MEGUIAR'S G12711 User Manual

G12711, NXT Paste Wax 2.0 (21-135A): G12711
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Safety Data Sheet
Copyright, 2013, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
27-6203-7
Version number:
3.00
Revision date:
16/12/2013
Supersedes date:
11/04/2013
Transportation version number: 1.00 (27/07/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G12711, NXT Paste Wax 2.0 (21-135A): G12711
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Flammable Solid, Category 1 - Flam. Sol. 1; H228 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H336
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Highly flammable; F; R11 Irritant; Xi; R38
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R67
For full text of R phrases, see Section 16.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
DANGER!
Symbols:
GHS02 (Flame) |GHS07 (Exclamation mark) |
Pictograms
Ingredient CAS Nbr % by Wt Naphtha (petroleum), hydrotreated heavy 64742-48-9 30 - 50
HAZARD STATEMENTS:
H228 Flammable solid. H315 Causes skin irritation. H336 May cause drowsiness or dizziness.
PRECAUTIONARY STATEMENTS General:
P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand.
Prevention:
P210A Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P271 Use only outdoors or in a well-ventilated area.
Response:
P332 + P313 If skin irritation occurs: Get medical advice/attention. P331 Do NOT induce vomiting. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P370 + P378G In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry
chemical or carbon dioxide to extinguish.
Disposal:
P501 Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
15% of the mixture consists of components of unknown acute oral toxicity.
Contains 92% of components with unknown hazards to the aquatic environment.
Notes on labelling
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H304 is not required on the label due to the product's viscosity Nota P applied to CASRN 64742-48-9.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
Highly Flammable
Irritant
Contains:
No ingredients are assigned to the label.
Risk phrases
R11 Highly flammable. R38 Irritating to skin. R67 Vapours may cause drowsiness and dizziness.
Safety phrases
S16 Keep away from sources of ignition - No Smoking. S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
S2 Keep out of the reach of children.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota P applied to CASRN 64742-48-9 and 8052-41-3. Nota N applied to CASRN 64742-46-7.
R11 assigned based on test data indicating that this product is a flammable solid.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
30 - 50 Xn:R65 - Nota 4,P (EU)
Xi:R38; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) Skin Irrit. 2, H315; STOT SE 3,
H336 (Self Classified) Siloxanes and silicones, di-Me 63148-62-9 10 - 30 Organic salt Trade Secret 10 - 30 Ceramic materials and wares, chemicals 66402-68-4 EINECS 266-
340-9
7 - 13
Distillates (petroleum), hydrotreated light 64742-47-8 EINECS 265- 3 - 7 Xn:R65 - Nota 4 (EU)
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149-8 R10; R66; R67 (Self Classified)
Asp. Tox. 1, H304 (CLP)
Flam. Liq. 3, H226; STOT SE 3,
H336; EUH066 (Self Classified) Conditioners Trade Secret < 5 Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3­tetramethyldisiloxane
212335-52-9 0.5 - 1.5
1-propoxypropan-2-ol 1569-01-3 EINECS 216-
372-4
0.1 - 1.0 Xi:R36; R10; R66; R67 (Self Classified)
Flam. Liq. 3, H226; Eye Irrit. 2, H319; STOT SE 3, H336; EUH066 (Self Classified)
Stoddard solvent 8052-41-3 EINECS 232-
489-3
<= 0.75 Xn:R48/20; Xn:R65 - Nota P
(EU) Xi:R38 (Self Classified)
Asp. Tox. 1, H304; STOT RE 1, H372 - Nota P (CLP) Skin Irrit. 2, H315 (Self Classified)
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
<= 0.5 Nota N (EU)
Xn:R20-65; R52/53; R66 (Self Classified)
Nota N (CLP) Acute Tox. 4, H332; Asp. Tox. 1, H304; STOT SE 3, H336; EUH066 (Self Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
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4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and Safety Data Sheet. Clean up residue. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Wear low
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static or properly grounded shoes. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Vapours may travel long distances along the ground or floor to an ignition source and flash back.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store away from heat. Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
Organic salt Trade
Secret
Health and Safety Comm. (UK)
TWA:2 mg/m3
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Wear eye/face protection. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Wear protective gloves. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
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type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Solid.
