MEGUIAR'S G136 User Manual

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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
27-9906-2
Version number:
3.02
Revision date:
25/04/2012
Supersedes date:
22/06/2011
Transportation version number:
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G136, Quik Interior Detailer (23-39A): G13600, G13616
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
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No ingredients are assigned to the label.
Risk phrases None. Safety phrases None.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents. Ingredients required per 648/2004: Contains: Perfumes, benzisothiazolinone, hexyl cinnam-aldehyde, methylchloroisothiazolinone, methylisothiazolinone.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non Hazardous ingredient Mixture 80 - 95 Propan-2-ol 67-63-0 EINECS 200-
661-7
1 - 5 F:R11; Xi:R36; R67 (EU)
Flam. Liq. 2, H225; Eye Irrit. 2,
H319; STOT SE 3, H336 (CLP) Conditioners Trade Secret < 5 Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate (REACH Reg. No.:01-0000015637-64)
88917-22-0 1 - 2
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
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SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Seal the container.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
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Ingredient CAS Nbr Agency Limit type Additional comments
Propan-2-ol 67-63-0 Health and
Safety Comm. (UK)
TWA:999 mg/m³(400 ppm);STEL:1250 mg/m³(500
ppm) Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
88917-22-0 Manufacturer
determined
TWA:100 ppm;STEL:150 ppm Skin Notation
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Skin protection is not required.
Respiratory protection
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapour cartridges and P2 particulate prefilters.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Slight flowery fragrance; Clear, water-like liquid.
pH
7 - 8
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
No flash point
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
0.94 - 1.04 [Ref Std:WATER=1]
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Water solubility
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
No data available.
Density
0.94 - 1.04 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
3.00 % weight
VOC less H2O & exempt solvents
751.67 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat. Light.
10.5 Incompatible materials
Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
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Skin contact
Contact with the skin during product use is not expected to result in significant irritation.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause target organ effects after ingestion.
Toxicological Data
Acute Toxicity
Name Route Species Value UN GHS Classification
Overall product Ingestion No test data available;
calculated ATE >5,000 mg/kg
Not classified (0% unknown)
Propan-2-ol Dermal Rabbit LD50 13 mg/kg Not classified Propan-2-ol Inhalation-Vapor
(4 hours)
Rat LC50 73 mg/l Not classified
Propan-2-ol Ingestion Rat LD50 4,710 mg/kg Category5 Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
Dermal Rat LD50 > 2,000 mg/kg Not classified
Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
Inhalation-Vapor (4 hours)
Rat LC50 > 5.7 mg/l Category5
Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
Ingestion Rat LD50 > 5,000 mg/kg Not classified
Conditioners Dermal LD50 > 2,000 mg/kg Not classified Conditioners Ingestion LD50 > 17,000 mg/kg Not classified
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to cause no significant irritation
Not classified
Propan-2-ol No significant irritation Not classified Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
No significant irritation Not classified
Conditioners Minimal irritation Not classified
Serious Eye Damage/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to cause no significant irritation
Not classified
Propan-2-ol Moderate irritant Category 2B Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
No significant irritation Not classified
Conditioners Mild irritant Not classified
Skin Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Propan-2-ol Not sensitizing Not classified Propanol, 1(or 2)-(2- Not sensitizing Not classified
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methoxymethylethoxy)-, acetate Conditioners No data available
Respiratory Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Propan-2-ol No data available Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
No data available
Conditioners No data available
Germ Cell Mutagenicity
Name Route Value UN GHS Classification
Overall product No data available Overall Germ Cell Mutagenicity
classification Not classified Overall product No test data available. Propan-2-ol In vivo Not mutagenic Not classified Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
In Vitro Not mutagenic Not classified
Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
In vivo Not mutagenic Not classified
Conditioners No data available
Carcinogenicity
Name Route Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data
Propan-2-ol Not specified. Some positive data
exist, but the data are not sufficient for classification
Not classified
Propanol, 1(or 2)-(2­methoxymethylethoxy)-, acetate
No data available
Conditioners No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
UN GHS Classification
Overall product No test data
available.
Not classified based on component data
Propan-2-ol Ingestion Some positive
reproductive/develo pmental data exist, but the data are not sufficient for classification
NOEL 400 mg/kg/day
Propan-2-ol Inhalation Some positive
reproductive/develo pmental data exist, but the data are not sufficient for classification
LOEL 9,001 mg/m3
Propanol, 1(or 2)-(2­methoxymethylethox y)-, acetate
Ingestion Not toxic to
reproduction and/or development
NOAEL 1,000 mg/kg/day
Conditioners No data available
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Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
UN GHS Classification
Propan-2-ol Inhalation central
nervous system depression
May cause drowsiness or dizziness
NOAEL N/A
Category 3
Propan-2-ol Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
RD50 5,000 ppm
Not classified
Propan-2-ol Ingestion central
nervous system depression
May cause drowsiness or dizziness
NOAEL N/A
Category 3
Propanol, 1(or
2)-(2­methoxymeth ylethoxy)-, acetate
No data available
Conditioners No data
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
UN GHS Classification
Overall product
No test data available.
Not classified based on component data
Propan-2-ol Inhalation auditory
system
Some positive data exist, but the data are not sufficient for classification
LOEL 969 mg/m3
Not classified
Propan-2-ol Inhalation kidney
and/or bladder
Some positive data exist, but the data are not sufficient for classification
NOEL 1.2 mg/l
Not classified
Propan-2-ol Inhalation nervous
system
All data are negative
NOEL 12 mg/l
Not classified
Propan-2-ol Ingestion kidney
and/or bladder
Some positive data exist, but the data are not sufficient for classification
NOEL N/A Not classified
Propanol, 1(or
2)-(2­methoxymeth ylethoxy)-, acetate
Ingestion liver Some positive data
exist, but the data are not sufficient for classification
NOEL 200 mg/kg/day
Not classified
Propanol, 1(or
2)-(2­methoxymeth ylethoxy)-, acetate
Ingestion heart |
endocrine system | hematopoie tic system | kidney and/or bladder
All data are negative
NOAEL 1,000 mg/kg/day
Not classified
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Aspiration Hazard
Name Value UN GHS Classification
Overall product No test data available. Not classified based on
component and/or viscosity
data Propan-2-ol Not an aspiration hazard Not classified Propanol, 1(or 2)-(2-methoxymethylethoxy)-, acetate Not an aspiration hazard Not classified Conditioners Not an aspiration hazard Not classified
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
GHS Acute 3: Harmful to aquatic life.
Chronic aquatic hazard:
GHS Chronic 3: Harmful to aquatic life with long lasting effects.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. This surfactant complies with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
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Dispose of contents/ container in accordance with the local/regional/national/international regulations
Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as hazardous as per applicable regulations) shall be considered,stored,treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Dispose of waste product in a permitted industrial waste facility.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR: Not restricted for transport. IMDG: Not restricted for transport. IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Aqua Isopropyl alcohol PPG-2 methyl ether acetate Conditioner Dipropylene glycols (mixed isomers) Perfumes Benzisothiazolinone Benzophenone-1 Hexyl cinnam-aldehyde Alcohols, C11-14-iso-, C13-rich, ethoxylated Magnesium nitrate Sodium hydroxide Zinc oxide PEG Dispersant/Additives Methylchloroisothiazolinone Copper-based stabilizers Magnesium chloride Methylisothiazolinone
15.2. Chemical Safety Assessment
Not applicable
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SECTION 16: Other information
List of relevant H statements
H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness.
List of relevant R-phrases
R11 Highly flammable. R36 Irritating to eyes. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 9: pH information was modified. Section 9: Evaporation Rate information was modified. Section 9: Viscosity information was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 9: n-octanol/water coefficient information was modified. Section 9: Boiling point information was modified. Section 9: Relative density information was modified. Section 9: Solubility in water text was modified. Section 13: EU waste code (product as sold) information was modified. Copyright was modified. Section 9: Flash point information was modified. Section 9: Melting point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Vapour density value was modified. Section 9: Vapour pressure value was modified. Section 9: Density information was modified. Section 9: Property description for optional properties was modified. Section 8: Occupational exposure limit table was modified. Section 8: mg/m³ key was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 11: Health Effects - Skin information was modified. Section 5: Hazardous combustion products table was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 13: Standard Phrase Category Waste GHS was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 9: Autoignition temperature information was added.
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Label: CLP Precautionary - General was deleted. Label: CLP Precautionary - General - Header was deleted. Label: Precautionary Statement - Header was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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