MEGUIAR'S G21 User Manual

G21, Convertible and Cabriolet Weatherproofer (S8135002F): G2112
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
29-4924-6
Version number:
3.00
Revision date:
24/02/2014
Supersedes date:
05/09/2013
Transportation version number: 1.00 (26/09/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G21, Convertible and Cabriolet Weatherproofer (S8135002F): G2112
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Aerosol, Category 1 - Aerosol 1; H222, H229 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H336 Hazardous to the Aquatic Environment (Acute), Category 1 - Aquatic Acute 1; H400 Hazardous to the Aquatic Environment (Chronic), Category 1 - Aquatic Chronic 1; H410
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
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Extremely flammable; F+; R12 Irritant; Xi; R38 R67 Dangerous for the environment; N; R50/53
For full text of R phrases, see Section 16.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
DANGER!
Symbols:
GHS02 (Flame) |GHS07 (Exclamation mark) |GHS09 (Environment) |
Pictograms
Ingredient CAS Nbr % by Wt Heptane 142-82-5 40 - 70
HAZARD STATEMENTS:
H222 Extremely flammable aerosol. H229 Pressurised container. may burst if heated. H315 Causes skin irritation. H336 May cause drowsiness or dizziness.
H410 Very toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS General:
P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.
Prevention:
P210A Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment.
Response:
P332 + P313 If skin irritation occurs: Get medical advice/attention.
Storage:
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50C/122F.
Disposal:
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P501 Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
6% of the mixture consists of components of unknown acute oral toxicity. 37% of the mixture consists of components of unknown acute dermal toxicity. 98% of the mixture consists of components of unknown acute inhalation toxicity. Contains 69% of components with unknown hazards to the aquatic environment.
Notes on labelling
H304 is not required on the label because the product is an aerosol. Nota P applied to CAS 64742-89-8.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
Extremely Flammable
Irritant Dangerous
for the environment
Contains:
No ingredients are assigned to the label.
Risk phrases
R12 Extremely flammable. R38 Irritating to skin. R67 Vapours may cause drowsiness and dizziness. R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Safety phrases
S16 Keep away from sources of ignition - No Smoking. S23C Do not breathe vapour or spray. S51 Use only in well ventilated areas. S24 Avoid contact with skin. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. S2 Keep out of the reach of children.
Special provisions concerning the labelling of certain substances
Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material.
Notes on labelling
R65 is not required on the label because the product is an aerosol.
Nota P applied CASRN 64742-89-8.
2.3. Other hazards
None known.
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SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Heptane 142-82-5 EINECS 205-
563-8
40 - 70 F:R11; Xn:R65; Xi:R38;
N:R50/53; R67 - Nota 4,C (EU)
Flam. Liq. 2, H225; Asp. Tox. 1, H304; Skin Irrit. 2, H315; STOT SE 3, H336; Aquatic Acute 1, H400,M=1; Aquatic Chronic 1, H410,M=1 - Nota C (CLP)
Butane 106-97-8 EINECS 203-
448-7
10 - 30 F+:R12 - Nota C (EU)
Flam. Gas 1, H220; Liquified gas, H280 - Nota C,U (CLP)
Propane 74-98-6 EINECS 200-
827-9
7 - 13 F+:R12 (EU)
Flam. Gas 1, H220; Liquified gas, H280 - Nota U (CLP)
Acetone 67-64-1 EINECS 200-
662-2
5 - 10 F:R11; Xi:R36; R66; R67 (EU)
Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336; EUH066 (CLP)
Octane isomers 601-009-00-
8
3 - 7 F:R11; Xn:R65; Xi:R38;
N:R50/53; R67 (EU)
Flam. Liq. 2, H225; Asp. Tox. 1, H304; Skin Irrit. 2, H315; STOT SE 3, H336; Aquatic Acute 1, H400,M=1; Aquatic Chronic 1, H410,M=1 (CLP)
Methylcyclohexane 108-87-2 EINECS 203-
624-3
1 - 5 F:R11; Xn:R65; Xi:R38;
N:R51/53; R67 - Nota 4 (EU)
Flam. Liq. 2, H225; Asp. Tox. 1, H304; Skin Irrit. 2, H315; STOT SE 3, H336; Aquatic Chronic 2, H411 (CLP) Aquatic Acute 1, H400,M=1 (Self Classified)
Solvent naphtha (petroleum), light aliphatic 64742-89-8 EINECS 265-
192-2
0.1 - 1 Xn:R65 - Nota 4,P (EU) F+:R12; Xi:R38; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) Flam. Liq. 1, H224; Skin Irrit. 2, H315 (Self Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
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4.1. Description of first aid measures
Inhalation
Remove person to fresh air. Get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Hydrocarbons. During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
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6.3. Methods and material for containment and cleaning up
If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and Safety Data Sheet. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Butane 106-97-8 Health and
Safety Comm. (UK)
TWA:1450 mg/m³(600 ppm);STEL:1810 mg/m³(750 ppm)
Heptane 142-82-5 Health and
Safety Comm. (UK)
TWA:2085 mg/m3(500 ppm)
Acetone 67-64-1 Health and
Safety Comm. (UK)
TWA:1210 mg/m³(500 ppm);STEL:3620 mg/m³(1500 ppm)
Propane 74-98-6 Health and
Safety Comm. (UK)
Limit value not established: asphyxiant
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
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8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect vented goggles.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Specific Physical Form:
Aerosol
Appearance/Odour
Clear aerosol liquid with pleasant odour.