Specific Physical Form:
Paste
Appearance/Odour
Pleasant odour; Soft, waxy, cream-coloured paste
Odour threshold
No data available.
pH
Not applicable.
Boiling point/boiling range
185 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Flammable Solid: Category 1.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
65.6 ºC [Test Method:Pensky-Martens Closed Cup]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
0.86 [Ref Std:WATER=1]
Water solubility
Nil
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
>=0.1 Pa-s
Density
0.86 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
44.6 % weight
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat. Sparks and/or flames.
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10.5 Incompatible materials
Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
Skin contact
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause target organ effects after ingestion.
Target Organ Effects:
Single exposure may cause:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Naphtha (petroleum), hydrotreated heavy Inhalation-
Vapor
LC50 estimated to be 20 - 50 mg/l
Naphtha (petroleum), hydrotreated heavy Dermal Rabbit LD50 > 3,000 mg/kg
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Naphtha (petroleum), hydrotreated heavy Ingestion Rat LD50 > 5,000 mg/kg Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg Organic salt Data not available or insufficient for classification Ceramic materials and wares, chemicals Dermal LD50 estimated to be > 5,000 mg/kg Ceramic materials and wares, chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Distillates (petroleum), hydrotreated light Dermal Rabbit LD50 > 3,160 mg/kg Distillates (petroleum), hydrotreated light Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 3.0 mg/l
Distillates (petroleum), hydrotreated light Ingestion Rat LD50 > 5,000 mg/kg Conditioners Ingestion Rat LD50 > 15,000 mg/kg Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane
Data not available or insufficient for classification
1-propoxypropan-2-ol Dermal Rabbit LD50 2,805 mg/kg 1-propoxypropan-2-ol Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 11.8 mg/l
1-propoxypropan-2-ol Ingestion Rat LD50 2,500 mg/kg Stoddard solvent Inhalation-
Vapor
LC50 estimated to be 20 - 50 mg/l
Stoddard solvent Dermal Rabbit LD50 > 3,000 mg/kg Stoddard solvent Ingestion Rat LD50 > 5,000 mg/kg Distillates (petroleum), hydrotreated middle Dermal Rabbit LD50 > 2,000 mg/kg Distillates (petroleum), hydrotreated middle Inhalation-
Dust/Mist (4 hours)
Rat LC50 4.6 mg/l
Distillates (petroleum), hydrotreated middle Ingestion Rat LD50 > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Rabbit Irritant Siloxanes and silicones, di-Me Rabbit No significant irritation Organic salt Data not available or insufficient for classification Ceramic materials and wares, chemicals Rabbit No significant irritation Distillates (petroleum), hydrotreated light Rabbit Mild irritant Conditioners Data not available or insufficient for classification Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3­tetramethyldisiloxane
Data not available or insufficient for classification
1-propoxypropan-2-ol Rabbit Minimal irritation Stoddard solvent Rabbit Irritant Distillates (petroleum), hydrotreated middle Rabbit Minimal irritation
Serious Eye Damage/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Rabbit No significant irritation Siloxanes and silicones, di-Me Rabbit No significant irritation Organic salt Data not available or insufficient for classification Ceramic materials and wares, chemicals Rabbit Mild irritant Distillates (petroleum), hydrotreated light Rabbit Mild irritant Conditioners Data not available or insufficient for classification Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3­tetramethyldisiloxane
Data not available or insufficient for classification
1-propoxypropan-2-ol Rabbit Severe irritant Stoddard solvent Rabbit No significant irritation Distillates (petroleum), hydrotreated middle Not
available
Mild irritant
Skin Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Guinea
pig
Not sensitizing
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Siloxanes and silicones, di-Me Data not available or insufficient for classification Organic salt Data not available or insufficient for classification Ceramic materials and wares, chemicals Data not available or insufficient for classification Distillates (petroleum), hydrotreated light Guinea
pig
Not sensitizing
Conditioners Data not available or insufficient for classification Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3­tetramethyldisiloxane
Data not available or insufficient for classification
1-propoxypropan-2-ol Data not available or insufficient for classification Stoddard solvent Guinea
pig
Not sensitizing
Distillates (petroleum), hydrotreated middle Data not available or insufficient for classification
Respiratory Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Data not available or insufficient for classification Siloxanes and silicones, di-Me Data not available or insufficient for classification Organic salt Data not available or insufficient for classification Ceramic materials and wares, chemicals Data not available or insufficient for classification Distillates (petroleum), hydrotreated light Data not available or insufficient for classification Conditioners Data not available or insufficient for classification Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3­tetramethyldisiloxane
Data not available or insufficient for classification
1-propoxypropan-2-ol Data not available or insufficient for classification Stoddard solvent Data not available or insufficient for classification Distillates (petroleum), hydrotreated middle Data not available or insufficient for classification
Germ Cell Mutagenicity
Name Route Value
Naphtha (petroleum), hydrotreated heavy In vivo Not mutagenic Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but the data are not
sufficient for classification Siloxanes and silicones, di-Me Data not available or insufficient for classification Organic salt Data not available or insufficient for classification Ceramic materials and wares, chemicals In Vitro Some positive data exist, but the data are not
sufficient for classification Distillates (petroleum), hydrotreated light In Vitro Not mutagenic Conditioners Data not available or insufficient for classification Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3­tetramethyldisiloxane
Data not available or insufficient for classification
1-propoxypropan-2-ol In Vitro Not mutagenic Stoddard solvent In vivo Not mutagenic Stoddard solvent In Vitro Some positive data exist, but the data are not
sufficient for classification Distillates (petroleum), hydrotreated middle In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Naphtha (petroleum), hydrotreated heavy Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Naphtha (petroleum), hydrotreated heavy Inhalation Human
and animal
Some positive data exist, but the data are not sufficient for classification
Siloxanes and silicones, di-Me Data not available or insufficient for classification Organic salt Data not available or insufficient for classification Ceramic materials and wares, chemicals Inhalation Multiple
animal species
Some positive data exist, but the data are not sufficient for classification
Distillates (petroleum), hydrotreated light Dermal Mouse Some positive data exist, but the data are not
sufficient for classification Conditioners Data not available or insufficient for classification Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Data not available or insufficient for classification
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Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane 1-propoxypropan-2-ol Data not available or insufficient for classification Stoddard solvent Dermal Mouse Some positive data exist, but the data are not
sufficient for classification Stoddard solvent Inhalation Human
and animal
Some positive data exist, but the data are not
sufficient for classification
Distillates (petroleum), hydrotreated middle Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy Inhalation Not toxic to development Rat NOAEL 2.4
mg/l
during organogenesis
Siloxanes and silicones, di-Me Data not available or insufficient for
classification
Organic salt Data not available or insufficient for
classification
Ceramic materials and wares, chemicals Data not available or insufficient for
classification
Conditioners Data not available or insufficient for
classification Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3­tetramethyldisiloxane
Data not available or insufficient for
classification
1-propoxypropan-2-ol Inhalation Some positive developmental data exist,
but the data are not sufficient for
classification
Rat NOAEL 3.6
mg/l
during organogenesis
Stoddard solvent Inhalation Not toxic to development Rat NOAEL 2.4
mg/l
during organogenesis
Distillates (petroleum), hydrotreated middle Data not available or insufficient for
classification
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human and animal
NOAEL Not available
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
NOAEL Not available
