MEGUIAR'S G128 User Manual

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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
27-4690-7
Version number:
2.01
Revision date:
28/03/2012
Supersedes date:
25/07/2011
Transportation version number: 1.00 (12/07/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G128, NXT Generation Spray Wax (21-95A): G12824
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
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No ingredients are assigned to the label.
Risk phrases None. Safety phrases
S23C Do not breathe vapour or spray. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota P applied to CASRN 64742-48-9.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-hazardous ingredients Mixture 70 - 90 Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
10 - 30 Xn:R65 - Nota 4,P (EU)
R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) STOT SE 3, H336; EUH066 (Self Classified)
Ceramic materials and wares, chemicals 66402-68-4 EINECS 266-
340-9
1 - 5
Conditioners Trade Secret < 5
Siloxanes and silicones, di-Me 63148-62-9 1 - 5 Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
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4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area or areas with little or no air movement. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Vapours may travel long distances along the ground or floor to an ignition source and flash back.
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7.2. Conditions for safe storage including any incompatibilities
Store away from heat. Protect from sunlight. Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Naphtha (petroleum),
hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
As a good industrial hygiene practice:
Wear eye/face protection.
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Respiratory protection
In case of inadequate ventilation wear respiratory protection. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with formaldehyde cartridges and P2 particulate prefilters.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
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Appearance/Odour
Sweet odour; Off-white liquid
pH
7.5 - 8.5
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
93.3 ºC [Test Method:Pensky-Martens Closed Cup] [Details:ASTM D93-90]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
0.96 - 0.98 [Ref Std:WATER=1]
Water solubility
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
< 1
Vapour density
No data available.
Viscosity
0.25 Pa-s
Density
0.96 - 0.98 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
14.95 % weight
VOC less H2O & exempt solvents
587.10 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
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The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
Acute Toxicity
Name Route Species Value UN GHS Classification
Overall product Ingestion No test data available;
calculated ATE >5,000 mg/kg
Not classified (0% unknown)
Naphtha (petroleum), hydrotreated heavy
Dermal Rabbit LD50 > 3,000 mg/kg Category5
Naphtha (petroleum), hydrotreated heavy
Inhalation-Vapor (4 hours)
Rat LC50 estimated to be 20
- 50 mg/l
Category5
Naphtha (petroleum), hydrotreated heavy
Ingestion Rat LD50 > 5,000 mg/kg Not classified
Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg Not classified Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg Not classified Ceramic materials and wares, chemicals
Dermal LD50 estimated to be >
5,000 mg/kg
Not classified
Ceramic materials and wares, chemicals
Ingestion LD50 estimated to be
2,000 - 5,000 mg/kg
Category5
Conditioners Ingestion LD50 estimated to be >
5,000
Not classified
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to be mild irritant
Category 3
Naphtha (petroleum), hydrotreated heavy Mild irritant Category 3 Siloxanes and silicones, di-Me Minimal irritation Not classified Ceramic materials and wares, chemicals No data available Conditioners Human Minimal irritation Not classified
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Serious Eye Damage/Irritation
Name Species Value UN GHS Classification
Overall product No test data available;
calculated to cause no significant irritation
Not classified
Naphtha (petroleum), hydrotreated heavy Mild irritant Not classified Siloxanes and silicones, di-Me Rabbit No significant irritation Not classified Ceramic materials and wares, chemicals No data available Conditioners Rabbit Mild irritant Not classified
Skin Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Naphtha (petroleum), hydrotreated heavy Not sensitizing Not classified Siloxanes and silicones, di-Me No data available Ceramic materials and wares, chemicals No data available Conditioners Human Some positive data exist, but
the data are not sufficient for classification
Not classified
Respiratory Sensitisation
Name Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Naphtha (petroleum), hydrotreated heavy No data available Siloxanes and silicones, di-Me No data available Ceramic materials and wares, chemicals No data available Conditioners No data available
Germ Cell Mutagenicity
Name Route Value UN GHS Classification
Overall product No data available Overall Germ Cell Mutagenicity
classification Not classified Overall product No test data available. Naphtha (petroleum), hydrotreated heavy Inhalation Not mutagenic Not classified Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but
the data are not sufficient for classification
Not classified
Siloxanes and silicones, di-Me No data available Ceramic materials and wares, chemicals In Vitro Some positive data exist, but
the data are not sufficient for classification
Not classified
Conditioners In Vitro Not mutagenic Not classified Conditioners In vivo Not mutagenic Not classified
Carcinogenicity
Name Route Species Value UN GHS Classification
Overall product No test data available. Not classified based on
component data Naphtha (petroleum), hydrotreated heavy
Dermal Some positive data
exist, but the data are not sufficient for classification
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation Some positive data
exist, but the data are not sufficient for classification
Not classified
Siloxanes and silicones, di-Me No data available
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Ceramic materials and wares, chemicals
Inhalation Carcinogenic. Category 2
Conditioners No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
UN GHS Classification
Overall product No test data
available.
