MEGUIAR'S G1900 User Manual

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G1900, Headlight Restoration Kit
Page: 1 of 2
Safety Data Sheet
Copyright, 2011, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document group:
28-9641-3
Version number:
1.00
Revision date:
26/09/2011
Supersedes date:
Initial issue.
Transportation version number: 1.00 (26/09/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
G1900, Headlight Restoration Kit
1.2. Relevant identified uses of the substance or mixture and uses advised against
Automotive.
1.3. Details of the supplier of the substance or mixture
Address: Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF Telephone: +44 (0)870 241 6696 E Mail: info@meguiars.co.uk Website: www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet for each of these components is included. Please do not separate the component Safety Data Sheets
from
this
cover page. The document numbers of the MSDSs for components of this product are:
G12304, G17104
27-7685-4, 28-8996-2
TRANSPORTATION INFORMATION
ADR/IMDG/IATA: Not restricted for transport.
KIT LABEL
2.2. Label elements
Dangerous
substances(67/548/EEC)/preparations(1999/45/EC)
directive
Symbols None.
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G1900, Headlight Restoration Kit
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Contains:
Consult the component labels for disclosable ingredients.
Risk phrases
R66 Repeated exposure may cause skin dryness or cracking. R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Safety phrases
S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label. S2 Keep out of the reach of children. S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
Special provisions concerning the labelling of certain substances
Contains
Bis(1,2,2,6, 6-pentamethyl -4-piperidyl)
sebacate. Contains polymeric benzotriazole. May produce an allergic
reaction.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota N applied CAS 64742-46-7, Nota P applied CAS 64742-48-9
Revision information:
No revision information is available.
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Meguiar's PlastX, G123
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Safety Data Sheet
Copyright, 2011, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document group:
27-7685-4
Version number:
2.01
Revision date:
26/09/2011
Supersedes date:
17/06/2011
Transportation version number: 1.00 (07/09/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Meguiar's PlastX, G123
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture
Address: Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF Telephone: +44 (0)870 241 6696 E Mail: info@meguiars.co.uk Website: www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous
substances(67/548/EEC)/preparations(1999/45/E C)
directive
2.2. Label elements
Dangerous
substances(67/548/EEC)/preparations(1999/45/EC)
directive
Symbols None.
Contains:
No ingredients are assigned to the label.
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Meguiar's PlastX, G123
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Risk phrases
R66 Repeated exposure may cause skin dryness or cracking.
Safety phrases
S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
S2 Keep out of the reach of children.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota N applied CAS 64742-46-7, Nota P applied to CAS 64742-48-9.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient
CAS Nbr
EU Inventory
% by Wt
Classification
Non-hazardous ingredients
Mixture
50 - 70
Distillates (petroleum), hydrotreated middle
64742-46-7
EINECS 265­148-2
7 - 13
Nota H,N (EU) Xn:R20-65; R66 (Self Classified)
Nota H,N (CLP) Acute Tox. 4, H332; Asp. Tox. 1, H304; STOT SE 3, H336 (Self Classified)
Naphtha (petroleum), hydrotreated heavy
64742-48-9
EINECS 265­150-3
5 - 10
Xn:R65 - Nota 4,H,P (EU) N:R51/53 (Vendor) R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota H,P (CLP) STOT SE 3, H336 (Self Classified)
Solvent naphtha (petroleum), medium aliphatic
64742-88-7
EINECS 265­191-7
5 - 10
Xn:R65 - Nota 4,H (EU) R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota H (CLP) STOT SE 3, H336 (Self Classified)
Aluminium oxide (REACH Reg. No.:01­2119529248-35)
1344-28-1
EINECS 215­691-6
3 - 7
STOT RE 2, H373 (Self Classified)
2-(2-Ethoxyethoxy)ethanol
111-90-0
EINECS 203­919-7
1 - 5
Siloxanes and silicones, di-Me
63148-62-9
1 - 5
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
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Meguiar's PlastX, G123
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SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
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6.3. Methods and material for containment and cleaning up
Clean up residue with detergent and water. Collect as much of the spilled material as possible. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Seal the container.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid breathing dust/fume/gas/mist/vapours/spray. Keep out of reach of children. Vapours may travel long distances along the ground or floor to an ignition source and flash back. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Aluminium oxide 1344-28-1 Health and
Safety Comm. (UK)
TWA(as inhalable dust):10 mg/m³;TWA(as respirable
dust):4 mg/m³ Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/fume/gas/mist/vapours/spray.