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive data exist, but the
data are not sufficient for classification
Dog NOAEL 6.5
mg/l
4 hours
Siloxanes and silicones, di­Me
Data not available or insufficient for classification
Organic salt Data not available or insufficient
for classification Distillates (petroleum), hydrotreated light
Inhalation central nervous
system depression
May cause drowsiness or
dizziness
NOAEL Not
available Distillates (petroleum), hydrotreated light
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
NOAEL Not
available
Conditioners Data not available or insufficient
for classification Siloxanes and Silicones, C10-16-alkyl Me, 3-
Data not available or insufficient
for classification
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hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3­diethenyl-1,1,3,3­tetramethyldisiloxane 1-propoxypropan-2-ol Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Multiple animal species
LOAEL 10.8 mg/l
6 hours
1-propoxypropan-2-ol Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
NOAEL Not available
1-propoxypropan-2-ol Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Rat LOAEL
1,770 mg/kg
not applicable
Stoddard solvent Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human and animal
NOAEL Not available
Stoddard solvent Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
NOAEL Not available
Stoddard solvent Inhalation nervous system Some positive data exist, but the
data are not sufficient for
classification
Dog NOAEL 6.5
mg/l
4 hours
Distillates (petroleum), hydrotreated middle
Inhalation central nervous
system depression | respiratory irritation
Some positive data exist, but the
data are not sufficient for
classification
Not available
NOAEL NA
Distillates (petroleum), hydrotreated middle
Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Not available
NOAEL NA
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive data exist, but the
data are not sufficient for classification
Rat LOAEL 4.6
mg/l
6 months
Naphtha (petroleum), hydrotreated heavy
Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL 1.9
mg/l
13 weeks
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Multiple animal species
NOAEL 0.6 mg/l
90 days
Naphtha (petroleum), hydrotreated heavy
Inhalation bone, teeth, nails,
and/or hair | blood | liver | muscles
All data are negative Rat NOAEL 5.6
mg/l
12 weeks
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are negative Multiple
animal species
NOAEL 1.3 mg/l
90 days
Organic salt Data not available or insufficient
for classification Ceramic materials and wares, chemicals
Inhalation pulmonary fibrosis Some positive data exist, but the
data are not sufficient for
classification
Multiple animal species
NOAEL not available
Ceramic materials and wares, chemicals
Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL not
available
occupational exposure
Conditioners Data not available or insufficient
for classification Siloxanes and Silicones, C10-16-alkyl Me, 3­hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3­diethenyl-1,1,3,3­tetramethyldisiloxane
Data not available or insufficient
for classification
1-propoxypropan-2-ol Inhalation liver | kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 9.5
mg/l
11 days
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Stoddard solvent Inhalation nervous system Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 4.6
mg/l
6 months
Stoddard solvent Inhalation kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 1.9
mg/l
13 weeks
Stoddard solvent Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Multiple animal species
NOAEL 0.6 mg/l
90 days
Stoddard solvent Inhalation bone, teeth, nails,
and/or hair | blood | liver | muscles
All data are negative Rat NOAEL 5.6
mg/l
12 weeks
Stoddard solvent Inhalation heart All data are negative Multiple
animal species
NOAEL 1.3 mg/l
90 days
Distillates (petroleum), hydrotreated middle
Data not available or insufficient
for classification
Aspiration Hazard
Name Value
Naphtha (petroleum), hydrotreated heavy Aspiration hazard Siloxanes and silicones, di-Me Not an aspiration hazard Organic salt Not an aspiration hazard Ceramic materials and wares, chemicals Not an aspiration hazard Distillates (petroleum), hydrotreated light Aspiration hazard Conditioners Not an aspiration hazard Siloxanes and Silicones, C10-16-alkyl Me, 3-hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl-1,1,3,3­tetramethyldisiloxane
Not an aspiration hazard
1-propoxypropan-2-ol Not an aspiration hazard Stoddard solvent Aspiration hazard Distillates (petroleum), hydrotreated middle Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for
classification 1­propoxypropan
-2-ol
1569-01-3 Water flea Experimental 48 hours EC50 >100 mg/l
1­propoxypropan
-2-ol
1569-01-3 Green algae Experimental 96 hours EC50 1,466 mg/l
1- 1569-01-3 Rainbow trout Experimental 96 hours LC50 >100 mg/l
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propoxypropan
-2-ol Conditioners Trade Secret Golden Orfe Experimental 48 hours LC50 >500 mg/l Ceramic materials and wares, chemicals
66402-68-4 Data not
available or
insufficient for
classification Distillates (petroleum), hydrotreated light
64742-47-8 Data not
available or
insufficient for
classification Siloxanes and Silicones, C10­16-alkyl Me, 3­hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl­1,1,3,3­tetramethyldisi loxane
212335-52-9 Data not
available or
insufficient for
classification
Organic salt Trade Secret Data not
available or
insufficient for
classification
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
1­propoxypropan
-2-ol
1569-01-3 Experimental
Biodegradation
20 days BOD 64 % weight Other methods
Conditioners Trade Secret Data not
available or insufficient for classification
N/A N/A N/A N/A
Ceramic materials and wares, chemicals
66402-68-4 Data not
available or insufficient for classification
N/A N/A N/A N/A
Distillates (petroleum), hydrotreated light
64742-47-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Siloxanes and Silicones, C10­16-alkyl Me, 3-
212335-52-9 Data not
available or insufficient for
N/A N/A N/A N/A
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hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl­1,1,3,3­tetramethyldisi loxane
classification
Organic salt Trade Secret Data not
available or insufficient for classification
N/A N/A N/A N/A
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
1­propoxypropan
-2-ol
1569-01-3 Estimated
Bioconcentrati on
Bioaccumulati on factor
3 Estimated:
Bioconcentration factor
Conditioners Trade Secret Data not
available or insufficient for classification
N/A N/A N/A N/A
Ceramic materials and wares, chemicals
66402-68-4 Data not
available or insufficient for classification
N/A N/A N/A N/A
Distillates (petroleum), hydrotreated light
64742-47-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
Siloxanes and Silicones, C10­16-alkyl Me, 3­hydroxypropyl Me, Me hydrogen, ethoxylated propoxylated, reaction products with 1,3-diethenyl­1,1,3,3­tetramethyldisi
212335-52-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
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loxane Organic salt Trade Secret Data not
available or insufficient for classification
N/A N/A N/A N/A
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
As a disposal alternative, Incinerate in a permitted waste incineration facility. Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 13* Solvents
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components
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of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H226 Flammable liquid and vapour. H228 Flammable solid. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H372 Causes damage to organs through prolonged or repeated exposure.
List of relevant R-phrases
R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Risk phrase information was modified. Safety phrase information was modified. Section 3 and Section 9: General physical form information information was modified. Section 9: Viscosity information information was modified. Section 16: List of relevant R phrase information information was modified. Section 3: Composition/ Information of ingredients table information was modified. Section 2: Indication of danger information information was modified. Section 9: Flammability (solid, gas) information information was modified. Section 14: Transportation classification information was modified. Section 2: Label remarks information was modified. Section 16: Regulations - Inventories - EU ONLY information was modified. Section 9: Flash point information information was modified. Section 8: Occupational exposure limit table information was modified. Aspiration Hazard Table information was modified. Section 11: Acute Toxicity table information was modified. Carcinogenicity Table information was modified. Serious Eye Damage/Irritation Table information was modified. Germ Cell Mutagenicity Table information was modified. Skin Sensitisation Table information was modified. Respiratory Sensitisation Table information was modified. Reproductive Toxicity Table information was modified. Skin Corrosion/Irritation Table information was modified.
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Target Organs - Repeated Table information was modified. Target Organs - Single Table information was modified. Section 11: Health Effects - Skin information information was modified. Section 5: Fire - Extinguishing media information information was modified. Section 5: Fire - Special hazards information information was modified. Section 5: Fire - Advice for fire fighters information information was modified. Section 6: Accidental release personal information information was modified. Section 6: Accidental release environmental information information was modified. Section 6: Accidental release clean-up information information was modified. Section 7: Precautions safe handling information information was modified. Section 7: Conditions safe storage information was modified. Section 8: Appropriate Engineering controls information information was modified. Section 8: Personal Protection - Eye information information was modified. Section 8: Personal Protection - Skin/hand information information was modified. Section 13: 13.1. Waste disposal note information was modified. Section 13: Standard Phrase Category Waste GHS information was modified. Section 4: First aid for skin contact information information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. information was modified. Label: Graphic information was modified. Label: Graphic Text information was modified. Section 9: Flammability (solid, gas) information information was modified. Section 12: Component ecotoxicity information information was added. Section 12: Persistence and Degradability information information was added. Section 12:Bioccumulative potential information information was added. Section 12: Component Ecotoxicity table Material column header information was added. Section 12: Component Ecotoxicity table CAS No column header information was added. Section 12: Component Ecotoxicity table Organism column header information was added. Section 12: Component Ecotoxicity table Type column header information was added. Section 12: Component Ecotoxicity table Exposure column header information was added. Section 12: Component Ecotoxicity table End point column header information was added. Section 12: Component Ecotoxicity table Result column header information was added. Section 12: Persistence and degradability table Material column header information was added. Section 12: Persistence and degradability table CAS No column header information was added. Section 12: Persistence and degradability table Test Type column header information was added. Section 12: Persistence and degradability table Duration column header information was added. Section 12: Persistence and degradability table Test Result column header information was added. Section 12: Persistence and degradability table Protocol column header information was added. Section 12:Bioccumulative potential table Material column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table Test Result column header information was added. Section 12:Bioccumulative potential table Protocol column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Label: Signal Word - Header information was added. Label: Signal Word information was added. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Label: CLP Classification information was added. Label: CLP Classification - Header information was added. Label: CLP Percent Unknown information was added. Label: CLP Percent Unknown information was added. Label: Graphic information was added. Label: Graphic information was added. Label: Symbol information was added. Label: Symbol information was added.
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Label: CLP Precautionary - Disposal information was added. Label: CLP Precautionary - Disposal - Header information was added. Label: CLP Precautionary - General information was added. Label: CLP Precautionary - General - Header information was added. Label: CLP Precautionary - Prevention information was added. Label: CLP Precautionary - Prevention - Header information was added. Label: CLP Precautionary - Response information was added. Label: CLP Precautionary - Response - Header information was added. Label: Precautionary Statement - Header information was added. CLP: Ingredient table information was added. Section 2: Notes on labelling heading information was added. Section 15: Label remarks and EU Detergent information was added. CLP Remark(phrase) information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Section 8: Personal Protection - Respiratory Information information was added. Label: CLP Ingredients table Ingredient heading information was added. Label: CLP Ingredients table CAS No heading information was added. Label: CLP Ingredients table Percent by Wt heading information was added. Section 12: Persistence and degradability table Study Type column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Label: Graphic Text information was added. Section 2: H phrase reference information was added. Section 10: Hazardous decomposition products during combustion text information was added. Section 11: Disclosed components not in tables text information was added. Section 8: Eye/face protection text information was deleted. Section 8: Respiratory protection - recommended respirators information was deleted. Section 12: Acute aquatic hazard information information was deleted. Section 12: Chronic aquatic hazard heading information was deleted. Section 12: Acute aquatic hazard heading information was deleted. Section 12: Chronic aquatic hazard information information was deleted. Prints No Data if Component ecotoxicity information is not present information was deleted. Prints No Data if Persistence and Degradability information is not present information was deleted. Prints No Data if Bioccumulative potential information is not present information was deleted. Section 8: mg/m³ key information was deleted. Section 8: ppm key information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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