Odour threshold
No data available.
pH
No data available.
Boiling point/boiling range
No data available.
Melting point
No data available.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
10 ºC [Test Method:Pensky-Martens Closed Cup]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
0.78 [Ref Std:WATER=1]
Water solubility
Negligible
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
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Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
No data available.
Density
0.78 g/ml
9.2. Other information
Volatile organic compounds (VOC)
93.48 %
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat. Sparks and/or flames.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Intentional concentration and inhalation may be harmful or fatal. Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
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Skin contact
May be harmful in contact with skin. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye contact
Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause target organ effects after ingestion.
Target Organ Effects:
Single exposure may cause:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Cardiac sensitisation: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE3,018.4 mg/kg Overall product Inhalation-
Dust/Mist(4 hr)
No data available; calculated ATE >12.5 mg/l
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Heptane Dermal Rabbit LD50 3,000 mg/kg Heptane Inhalation-
Vapor (4 hours)
Rat LC50 103 mg/l
Heptane Ingestion Rat LD50 > 15,000 mg/kg Butane Inhalation-
Gas (4 hours)
Rat LC50 277,000 ppm
Propane Inhalation-
Gas (4 hours)
Rat LC50 > 200,000 ppm
Acetone Dermal Rabbit LD50 > 15,688 mg/kg Acetone Inhalation-
Vapor (4 hours)
Rat LC50 76 mg/l
Acetone Ingestion Rat LD50 5,800 mg/kg Methylcyclohexane Inhalation-
Vapor (4 hours)
Mouse LC50 26 mg/l
Methylcyclohexane Dermal Rabbit LD50 > 86,700 mg/kg Methylcyclohexane Ingestion Rat LD50 > 3,200 mg/kg Solvent naphtha (petroleum), light aliphatic Dermal Rabbit LD50 3,000 mg/kg Solvent naphtha (petroleum), light aliphatic Inhalation-
Vapor (4 hours)
Rat LC50 > 5.2 mg/l
Solvent naphtha (petroleum), light aliphatic Ingestion Rat LD50 > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Heptane Human Mild irritant Butane No significant irritation
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Propane Rabbit Minimal irritation Acetone Mouse Minimal irritation Methylcyclohexane Rabbit Minimal irritation Solvent naphtha (petroleum), light aliphatic Rabbit Irritant
Serious Eye Damage/Irritation
Name Species Value
Heptane Moderate irritant Butane Rabbit No significant irritation Propane Rabbit Mild irritant Acetone Rabbit Severe irritant Methylcyclohexane Rabbit Mild irritant Solvent naphtha (petroleum), light aliphatic Rabbit No significant irritation
Skin Sensitisation
Name Species Value
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Heptane In Vitro Not mutagenic Butane In Vitro Not mutagenic Propane In Vitro Not mutagenic Acetone In vivo Not mutagenic Acetone In Vitro Some positive data exist, but the data are not
sufficient for classification
Solvent naphtha (petroleum), light aliphatic In Vitro Not mutagenic
Carcinogenicity
Name Route Species Value
Acetone Not
specified.
Multiple animal species
Not carcinogenic
Methylcyclohexane Inhalation Multiple
animal species
Not carcinogenic
Solvent naphtha (petroleum), light aliphatic Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Acetone Ingestion Not toxic to female reproduction Mouse NOAEL
11,298 mg/kg/day
13 weeks
Acetone Ingestion Some positive male reproductive data
exist, but the data are not sufficient for classification
Rat NOAEL
1,700 mg/kg/day
13 weeks
Acetone Inhalation Some positive developmental data exist,
but the data are not sufficient for classification
Rat NOAEL 5.2
mg/l
during organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Heptane Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
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Heptane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
Human NOAEL Not
available
Heptane Ingestion central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
Butane Inhalation cardiac
sensitization
Causes damage to organs Human NOAEL Not
available
Butane Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human and animal
NOAEL Not available
Butane Inhalation heart Some positive data exist, but the
data are not sufficient for classification
Dog NOAEL
5,000 ppm
25 minutes
Butane Inhalation respiratory irritation All data are negative Rabbit NOAEL Not
available
Propane Inhalation cardiac
sensitization
Causes damage to organs Human NOAEL Not
available
Propane Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
Propane Inhalation respiratory irritation All data are negative Human NOAEL Not
available
Acetone Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
Acetone Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
Human NOAEL Not
available
Acetone Inhalation immune system Some positive data exist, but the
data are not sufficient for classification
Human NOAEL 1.19
mg/l
6 hours
Acetone Inhalation liver Some positive data exist, but the
data are not sufficient for classification
Guinea pig
NOAEL Not available
Acetone Ingestion central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
poisoning and/or abuse
Methylcyclohexane Inhalation central nervous
system depression
May cause drowsiness or dizziness
Multiple animal species
NOAEL Not available
Methylcyclohexane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
Human NOAEL Not
available
occupational exposure
Solvent naphtha (petroleum), light aliphatic
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL Not
available Solvent naphtha (petroleum), light aliphatic
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Heptane Inhalation liver | nervous
system | kidney and/or bladder
All data are negative Rat NOAEL 12
mg/l
26 weeks
Butane Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL
4,489 ppm
90 days
Butane Inhalation blood All data are negative Rat NOAEL
4,489 ppm
90 days
Acetone Dermal eyes Some positive data exist, but the
data are not sufficient for classification
Guinea pig
NOAEL Not
available
3 weeks
Acetone Inhalation hematopoietic
system
Some positive data exist, but the data are not sufficient for classification
Human NOAEL 3
mg/l
6 weeks
Acetone Inhalation immune system Some positive data exist, but the
data are not sufficient for classification
Human NOAEL 1.19
mg/l
6 days
Acetone Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for
Guinea pig
NOAEL 119
mg/l
not available
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classification
Acetone Inhalation heart | liver All data are negative Rat NOAEL 45
mg/l
8 weeks
Acetone Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 900
mg/kg/day
13 weeks
Acetone Ingestion heart Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL
2,500
mg/kg/day
13 weeks
Acetone Ingestion hematopoietic
system
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 200
mg/kg/day
13 weeks
Acetone Ingestion liver Some positive data exist, but the
data are not sufficient for classification
Mouse NOAEL
3,896
mg/kg/day
14 days
Acetone Ingestion eyes All data are negative Rat NOAEL
3,400
mg/kg/day
13 weeks
Acetone Ingestion respiratory system All data are negative Rat NOAEL
2,500
mg/kg/day
13 weeks
Acetone Ingestion muscles All data are negative Rat NOAEL
2,500 mg/kg
13 weeks
Acetone Ingestion skin | bone, teeth,
nails, and/or hair
All data are negative Mouse NOAEL
11,298
mg/kg/day
13 weeks
Methylcyclohexane Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 1.6
mg/l
12 months
Methylcyclohexane Inhalation liver Some positive data exist, but the
data are not sufficient for classification
Rabbit NOAEL 12
mg/l
10 weeks
Aspiration Hazard
Name Value
Heptane Aspiration hazard Methylcyclohexane Aspiration hazard Solvent naphtha (petroleum), light aliphatic Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Acetone 67-64-1 Water flea Experimental 48 hours EC50 13,500 mg/l Acetone 67-64-1 Rainbow trout Experimental 96 hours LC50 5,540 mg/l Acetone 67-64-1 Green Algae Experimental 96 hours EC50 2,574 mg/l Methylcyclohe xane
108-87-2 Green Algae Experimental 72 hours EC50 0.34 mg/l
Methylcyclohe 108-87-2 Water flea Experimental 48 hours EC50 0.33 mg/l
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xane Methylcyclohe xane
108-87-2 Ricefish Experimental 96 hours LC50 2.1 mg/l
Methylcyclohe xane
108-87-2 Green Algae Experimental 72 hours NOEC 0.067 mg/l
Butane 106-97-8 Data not
available or insufficient for classification
Heptane 142-82-5 Data not
available or insufficient for classification
Propane 74-98-6 Data not
available or insufficient for
classification Solvent naphtha (petroleum), light aliphatic
64742-89-8 Data not
available or
insufficient for
classification Octane isomers 601-009-00-8 Data not
available or
insufficient for
classification
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Solvent naphtha (petroleum), light aliphatic
64742-89-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Octane isomers 601-009-00-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Methylcyclohe xane
108-87-2 Experimental
Photolysis
Photolytic half­life (in air)
3 days (t 1/2) Other methods
Methylcyclohe xane
108-87-2 Experimental
Biodegradation
28 days BOD 0 % weight OECD 301D - Closed
bottle test
Acetone 67-64-1 Experimental
Biodegradation
28 days BOD 96 % weight OECD 301C - MITI
test (I)
Butane 106-97-8 Experimental
Photolysis
Photolytic half­life (in air)
6.3 days (t 1/2) Other methods
Heptane 142-82-5 Experimental
Photolysis
Photolytic half­life (in air)
4.24 days (t 1/2)
Other methods
Heptane 142-82-5 Experimental
Biodegradation
28 days BOD 101 % weight OECD 301C - MITI
test (I)
Propane 74-98-6 Experimental
Photolysis
Photolytic half­life (in air)
27.5 days (t 1/2)
Other methods
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
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Solvent naphtha (petroleum), light aliphatic
64742-89-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Octane isomers 601-009-00-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Methylcyclohe xane
108-87-2 Experimental
BCF-Carp
56 days Bioaccumulati
on factor
321 OECD 305E -
Bioaccumulation flow­through fish test
Acetone 67-64-1 Experimental
BCF - Other
Bioaccumulati on factor
0.65 Other methods
Butane 106-97-8 Experimental
Bioconcentrati on
Log Kow 2.88 Other methods
Heptane 142-82-5 Estimated BCF
- Other
Bioaccumulati on factor
107 Estimated:
Bioconcentration factor
Propane 74-98-6 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Dispose of waste product in a permitted industrial waste facility. Facility must be capable of handling aerosol cans. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
16 05 04* Gases in pressure containers (including halons) containing dangerous substances 20 01 13* Solvents
EU waste code (product container after use)
15 01 04 Metallic packaging
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SECTION 14: Transportation information
ADR: UN1950 Aerosols; 2; (D); 5F IMDG: UN1950 Aerosols; 2; EmS: F-D, S-U; Marine Pollutant (Methylcyclohexane) IATA: UN1950 Aerosols, flammable; 2.1
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H220 Extremely flammable gas. H222 Extremely flammable aerosol. H224 Extremely flammable liquid and vapour. H225 Highly flammable liquid and vapour. H229 Pressurised container. may burst if heated. H280 Contains gas under pressure; may explode if heated. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R11 Highly flammable. R12 Extremely flammable. R36 Irritating to eyes. R38 Irritating to skin. R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
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Revision information:
Revision Changes: Section 3: Composition/ Information of ingredients table information was modified. Section 12: Component ecotoxicity information information was modified. Section 12: Persistence and Degradability information information was modified. Section 12:Bioccumulative potential information information was modified. Section 14: Transportation classification information was modified. Copyright information was modified. Section 11: Aspiration Hazard Table information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Reproductive Toxicity Table information was modified. Section 11: Target Organs - Repeated Table information was modified. Section 11: Health Effects - Skin information information was modified. Section 5: Fire - Extinguishing media information information was modified. Section 7: Precautions safe handling information information was modified. Section 8: Appropriate Engineering controls information information was modified. Section 8: Personal Protection - Eye information information was modified. Section 13: 13.1. Waste disposal note information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. information was modified. Label: Signal Word - Header information was added. Label: Signal Word information was added. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Label: CLP Classification information was added. Label: CLP Classification - Header information was added. Label: CLP Percent Unknown information was added. Label: CLP Percent Unknown information was added. Label: CLP Percent Unknown information was added. Label: CLP Percent Unknown information was added. Label: CLP Environmental Hazard Statements information was added. Label: Graphic information was added. Label: Graphic information was added. Label: Symbol information was added. Label: Symbol information was added. Label: CLP Precautionary - Disposal information was added. Label: CLP Precautionary - Disposal - Header information was added. Label: CLP Precautionary - General information was added. Label: CLP Precautionary - General - Header information was added. Label: CLP Precautionary - Prevention information was added. Label: CLP Precautionary - Prevention - Header information was added. Label: CLP Precautionary - Response information was added. Label: CLP Precautionary - Response - Header information was added. Label: CLP Precautionary - Storage information was added. Label: CLP Precautionary - Storage - Header information was added. Label: Precautionary Statement - Header information was added. CLP: Ingredient table information was added. Section 2: Notes on labelling heading information was added. Section 15: Label remarks and EU Detergent information was added. CLP Remark(phrase) information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Section 8: Personal Protection - Skin/hand information information was added. Section 8: Personal Protection - Respiratory Information information was added.
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Label: CLP Ingredients table Ingredient heading information was added. Label: CLP Ingredients table CAS No heading information was added. Label: CLP Ingredients table Percent by Wt heading information was added. Section 2: H phrase reference information was added. Section 11: Disclosed components not in tables text information was added. Section 8: Eye/face protection text information was deleted. Section 8: Respiratory protection - recommended respirators information was deleted. Section 8: Skin protection - protective clothing text information was deleted. Section 8: mg/m³ key information was deleted. Section 8: ppm key information was deleted. Section 11: Skin Sensitization Table information was deleted. Section 11: Respiratory Sensitization Table information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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