Not classified based on
component data Naphtha (petroleum), hydrotreated heavy
Inhalation Not toxic to
reproduction and/or development
NOAEL
2.356 mg/l
Siloxanes and silicones, di-Me
No data available
Ceramic materials and wares, chemicals
No data available
Conditioners Ingestion Not toxic to female
reproduction
Rat NOAEL
4,800 mg/kg/day
13 weeks
Conditioners Ingestion Not toxic to male
reproduction
Rat NOAEL
4,800 mg/kg/day
13 weeks
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
UN GHS Classification
Naphtha (petroleum), hydrotreated heavy
Inhalation central
nervous system depression
May cause drowsiness or dizziness
NOAEL N/A
Category 3
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous
system
Some positive data exist, but the data are not sufficient for classification
NOEL 6.5 mg/l
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 2.4 mg/l
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL
2.5 mg/l
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation liver All data are
negative
NOAEL
0.610 mg/l
Not classified
Naphtha (petroleum),
Inhalation muscles All data are
negative
NOAEL
0.61 mg/l
Not classified
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hydrotreated heavy Naphtha (petroleum), hydrotreated heavy
Inhalation kidney
and/or bladder
All data are negative
NOAEL
0.610 mg/l
Not classified
Siloxanes and silicones, di­Me
No data available
Ceramic materials and wares, chemicals
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Not classified
Conditioners No data
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
UN GHS Classification
Overall product
No test data available.
Not classified based on
component data Naphtha (petroleum), hydrotreated heavy
Dermal nervous
system
Some positive data exist, but the data are not sufficient for classification
LOEL 691 mg/kg
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation endocrine
system | muscles
Some positive data exist, but the data are not sufficient for classification
LOEL
0.616 mg/l
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous
system
Some positive data exist, but the data are not sufficient for classification
LOEL
4.580 mg/l
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation kidney
and/or bladder
Some positive data exist, but the data are not sufficient for classification
LOEL 0.57 mg/l
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL
0.619 mg/l
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL
1.271 mg/l
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation bone, teeth,
nails, and/or hair | blood | liver
All data are negative
NOAEL
5.62 mg/l
Not classified
Naphtha (petroleum), hydrotreated heavy
Inhalation immune
system
All data are negative
NOAEL
0.616 mg/l
Not classified
Ceramic materials and wares, chemicals
Inhalation pulmonary
fibrosis
May cause damage to organs though prolonged or repeated exposure
NOAEL N/A
Category 2
Ceramic Inhalation respiratory Some positive data NOEL N/A Not classified
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materials and wares, chemicals
system exist, but the data
are not sufficient for classification
Conditioners Ingestion heart |
hematopoie tic system | liver
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL
4,800 mg/kg/day
13 weeks Not classified
Conditioners Ingestion kidney
and/or bladder
Some positive data exist, but the data are not sufficient for classification
Mouse NOAEL
13,000 mg/kg/day
13 weeks Not classified
Aspiration Hazard
Name Value UN GHS Classification
Overall product No test data available. Not classified based on
component and/or viscosity
data Naphtha (petroleum), hydrotreated heavy Aspiration hazard Category 1 Siloxanes and silicones, di-Me Not an aspiration hazard Not classified Ceramic materials and wares, chemicals Not an aspiration hazard Not classified Conditioners Not an aspiration hazard Not classified
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
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12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in a permitted industrial waste facility. Empty and clean product containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to determine available options and requirements.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 13* Solvents
SECTION 14: Transportation information
ADR: Not restricted for transport. IMDG: Not restricted for transport. IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H304 May be fatal if swallowed and enters airways. H336 May cause drowsiness or dizziness.
List of relevant R-phrases
R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Safety phrase was modified.
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Section 9: pH information was modified. Section 9: Evaporation Rate information was modified. Section 9: Viscosity information was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 9: n-octanol/water coefficient information was modified. Section 9: Boiling point information was modified. Section 9: Relative density information was modified. Section 9: Solubility in water text was modified. Section 13: EU waste code (product as sold) information was modified. Section 2: Label remarks was modified. Copyright was modified. Section 9: Flash point information was modified. Section 9: Melting point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Vapour density value was modified. Section 9: Vapour pressure value was modified. Section 9: Density information was modified. Section 9: Property description for optional properties was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 11: Health Effects - Skin information was modified. Section 5: Hazardous combustion products table was modified. Section 6: Accidental release personal information was modified. Section 6: Accidental release clean-up information was modified. Section 7: Precautions safe handling information was modified. Section 7: Conditions safe storage was modified. Section 8: Personal Protection - Eye information was modified. Section 8: Personal Protection - Skin/hand information was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 13: Standard Phrase Category Waste GHS was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 12: Acute aquatic hazard information was added. Section 12: Chronic aquatic hazard heading was added. Section 12: Acute aquatic hazard heading was added. Section 12: Chronic aquatic hazard information was added. Section 8: OEL table agency column heading was added. Section 8: OEL table limit type column heading was added. OEL Ceiling Heading was added. Section 8: Occupational exposure limit table was added. Section 8: OEL table Ingredient column heading was added. Section 8: OEL table Additional Comments column heading was added. OEL Reg Agency Desc was added. Section 8: TWA key was added. Section 8: STEL key was added.
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Section 8: mg/m³ key was added. Section 8: ppm key was added. Section 8: OEL table CAS No Column heading was added. Section 8: Personal Protection - Respiratory Information was added. Section 9: Autoignition temperature information was added. Section 8: Occupational exposure limit table was deleted. Section 11: Carcinogenicity heading was deleted. Section 11: Target Organ Effects heading was deleted. Section 11: Health Effects - Other information was deleted. Section 11: Cancer Hazards information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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