If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
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Gloves made from the following material(s) are recommended: Neoprene. Nitrile rubber.
Respiratory protection
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapour cartridges and P2 particulate prefilters.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state Liquid.
Appearance/Odour Pleasant Odour; Light Blue pH 8.0 - 8.9 Boiling point/boiling range 176.7 ºC Melting point No data available. Flammability (solid, gas) Not classified Explosive properties Not classified Oxidising properties Not classified Flash point 93.3 ºC [Test Method:Closed Cup] Autoignition temperature No data available. Flammable Limits(LEL) No data available. Flammable Limits(UEL) No data available.
Relative density 0.96 [Ref Std:WATER=1]
Water solubility Moderate Partition coefficient: n-octanol/water No data available. Evaporation rate No data available.
Vapour density No data available. Viscosity 10 - 16 Pa-s Density 0.96 g/ml
9.2. Other information
Hazardous air pollutants 0.000847 % weight [Test Method:Calculated] Volatile organic compounds (VOC) 16.3 % weight [Test Method:calculated per CARB title 2] Volatile organic compounds (VOC) 156 g/l [Test Method:calculated SCAQMD rule 443.1] VOC less H2O & exempt solvents 418 g/l [Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
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10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Target Organ Effects:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests.
Toxicological Data
Acute Toxicity
Name
Route
Species
Value
UN GHS Classification
Overall product
Ingestion
No test data available; calculated ATE >5,000 mg/kg
Not classified (10% unknown)
Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
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Naphtha (petroleum), hydrotreated heavy
No data available Aluminium oxide
No data available
Siloxanes and silicones, di-Me
No data available
2-(2-Ethoxyethoxy)ethanol
No data available
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name
Species
Value
UN GHS Classification
Overall product
No test data available; calculated to be mild irritant
Category 3 Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Naphtha (petroleum), hydrotreated heavy
No data available Aluminium oxide
No data available
Siloxanes and silicones, di-Me
Minimal irritation
Not classified
2-(2-Ethoxyethoxy)ethanol
No data available
Serious Eye Damage/Irritation
Name
Species
Value
UN GHS Classification
Overall product
No test data available; calculated to cause no significant irritation
Not classified Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha (petroleum), medium aliphatic
Mild irritant
Not classified
Naphtha (petroleum), hydrotreated heavy
No data available Aluminium oxide
No data available
Siloxanes and silicones, di-Me
No data available
2-(2-Ethoxyethoxy)ethanol
No data available
Skin Sensitisation
Name
Species
Value
UN GHS Classification
Overall product
No test data available.
Not classified based on component data
Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Naphtha (petroleum), hydrotreated heavy
No data available Aluminium oxide
No data available
Siloxanes and silicones, di-Me
No data available
2-(2-Ethoxyethoxy)ethanol
No data available
Respiratory Sensitisation
Name
Species
Value
UN GHS Classification
Overall product
No test data available.
Not classified based on
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Name
Route
Value
Species
Test result
Exposure Duration
UN GHS Classification
Overall product
No test data available.
Not classified based on component data
Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha
No data available
component data
Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Naphtha (petroleum), hydrotreated heavy
No data available Aluminium oxide
No data available
Siloxanes and silicones, di-Me
No data available
2-(2-Ethoxyethoxy)ethanol
No data available
Germ Cell Mutagenicity
Name
Route
Value
UN GHS Classification
Overall product
No data available
Overall Germ Cell Mutagenicity classificationNot classified
Overall product
No test data available.
Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Naphtha (petroleum), hydrotreated heavy
No data available Aluminium oxide
No data available
Siloxanes and silicones, di-Me
No data available
2-(2-Ethoxyethoxy)ethanol
No data available
Carcinogenicity
Name
Route
Species
Value
UN GHS Classification
Overall product
No test data available.
Not classified based on component data
Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Naphtha (petroleum), hydrotreated heavy
No data available Aluminium oxide
No data available
Siloxanes and silicones, di-Me
No data available
2-(2-Ethoxyethoxy)ethanol
No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
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Name
Route
Target Organ(s)
Value
Species
Test result
Exposure Duration
UN GHS Classification
Overall product
No test data available.
Category 2 based on component data
(petroleum), medium aliphatic
Naphtha (petroleum), hydrotreated heavy
No data available
Aluminium oxide
No data available
Siloxanes and silicones, di-Me
No data available
2-(2­Ethoxyethoxy)etha nol
No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name
Route
Target Organ(s)
Value
Species
Test result
Exposure Duration
UN GHS Classification
Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha (petroleum), medium aliphatic
Inhalation
central nervous system depressio n
May cause drowsiness or dizziness
NOAEL N/A
Category 3
Naphtha (petroleum), hydrotreated heavy
Inhalation
central nervous system depressio n
May cause drowsiness or dizziness
NOAEL N/A
Category 3
Solvent naphtha (petroleum), medium aliphatic
Inhalation
respirator y irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Not classified
Aluminium oxide
No data available
Siloxanes and silicones, di­Me
No data available
2-(2­Ethoxyethox y)ethanol
Ingestion
central nervous system depressio n
May cause drowsiness or dizziness
Category 3
Specific Target Organ Toxicity - repeated exposure
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Distillates (petroleum), hydrotreated middle
No data available
Solvent naphtha (petroleum), medium aliphatic
No data available
Naphtha (petroleum), hydrotreated heavy
No data available
Aluminium oxide
Inhalation
pneumoco niosis
May cause damage to organs though prolonged or repeated exposure
NOAEL N/A
Category 2
Siloxanes and silicones, di­Me
No data available
2-(2­Ethoxyethox y)ethanol
No data available
Aspiration Hazard
Name
Value
UN GHS Classification
Overall product
No test data available.
Not classified based on component and/or viscosity data
Solvent naphtha (petroleum), medium aliphatic
Aspiration hazard
Category 1
Naphtha (petroleum), hydrotreated heavy
Aspiration hazard
Category 1
Aluminium oxide
Not an aspiration hazard
Not classified
Siloxanes and silicones, di-Me
Not an aspiration hazard
Not classified
2-(2-Ethoxyethoxy)ethanol
Not an aspiration hazard
Not classified
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the
data
is
considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available. No component test data available.
12.2. Persistence and degradability
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No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the
local/regional/national/international
regulations
As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. Incinerate in an industrial or commercial facility. Incinerate in an industrial or commercial facility in the presence of a combustible material.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 13* Solvents
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H304 May be fatal if swallowed and enters airways. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H373 May cause damage to organs through prolonged or repeated exposure.
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List of relevant R-phrases
R20 Harmful by inhalation. R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 1: Product name was modified. Risk phrase was modified. Safety phrase was modified. Page Heading: Product name was modified. Section 9: Vapor density text was modified. Section 9: pH information was modified. Section 9: Evaporation Rate information was modified. Section 9: Viscosity information was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 9: n-octanol/water coefficient information was
modified.
Section
9: Boiling point information was modified. Section 9: Relative density information was modified. Section 9: Solubility in water text was modified. Section 13: EU waste code (product as sold) information was modified. Section 16: Regulations – Inventories – EU ONLY was modified. Section 9: Flash point information was modified. Section 9: Melting point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Density information was modified. Section 9: Property description for optional properties was modified. Section 8: Occupational exposure limit table was modified. Section 8: mg/m³ key was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 11: Health Effects - Skin information was modified. Section 5: Hazardous combustion products table was modified. Section 10: Hazardous decomposition or by-products table was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 9: Autoignition temperature information was added.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to
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satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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G171, Headlight Protectant (XP4-137A): G17104
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Safety Data Sheet
Copyright, 2011, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document group:
28-8996-2
Version number:
1.00
Revision date:
23/09/2011
Supersedes date:
Initial issue.
Transportation version number: 1.00 (23/09/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G171, Headlight Protectant (XP4-137A): G17104
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture
Address: Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF Telephone: +44 (0)870 241 6696 E Mail: info@meguiars.co.uk Website: www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous
substances(67/548/EEC)/preparations(1999/45/EC)
directive
2.2. Label elements
Dangerous
substances(67/548/EEC)/preparations(1999/45/EC)
directive
Symbols None.
Contains:
No ingredients are assigned to the label.
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Risk phrases
R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Safety phrases
S2 Keep out of the reach of children. S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
Special provisions concerning the labelling of certain substances
Contains
Bis(1,2,2,6, 6-pentamethyl -4-piperidyl)
sebacate. Contains polymeric benzotriazole. May produce an allergic
reaction.
Notes on labelling
Nota N applied CAS 64742-46-7
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient
CAS Nbr
EU Inventory
% by Wt
Classification
Non-hazardous ingredients
Mixture
60 - 80
Siloxanes and silicones, di-Me
63148-62-9
10 - 30
Distillates (petroleum), hydrotreated middle
64742-46-7
EINECS 265­148-2
5 - 10
Nota H,N (EU) Xn:R20-65; R66 (Self Classified)
Nota H,N (CLP) Acute Tox. 4, H332; Asp. Tox. 1, H304; STOT SE 3, H336 (Self Classified)
Acrylic polymer
Trade Secret
1 - 5
Processed oil
Trade Secret
1 - 5
Polymeric benzotriazole
104810-47-1
< 1
Repr.Cat.3:R63; N:R51/53; R43 (Self Classified)
Skin Sens. 1, H317; Repr. 2, H361d; Aquatic Chronic 2, H411 (Self Classified)
Bis(1,2,2,6,6-pentamethyl-4­piperidyl)sebacate
41556-26-7
EINECS 255­437-1
< 1
N:R50/53; R43 (Self Classified)
Skin Sens. 1, H317; Aquatic Acute 1, H400,M=1; Aquatic Chronic 1, H410,M=1 (Self Classified)
Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H­benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4­hydroxyphenyl]-1-oxopropyl]-ω-hydroxy-
104810-48-2
< 1
Repr.Cat.3:R63; N:R51/53; R43 (Self Classified)
Skin Sens. 1, H317; Repr. 2, H361d; Aquatic Chronic 2, H411 (Self Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
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For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate the area with fresh air.
6.2. Environmental precautions
Avoid release to the environment.
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6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Clean up residue with water. Place in a closed container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Vapours may travel long distances along the ground or floor to an ignition source and flash back. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidising agents (eg. chlorine, chromic
acid
etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/f ume/gas/mist/vapours/spray.
If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Wear protective gloves. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
None required.
SECTION 9: Physical and chemical properties
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9.1. Information on basic physical and chemical properties
Physical state Liquid.
Appearance/Odour Semi-pourable creamy gel; Pleasant odour pH 8.5 - 9.5 Boiling point/boiling range No data available. Melting point No data available. Flammability (solid, gas) Not classified Explosive properties Not classified Oxidising properties Not classified Flash point > 93.3 ºC Flammable Limits(LEL) No data available. Flammable Limits(UEL) No data available.
Relative density 0.93 - 1.03 [Ref Std:WATER=1]
Water solubility Complete Partition coefficient: n-octanol/water No data available. Evaporation rate No data available. Evaporation rate No data available.
Vapour density No data available. Viscosity 4 - 7 Pa-s Density 0.93 - 1.03 g/ml
9.2. Other information
Hazardous air pollutants 0.0000820 % weight [Test Method:Calculated] Volatile organic compounds (VOC) 0.4 % weight [Test Method:calculated per CARB title 2] Volatile organic compounds (VOC) 16 g/l [Test Method:calculated SCAQMD rule 443.1] VOC less H2O & exempt solvents 5 g/l [Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong oxidising agents. Strong acids. Strong bases.
10.6 Hazardous decomposition products
Substance Condition
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None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Contact with the skin during product use is not expected to result in significant irritation. Allergic skin reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
Acute Toxicity
Name
Route
Species
Value
UN GHS Classification
Overall product
Ingestion
No test data available; calculated ATE >5,000 mg/kg
Not classified (8.61% unknown) Siloxanes and silicones, di-Me
No data available
Distillates (petroleum), hydrotreated middle
No data available Processed oil
No data available
Poly(oxy-1,2-ethanediyl), α-[3­[3-(2H- benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4­hydroxyphenyl]-1-oxopropyl]-ω­hydroxy-
No data available
Polymeric benzotriazole
No data available
Bis(1,2,2,6,6-pentamethyl-4­piperidyl)sebacate
No data available
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name
Species
Value
UN GHS Classification
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Name
Species
Value
UN GHS Classification
Overall product
No test data available.
Not classified based on component data
Siloxanes and silicones, di-Me
No data available
Distillates (petroleum), hydrotreated middle
No data available
Overall product
No test data available; calculated to cause no significant irritation
Not classified
Siloxanes and silicones, di-Me
No data available
Distillates (petroleum), hydrotreated middle
No data available Processed oil
No data available
Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H­benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4- hydroxyphenyl]-1­oxopropyl]-ω-hydroxy-
No data available
Polymeric benzotriazole
No data available
Bis(1,2,2,6,6-pentamethyl-4­piperidyl)sebacate
No data available
Serious Eye Damage/Irritation
Name
Species
Value
UN GHS Classification
Overall product
No test data available; calculated to cause no significant irritation
Not classified
Siloxanes and silicones, di-Me
No data available
Distillates (petroleum), hydrotreated middle
No data available Processed oil
No data available
Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H­benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4- hydroxyphenyl]-1­oxopropyl]-ω-hydroxy-
No data available
Polymeric benzotriazole
No data available
Bis(1,2,2,6,6-pentamethyl-4­piperidyl)sebacate
No data available
Skin Sensitisation
Name
Species
Value
UN GHS Classification
Overall product
No test data available.
Category 1 based on component data
Siloxanes and silicones, di-Me
No data available
Distillates (petroleum), hydrotreated middle
No data available Processed oil
No data available
Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H­benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4- hydroxyphenyl]-1­oxopropyl]-ω-hydroxy-
No data available
Polymeric benzotriazole
No data available
Bis(1,2,2,6,6-pentamethyl-4­piperidyl)sebacate
Sensitising
Category 1
Respiratory Sensitisation
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Processed oil
No data available
Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H­benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4- hydroxyphenyl]-1­oxopropyl]-ω-hydroxy-
No data available
Polymeric benzotriazole
No data available
Bis(1,2,2,6,6-pentamethyl-4­piperidyl)sebacate
No data available
Germ Cell Mutagenicity
Name
Route
Value
UN GHS Classification
Overall product
No data available
Overall Germ Cell Mutagenicity classificationNot classified
Overall product
No test data available.
Siloxanes and silicones, di-Me
No data available
Distillates (petroleum), hydrotreated middle
No data available Processed oil
No data available
Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H­benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4- hydroxyphenyl]-1­oxopropyl]-ω-hydroxy-
No data available
Polymeric benzotriazole
No data available
Bis(1,2,2,6,6-pentamethyl-4­piperidyl)sebacate
No data available
Carcinogenicity
Name
Route
Species
Value
UN GHS Classification
Overall product
No test data available.
Not classified based on component data
Siloxanes and silicones, di-Me
No data available
Distillates (petroleum), hydrotreated middle
No data available Processed oil
No data available
Poly(oxy-1,2-ethanediyl), α-[3­[3-(2H- benzotriazol-2-yl)-5-(1,1­dimethylethyl)-4­hydroxyphenyl]-1-oxopropyl]-ω­hydroxy-
No data available
Polymeric benzotriazole
No data available
Bis(1,2,2,6,6-pentamethyl-4­piperidyl)sebacate
No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name
Route
Value
Species
Test result
Exposure Duration
UN GHS Classification
Overall product
No test data available.
Not classified based on component data
Siloxanes and silicones, di-Me
No data available
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Name
Route
Target Organ(s)
Value
Species
Test result
Exposure Duration
UN GHS Classification
Siloxanes and silicones, di­Me
No data available
Distillates (petroleum), hydrotreated middle
No data available Processed oil
No data available
Poly(oxy­1,2­ethanediyl), α-[3-[3-(2H­benzotriazol
-2-yl)-5­(1,1­dimethyleth yl)-4­hydroxyphe nyl]-1­oxopropyl]­ω-hydroxy-
No data available
Polymeric benzotriazol e
No data available
Bis(1,2,2,6,6
­pentamethyl
-4-
No data available
Distillates (petroleum), hydrotreated middle
No data available
Processed oil
No data available
Poly(oxy-1,2­ethanediyl), α-[3­[3-(2H­benzotriazol-2-yl)­5-(1,1­dimethylethyl)-4­hydroxyphenyl]-1­oxopropyl]-ω­hydroxy-
No data available
Polymeric benzotriazole
No data available
Bis(1,2,2,6,6­pentamethyl-4­piperidyl)sebacate
No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
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piperidyl)se bacate
Specific Target Organ Toxicity - repeated exposure
Name
Route
Target Organ(s)
Value
Species
Test result
Exposure Duration
UN GHS Classification
Overall product
No test data available.
Not classified based on component data
Siloxanes and silicones, di­Me
No data available
Distillates (petroleum), hydrotreated middle
No data available Processed oil
No data available
Poly(oxy­1,2­ethanediyl), α-[3-[3-(2H­benzotriazol
-2-yl)-5­(1,1­dimethyleth yl)-4­hydroxyphe nyl]-1­oxopropyl]­ω-hydroxy-
No data available
Polymeric benzotriazol e
No data available
Bis(1,2,2,6,6
­pentamethyl
-4­piperidyl)se bacate
No data available
Aspiration Hazard
Name
Value
UN GHS Classification
Overall product
No test data available.
Not classified based on component and/or viscosity data
Siloxanes and silicones, di-Me
Not an aspiration hazard
Not classified
Distillates (petroleum), hydrotreated middle
Not an aspiration hazard
Not classified
Processed oil
Not an aspiration hazard
Not classified
Poly(oxy-1,2-ethanediyl), α-[3-[3-(2H- benzotriazol-2-yl)­5-(1,1-dimethylethyl)-4- hydroxyphenyl]-1-oxopropyl]-ω­hydroxy-
Not an aspiration hazard
Not classified
Polymeric benzotriazole
Not an aspiration hazard
Not classified
Bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate
Not an aspiration hazard
Not classified
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Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the
data
is
considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the
local/reg ional/national/international
regulations
Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
200115*
Alkalines
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SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H304 May be fatal if swallowed and enters airways. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R20 Harmful by inhalation. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R63 Possible risk of harm to the unborn child. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking.
Revision information:
No revision information is available.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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