B, H314; Skin Sens.

1A, H317; Aquatic Acute 1,

H400,M=10; Aquatic Chronic 1,

H410,M=10 (CLP)

Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

G71, Gold Class Car Wash Shampoo & Conditioner (24-141C): G7101, G7116, G7164

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4.1. Description of first aid measures

Inhalation

Remove person to fresh air. If you feel unwell, get medical attention.

Skin contact

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Material will not burn. Use a fire fighting agent suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.

5.3. Advice for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition
source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS
for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled
material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with

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water. Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid eye contact. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.

7.2. Conditions for safe storage including any incompatibilities

Store away from heat.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.

Biological limit values

No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect vented goggles.

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Nitrile rubber.

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator

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type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state

Liquid.

Appearance/Odour

Pleasantly fruity, sweet, clean smell; Bright yellow, viscous
liquid

Odour threshold

No data available.

pH

8 - 9.5

Boiling point/boiling range

No data available.

Melting point

Not applicable.

Flammability (solid, gas)

Not applicable.

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

No flash point

Autoignition temperature

Not applicable.

Flammable Limits(LEL)

Not applicable.

Flammable Limits(UEL)

Not applicable.

Vapour pressure

No data available.

Relative density

1 [Ref Std:WATER=1]

Water solubility

Complete

Solubility- non-water

Complete

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

Vapour density

No data available.

Decomposition temperature

No data available.

Viscosity

No data available.

Density

1 g/cm3

9.2. Other information

Volatile organic compounds (VOC)

0 % weight

SECTION 10: Stability and reactivity

10.1 Reactivity

This material is considered to be non reactive under normal use conditions

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

Heat.

10.5 Incompatible materials

None known.

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10.6 Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin contact

Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.

Eye contact

Moderate eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Ingestion

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Sodium Chloride Dermal Rabbit LD50 > 10,000 mg/kg
Sodium Chloride Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 10.5 mg/l

Sodium Chloride Ingestion Rat LD50 3,000 mg/kg
2,4-Dihydroxybenzophenone Ingestion Rat LD50 8,600 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Rabbit LD50 87 mg/kg

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Inhalation­Dust/Mist
(4 hours)

Rat LC50 0.33 mg/l

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat LD50 40 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

2,4-Dihydroxybenzophenone Rabbit No significant irritation
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3- Rabbit Corrosive

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one

Serious Eye Damage/Irritation

Name Species Value

2,4-Dihydroxybenzophenone Rabbit Severe irritant
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Rabbit Corrosive

Skin Sensitisation

Name Species Value

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Sensitising

Photosensitisation

Name Species Value

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Not sensitizing

Respiratory Sensitisation

Name Species Value

Germ Cell Mutagenicity

Name Route Value

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In vivo Not mutagenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In Vitro Some positive data exist, but the data are not

sufficient for classification

Carcinogenicity

Name Route Species Value

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Mouse Not carcinogenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure

Duration

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to female reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to male reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to development Rat NOAEL 15

mg/kg/day

during

organogenesis

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Mixture of 5-chloro-2­methyl-2H-isothiazol-3­one and 2-methyl-2H­isothiazol-3-one

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

similar
health
hazards

NOAEL Not
available

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Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

Aspiration Hazard

Name Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from
3M assessments.

12.1. Toxicity

No product test data available.

Material CAS Nbr Organism Type Exposure Test endpoint Test result

2,4­Dihydroxybenz
ophenone

131-56-6 Ricefish Estimated 96 hours LC50 3.8 mg/l

2,4­Dihydroxybenz
ophenone

131-56-6 Green algae Estimated 72 hours EC50 0.67 mg/l

2,4­Dihydroxybenz
ophenone

131-56-6 Water flea Estimated 24 hours EC50 0.28 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Diatom Experimental 72 hours EC50 0.021 mg/l

Sodium
Chloride

7647-14-5 Water flea Experimental 48 hours EC50 4,135 mg/l

Sodium
Chloride

7647-14-5 Fathead

minnow

Experimental 96 hours LC50 7,650 mg/l

Sodium
Chloride

7647-14-5 Algae or other

aquatic plants

Experimental 96 hours EC50 2,430 mg/l

2,4­Dihydroxybenz

131-56-6 Green algae Analogous

Compound

72 hours NOEC 0.18 mg/l

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ophenone
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Diatom Experimental 72 hours NOEC 0.01 mg/l

12.2. Persistence and degradability

Material CAS Nbr Test type Duration Study Type Test result Protocol

Non­Hazardous
Ingredients

Mixture Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Sodium
Chloride

7647-14-5 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

2,4­Dihydroxybenz
ophenone

131-56-6 Experimental

Biodegradation

28 days BOD 0 % weight OECD 301C - MITI

test (I)

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

12.3 : Bioaccumulative potential

Material CAS Nbr Test type Duration Study Type Test result Protocol

Non­Hazardous
Ingredients

Mixture Data not

available or
insufficient for
classification

N/A N/A N/A N/A

Sodium
Chloride

7647-14-5 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

2,4­Dihydroxybenz
ophenone

131-56-6 Estimated BCF

- Other

70 days Bioaccumulati

on factor

160 Other methods

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Data not

available or
insufficient for
classification

N/A N/A N/A N/A

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12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effects

No information available.

The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

See Section 11.1 Information on toxicological effects

This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations
to insure proper classification. Dispose of waste product in a permitted industrial waste facility. Empty and clean product
containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to determine
available options and requirements.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

20 01 30 Detergents other than those mentioned in 20 01 29.

SECTION 14: Transportation information

ADR/IMDG/IATA: Not restricted for transport.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Global inventory status

Contact manufacturer for more information The components of this material are in compliance with the provisions of
Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply.
Contact the selling division for additional information. The components of this product are in compliance with the new
substance notification requirements of CEPA. The components of this product are in compliance with the chemical
notification requirements of TSCA.

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

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H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

List of relevant R-phrases

R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Revision information:

Revision Changes:
Section 8: Eye/face protection information information was modified.
Section 16: List of relevant R phrase information information was modified.
Section 3: Composition/ Information of ingredients table information was modified.
Section 12: Component ecotoxicity information information was modified.
Section 12: Persistence and Degradability information information was modified.
Section 12:Bioccumulative potential information information was modified.
Section 1: Address information was modified.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 5: Fire - Extinguishing media information information was modified.
Section 5: Fire - Advice for fire fighters information information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. information was modified.
Section 12: Classification Warning information was added.
Section 11: Classification disclaimer information was added.
Section 11: Classification disclaimer information was deleted.
Section 12: Classification Warning information was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk