MEGUIAR'S G179 User Manual

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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
27-7791-0
Version number:
2.02
Revision date:
15/08/2012
Supersedes date:
30/07/2012
Transportation version number: 1.00 (07/06/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G179, Leather Gel (21-37C): G17914
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
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No ingredients are assigned to the label.
Risk phrases None. Safety phrases None.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents. Ingredients required per 648/2004: Contains: Perfumes, amyl cinnamal, methylchloroisothiazolinone, methylisothiazolinone.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-hazardous ingredients Mixture 50 - 65 Propylene Glycol 57-55-6 EINECS 200-
338-0
15 - 40
Siloxanes and silicones, di-Me 63148-62-9 1 - 10 Conditioners Trade Secret < 5 Triethanolamine 102-71-6 EINECS 203-
049-8
0.5 - 1.5
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
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In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes. During combustion. Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area or areas with little or no air movement. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Store away from heat. Protect from sunlight. Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
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8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Propylene Glycol 57-55-6 Health and
Safety Comm. (UK)
TWA(as particulate):10 mg/m3;TWA(as total vapour and particulates):474 mg/m3(150 ppm)
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
As a good industrial hygiene practice:
Wear eye/face protection.
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
As a good industrial hygiene practice:
Wear protective gloves.
Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
In case of inadequate ventilation wear respiratory protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Pleasant Odour; Light Yellow
pH
8.20 - 9.00
Boiling point/boiling range
No data available.
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Melting point
No data available.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
>=98.9 ºC [Test Method:Closed Cup]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Moderate
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
6 - 8 Pa-s
Density
1 g/ml
9.2. Other information
Volatile organic compounds (VOC)
0.0 %
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
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11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Contact with the skin during product use is not expected to result in significant irritation.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause target organ effects after ingestion.
Target Organ Effects:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg Propylene Glycol Dermal Rabbit LD50 20,800 mg/kg Propylene Glycol Ingestion Rat LD50 22,000 mg/kg Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg Triethanolamine Dermal Rabbit LD50 > 2,000 mg/kg Triethanolamine Ingestion Rat LD50 9,000 mg/kg Conditioners No data available
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Propylene Glycol Rabbit No significant irritation Siloxanes and silicones, di-Me Minimal irritation Triethanolamine Rabbit Minimal irritation Conditioners No data available
Serious Eye Damage/Irritation
Name Species Value
Propylene Glycol Mild irritant Siloxanes and silicones, di-Me Rabbit No significant irritation Triethanolamine Rabbit Mild irritant Conditioners No data available
Skin Sensitisation
Name Species Value
Propylene Glycol Human Some positive data exist, but the data are not
sufficient for classification
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Siloxanes and silicones, di-Me No data available Triethanolamine Human Some positive data exist, but the data are not
sufficient for classification
Conditioners No data available
Respiratory Sensitisation
Name Species Value
Propylene Glycol No data available Siloxanes and silicones, di-Me No data available Triethanolamine No data available Conditioners No data available
Germ Cell Mutagenicity
Name Route Value
Propylene Glycol In Vitro Not mutagenic Propylene Glycol In vivo Not mutagenic Siloxanes and silicones, di-Me No data available Triethanolamine In Vitro Not mutagenic Triethanolamine In vivo Not mutagenic Conditioners No data available
Carcinogenicity
Name Route Species Value
Propylene Glycol Dermal Mouse Not carcinogenic Propylene Glycol Ingestion Multiple animal
species
Not carcinogenic
Siloxanes and silicones, di-Me No data available Triethanolamine Dermal Multiple animal
species
Not carcinogenic
Triethanolamine Ingestion Mouse Some positive data exist, but the data
are not sufficient for classification
Conditioners No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Propylene Glycol Ingestion Not toxic to female
reproduction
Mouse NOAEL
10,100 mg/kg/day
2 generation
Propylene Glycol Ingestion Not toxic to male
reproduction
Mouse NOAEL
10,100 mg/kg/day
2 generation
Propylene Glycol Ingestion Not toxic to
development
Multiple animal species
NOAEL 1,230 mg/kg/day
during organogenesis
Siloxanes and silicones, di-Me
No data available
Triethanolamine Ingestion Not toxic to
development
Mouse NOAEL
1,125 mg/kg/day
during organogenesis
Conditioners No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Propylene Ingestion central nervous May cause NOAEL N/A
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Glycol system
depression
drowsiness or
dizziness Siloxanes and silicones, di­Me
No data available
Triethanolami ne
No data available
Conditioners No data available
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Propylene Glycol
Ingestion hematopoietic
system
Some positive data exist, but the data are not sufficient for classification
Multiple animal species
NOAEL 1,370 mg/kg/day
117 days
Propylene Glycol
Ingestion kidney and/or
bladder
All data are negative
Dog NOAEL 5,000
mg/kg/day
104 weeks
TriethanolamineDermal kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Multiple animal species
NOAEL 2,000 mg/kg/day
2 years
TriethanolamineDermal liver Some positive
data exist, but the data are not sufficient for classification
Mouse NOAEL 4,000
mg/kg/day
13 weeks
TriethanolamineIngestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL 1,000
mg/kg/day
2 years
TriethanolamineIngestion liver Some positive
data exist, but the data are not sufficient for classification
Guinea pig NOAEL 1,600
mg/kg/day
24 weeks
Conditioners No data available
Aspiration Hazard
Name Value
Propylene Glycol Not an aspiration hazard Siloxanes and silicones, di-Me Not an aspiration hazard Triethanolamine Not an aspiration hazard Conditioners Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
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12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR: Not restricted for transport. IMDG: Not restricted for transport. IATA: Not restricted for transport.
SECTION 15: Regulatory information
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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Triethanolamine 102-71-6 Gr. 3: Not classifiable International Agency
for Research on Cancer
Global inventory status
Contact manufacturer for more information
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Aqua Propylene glycol Dimethicone Triethanolamine Perfumes Amyl cinnamal Aloe Barbadensis leaf juice Colorant Magnesium nitrate Diethanolamine Methylchloroisothiazolinone Ethanolamine Magnesium chloride Copper-based stabilizers Methylisothiazolinone
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
Revision information:
Revision Changes: Section 13: Standard Phrase Category Waste GHS was modified.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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